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Isotopic compositions of small shelly fossil Anabarites from Lower Cambrian in Yangtze Platform of South china: Implications for palaeocean temperature

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Progress in Natural Science:Materials International 2007年第10期17卷 1185-1191页

作者： Chen Yongquan1,2. Jiang Shaoyong1, Ling Hongfei1, Yang Jinghong1 and Wan Defan3.1. State Key Laboatory for mineral {2. Research and Center for Marine Geochemistry Research, Department of Earth Sciences, Nanjing University, Nanjing 2.0093.{2. 2. Tarim Oilfield Company Exploration & Development Research {3., Ku’erle 841000,{2. 3. {3. of mineral Resources, Chinese Academy of Geological Sciences, beijing 100037,{2.) State Key Laboatory for mineral deposits Research and Center for Marine Geochemistry Research Department of Earth Sciences Nanjing University Nanjing 210093 China arim Oilfield Company Exploration & Development Research institute Ku’erle 841000 China institute of mineral Resources Chinese Academy of Geological Sciences Beijing 100037 China

Anabarites belong to small shelly fossils (SSF), which occur widely in the Lower Cambrian strata of Yangtze Platform in South china. They are phosphate shell in composition and represent the earliest stage of the Cambrian bioradiation of Bilateria, the so-called "Cambrian Explosion". In this study, we attempted to separate Anabarites fossils from Lower Cambrian dolostones, and we obtained samples of both the fossils (SSF) and the granular phosphates (GP). Isotopic analyses were performed on samples of SSF, GP, and matrix dolostone (DH-2.1}. The results showed that the δ3.Si values of the quartz filling in fossils celoms, and the siliceous materials in granular phosphates are -0.6‰ and -0.7‰, which is different from normal sedimentary siliceous rocks from the Lower Cambrian strata (0—0.7‰) as reported by Li et al., but is consistent with the data for siliceous rocks and cherts of submarine hydrothermal origin. It is likely that a later hydrothermal replacement could have taken place in the SSF-bearing sedimentary rocks. The oxygen isotope values of the phosphate of SSF and GP are 16.8‰ and 17.0‰, respectively. These are significantly higher than the Neoproterozoic phosphate ores (10.9‰—13.9‰) as reported by Ling et al., hence, late diagenesis and hydrothermal replacement may not have caused a significant change in the oxygen isotope compositions of the small shelly fossils, and the calculated temperatures (2..4—2..3.) for palaeo-seawater using a SSF phosphate oxygen isotope thermometer are therefore considered here as the upper limit of seawater temperature in the Early Cambrian ocean of the Yangtze Platform.

关键词： Anabarites oxygen isotope silicon isotope paleo-temperature.

^(40)Ar/^(3.)Ar dating of shear deformation of the Xianshuihe fault zone in west Sichuan and its tectonic significance

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Science china Earth Sciences 2004年第9期47卷 794-803页

作者： ZHANG Yueqiao1, CHEN Wen2. 3.& YANG Nong1 1. institute of Geomechanics, Chinese Academy of Geological Sciences, {2. 100081,{2. 2. institute of Geology, Chinese Academy of Geological Sciences, beijing 100037,{2. 3. institute of Geology and Geophysics, Chinese Academy of Sciences, {2. 10002.,{2. institute of Geomechanics Chinese Academy of Geological Sciences Beijing 100081 China institute of Geology Chinese Academy of Geological Sciences Beijing 100037 China institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China

Based on field geological survey, structural measurements and classical Ar/Ar dating of mica, biotite and K-feldspar, we obtain cooling ages for Miocene left-lateral shear along the Xianshuihe fault zone. The results document two thermal events during the sinistral shear. The early event (12.10 Ma) corresponds to rapid cooling of the Zheduoshan granitic massif from above 700℃ to below 3.0℃. The late event (5-3.5 Ma) corresponds to cooling of granites intruded along the eastern side of the fault zone. These dating results provide important thermochronological constraint on the timing of late Cenozoic eastward extrusion of the Chuan-Dian Block in the SE Tibetan margin.

关键词： Xianshuihe fault zone, Zheduoshan granitic massif, sinistral shear deformation, 40Ar/3.Ar dating, late Cenozoic.

Re-Os(ICP-MS)dating of the massive sulfide ores from the Jinchuan Ni-Cu-PGE deposit

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Science china Earth Sciences 2005年第10期48卷 1672-1677页

作者： YANG Gang1,2. DU Andao1, LU Jiren3. QU Wenjun1 & CHEN Jiangfeng2.1. National Research Center of Geoanalysis, beijing 100037,{2. 2. Laboratory for Earth Material Cycling, School of Earth and Space Sciences, University of Science and Technology of{2., Hefei 2.0}02.,{2. 3. institute of mineral Resource, Chinese Academy of Geological Sciences, beijing 100037,{2. National Research Center of Geoanalysis beijing china Laboratory for Earth Material Cycling School of Earth and Space Sciences University of Science and Technology of China Hefei China institute of mineral Resource Chinese Academy of Geological Sciences {2.{3.

Massive sulfide ore from the Jinchuan Ni-Cu-PGE deposit was dated by Re-Os technique using Carius Tube digestion, Os distillation, Re extraction by acetone and ICP-MS measurement. An isochron giving an age of 83. ± 3. Ma, initial 187Os/188Os ratio of 0.2.9 ± 0.018 (MSWD = 1.7) and γOs = 13. ± 15 is obtained. The Re-Os age obtained agrees, within analytical uncertainties, with previous SHRIMP zircon U-Pb age of 82. ± 8 Ma (n=5, MSWD = 4.3.. The result suggests that the deposit was formed at Neoproterozoic and that the formation of the Jinchuan Ni-Cu-PGE sulfide deposit may be closely related to the plume activity, which were attributed to the breakup of the Rodinia supercontinent. The high γOs of the massive ores sug-gests that crustal material was involved in the formation of the Jinchuan deposit, however, the quantity of the added crustal material is less than 10%.

关键词： Jinchuan Ni-Cu-PGE deposit, Re-Os dating, ICP-MS.

The species diversity of fusulinaceans and high-frequency sea-level changes in the Carboniferous-Permian boundary section at Xikou, Zhen'an County,Shaanxi Province, china

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Science china Earth Sciences 2006年第7期49卷 673-683页

作者： ZHANG Haijun1, WANG Xunlian2. DING Lin1, XIA Guoying3.& WANG Lei2.1. institute of Tibetan Plateau Research, Chinese Academy of Sciences, {2. 100085,{2. 2. Faculty of Earth Sciences and {3. Resources,{2. University of Geosciences, {2. 100083.{2. 3. Tianjin institute of Geology and {3. Resources, Tianjin 3.0170,{2. 1. institute of Tibetan Plateau Research Chinese Academy of Sciences Beijing 100085 China 2. Faculty of Earth Sciences and mineral Resources China University of Geosciences Beijing 100083 China 3. Tianjin institute of Geology and {2. Resources Tianjin 300170 China

The study on the interrelation between sea-level changes and biodiversity with its evolu-tion has great significance for understanding the impact of global changes on organic evolution and exploring the inherent laws of life-environment coevolution in geological history. In this paper, the stratigraphic distribution of fusulinacean fauna in the Carboniferous-Permian boundary section at Xikou, Zhen’an County, Shaanxi Province, is analyzed quantitatively, and the relationship between the species diversity of fusulinaceans and relative sea-level changes is discussed. As a whole, the spe-cies numbers of fusulinacean fauna experience a rapid increase and an obvious decline in Xikou, Zhen’an County, from the Late Carboniferous to the Early Permian. There is a significant increase in species diversity around the Carboniferous-Permian boundary, which is one of the biggest bio-events of the fusulinacean fauna, and represents the radiation of Pseudoschwagerininae subfamily in the studied area. Integrated fusulinacean species diversity into sequence stratigraphic framework, de-tailed study suggests that the species diversity of the fusulinaceans is closely related to its relative stratigraphic location, and is essentially controlled by the sea-level changes, especially by the high-frequency sea-level changes. Generally, the species diversity of fusulinaceans is low, and the number of first and last appearance datum is small in the lower unit of high-frequency depositional cycle formed during the quick rise of the sea level; whereas the species diversity of fusulinaceans is high, and the number of first and last appearance datum is large in the upper unit of high-frequency cycle formed during the slow fall of the sea level. Within the third-order depositional sequence, the species diversity of the fusulinaceans at the first flooding surfaces and the maximum flooding surfaces is low, and it increases upward. The fusulinacean species diversity is low within the transgressive syst

关键词： fusulinaceans, species diversity, high-frequency cyclothem, sequence stratigraphy, sea-level changes, Carboniferous-Permian boundary, Zhen'an, Shaanxi.

Re-Os age for molybdenite from the Gangdese porphyry copper belt on Tibetan plateau: Implication for geody- namic setting and duration of the Cu mineralization

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Science china Earth Sciences 2004年第3期47卷 221-231页

作者： HOU Zengqian1, QU Xiaoming1, WANG Shuxian2. DU Andao2. GAO Yongfeng3.& HUANG Wei4 1. institute of {2. Resources, Chinese Academy of Geological Sciences,{2.,{3. 2. National Center of Geoanalysis, Chinese Academy of Geological Sciences,{2.,{3. 3. Shijiazhuang College of Economy, Shijiazhuang 056000,{3. 4. Xizang Bureau of Geology and {2. Resources, Lhasa 850000,{3. Chinese Acad Geol Sci Inst Mineral Resources Beijing 100037 Peoples R China Chinese Acad Geol Sci Natl Ctr Geoanal Beijing 100037 Peoples R China Shijiazhuang Coll Econ Shijiazhuang 056000 Peoples R China Xizang Bur Geol & mineral Resources Lhasa 850000 Peoples R China

The Gangdese porphyry copper belt consists of one large and five middle-small deposits in addition to dozens of ore-bearing porphyry bodies. The belt trends 3.0 km long along the EW-striking Gangdese batholith, and locally occurs as a string of beads extending about 50 km within the SN-trending rifting zones (grabens) on the Tibetan plateau. Monzonitic granite- porphyry and quartz monzonitic porphyry, as dominant host rocks, are shoshonitic and potassic calc-alkaline. Available dating data indicate that the ages of the shallow-level emplacement for these porphyries vary from 10 Ma to 18 Ma, which are identical to that of associated potassic calc-alkaline volcanic rocks (10—15 Ma) and mafic dykes (13.18 Ma). The timing and duration of Cu mineralization events are constrained by Re-Os ages for molybdenites from three porphyry copper deposits in the Gangdese porphyry copper belt. Five molybdenite samples from the Nanmu deposit yielded an 187Re-187Os isochron with a highly pre-cise age of (14.76?.2.) Ma; six molybdenites from the Chongjiang deposit gave an isochron age of (14.04?.16) Ma. Re-Os model ages for two molybdenite samples from Lakang抏 deposit vary from 13.5 Ma to 13.6 Ma, which are basically identical to isochron ages mentioned above. All the thirteen samples from these three deposits yielded a linear array in the isochron diagram with a higher correlation coefficient of 0.99719 and an isochron age of (14.3.?.2.) Ma (1s error), suggesting an coeval event of the Cu mineralization and a shared source of ore materials for the Gangdese porphyry copper belt. Compared with the longer-lived felsic magmatic-hydrothermal system, the Cu mineralization is a relatively short event with duration of about 0.5 Ma, and usu-ally occurs in the later-stage of the complicate magmatic system. The emplacement age of the Gangdese porphyries indicates that they intruded after the rapid rising of the Gangdese Mountains at 2.—2.1}Ma, and formed in a post-collision crustal ex-tension env

关键词： porphyry copper deposit, Re-Os age, Gangdese, Tibetan plateau.

Crustal structure of Gondwana-and Yangtze-typed blocks:An example by wide-angle seismic profile from Menglian to Malong in western Yunnan

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Science china Earth Sciences 2005年第11期48卷 1828-1836页

作者： ZHANG Zhongjie1, BAI Zhiming1, WANG Chunyong2. TENG Jiwen1, Lü Qingtian3. LI Jiliang1, SUN Shanxue1 & WANG Xinzheng1 1. institute of Geology and Geophysics, Chinese Academy of Sciences, {2. 10002.,{2. 2. institute of Geophysics, Chinese Seismological Bureau, {2. 100081,{2. 3. institute of Deposition Resource, Chinese Academy of Geological Sciences, beijing 100037,{2. 1. institute of Geology and Geophysics Chinese Academy of Sciences 100029 Beijing China 2. institute of Geophysics Chinese Seismological Bureau 100081 Beijing China 3. institute of Deposition Resource Chinese Academy of Geological Sciences 100037 Beijing China

The wide-angle seismic profile between Menglian and Malong crosses the Baoshan block (Gondwana-typed), and Simao and southwestern Yangtze blocks (Yangtze-typed). By in-terpreting the wide-angle seismic data, we obtained the seismic crust/upper mantle structure of P-wave velocities together with the seismic reflections of these three blocks, Changning- Menglian and Mojiang suture zones among the mentioned three blocks. Our interpreting results demonstrate that the P-wave crustal velocity of Simao block is slower than that of Baoshan and southwestern Yangtze block and the crustal thickness gradually thickens from the Baoshan block, Simao to southwestern Yangtze block. Crustal reflection patterns of these three blocks have dis-tinct differences too. For the Gondwana-typed blocks, seismic reflections in the upper crust are well developed while in middle-lower crust they are very weak. The crustal reflections in the Yangtze block are very well developed. The crustal reflection patterns in Simao and southwest-ern Yangtze blocks are distinguishable. The average thickness of the crust in the studied area is about 40 km. And we make some discussions on the crustal thickening model of the three blocks in western Yunnan and tectonic setting of seismic developing and interaction of Gondwana and Yangtze blocks.

关键词： Gondwana blocks,Yangtze blocks,wide-angle profile,crustal structure,tectonic setting

Cesium accumulation by bacterium Thermus sp. TibetanG7:hints for biomineralization of cesium-bearing geyserite in hot springs in Tibet,china

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Chinese Science Bulletin 2007年第19期52卷 2680-2686页

作者： WANG HaiLei1,2.3. ZHENG MianPing1,2.3.& HUANG XiaoXing4 1 {2. of mineral Resources, Chinese Academy of Geological Sciences (CAGS),{2.,{3. 2.R&D Center for Saline Lake and Epithermal deposits, CAGS,{2.,{3. 3.Open Laboratory of Saline Lake Resourses and Environment, CAGS,{2.,{3. 4 Laboratory of Microbial Resources, {2. of Microbiology, Chinese Academy of Sciences, beijing 100081,{3. institute of mineral Resources Chinese Academy of Geological Sciences (GAGS) Beijing 100037 China

The bacterium Thermus sp. TibetanG7, isolated from hot springs in Tibet, china, was examined for the ability to accumulate cesium from solutions. Environmental conditions were simulated and the effects of pH, K+, Na+ and K+-regimes were then studied to determine the possible role of the bacterium in the formation of cesium-bearing geyserite around these hot springs. In despite of the inhibition of K+ and Na+, the bacterium Thermus sp. TibetanG7 revealed noticeable accumulation of cesium from solutions, with maximum accumulations of 53.49 and 40.41 μmol Cesium/g cell dry weight in Na+ and K+ inhibition experiments, respectively. The accumulation of cesium by this microorganism is rapid, with 40%―50% accumulated within the first 5 min. K+-deficient cells showed a much higher capacity of cesium accu- mulation compared with K+-sufficient cells. It is evident that the bacteria within the genus thermus play a significant role in the cesium assembly. The formation of cesium-bearing geyserite is also considered.

关键词：铯元素沉积物硅华生物矿化

Identification of Hercynian shoshonitic intrusive rocks in central Hainan Island and its geotectonic implications

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Science Bulletin 2006年第20期51卷 2507-2519页

作者： XIE Caifu1, 2. ZHU Jinchu1, DING Shijiang3. ZHANG Yeming2. FU Tai’an2.& LI Zhihong2.1. State Key Laboratory for mineral {2. Research and Department of Earth Sciences, Nanjing University, Nanjing 2.0093.{2. 2. Yichang {3. of Geology and mineral Resources, Yichang 443.03.{2. 3. Hainan Bureau of Geology and mineral Resources, Haikou 5702.6,{2. Department of Otolaryngology University Hospital VU P.O. Box 7057 1007 MB Amsterdam The Netherlands State Key Laboratory for mineral deposits Research and Department of Earth Sciences Nanjing University Nanjing 210093 China

An identification has been made of some shoshonitic intrusive rocks in central Hainan Island recently. These rocks are K-rich (K2.=2.9%―5.1%, K2./Na2.=0.95―2.12., distinctly enriched in LILE and LREE, strongly depleted in Nb, Ta, and moder- ately depleted in Sr and Ti, with (87Sr/86Sr)i = 0.70859―0.7142. and ε Nd(t) = (?2.77―?7.49). They were derived from an EMⅡ-type mantle source. The enrichment process is related to metasomatism of depleted mantle caused by a great amount of fluid-melt released from oceanic crust and terri- genous sediments at great depth (eclogite facies) during the subduction of the South china plate under the Indochina-South china Sea plate in the Carbon- iferous–Early Permian. A SHRIMP U-Pb zircon dating yields a crystallization age of 2.2.7 Ma for the sho- shonitic intrusions, which is coeval with the strongly peraluminous granites found in central Hainan Island. These two kinds of rocks generally possess syn-intrusion ductile deformation structures. Thus they are considered to have been generated during the early stage (syn-thrust phase) of a post-collisional event. The primary magma of shoshonitic rocks was produced at a depth > 80 km by decompression- dehydration melting of previously enriched litho- spheric mantle wedge, phlogopite-bearing garnet peridotite, which was in turn caused by the break-off of a descendent slab and upwelling of a hot as- thenosphere. The rising of melts was accompaniedby crustal contamination and crystallization fractiona- tion (AFC). Combining with other related data, it is proposed that the southwards subduction and amal- gamation of the South china plate with the Indo- china-South china Sea plate took place at ca. 2.7- 2.8 Ma, which was a part of the convergence proc- ess of the Pangea supercontinent. The suture zone was probably located along the line of Song Ma-Beibu Gulf-north margin of the Yunkai Moun- tains-Wuyi Mountains.

关键词： SHRIMP U-Pb dating Hercynian shoshonitic intrusive rocks post-collisional event enriched mantle Hainan Island.

The crustal structure under Sanjiang and its dynamic implications:Revealed by seismic reflection/refraction profile between Zhefang and Binchuan,Yunnan

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Science china Earth Sciences 2005年第9期48卷 1329-1336页

作者： ZHANG Zhongjie1, BAI Zhiming1, WANG Chunyong2. TENG Jiwen1, Lü Qingtian3. LI Jiliang1, LIU Yifeng1 & LIU Zhenkuan4 1. institute of Geology and Geophysics, Chinese Academy of Sciences, {2. 10002.,{2. 2. institute of Geophysics,{2. Seismological Bureau, {2. 100085,{2. 3. institute of Deposition Resource, Chinese Academy of Geosciences, beijing 100037,{2. 4. School of Exploration and Information,{2. University of Geosciences, {2. 100083.{2. 1. institute of Geology and Geophysics Chinese Academy of Sciences 100029 Beijing China 2. institute of Geophysics China Seismological Bureau 100085 Beijing China 3. institute of Deposition Resource Chinese Academy of Geosciences 100037 Beijing China 4. School of Exploration and Information China University of Geosciences 100083 Beijing China

The fault belts in Sanjiang mainly include Jinshajiang-Honghe fault, Lancangjiang fault and Nujiang fault (called Sanjiang faults) in western Yunnan Province, china. By interpreting the wide-angle seismic reflection/refraction profile between Zhefang and Binchuan, which crosses Tengchong and Baoshan blocks in Dianxi (western Yunnan) tectonic zone, we recon- struct the crustal structure with seismic traveltime tomography for crustal P-wave velocity and the seismic scattering image for crustal seismic reflection structure. In this paper, we firstly present the crustal structure images of P-wave velocity and seismic reflection under the wide-angle seismic profile. These results demonstrate that, the crustal velocity structure and seismic reflec- tion structure along the profile can be divided into 3.segments, and there is an obvious difference of crustal structure among the eastern, the western and the middle segment. Generally, crustal P-wave velocities in the Baoshan segment are 0.1―0.2.km/s slower and seismic reflection am- plitudes from Moho discontinuity are stronger than the other 2.segments. In the studied area, crustal thickness is about 40 km, and shows the thickening tendency from west to east along the profile. Additionally, it can be seen that there is one strong-amplitude seismic reflection event as bright points at the depths of 8―10 km, along the segment of 80―115 km of the profile (south- ward of Tengchong); and seismic reflection wave-field from Moho discontinuity varies obviously along the lateral direction. Finally, we make some discussions on the crustal thickening pattern in the Sanjiang fault belt, structural environment of earthquake development and the contact rela- tionship between the Tengchong block, Banshan block and Luxi trough.

关键词： Sanjiang area wide-angle seismic profile crustal structure.