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Science China Chemistry 2006年第2期49卷 162-168页

作者： CUI Wenquan1,3. LIU Li2. FENG Liangrong1, XU Chenghua1, LI Zijian1, Lü Shaojie1 & QIU Fali1 1. Chengdu Institute of Organic Chemistry, chinese {2. of Sciences, Chengdu 610041, China 2. Chemistry Department, Sichuan university of Science & Engineering, Zigong 643.3., China 3.{3. School of the chinese {2. of Sciences, beijing 10003., China Correspondence should be addressed to Qiu Fali 1. Chengdu Institute of Organic Chemistry Chinese Academy of Sciences Chengdu 610041 China 3. graduate School of the {2. academy of Sciences Beijing 100039 China 2. Chemistry Department Sichuan University of Science & Engineering Zigong 643033 China

A layered perovskite-type oxide K2.a2.i3.10 was prepared with high-temperature solid-state reaction, and characterized with X-ray diffraction (XRD) and ultraviolet-visible diffuse re-flectance spectroscopy (UV-Vis DRS). Platinum was loaded onto K2.a2.i3.10 as a co-catalyst with different methods. The dispersion of platinum on K2.a2.i3.10 was determined with HOT method. The photocatalytic activity of Pt/K2.a2.i3.10 was studied. This catalyst showed much higher activity in hydrogen evolution reaction than Ni/K2.a2.i3.10. The effects of different amounts of loaded platinum and several preparation methods were evaluated. The best achieved hydrogen evolution rate was 2.0}.88 μmol·h?1 by Pt(2.)/K2.a2.i3.10. A possible band structure and mechanism were discussed based on the results.

关键词： photocatalysis hydrogen platinum K_2.a_2.i_3._(10) support

A new DNA algorithm to solve graph coloring problem

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Progress in Natural Science:Materials International 2007年第6期17卷 733-738页

作者： Jiang Xingpeng1, Li Yin2. Meng Ya3.and Meng Dazhi2.1. National Laboratory of Pattern Recognition,Institute of Automation, chinese {2. of Sciences, beijing 100080, China 2. College of Applied Sciences, beijing university of Technology, beijing 10002., China 3. School of Science, beijing Institute of Technology, beijing 100081, China) National Laboratory of Pattern Recognition Institute of Automation Chinese Academy of Sciences Beijing 100080 China College of Applied Sciences Beijing University of Technology Beijing 100022 China School of Science Beijing Institute of Technology Beijing 100081 China

Using a small quantity of DNA molecules and little experimental time to solve complex problems successfully is a goal of DNA computing. Some NP-hard problems have been solved by DNA computing with lower time complexity than conventional computing. However, this advantage often brings higher space complexity and needs a large number of DNA encoding molecules. One example is graph coloring problem. Current DNA algorithms need exponentially increasing DNA encoding strands with the growing of problem size. Here we propose a new DNA algorithm of graph coloring problem based on the proof of four-color theorem. This algorithm has good properties of needing a relatively small number of operations in polynomial time and needing a small number of DNA encoding molecules (we need only 6R DNA encoding molecules if the number of regions in a graph is R).

关键词： DNA computing NP-hard problem graph coloring problem.

Constraints of authigenic carbonates on trace elements (Sr,Mg) of lacustrine ostracod shells in paleoenviron-ment reconstruction and its mechanism

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Science China Earth Sciences 2008年第5期51卷 654-664页

作者： HU Guang1,2. JIN ZhangDong1 & ZHANG Fei3.1 State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, chinese {2. of Sciences, Xi’an 710075, China 2.graduate{3. of the chinese {2. of Sciences, beijing 100049, China 3.College of Resources and Environmental Science, Nanjing Agricultural{3., Nanjing 2.0095, China State Key Laboratory of Loess and Quaternary Geology Institute of Earth Environment Chinese Academy of Sciences Xi’an 710075 China graduate university of the {2.{3. of Sciences Beijing 100049 China College of Resources and Env

Molar ratios of Mg/Ca and Sr/Ca were measured in two species of ostracod shells preserved in the upper core (15–55 m) of the Hequing Basin in Yunnan Province, southwest China. By correlating the molar ratios between Mg/Ca and Sr/Ca and comparing them with Sr concentrations of the sediments, we suggested that: (1) the molar Mg/Ca and Sr/Ca ratio variations in respective ostracod primo reflected the changes in its ambient water composition and ecology; (2. the molar Sr/Ca ratios responded better to the salinity change linearly than Mg/Ca without aragonite precipitation in the system, and otherwise there was no linear relation between them; and (3. the molar Sr/Ca ratios were mainly controlled by salinity and authigenic carbonate precipitation, whereas the molar Mg/Ca ratios were related to both salinity and temperature. In fact, the rate of ostracod growth owing to temperature controls the fluctuation of Mg/Ca in shells. Here, more attentions should be paid to the constraint of authigenic mineral precipitation processes on the trace elements in ostracod shells and to the correlation between these trace elements in biogenic carbonates and compositions of the sediments in systems and in future in vitro experiments.

关键词： ostracod shell molar Sr/Ca ratio molar Mg/Ca ratio environmental response Heqing Basin

Prediction method for October 2.03.solar storm

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Science China(Technological Sciences) 2006年第5期49卷 629-640页

作者： XIE Yanqiong1, 2. 3. WEI Fengsi1, FENG Xueshang1 & ZHONG Dingkun1, 2.1. State Key Laboratory of Space Weather, Center for Space Science and Applied Research, chinese {2. of Sciences, beijing 100080, China 2.{3. School, chinese {2. of Sciences, beijing 10003., China 3. Institute of Meteorology, PLA university of Science and Technology, Nanjing 2.1101, China State Key Laboratory of Space Weather Center for Space Science Applied Research Chinese Academy of Sciences Beijing 100080 China graduate School Chinese Academy of Sciences Beijing 100039 China Institute of Meteorology PLA University of Science Technology Nanjing 211101 China

Aiming at two intense shock events on October 2. and 2., 2.03. this paper presents a two-step method, which combines synoptic analysis of space weather ——“observing” and quantitative prediction ——“palpating”, and then uses it to test predictions. In the first step of “observing”, on the basis of observations of the solar source surface magnetic field, interplanetary scintillation (IPS) and ACE spacecraft, we find that the propagation of the shocks is asymmetric relative to the normal direction of their solar sources, and the Earth is located near the direction of the fastest speed and the greatest energy of the shocks. As the two fast ejection shock events, the fast explosion of coronal mass of the extremely high temperature, the strong magnetic field, and the high speed background solar wind are also helpful to their rapid propagation. In the second step of “palpating”, we adopt a new membership function of the fast shock events for the ISF method. The predicted results show that for the onset time of the geomagnetic disturbance, the relative errors between the observational and the predicted results are 1.8% and 6.7%; and for the magnetic disturbance magnitude, the relative errors are 4.1% and 3.1%, re- spectively. Furthermore, the comparison among the predicted results of our two-step method with those of five other prevailing methods shows that the two-step method is advantageous. The results tell us that understanding the physical features of shock propagation thoroughly is of great importance in improving the prediction precision.

关键词： solar storm, interplanetary shock, interplanetary scintillation, two-step method, ISF method.

Quaternary marine transgressions in eastern China

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Journal of Palaeogeography 2012年第2期1卷 105-125页

作者： Lin Jingxing1, 3. Dai Luping2. 3.1. Institute of Geology, {2. academy of Geological Sciences, beijing 10003., China 2. Key Laboratory of Marine Ecology and Environmental Sciences, Institute of Oceanology, {2. academy of Sciences, Qingdao 2.6071, China 3. College of Earth Science, graduate university of {2. academy of Sciences, beijing 100049, China Institute of Geology Chinese Academy of Geological Sciences Beijing 100037 China College of Earth Science Graduate University of Chinese Academy of Sciences Beijing 100049 China Key Laboratory of Marine Ecology and Environmental Sciences Institute of Oceanology Chinese Academy of Sciences Qingdao 266071 China

Based on the data from 117 holes (9151 samples) and the research on ecology and palaeoecology of Foraminifera combined with that on Ostracoda, diatoms, pollen and spores, eight marine transgressions have been recognized in the great plain regions through the Quaternary sequences and two marine transgressions have been found since the Late Pleistocene in the coastal plain (bedrock coast) areas. In the North China Plain, these are in ascending order:the Bohai transgression in the Early Pleistocene, the Haixing and Huanghua transgressions in the Middle Pleistocene, the Baiyangdian and Cangzhou transgressions in the Late Pleistocene, and the Tianjin transgression in the Holocene. In the Yangtze River Delta region the Rugao and Zhoupu transgressions occurred in the Early Pleistocene, the Shanghai, Jiading, and Wangdian transgressions in the Middle Pleistocene, the Jiangyin and Ge Hu transgressions in the Late Pleistocene, and the Zhenjiang transgression in the Holocene. In the coastal plain (bedrock coast) areas of North China, the Cangzhou transgression was recorded in the Late Pleistocene and the Tianjin transgression in the Holocene, whereas in South China the Fuzhou transgression took place in the Late Pleistocene and the Changle transgression in the Holocene. The transgressions correspond to warm periods and regressions to cold periods. The younger transgressions were not only of shorter duration, but also of larger magnitude. These findings point to the existence of four flood event strata since the Middle Pleistocene: two in the late Middle Pleistocene and another two in the Late Pleistocene.

关键词： Quaternary marine transgressions palaeoclimate eastern China

Ionization state of cosmic hydrogen by early stars and quasars

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Research in Astronomy and Astrophysics 2009年第6期9卷 665-681页

作者： Xiao-Chun Mao1,2.1 National Astronomical Observatories, chinese academy of Sciences, {2. 100012. China 2.3. university of chinese academy of Sciences, beijing 100049, China National Astronomical Observatories Chinese Academy of Sciences Beijing 100012 China graduate university of {2.{3. of Sciences Beijing 100049 China

Cosmic hydrogen is reionized and maintained in its highly ionized state by the ultraviolet emission attributed to an early generation of stars and quasars. The Lyα opacity observed in absorption spectra of high-redshift quasars permits more stringent constraints on the ionization state of cosmic hydrogen. Based on density perturbation and structure formation theory, we develop an analytic model to trace the evolution of the ionization state in the post-overlap epoch of reionization, in which the bias factor is taken into account. For quasars, we represent an improved luminosity function by utilizing a hybrid approach for the halo formation rate that is in reasonable agreement with the published measurements at 2.≤ z ≤ 6. Comparison with the classic Press-Schechter mass function of dark matter halos, we demonstrate that the biased mass distribution indeed enhances star formation efficiency in the overdense environment by more than 2. per cent following the overlap of ionized bubbles. In addition, an alternative way is introduced to derive robust estimates of the mean free path for ionizing photons. In our model, star-forming galaxies are likely to dominate the ionizing background radiation beyond z = 3. and quasars contribute equally above a redshift of z ～ 2.5. From 5 ≤ z ≤ 6, the lack of evolution in photoionization rate can thus be explained by the relatively flat evolution in star formation efficiency, although the mean free path of ionizing photons increases rapidly. Moreover, in the redshift interval z ～ 2.- 6, the expected mean free path and Gunn-Peterson optical depth obviously evolve by a factor of ～ 500 and ～50 respectively. We find that the relative values of critical overdensities for hydrogen ionization and collapse could be 43.% at z ≈2.and 2. at z ≈6, suggesting a rapid overlap process in the overdense regions around instant quasars following reionization. We further illustrate that the absolute estimates of the fraction of neutral hydrogen computed fr

关键词： cosmology theory -- formation galaxies -- quasars general -- diffuse radiation -- intergalactic medium

A trust region algorithm for bilevel programing problems

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chinese Science Bulletin 1998年第10期43卷 820-824页

作者： LIU Guoshan 1, HAN Jiye 2.and WANG Shouyang 3.1. Department of Mathematics, beijing Normal {2., beijing 100875, China 2. Institute of Applied Mathematics,{3. academy of Sciences, beijing 100080, China 3. Institute of Systems Science, Chi Department of Mathematics Beijing Normal University Beijing China Institute of Applied Mathematics Chinese Academy of Sciences Beijing China Institute of Systems Science Chinese Academy of Sciences Beijing China

A trust region algorithm is proposed for solving bilevel programming problems where the lower level programming problem is a strongly convex programming problem with linear constraints. This algorithm is based on a tr... 详细信息

关键词： bilevel programming problem trust region algorithm global convergence.

Quantitative analysis of soil pores under natural vegetation successions on the Loess Plateau

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Science China Earth Sciences 2010年第4期53卷 617-625页

作者： ZHAO ShiWei1,ZHAO YongGang1,2.& WU JinShui3.1 State Key Laboratory of Soil Erosion and Dryland Farming on the Loess Plateau,Institute of Soil and Water Conservation,Northwest Agriculture & Forestry university,Yangling 712.00,China 2.{2. university of{3. academy of Sciences,beijing 100049,China 3.Institute of Subtropical Agriculture,chinese academy of Sciences,Changsha 41012.,China 1. State Key Laboratory of Soil Erosion and Dryland Farming on the Loess Plateau Institute of Soil and Water Conservation Northwest Agriculture & Forestry University Yangling 712100 China2. Graduate University of Chinese Academy of Sciences Beijing 100049 China3. Institute of Subtropical Agriculture Chinese Academy of Sciences Changsha 410125 China

Soil pore is a key attribute of the soil structure that affects soil reservoir under natural vegetation recovery on the Loess *** study is to quantitatively analyze soil pore parameters,measured with Computed Tomography(CT) at 15-57 mm depths under five different vegetation succession stages using a concept of substituting "space" for "time" in the Ziwuling Forest Region of the Loess *** results showed that the soil pore parameters,such as pore number,porosity,circularity,and fractal dimension,increased significantly under the natural vegetation successions and varied with the pattern climax community stage>pioneering arbor community stage>scrub community stage>herbaceous community stage>abandoned farmland stage,indicating that natural vegetation recovery could remarkably improve soil pore *** the vegetation succession,this positive effect will be strengthened gradually,which means that the soil pore parameters may appear to be best at the climax community *** organic matter content increased linearly with the soil pore parameters(P<0.001).Increased organic matter accumulation was one of the major reasons for the changes in soil pore characteristics in natural vegetation succession.

关键词： Computed Tomography Loess Plateau natural vegetation succession soil pore soil organic matter

Modeling of elastic wave propagation on a curved free surface using an improved finite-difference algorithm

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Science China(Physics,Mechanics & Astronomy) 2004年第5期47卷 633-648页

作者： WANG Xiuming1,3.& ZHANG Hailan2.1. CSIRO Petroleum, ARRC, PO BOX 113., Technology Park, Bentley, WA 6102. Australia 2. Institute of Acoustics, {2. academy of Sciences, beijing 100080, China 3. Present address: Institute of Acoustics, {2. academy of Sciences, beijing 100080, China 1. CSIRO Petroleum ARRC Technology Park PO BOX 1130 6102 Bentley WA Australia 2. Institute of Acoustics Chinese Academy of Sciences 100080 Beijing China

Based on existing direct and imaging methods of a staggered finite-difference scheme, an improved algorithm for staggered finite-difference is proposed to implement rugged topographic free boundary conditions. This method assumes that the free surface can be implemented with horizontal and vertical free surface segments and their corners; the free surface passes through the grid points of shear stress components, instead of the normal stress components. Imaging is carried out for stress components in both horizontal and vertical directions, thus increasing the accuracy. To update particle- velocities, imaging and updating are first performed in the horizontal direction, and then in the vertical direction. The numerical results for elastic flat horizontal free surface with the imaging method and those for flat free surfaces of various slope angles with the proposed method are compared, and are shown to be in good agreement. The advantage of the proposed method is that only the stresses are dealt with in implementing the free surface into the staggered algorithm, which improves computation efficiency.

关键词： elastic wave simulation, curved free surface, staggered finite-difference, algorithm stability.

Eclogites in the interior of the Tibetan Plateau and their geodynamic implications

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chinese Science Bulletin 2009年第15期54卷 2556-2567页

作者： ZHANG KaiJun1,2.& TANG XianChun2.3.1 Department of Earth Sciences, Nanjing university, Nanjing 2.0093. China 2.Guangzhou Institute of Geochemistry, chinese academy of Sciences, Guangzhou 510640, China 3.3. university of chinese academy of Sciences, beijing 100049, China Department of Earth Sciences Nanjing University Nanjing 210093 China Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China graduate university of {2.{3. of Sciences Beijing 100049 China

Eclogites have been recently reported in the interior of the Tibetan Plateau, including in the central Qiangtang metamorphic belt, in the Basu metamorphic massif of the eastern Bangong-Nujiang suture zone, and at Songdo and Pengco in the eastern Lhasa terrane. Some typical ultrahigh-pressure (UHP) metamorphic phenomena, e.g., garnet exsolution from clinopyroxene, were documented in the Basu and Pengco eclogites. The UHP metamorphism in the interior of the Tibetan Plateau marked by these eclogites generally took place in the Early Mesozoic. Along with exhumation of these eclogites, (post-) collision-related magmatism extensively occurred around the central Qiangtang belt, the eastern Ban-gong-Nujiang suture zone, and the eastern Lhasa terrane. The occurrence of these Early Mesozoic ec-logites manifests an out-of-sequence evolution of the Tethys, and they could be a product of diachro-nous collision between the eastern Qiangtang terrane and the irregular continental margin of the united western Qiangtang-Lhasa plate, along the linked eastern Bangong-Nujiang-central Qiangtang zone. The collision-related magmatic rocks could have been originated from lithospheric thickening, melting, or detachment due to the collision. The presence of UHP metamorphic rocks in central Qiangtang and Basu implies likely continental deep-subduction, and the denudation of these two metamorphic zones could have served as the source of the Triassic turbidites in the Songpan-Garzê complex and the Ju-rassic turbidites in the western Bangong-Nujiang zone, respectively. However, studies of the eclogites in the interior of the Tibetan Plateau just began, and many principal aspects still remain to be explored, such as their distributions, typical lithologies and minerals, temperature-pressure conditions, timing of formation and exhumation, protoliths and tectonic setting, and relationship with the evolution of the Tethys and large-scale basins in Tibet.

关键词：地球动力学意义青藏高原榴辉岩