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Discovery of seep carbonate nodules as new evidence for gas venting on the northern continental slope of South china Sea

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chinese Science Bulletin 2006年第10期51卷 1228-1237页

作者： CHEN Zhong1,2.3. YAN Wen1,2.3. CHEN Muhong1,3. WANG Shuhong1,2.3. LU Jun1,3. ZHANG Fan1,3. XIANG Rong1,3. XIAO Shangbin1,3. YAN Pin1,2.3.& GU Senchang1,2.3.1. South china Sea institute of Oceanology, {12. {3. of Sci-ences, Guangzhou 5103.1, china 2. Guangzhou Center for Gas Hydrate Research, {12. {3. of Sciences, Guangzhou 5103.1, china 3. Key Laboratory of Marginal Sea Geology, South china Sea institute of Oceanology and Guangzhou institute of Geochemistry, {12. {3. of Sciences, Guangzhou 5103.1, china South china Sea institute of Oceanology Chinese Academy of Science Guangzhou China Guangzhou Center for Gas Hydrate Research Chinese Academy of Sciences Guanzhou China Key Laboratory of Marginal Sea Geology South China Sea Institute of Oceanology and Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China

Seep carbonate nodules were firstlycollected from the southwestern Dongsha area onnorthern continental slope of South china Sea formineralogical and geochemical studies. The resultsof X-ray diffraction show that carbonate nodules arecomposed of Fe-rich domolite,siderite and a few cal-cite and aragonite, as well as a small quantity ofnon-carbonate minerals such as goethite, quartz andclay minerals. Fe-rich dolomite and siderite charac-terized by euhedral microcrystalline structure weredirectly precipitated at cold seeps. The δ 13. valuesfor Fe-rich dolomite and siderite in the bulk nodulesvary from ?18.2.‰ to ?3..07‰, and the δ 18O valuesrange from 0.42.to 2.76‰. Their moderate depleted13. reflects that carbon origin is possibly thermoge- netic gas or mixed gas, which is evidence of gasventings in the seafloor. Moreover, massive wormtube fossils related to cold seeps were found on thesurfaces of carbonate nodules, and the conduitsand/or channels in semi-solidified nodules whichwere not filled by carbonate or sediment were alsoobserved. A preliminary conclusion is that activemicro gas venting with a conduit/channel diameterrange from 2.0 μm to 600 μm possibly exists inmodern seafloor of the carbonate nodule area.

关键词：渗出碳酸盐节碳氧同位素甲烷渗漏天然气水化物

The biomarkers of 2.6,10,15, 19-pentamethylicosenes and their carbon isotopic composition in the sediments from the Gulf of Mexico

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chinese Science Bulletin 2006年第14期51卷 1736-1740页

作者： SONG Zhiguang1,2.& WANG Cuiping1,3.. State Key Laboratory of Organic Geochemistry, Guangzhou institute of Geochemistry, {2. academy of Sciences, Guangzhou 510640,{3. 2. Guangzhou Research Center of Gas Hydrate, {2. academy of Sciences, Guangzhou 510640,{3. 3. Graduate School of {2. academy of Sciences, Beijing 10003.,{3. State Key Laboratory of Organic Geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China Guangzhou Research Center of Gas Hydrate Chinese Academy of Sciences Guangzhou 510640 China Graduate School of chinese academy of Sciences Beijing 100039 China

A group of 2.6,10,15,19-pentamethyli- cosenes (PMIΔ) containing 1―5 unsaturated double bonds has been identified in the sea floor sediments from the Gulf of Mexico at the Green Canyon 2.0} *** PMIΔ compounds are distributed between nC2. and nC2. on the mass chromatogram of aliphatic fraction. Their δ 13. values are very much depleted in 13. and in the range of ?86.7‰ to ?115.5‰, whereas the δ 13. values of companion n-alkanes range from ?2..4‰ to ?3..6‰. These unsaturated PMIΔ com-pounds are typical biomarkers derived from the an-aerobic oxidation of methane mediated by meth-ane-oxidizing archaeal bacteria and indicative of the gas seeps or even the occurrence of gas hydrates in the deep sea sediments.

关键词：生物标志墨西哥湾沉积物 PMIA 天然气水化物

Quaternary marine transgressions in eastern china

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Journal of Palaeogeography 2012年第2期1卷 105-125页

作者： Lin Jingxing1, 3. Dai Luping2. 3.1. {2. of Geology, chinese academy of {3. Sciences, Beijing 10003., china 2. Key Laboratory of Marine Ecology and Environmental Sciences, {2. of Oceanology, chinese academy of Sciences, Qingdao 2.6071, china 3. College of Earth Science, Graduate University of chinese academy of Sciences, Beijing 100049, china institute of Geology Chinese Academy of Geological Sciences Beijing 100037 China College of Earth Science Graduate University of Chinese Academy of Sciences Beijing 100049 China Key Laboratory of Marine Ecology and Environmental Sciences Institute of Oceanology Chinese Academy of Sciences Qingdao 266071 China

Based on the data from 117 holes (9151 samples) and the research on ecology and palaeoecology of Foraminifera combined with that on Ostracoda, diatoms, pollen and spores, eight marine transgressions have been recognized in the great plain regions through the Quaternary sequences and two marine transgressions have been found since the Late Pleistocene in the coastal plain (bedrock coast) areas. In the North china Plain, these are in ascending order:the Bohai transgression in the Early Pleistocene, the Haixing and Huanghua transgressions in the Middle Pleistocene, the Baiyangdian and Cangzhou transgressions in the Late Pleistocene, and the Tianjin transgression in the Holocene. In the Yangtze River Delta region the Rugao and Zhoupu transgressions occurred in the Early Pleistocene, the Shanghai, Jiading, and Wangdian transgressions in the Middle Pleistocene, the Jiangyin and Ge Hu transgressions in the Late Pleistocene, and the Zhenjiang transgression in the Holocene. In the coastal plain (bedrock coast) areas of North china, the Cangzhou transgression was recorded in the Late Pleistocene and the Tianjin transgression in the Holocene, whereas in South china the Fuzhou transgression took place in the Late Pleistocene and the Changle transgression in the Holocene. The transgressions correspond to warm periods and regressions to cold periods. The younger transgressions were not only of shorter duration, but also of larger magnitude. These findings point to the existence of four flood event strata since the Middle Pleistocene: two in the late Middle Pleistocene and another two in the Late Pleistocene.

关键词： Quaternary marine transgressions palaeoclimate eastern china

Sporopollen analysis of Core B10 in the southern Yellow Sea and the reflected characteristics of climate changes

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chinese Science Bulletin 2003年第B06期48卷 42-48页

作者： FU Mingzuo~(1,2.3., LI Zhen~1, XU Xiaowei~1 & SHl Xuefa~1 1. Key Laboratory of Marine Sedimentology and Environmental Geology, First institute of Oceanography. State Oceanic Administration, Qingdao 2.6061.{2. 2. institute of Oceanology, {3. academy of Sciences, Qingdao 2.6071.{2. 3. Graduate School, {3. academy of Sciences, Beijing 10003..{2. 1. Key Laboratory of Marine Sedimentology and Environmental Geology First institute of Oceanography State Oceanic Administration 266061 Qingdao China 2. institute of Oceanology Chinese Academy of Sciences 266071 Qingdao China 3. Graduate School Chinese Academy of Sciences 100039 Beijing China

Eight sporopollen zones have been divided based on the results of high-resolution sporopollen analysis of Core B10 in the southern Yellow Sea. Based on the results along with ^14C datings and the subbottom profiling data,climatic and environmental changes since the last stage of late Pleistocene are discussed. The main conclusions are drawn as follows: (1) the vegetation evolved in the process of coniferous forest-grassland containing broad-leaved trees→coniferous and broad-leaved mixed forest→coniferons and broad-leaved mixed forest-grassland prevailed by coniferous trees→coniferous and broad-leaved mixed forest-grassland containing evergreen broad-leaved trees→coniferons and broad-leaved mixed forest-grassland prevailed by broadleaved trees→deciduous broad-leaved forest-meadow containing evergreen broad-leaved trees→coniferous and broadleaved mixed forest-grassland prevailed by broad-leaved trees→coniferous and broad-leaved mixed forest containing evergreen broad-leaved trees; (2. eight stages of climate changes are identified as the cold and dry stage, the temperate and wet stage, the cold and dry stage, the warm and dry stage, the temperate and wet stage, the hot and dry stage, the temperate and dry stage, then the warm and dry stage in turn; (3. the sedimentary environment developed from land,to littoral zone, to land again, then to shore-neritic zone; and (4) the Yellow Sea Warm Current formed during early-Holocene rather than Atlantic stage.

关键词：中国黄海气候变化碳14年代测定底基压型数据更新世沉积环境大西洋

Zijinshan-Bitian Cu-Au-Mo orefield, SW Fujian——An example of gold-rich PCS zoning

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chinese Science Bulletin 1999年第S2期44卷 134-135页

作者： QI Jianzhong~1, LI Zhaonai~2. ZHANG Dequan~3. FANG Xiheng~4 and XIAO Huiliang~1 1. Nanjing institute of Geology and Mineral Resources, {2. academy of {3. Sciences, Nanjing 2.0016, china 2. institute of Geology, {2. academy of {3. Sciences, Beijing 10003., china 3. institute of Mineral Deposits, {2. academy of {3. Sciences, Beijing 10003., china 4. institute of Geology, Ministry of Nuclear Industry, Beijing 100013. china Nanjing institute of Geology and Mineral Resources Chinese Academy of Geological Sciences Nanjing 210016 China institute of Geology Chinese Academy of Geological Sciences Beijing 100037 China institute of Mineral Deposits Chinese Academy of Geological Sciences Beijing 100037 China institute of Geology Ministry of Nuclear Industry Beijing 100013 China

THE Zijinshan-Bitian Cu-Au-Mo orefield is spread to north of the Shanghang County, SW *** geological structure it is located at the plunging end of NE-trending Xuanhe anticlinorium, in the NE rim ofthe NW trending Shanghang volcano-sedimentary basin. Orefield basement is composed of the Archean-Middle Proterozoic low-grade metamorphic rock formations, containing marine basic metavolcanic sequenses. Lower Cretaceous subaerial volcanic rocks of andesite-trachy andesite-rhyolite composition fill inthe volcano-sedimentary basin. Pre-mineralization granitic batholith dated 145Ma（Rb-Sr）and 157Ma（U-Pb） occupies the axial part of the plunging anticlinorium, which was regarded as crust-remelting typegranitoids. Mineralization-affiliated subvolcanic dacite porphyrite, co-volcanic granodiorite and quartzdiorite porphyrite （102.2.Ma（Rb-Sr）, Sr1 = 0.708 9） belong to syntactic type in genesis and

关键词： gold-rich porphyre copper system zoning Fujian Zijinshan.

Nitrogen isotopic geochemical characteristics of crude oils in several basins of china

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Science china Earth Sciences 2005年第8期48卷 1211-1219页

作者： CHEN Chuanping1,2. MEI Bowen1 & CAO Yacheng3.1. Jianghan Petroleum University, Jingzhou 43.100,{2. 2. Huazhong University of Science and Technology, Wuhan 43.047,{2. 3. Nanjing institute of Soil Science, {3. academy of Sciences, Nanjing 2.0008,{2. 1. Jianghan Petroleum University 434100 Jingzhou China 2. Huazhong University of Science and Technology 430047 Wuhan China 3. Nanjing institute of Soil Science Chinese Academy of Sciences 210008 Nanjing China

Nitrogen isotopic ratios of crude oils with different physical and chemical properties in several basins of china have been measured and their geochemistry has been studied ele-mentally combined with molecular organic geochemistry methods. The data indicate that δ 15N is in the range of ?6‰-2.‰. They vary with the oils in different sedimentary types of basins. The oils forming in the limnic environment have lower δ 15N with the value of about 1‰-5‰ whereas the oils in saline or semi-saline environment have higher δ 15N, with most samples being above 10‰ and some exceeding 17‰. The average nitrogen isotopic ratio of oils from the Ordovician formation in the Tarim Basin is the lowest, with most samples having δ 15N below zero, which reflects possibly the characteristic of the oils originating mainly from the organic matter formed in marine carbonate sedimentary environment. The δ 15N distribution can be altered by fractionation. It increases obviously because of biodegradation and decreases during hydrocarbon migration. However, the effect of nitrogen isotopic fractionation in the short distance migration is uncon-spicuous.

关键词： nitrogen isotope, crude oil, sedimentary environment, isotopic fractionation, china.

A new DNA algorithm to solve graph coloring problem

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Progress in Natural Science:Materials International 2007年第6期17卷 733-738页

作者： Jiang Xingpeng1, Li Yin2. Meng Ya3.and Meng Dazhi2.1. National Laboratory of Pattern Recognition,institute of Automation, {2. academy of Sciences, Beijing 100080,{3. 2. College of Applied Sciences, Beijing University of Technology, Beijing 10002.,{3. 3. School of Science, Beijing institute of Technology, Beijing 100081,{3.) National Laboratory of Pattern Recognition Institute of Automation Chinese Academy of Sciences Beijing 100080 China College of Applied Sciences Beijing University of Technology Beijing 100022 China School of Science Beijing Institute of Technology Beijing 100081 China

Using a small quantity of DNA molecules and little experimental time to solve complex problems successfully is a goal of DNA computing. Some NP-hard problems have been solved by DNA computing with lower time complexity than conventional computing. However, this advantage often brings higher space complexity and needs a large number of DNA encoding molecules. One example is graph coloring problem. Current DNA algorithms need exponentially increasing DNA encoding strands with the growing of problem size. Here we propose a new DNA algorithm of graph coloring problem based on the proof of four-color theorem. This algorithm has good properties of needing a relatively small number of operations in polynomial time and needing a small number of DNA encoding molecules (we need only 6R DNA encoding molecules if the number of regions in a graph is R).

关键词： DNA computing NP-hard problem graph coloring problem.

The crustal structure under Sanjiang and its dynamic implications:Revealed by seismic reflection/refraction profile between Zhefang and Binchuan,Yunnan

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Science china Earth Sciences 2005年第9期48卷 1329-1336页

作者： ZHANG Zhongjie1, BAI Zhiming1, WANG Chunyong2. TENG Jiwen1, Lü Qingtian3. LI Jiliang1, LIU Yifeng1 & LIU Zhenkuan4 1. institute of Geology and Geophysics, {2. academy of Sciences, Beijing 10002.,{3. 2. institute of Geophysics,{3. Seismological Bureau, Beijing 100085,{3. 3. institute of Deposition Resource, {2. academy of Geosciences, Beijing 10003.,{3. 4. School of Exploration and Information,{3. University of Geosciences, Beijing 100083.{3. 1. institute of Geology and Geophysics Chinese Academy of Sciences 100029 Beijing China 2. institute of Geophysics China Seismological Bureau 100085 Beijing China 3. institute of Deposition Resource Chinese Academy of Geosciences 100037 Beijing China 4. School of Exploration and Information China University of Geosciences 100083 Beijing China

The fault belts in Sanjiang mainly include Jinshajiang-Honghe fault, Lancangjiang fault and Nujiang fault (called Sanjiang faults) in western Yunnan Province, china. By interpreting the wide-angle seismic reflection/refraction profile between Zhefang and Binchuan, which crosses Tengchong and Baoshan blocks in Dianxi (western Yunnan) tectonic zone, we recon- struct the crustal structure with seismic traveltime tomography for crustal P-wave velocity and the seismic scattering image for crustal seismic reflection structure. In this paper, we firstly present the crustal structure images of P-wave velocity and seismic reflection under the wide-angle seismic profile. These results demonstrate that, the crustal velocity structure and seismic reflec- tion structure along the profile can be divided into 3.segments, and there is an obvious difference of crustal structure among the eastern, the western and the middle segment. Generally, crustal P-wave velocities in the Baoshan segment are 0.1―0.2.km/s slower and seismic reflection am- plitudes from Moho discontinuity are stronger than the other 2.segments. In the studied area, crustal thickness is about 40 km, and shows the thickening tendency from west to east along the profile. Additionally, it can be seen that there is one strong-amplitude seismic reflection event as bright points at the depths of 8―10 km, along the segment of 80―115 km of the profile (south- ward of Tengchong); and seismic reflection wave-field from Moho discontinuity varies obviously along the lateral direction. Finally, we make some discussions on the crustal thickening pattern in the Sanjiang fault belt, structural environment of earthquake development and the contact rela- tionship between the Tengchong block, Banshan block and Luxi trough.

关键词： Sanjiang area wide-angle seismic profile crustal structure.

Formal analysis and design of multi-party fair exchange protocols

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Science in china(Series F) 2006年第2期49卷 155-174页

作者： QING Sihan1,2.3.& LI Gaicheng1,3.1. Engineering Research Center for Information Security Technology, {2. of Software, chinese academy of Sciences, Beijing 100080,{3. 2. Beijing Zhongke Ansheng Corporation of Information Technology, Beijing 100080,{3. 3. Graduate School of the chinese academy of Sciences, Beijing 10003.,{3. 1. Engineering Research Center for Information Security Technology Institute of Software Chinese Academy of Sciences Beijing 100080 China 2. Beijing Zhongke Ansheng Corporation of Information Technology Beijing 100080 China 3. Graduate School of the chinese {2. of Sciences Beijing 100039 China

Based on the origin of message items and channel combination between transacting parties, and events and relations among events, this paper presents a concise, precise, and hierarchical model for general fair exchange protocols, formally specifies various security requirements which are able to reflect inherent requirements for fair exchange protocols more rigorously, and partition these security requirements with fine granularity. This work helps analyze, debug, and design multi-party fair exchange protocols more effectively and elaborately,

关键词： fair exchange logical protocol formal model security requirement.