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Preparation of Pt/K_2La_2Ti_3._(10) and its photo-catalytic activity for hydrogen evolution from methanol water solution

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Science china Chemistry 2006年第2期49卷 162-168页

作者： CUI Wenquan1,3. LIU Li2, FENG Liangrong1, XU Chenghua1, LI Zijian1, Lü Shaojie1 & qiu fali1 1. Chengdu Institute of Organic Chemistry, chinese {3. of sciences, Chengdu 610041, china 2. Chemistry Department, Sichuan University of Science & Engineering, Zigong 643.3., china 3. graduate school of the chinese academy of sciences, beijing 10003., china correspondence should be addressed to qiu fali 1. Chengdu Institute of Organic Chemistry Chinese Academy of Sciences Chengdu 610041 China 3. graduate school of the chinese academy of sciences Beijing 100039 China 2. Chemistry Department Sichuan University of Science & Engineering Zigong 643033 China

A layered perovskite-type oxide K2La2Ti3.10 was prepared with high-temperature solid-state reaction, and characterized with X-ray diffraction (XRD) and ultraviolet-visible diffuse re-flectance spectroscopy (UV-Vis DRS). Platinum was loaded onto K2La2Ti3.10 as a co-catalyst with different methods. The dispersion of platinum on K2La2Ti3.10 was determined with HOT method. The photocatalytic activity of Pt/K2La2Ti3.10 was studied. This catalyst showed much higher activity in hydrogen evolution reaction than Ni/K2La2Ti3.10. The effects of different amounts of loaded platinum and several preparation methods were evaluated. The best achieved hydrogen evolution rate was 23..88 μmol·h?1 by Pt(2%)/K2La2Ti3.10. A possible band structure and mechanism were discussed based on the results.

关键词： photocatalysis hydrogen platinum K_2La_2Ti_3._(10) support

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Study on the coating of nano-scale SiO_2 film on the surface of nanocrystalline Mg-Al layered double hydroxides

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Science china Chemistry 2005年第2期48卷 107-114页

作者： ZHANG Zejiang1,2,3. MEI Xiujuan2, XU Chenghua1 & qiu fali1 1. Chengdu Institute of Organic Chemistry, chinese {3. of sciences, Chengdu 610041, china 2. Sichuan Fire Research Institute of Public Security Ministry, Chengdu 61183., china 3. graduate school of the chinese academy of sciences, beijing 10003., china correspondence should be addressed to Zhang Zejiang (email: zzjzzjzz@***) 1. Chengdu Institute of Organic Chemistry Chinese Academy of Sciences 610041 Chengdu China 2. Sichuan Fire Research Institute of Public Security Ministry 611830 Chengdu China 3. graduate school of the chinese academy of sciences 100039 Beijing China

The coating process of a nano-scale SiO2 film on the nanocrystalline Mg-Al layered double hydroxides via a sol-gel process was investigated. The uniform and dense SiO2film with a thickness of about 5 nm on the nano-LDHs particles was characterized by the solubility test in the dilute HNO3.or HCl acid, TEM and FT-IR, XRD, TG and DSC. The chemical shifts of binding en- ergies of Al 2p, Mg 2p, Si 2s and O 1s on the coated particles indicate that the coating of the SiO2 nano-film on the surface of the nano-LDHs proceeds through the formation of Mg-O-Si and Al-O-Si bonds. The thermal analysis shows that both the SiO2-coated nano-LDHs and the nano-LDHs have a similar mass loss process, in which there are three obvious stages of mass loss in the temperature range of 40—700℃. Furthermore, the more the coatedamount of SiO2on the surface of the nano-LDHs is, the less the mass loss of the samples is at 700℃.The nano- LDHs have two obvious endothermic peaks at 244.67℃ and 43..13., whose corresponding heat absorption capacities are 412.28 J/g and 3.6.3. J/g, respectively. In contrast, the coated nano-LDHs have only one endothermic peak at 243.60℃ with a heat absorption capacity of 221.25 J/g.

关键词： layered double hydroxides, nanocrystalline, silica, coating.

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