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Role of gallium wetting layer in high-quality ZnO growth on sapphire (0001) substrates

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Science china(Physics,Mechanics & Astronomy) 2004年第5期47卷 612-620页

作者： ZENG Zhaoquan1,3. WANG Yong2, DU Xiaolong1, MEI Zengxia1, KONG Xianghe3. JIA Jinfeng1, XUE Qikun1 & ZHANG Ze2, 4.1. State Key Laboratory for Surface Physics, institute of Physics, Chinese academy of Sciences,{4.,{3. 2. Laboratory of Electron Microscopy, institute of Physics, Chinese academy of Sciences,{4.,{3. 3. College of Physics and Engineering, Qufu Normal University, Qufu 273.65,{3. 4. beijing University of Technology, beijing 100022,{3. 1. State Key Laboratory for Surface Physics Institute of Physics Chinese Academy of Sciences 100080 Beijing China 2. College of Physics and Engineering Qufu Normal University 273165 Qufu China 3. Laboratory of Electron Microscopy Institute of Physics Chinese Academy of Sciences 100080 Beijing China 4. beijing University of Technology 100022 Beijing China

A Ga wetting layer was used to modify the surface structure of sapphire (0001) substrate to prepare high-quality ZnO film by radio frequency plasma-assisted molecule beam epitaxy. We found that this Ga layer plays a crucial role in eliminating 3. rotation domains, controlling polarity and decreasing defect density in ZnO epilayers, as demonstrated by in situ reflection high energy electron diffraction, ex situ high resolution X-ray diffraction and high resolution cross-sectional transmission electron microscopy. Zn-polar film of ZnO was determined by convergent beam electron diffraction. A Ga bilayer model is proposed to understand the effects of the Ga wetting layer on high-quality ZnO growth.

关键词： Ga wetting layer, sapphire, polarity, defect density, zinc oxide, rf-MBE, RHEED, HRXRD, TEM, CBED.

Formal analysis and design of multi-party fair exchange protocols

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Science in china(Series F) 2006年第2期49卷 155-174页

作者： QING Sihan1,2,3.& LI Gaicheng1,3.1. Engineering Research Center for Information Security Technology, institute of software, Chinese {4. of Sciences,{3., china 2. beijing Zhongke Ansheng Corporation of Information Technology,{3., china 3. Graduate School of the Chinese {4. of Sciences, beijing 10003., china 1. Engineering Research Center for Information Security Technology Institute of Software Chinese Academy of Sciences Beijing 100080 China 2. beijing Zhongke Ansheng Corporation of Information Technology Beijing 100080 China 3. Graduate School of the Chinese academy of Sciences Beijing 100039 China

Based on the origin of message items and channel combination between transacting parties, and events and relations among events, this paper presents a concise, precise, and hierarchical model for general fair exchange protocols, formally specifies various security requirements which are able to reflect inherent requirements for fair exchange protocols more rigorously, and partition these security requirements with fine granularity. This work helps analyze, debug, and design multi-party fair exchange protocols more effectively and elaborately,

关键词： fair exchange logical protocol formal model security requirement.

Fluorescence dynamics of interactions between polyamide PyPyPyβDp and DNA

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Science china Chemistry 2006年第1期49卷 75-80页

作者： ZHANG Huijuan1,2, WANG Jin3. WU Yishi1, YUAN Gu3. AI Xicheng1, WANG Li4.& ZHANG Jianping1 1. State Key Laboratory for Structural Chemistry of Unstable and Stable Species, institute of Chemistry, Chinese academy of Sciences,{4.,{3. 2. School of Life Science and Technology, beijing institute of Technology, beijing 100081,{3. 3. College of Chemistry and Molecular Engineering, Peking University,{4.,{3. 4. Center for Condensed Matter Physics, institute of Physics, Chinese academy of Sciences,{4.,{3. Correspondence should be addressed to Ai Xicheng and Zhang Jianping 1. State Key Laboratory for Structural Chemistry of Unstable and Stable Species Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China 2. School of Life Science and Technology Beijing Institute of Technology Beijing 100081 China 3. College of Chemistry and Molecular Engineering Peking University Beijing 100080 China 4. Center for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences Beijing 100080 China

The photophysical properties of the polyamide PyPyPyβDp (PPP) were investigated by means of steady-state absorption and fluorescence spectroscopies, as well as time-resolved fluo-rescence spectroscopy. It was found that the excited-state properties of PPP are very sensitive to solvents. In TKMC buffer PPP exhibited weak fluorescence with a decay time constant of 16 ps, while with the decrease of the solvent polarity PPP showed the blue-shifted peak position, increased inten-sity and lengthened life-time for its fluorescence behavior. In the presence of calf thymus DNA, it was observed that the fluorescence intensity was enhanced and the fluorescence lifetime increased from 16 to 3. ps for PPP, which verified that PPP bound into the minor groove of DNA duplex.

关键词： polyamide (PPP), calf thymus DNA (ctDNA), time-resolved fluorescence spectroscopy, recognition dynamics.

SHRIMP zircon U-Pb geochronology of early Mesozoic felsic igneous rocks from the southern Lancangjiang and its tectonic implications

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Science china Earth Sciences 2006年第10期49卷 1032-1042页

作者： PENG Touping1,2, WANG Yuejun1, FAN Weiming1, LIU Dunyi3. SHI Yuruo3.& MIAO Laicheng4.1. Key Laboratory of Isotope Geochronology and Geochemistry, Guangzhou institute of Geochemistry, Chinese academy of Sciences, Guangzhou 51064.,{4. 2. Graduate University of Chinese academy of Sciences, beijing 10003.,{4. 3. SHRIMP isotope Laboratory, Chinese academy of Geological Sciences, beijing 10003.,{4. 4. institute of Geology and Geophysics, Chinese academy of Sciences, beijing 100029,{4. Key Laboratory of Isotope Geochronology and Geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China Graduate University of Chinese academy of Sciences Beijing China SHRIMP isotope Laboratory Chinese Academy of Geological Sciences Beijing China institute of Geology and Geophysics Chinese Academy of Sciences Beijing China

The SHRIMP zircon U-Pb geochronology of three typical samples, including two monzo nitic granites from the Lincang batholith and a rhyolite from the Manghuai Formation are presented in the southern Lancangjiang, western Yunnan Province. The analyses of zircons for the biotite monzonitic granites from the northern (02DX-13.) and southern (20JH-10) Lincang batholith show the single and tight clusters on the concordia, and yield the weighted mean 206Pb/23.U ages of 229.4.± 3.0 Ma and 23..4.± 3.6 Ma, respectively, representing the crystallized ages of these granites. The zircons for the rhyolitic sample (02DX-95) from the Manghuai Formation give a weighted mean 206Pb/23.U age of 23..0 ± 5.0 Ma. These data suggest that the igneous rocks from the Lincang granitic batholith and Manghuai Formation have a similar crystallized age. In combination with other data, it is inferred that both were generated at a narrow age span (~23. Ma) and were originated from the postcollisional tectonic regime. An early Proterozoic 206Pb/23.U apparent age of 1977±4. Ma is additionally obtained from one zircon from the biotite monzonitic granite (southern Lincang batholith), indicative of devel- opment of the early Proterozoic Yangtze basement in the region. These precisely geochronological data provide important constraints on better understanding the Paleozoic tectonic evolution of the Tethys, western Yunnan Province.

关键词： SHRIMP zircon U-Pb dating, Middle Triassic, Lincang granitic batholith, Manghuai Formation rhyolite, southern Lancangjiang.

Analysis and application of automatic deformation monitoring data for buildings and structures of mining area

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中国有色金属学会会刊：英文版 2011年第S3期21卷 516-522页

作者： XIAO Jie1, 2, 3. ZHANG Jin4.1. institute of Geodesy and Geophysics, Chinese academy of Sciences, Wuhan 4.0}077,{4. 2. Key Laboratory of Dynamic Geodesy, institute of Geodesy and Geophysics, Chinese academy of Sciences, Wuhan 4.0}077,{4. 3. Graduate School of Chinese academy of Sciences, beijing 10004.,{4. 4. Department of Surveying and Mapping, Taiyuan University of Technology, Taiyuan 03.024.{4. Taiyuan Univ Technol Dept Surveying & Mapping Taiyuan 030024 Peoples R China Chinese Acad Sci Inst Geodesy & Geophys Key Lab Dynam Geodesy Wuhan 430077 Peoples R China Chinese Acad Sci Grad Sch Beijing 100049 Peoples R China

The buildings and structures of mines were monitored automatically using modern surveying technology. Through the analysis of the monitoring data, the deformation characteristics were found out from three aspects containing points, lines and regions, which play an important role in understanding the stable state of buildings and structures. The stability and deformation of monitoring points were analysed, and time-series data of monitoring points were denoised with wavelet analysis and Kalman filtering, and exponent function and periodic function were used to get the ideal deformation trend model of monitoring points. Through calculating the monitoring data obtained, analyzing the deformation trend, and cognizing the deformation regularity, it can better service mine safety production and decision-making.

关键词： wavelet analysis Kalman filtering deformation monitoring data analysis mine

A mixed method for measuring low-frequency acoustic properties of macromolecular materials

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Science china(Physics,Mechanics & Astronomy) 2006年第6期49卷 729-739页

作者： LIU Hongwei1,YAO Lei1,3.ZHAO Hong1,3.ZHANG Jichuan2,3.& XUE Zhaohong2 1. National Key Laboratory of Acoustics,institute of Acoustics,Chinese {4. of Sciences,beijing {3.,china 2. institute of Chemistry,Chinese {4. of Sciences,beijing {3.,china 3. Graduate University of Chinese {4. of Sciences,beijing 10004.,china National Key Laboratory of Acoustics Institute of Acoustics Chinese Academy of Sciences Beijing 100080 China institute of Chemistry Chinese Academy of Sciences Beijing 100080 China Graduate University of Chinese academy of Sciences Beijing 100049 China

A mixed method for measuring low-frequency acoustic properties of macro-molecular materials is presented. The dynamic mechanical parameters of materials are first measured by using Dynamic Mechanical Thermal Apparatus(DMTA) at low frequen-cies,usually less than 100 Hz; then based on the Principles of Time-Temperature Super-position (TTS),these parameters are extended to the frequency range that acousticians are concerned about,usually from hundreds to thousands of hertz; finally the extended dynamic mechanical parameters are transformed into acoustic parameters with the help of acoustic measurement and inverse analysis. To test the feasibility and accuracy,we measure a kind of rubber sample in DMTA and acquire the basic acoustic parameters of the sample by using this method. While applying the basic parameters to calculating characteristics of the sample in acoustic pipe,a reasonable agreement of sound absorp-tion coefficients is obtained between the calculations and measurements in the acoustic pipe.

关键词： low-frequency acoustic properties,dynamic mechanical properties,Principles of Time-Temperature Superposition,acoustic pipe,sound absorption coefficient.

A formal model of fair exchange protocols

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Science in china(Series F) 2005年第4期48卷 499-512页

作者： QING Sihan1,2,3.& LI Gaicheng1,2,3.1. Engineering Research Center for Information Security Technology, institute of software, Chinese Aca- demy of Sciences,{4.,{3. 2. beijing Zhongke Ansheng Corporation of Information Technology,{4.,{3. 3. Graduate School of the Chinese academy of Sciences, beijing 10003.,{3. 1. Engineering Research Center for Information Security Technology Institute of Software Chinese Academy of Sciences 100080 Beijing China 2. beijing Zhongke Ansheng Corporation of Information Technology 100080 Beijing China 3. Graduate School of the Chinese academy of Sciences 100039 Beijing China

Based on the study of existing fair exchange protocols, this paper sets up an accurate formal model by stepwise refinement. In the process of refinement an unreliable channel is employed to simulate an attack behavior. The model provides a novel formal definition of exchanged items, and presents the formal goals for fairness, accountability, etc., reflecting the inherent requirements for fair exchange protocols across-the-board. In order to check, prove, and design fair exchange protocols effectively and efficiently, the model puts forward a novel property of abuse-freeness which applies to all fair exchange protocols, gives a formal definition for trust strand of the third party, and presents general criteria of designing a secure and effective fair exchange protocol. Taking a typical fair exchange protocol as an example, this paper presents the analysis steps of fair exchange protocols appealing to our model. An unknown attack is uncovered. The analysis reveals the process of a complete attack, discovering deeper reasons for causing an attack. Finally, we modify the flawed protocol and the revised protocol ensures the desirable properties.

关键词： events local causal relation local temporal relation global relation exchanged item security goals.

The crustal structure under Sanjiang and its dynamic implications:Revealed by seismic reflection/refraction profile between Zhefang and Binchuan,Yunnan

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Science china Earth Sciences 2005年第9期48卷 1329-1336页

作者： ZHANG Zhongjie1, BAI Zhiming1, WANG Chunyong2, TENG Jiwen1, Lü Qingtian3. LI Jiliang1, LIU Yifeng1 & LIU Zhenkuan4.1. institute of Geology and Geophysics, Chinese academy of Sciences, beijing 100029,{3. 2. institute of Geophysics,{3. Seismological Bureau, beijing 100085,{3. 3. institute of Deposition Resource, Chinese academy of Geosciences, beijing 10003.,{3. 4. School of Exploration and Information,{3. University of Geosciences, beijing 100083.{3. 1. institute of Geology and Geophysics Chinese Academy of Sciences 100029 Beijing China 2. institute of Geophysics China Seismological Bureau 100085 Beijing China 3. institute of Deposition Resource Chinese Academy of Geosciences 100037 Beijing China 4. School of Exploration and Information China University of Geosciences 100083 Beijing China

The fault belts in Sanjiang mainly include Jinshajiang-Honghe fault, Lancangjiang fault and Nujiang fault (called Sanjiang faults) in western Yunnan Province, china. By interpreting the wide-angle seismic reflection/refraction profile between Zhefang and Binchuan, which crosses Tengchong and Baoshan blocks in Dianxi (western Yunnan) tectonic zone, we recon- struct the crustal structure with seismic traveltime tomography for crustal P-wave velocity and the seismic scattering image for crustal seismic reflection structure. In this paper, we firstly present the crustal structure images of P-wave velocity and seismic reflection under the wide-angle seismic profile. These results demonstrate that, the crustal velocity structure and seismic reflec- tion structure along the profile can be divided into 3.segments, and there is an obvious difference of crustal structure among the eastern, the western and the middle segment. Generally, crustal P-wave velocities in the Baoshan segment are 0.1―0.2 km/s slower and seismic reflection am- plitudes from Moho discontinuity are stronger than the other 2 segments. In the studied area, crustal thickness is about 4. km, and shows the thickening tendency from west to east along the profile. Additionally, it can be seen that there is one strong-amplitude seismic reflection event as bright points at the depths of 8―10 km, along the segment of 80―115 km of the profile (south- ward of Tengchong); and seismic reflection wave-field from Moho discontinuity varies obviously along the lateral direction. Finally, we make some discussions on the crustal thickening pattern in the Sanjiang fault belt, structural environment of earthquake development and the contact rela- tionship between the Tengchong block, Banshan block and Luxi trough.

关键词： Sanjiang area wide-angle seismic profile crustal structure.

Theoretical study on the reaction mechanism of(CH_3._3.O+CO

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Science china Chemistry 2005年第1期48卷 18-24页

作者： ZHAO Hongmei1,2,3. SUN Chengke1,4. ZHANG Rongchang3. XI Hongmin3.& LI Zonghe1 1. Department of Chemistry, beijing Normal University, beijing 100875, china 2. The Laboratory of Molecular Reaction Dynamics, {3. of Chemistry, Chinese academy of Sciences, beijing 100080, china 3. Department of Chemistry, Beihua University, Jilin 13.013. china 4. Department of Chemistry, Qujing Normal University, Yunnan 655000, china 1. Department of Chemistry Beijing Normal University 100875 Beijing China 2. The Laboratory of Molecular Reaction Dynamics Institute of Chemistry Chinese Academy of Sciences 100080 Beijing China 3. Department of Chemistry Beihua University 132013 Jilin China 4. Department of Chemistry Qujing Normal University 655000 Yunnan China

The reaction mechanism of (CH3.3.O with CO has been theoretically investigated using density-functional theory (DFT) calculations at B3.YP/6-3.G* level. In order to get more reliable energy values the single-point energy is evaluated at CCSD (T)/6-3.++G** level. The results show that the reaction is multi-channel and the reaction of (CH3.3.O radical with CO mostly produces (CH3.3. + CO2. The reaction could play a role in eliminating air pollution.

关键词： DFT, B3.YP, (CH3.3.O, radical.