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Analytical method of Cr stable isotope and its application to water pollution survey

Chinese Science Bulletin 2010年第7期55卷 664-669页

作者： GAO YongJuan 1,2,3.MA Teng 4,5,LING WenLi 1,2,LIU CunFu 4,5 & LI Li 4,5 1faculty of earth Science,china University of {3.,wuhan 4.0074,china 2State Key Laboratory of Geological Processes and Mineral Resources,china University of {3.,wuhan 4.0074,china 3.Graduate School,china University of {3.,wuhan 4.0074,china 4 Biogeological and Environmental Geology Laboratory of Ministry of Education(china University of {3.) ,wuhan 4.0074,china 5 Sino-Hungary Joint Laboratory of Environmental sciences and Health,china University of {3.,wuhan 4.0074,china faculty of earth Science China University of Geosciences Wuhan 430074 China State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Wuhan 430074 China Graduate School China University of Geosciences Wuhan 430074 China Biogeological and Environmental Geology Laboratory of Ministry of Education (china University of geosciences) Wuhan 430074 China Sino-Hungary Joint Laboratory of Environmental sciences and Health China University of Geosciences Wuhan 430074 China

High Cr(VI) concentration is a potential serious risk to environment and ecologic ***,it is essential to effectively monitor Cr contamination in water systems and scientifically evaluate its evolution trend.A new method of in-situ tracer technique by Cr isotopic analysis for quantitatively estimating Cr-contamination and its regional evolution in natural waters as well as a case application are reported in this *** on documented literatures,an experimental procedure for chemical separation and purification of Cr in water samples and its analytical method for Cr isotopic measurement by thermal ionization mass spectrometry(TIMS) are *** samples collected around a chemical factory in Hubei Province were analyzed by this *** samples showδ53.r values ranging from-1.7‰to 7.3.and an elevating trend with an increasing in distance from the sampling site to pollution source.A functional correlation following Rayleigh fractionation law was established between sample'sδ53.r value and its extent of Cr *** study suggests that Cr isotopic analysis is an effective method to reveal the spatial distribution and its evolution trend of Cr contamination in the regional water *** is thus helpful to assessing the self-purifying ability of local water system according to Cr isotopic fractionation.

关键词：铬(VI) 水污染调查稳定同位素应用同位素分析供水系统演变趋势示踪技术

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Petrogenesis of Indosinian volcanic rocks in Songpan-Garze fold belt of the northeastern Tibetan Plateau:New evidence for lithospheric delamination

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Science china earth {2. 2010年第9期53卷 1316-1328页

作者： CAI HongMing1,2. ZHANG HongFei1,2. XU WangChun1,2. SHI ZhangLiang1,2.& YUAN HongLin3.1 State Key Laboratory of Geological Processes and Mineral Resources, wuhan 4.0074,{2. 2.faculty of {3. sciences,{2. University of geosciences, wuhan 4.0074,{2. 3.State Key Laboratory of Continental Dynamics, Northwest University, Xi’an 710069,{2. 1. State Key Laboratory of Geological Processes and Mineral Resources Wuhan 430074 China2. Faculty of Earth Sciences China University of Geosciences Wuhan 430074 China3. State Key Laboratory of Continental Dynamics Northwest University Xi’an 710069 China

In the Songpan-Garze fold belt of the northeastern Tibetan Plateau, an Indosinian lithospheric delamination model has been proposed, based on previous investigation of widespread granitoids. However, this model lacks comparable information from volcanism in the area. During the Indosinian delamination in the Songpan-Garze fold belt, whether partial melting of litho- spheric mantle taken place is debated. This paper reports U-Pb zircon LA-ICP-MS ages, geochemical and Sr-Nd-Hf isotopic compositions from the Aba and Wasai calc-alkaline volcanic rocks in the central Songpan-Garze fold belt. Obtained magma crystallization ages are 2.0±3.Ma for the Aba andesite and 2.5±1 Ma for the Wasai andesite. These are consistent with magma crystallization ages of the late Indosinian granitoids in the Songpan-Garze fold belt that formed in a post-collisional tectonic setting. The Aba and Wasai andesites have distinct geochemical singnatures. The former has higher Al2.3. K2., Rb but lower Na2., Ba and Sr contents, suggesting differences in their magmatic evolution. The Aba andesites have ISr values of 0.7070-0.7076 and εNd(t) values of -3.9 to -5.3. and the Wasai andesites have ISr values of 0.7075-0.7077 and εNd(t) values of -3.6 to -3.9. Zircons show εHf(t) values of -3.7 to 0.3.for the Aba andesites and -2.7 to 5.5 for the Wasai andesites. Geochemical and Sr-Nd-Hf isotopic compositions indicate that fractional crystallization and crustal assimilation processes are not key roles for their magma evolution, implying that their chemical compositions are those of primary melts. We suggest that the magma of the Aba andesites originated predominantly from a crustal source, with a minor mantle-derived component. The source region of the magma was likely at the crust-mantle boundary. The magma of the Wasai andesites resulted from partial melting of lithospheric mantle, which was probably metasomatized by fluids so that it was amphibole bearing. The petrogenesis of the Aba and Wasai andesite

关键词： volcanism U-Pb dating geochemistry petrogenesis lithospheric delamination Songpan-Garze fold belt

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Genomics,metagenomics,and microbial oceanography—A sea of opportunities

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Science china earth {2. 2011年第4期54卷 473-480页

作者： FANG JiaSong 1,2.&ZHANG Li 3.1 State Key Laboratory of Marine Geology,Tongji University,Shanghai 2.0092.china 2.College of Natural and Computational {2.,Hawaii Pacific University,Kaneohe,HI 96744,USA 3.tate Key Laboratory of Geological Processes and Mineral Resources,faculty of {3. {2.,china University of geosciences,wuhan 4.0074,china 1. State Key Laboratory of Marine Geology Tongji University Shanghai 200092 China2. College of Natural and Computational Sciences Hawaii Pacific University Kaneohe HI 96744 USA3. State Key Laboratory of Geological Processes and Mineral Resources Faculty of Earth Sciences China University of Geosciences Wuhan 430074 China

Microbial oceanography is an emerging discipline resulted from the interaction,cross-fertilization and integration of life science and ocean *** oceanography integrates the principles of marine microbiology,microbial ecology and oceanography to study the role of microorganisms in the biogeochemical dynamics of natural marine *** application of genomics tools to study marine microbes is resulting in rapid advancements in microbial oceanography that has important implications in global carbon cycle,climate change,and ecosystem *** we review the application of genomics and metagenomics in microbial oceanography and suggest future directions in microbial oceanography research.

关键词： microbial oceanography genomics metagenomics genes biomass bacteria archaea eukarya phylogeny physiology metabolism ecology biogeochemistry microbiology ecosystem function

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Middle Triassic Stratigraphy and Sedimentary Paleogeography of South china

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Journal of earth Science 2000年第3期19卷 70-76页

作者： Tong Jinnan Liu Zhili faculty of earth {2.,{3. University of geosciences, wuhan 4.0074,{3.

The Middle Triassic was the great turning period of South china from marine sedimentary basins to continental deposits or erosion. This paper summarizes the distribution and variation of the stratigraphic sequences, lithofacies and biotas in various Middle Triassic depositional basins of South china. The close relationship between the biotic paleoecology and the lithofacies as well as the sedimentary facies, thus the paleogeography, is demonstrated. The process of the transition from the depositional paleogeography and its relation to the tectonic settings is concluded.

关键词： Middle Triassic sedimentary facies and paleogeography South china.

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Zircon geochronology and geochemistry of mafic xenoliths from Liaoning kimberlites:Track the early evolution of the lower crust,North china Craton

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Science china earth {2. 2004年第11期47卷 961-972页

作者： ZHENG Jianping1,YU Chunmei1,LU Fengxiang1 & LI Huimin2.1.faculty of earth {2.,{3. University of geosciences,wuhan 4.0074,{3. 2.Tianjin Institute of Geology and Mineral Resources,Tianjin 3.0170,{3. 1. faculty of earth {2. China University of Geosciences 430074 Wuhan China 2. Tianjin Institute of Geology and Mineral Resources 300170 Tianjin China

Mafic xenoliths from Paleozoic Fuxian kimberlites (Liaoning Province) mainly in- clude garnet granulite, with minor pyroxene amphibolite, meta-gabbro and pyroxene syenite. The SiO2.contents of the xenoliths are from 47.3.wt% to 49.9 wt%. The granulites are mainly coarse-medium grained and reasonably with well-developed granoblastic (mostly polygonal) texture, contain the assemblage of garnet + plagioclase + pyroxene + K-feldspar ±phlogopite. The mineral assemblage of the amphibolites is plagioclase + pyroxene + amphibole ±K-feldspar, with the equilibrium temperature and pressure conditions of 744—82.℃ and 0.76—0.88 GPa. The granulites are regarded as derivation from the lower crust depth (more than 2. km), below the amphibolites. Garnet granulites compositionally correspond to sub-alkalic basalt, and have wide ranges of Ni abundance (13.—840 ppm), and Nb/Y (0.12.1.85), Nb/U (3.51—53.86) and Ta/U (0.3.—2.48). The amphibolite and the syenite correspond to alkalic basalt. The Fuxian ma- fic xenoliths are regarded as the metamorphic product of the underplated magmas (including fractional crystallization or not) experienced the contamination with the pre-existed crustal com- ponents, and partly effected by kimberlitic magmas. The concordant ages of zircons for the gab- bro (2.10—2.80 Ma) and the near-concordant upper intercept ages of zircons for the garnet granulite and pyroxene amphibolite (2.78—2.3. Ma) indicate that they are currently known as the oldest deep-seated xenoliths from the lower crust of the North china Craton. These ages recorded the formation of the united Eastern Block of the North china Craton, That is, Neoar- chean (2.6—2.5 Ga) is an important continental crustal growth period of the North china Craton. The lower intercept age of the garnet granulite (1853.Ma) recorded an important tectonic thermal event in Paleoproterozoic. This event was probably related to collision of the East and West block, and resulted in the final assembly of the North china

关键词： mafic xenolith, petrochemistry, zircon geochronology, petrogenesis, lower crustal evolution, North china Craton.

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Research on the dynamics of the South china Sea opening:Evidence from analogue modeling

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Science china earth {2. 2006年第10期49卷 1053-1069页

作者： SUN Zhen1,2. ZHOU Di1, ZHONG Zhihong3. XIA Bin2. QIU Xuelin1, ZENG Zuoxun4 & JIANG Jianqun5 1. CAS Key Laboratory of Marginal Sea Geology, South china Sea Institute of Oceanology, Chinese Academy of {2., Guangzhou 5103.1, china 2. CAS Key Laboratory of Marginal Sea Geology, Guangzhou Institute of Geochemistry, Chinese Academy of {2., Guangzhou 510640, china 3. Department of Technology, Shenzhen Branch of CNOOC, Guangzhou 5102.0, china 4. faculty of earth {2., china University of geosciences, wuhan 4.0074, china 5. Hainan Oil & Gas Exploration Company, Liaohe Oilfield Petro{13., Panjin 12.010, china 1. CAS Key Laboratory of Marginal Sea Geology South China Sea Institute of Oceanology Chinese Academy of Sciences Guangzhou 510301 China 2. CAS Key Laboratory of Marginal Sea Geology Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China 3. Department of Technology Shenzhen Branch of CNOOC Guangzhou 510240 China 4. faculty of earth {2. China University of Geosciences Wuhan 430074 China 5. Hainan Oil & Gas Exploration Company Liaohe Oilfield PetroChina Panjin 124010 China

Independent of Indochina extrusion, the South china Sea experienced a process from passive continental rifting to marginal sea drifting. According to the fault patterns in the Beibu Gulf basin and the Pearl River Mouth basin, the continental rifting and early spreading stage from {2. to 2. Ma were controlled by extensional stress field, which shifted clockwise from southeastward to south southeastward. From 2. Ma on, the sea spread in NW-SE direction and ceased spreading at around 15.5 Ma. Integrated geological information with the assumption that the South china Sea developed along a pre-Cenozoic weakness zone, we did analogue experiments on the South china Sea evolu- tion. Experiments revealed that the pre-existing weakness zone goes roughly along the uplift zone between the present Zhu-1 and Zhu-2.depression. The pre-existing weakness zone is composed of three segments trending NNE, roughly EW and NEE, respectively. The early opening of the South china Sea is accompanied with roughly 15° clockwise rotation, while the SE sub-sea basin opened with SE extension. Tinjar fault was the western boundary of the Nansha block (Dangerous Ground), while Lupar fault was the eastern boundary of the Indochina, NW-trending rift belt known as Zengmu basin developed between above two faults due to block divergent of Indochina from Nansha. In the experiment, transtensional flower structures along NW-trending faults are seen, and slight inversion occurs along some NE-dipping faults. The existence of rigid massifs changed the orientations of some faults and rift belt, and also led to deformation concentrate around the massifs. The rifting and drifting of the South china Sea might be caused by slab pull from the proto South china Sea subducting toward Borneo and/or mantle flow caused by India-Asia collision.

关键词： South china Sea, rifting and drifting, clockwise rotation, analogue modeling, rigid massifs.

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Exploring the deep biosphere

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Science china earth {2. 2011年第2期54卷 157-165页

作者： FANG JiaSong1,2.& ZHANG Li3.1 State Key Laboratory of Marine Geology, Tongji University, Shanghai 2.0092. china 2.College of Natural and Computational {2., Hawaii Pacific University, Kaneohe, HI 96744, USA 3.State Key Laboratory of Geological Processes and Mineral Resources, faculty of {3. {2., china University of geosciences, wuhan 4.0074, china 1. State Key Laboratory of Marine Geology Tongji University Shanghai 200092 China2. College of Natural and Computational Sciences Hawaii Pacific University Kaneohe HI 96744 USA3. State Key Laboratory of Geological Processes and Mineral Resources Faculty of Earth Sciences China University of Geosciences Wuhan 430074 China

Over the past two decades, scientific drilling into sediments and rocks in the ocean and the continent has revealed the presence of physiologically and phylogenetically complex microbial life in the deep subsurface. Microorganisms, most of which have no cultured or known relatives in the surface biosphere, have been discovered in sediments and rock at depth as deep as 1 km below the seafloor and more than 3.km deep in the continent. The deep biosphere probably represents the most voluminous part of the global biosphere and may constitute as much as 50% of the earth’s biomass. In this article, we review the current knowledge of and most recent advances in studying the deep biosphere and suggest directions in future research.

关键词： deep biosphere Thomas Gold microorganism biomass DNA ribosome ODP CARD-FISH dark energy lipids serpentinization

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Sedimentary geochemistry of the Cambrian-Ordovician cherts: Implication on archipelagic ocean of North Qilian orogenic belt

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Science china earth {2. 2007年第11期50卷 1628-1644页

作者： DU YuanSheng1,2. ZHU Jie1, GU SongZhu1, 2. XU YaJun1 & YANG JiangHai1 1 faculty of earth {2.,{3. University of geosciences, wuhan 4.0074,{3. 2.Key Laboratory of Biogeology and Environment Geology of Education Ministry, wuhan 4.0074,{3. 1. faculty of earth {2. China University of Geosciences Wuhan 430074 China 2. Key Laboratory of Biogeology and Environment Geology of Education Ministry Wuhan 430074 China

The Caledonian North Qilian orogenic belt lies between the North china plate and the Qaidam mi-croplates, and resulted from the collision among the Qaidam microplate, mid-Qilian block and the North china plate. The orogen initiated from the rifting of the Late Proterozoic Rodinia, and then it experi-enced stages of Cambrian rift basin and Ordovician archipelagic oceanic basin, and foreland basin during Silurian to Early-Middle Devonian. The average ratios of Al/(Al+Fe+Mn), Al/(Al+Fe), δ Ce, Lan/Ybn and Lan/Cen from cherts of Cambrian Heicigou Formation are 0.797, 0.62., 1.114, 0.994 and 1.0{2. re-spectively. In the NAS standardized REE distribution pattern, the cherts from Xiangqianshan is slightly HREE enriched, and the cherts from Ganluci and Shiqingdong are plane. All of these features indicated that Cambrian cherts of the Heicigou Formation originated from a continental margin rift background. On the contrary, the average ratios of Al/(Al+Fe+Mn), Al/(Al+Fe), δ Ce, Lan/Ybn, Lan/Cen of the Ordovician chert from Dakecha, Cuijiadun, Shihuigou, Laohushan, Heicigou, Maomaoshan, Bianmagou, Da-chadaban, Baiquanmen, Jiugequan and Angzanggou, are respectively 0.72. 0.58, 0.99, 1.09 and 0.96 respectively. Their NAS standardized REE distribution patterns of most Ordovician cherts are plane mode or slightly HREE enriched. The REE distribution pattern of few samples of cherts are slightly LREE enriched. Characteristics of sedimentary geochemistry and tectonic evolution demonstrated that the Cambrian-Ordovician cherts, associated with rift, oceanic, island arc and back-arc volcanic rocks, was not formed in a typical abyssal oceanic basin or mid-oceanic ridge. On the contrary, they formed in a deepwater basin of continental margin or a archipelagic ocean tectonic setting. Several Early Paleo-zoic ophiolite belts in North Qilian and adjacent periphery Qaidam microplate imply that an archipelagic ocean during Ordovician existed in the east of Pro-Tethys.

关键词： North Qilian orogenic belt,Cambrian-Ordovician,cherts sedimentary geochemistry,archipelagic ocean

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Crustal　Texture　and　Rheological　Evolution　of　Tongbai－Dabie　Orogenic　Belt，china

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Journal of earth Science 1995年第1期14卷 59-63页

作者： Suo Shutian(faculty of earth {2.,{3. University of geosciences, wuhan 4.0074)

The crustal texture and rheological evolution of the Tongbai-Dabie orogenic belt are approached from a physical standpoint on the basis of a large body of geological, chronological and geophysical data available in the region. Rheological profiles showing variation of rock Strength with depth in the continental crust are constructed for 1-D crustal structure limited to the Present and Meso-Neoproterozoic structural configurations of the deformed belt, respectively .It is emphasized that the crustal texture and composition have been heterogeneous with the rheological stratification and complicated rheological evolution since the Meso-Neoproterozoic at least. The data appear that the Tongbai - Dabie tectonic belt is a polyphase collisional orogen with evidence for cyclically transition from compressional to extensional regimes and rheological behavior in the levels of the crust.

关键词： orogenic belt Physical condition rheological Stratification fluid crustal layer paleorheological Profile.

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Characteristics of Coal Accumulation of Transform-Extensional Basins in Linear Fracture Zones: A Case Study of the Meihekou Basin

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Acta Geologica Sinica(English Edition) 1999年第1期73卷 104-110页

作者： ZHUANG Xinguo Institute of Sedimentary Basin, faculty of earth Resources{2. University of {3., wuhan, Hubei 4.0074 china Univ Geosci Fac Earth Resources Inst Sedimentary Basin Wuhan 430074 Hubei Peoples R China

This paper discusses the characteristics of coal accumulation of transfor-extensional basins in linear fracture zones on the basis of an analysis of tectonic evolution and sequence stratigraphy in the Meihekou basin. Coal accumulation of the basin occurred mainly in the accelerated rifting period of the transtentional regime and in the late period of tectonic transformation of the transpressional regime. In the former period, swamps developed in shallow lakes. The thickness of coal seams was controlled by the activity of fault block. Thick coal was formed in a downfaulted trough. In the latter period, swamps developed in a braided fan delta plain. The coal seams are thin and have poor lateral continuity. The thickness of coal seams was controlled by the migration of water channels in the braided plain.

关键词： coal accumulation sequence stratigraphy tectonic evolution Meihekou basin

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