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STUDY ON THE IMMOBILIZATION OF PAPAIN WITH A MACROPOROUS BEAD CARRIER OF COPOLYMER CONTAINING MONOMER UNITS OF NAMINOETHYL ACRYLAMIDE AND VINYL ALCOHOI

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Chinese Journal of Polymer Science 2000年第1期18卷 25-31页

作者： Yan-feng Li Jun-rong Li Lian-di Fu Yao-zeng Li department of Chemistry, lanzhou university, lanzhou 730000,{3. Gansu Natural Energy Research Institute, lanzhou 730000,{3. Gansu Provincial Institute of Drug Control, lanzhou 730000,{3. 兰州大学甘肃兰州甘肃自然能源所甘肃兰州 730000 甘肃省药检所甘肃兰州 730000

A kind of macroporous bead carrier of copolymer containing monomer units of N-aminoethyl acrylamide and vinylalcohol was synthesized, i.e. the MR-AA carrier. Papain was immobilized on the carrier using glutaraldehyde as the couplingagent. The enzymatic activity of the immobilized papain was compared with free papain using casein as a substrate, and theeffects of glutaraldehyde concentration, pH, temperature, time and papain amount added on the activity recovery were alsoinvestigated. The results show that the MR-AA carrier contains reactive primary amine groups, hydrophilic amido links andhydroxyl groups, as well as macroporous structures based on its matrix (MR-AV matrix), furthermore, the activity recoveryof papain in the immobilization could reach 48%/～58%. In comparison with free papain, the resulting immobilized papainexhibits a remarkable thermostability and better reusability.

关键词： Immobilization Papain Proteolytic enzyme Macroporous bead carrier

STABILITIES OF (A,B,C) AND NPDIRK METHODS FOR SYSTEMS OF NEUTRAL DELAY-DIFFERENTIAL EQUATIONS WITH MULTIPLE DELAYS

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Journal of Computational Mathematics 2003年第3期21卷 375-382页

作者： Guo-feng Zhang (department of Mathematics, lanzhou university, lanzhou 730000,{3.) department of Mathematics Lanzhou University Lanzhou 730000

Consider the following neutral delay-differential equations with multiple delays (NMDDE)where γ> 0, L, Mj and Nj are constant complex- value d×d matrices. A sufficient condition for the asymptotic stability of NMDDE system (0.1) is given. The stability of Butcher's (A,B,C)-method for systems of NMDDE are studied. In addition, we present a parallel diagonally-implicit iteration RK (PDIRK) methods(NPDIRK) for systems of NMDDE, which is easier to be implemented than fully implicit RK methods. We also investigate the stability of a special class of NPDIRK methods by analyzing their stability behaviors of the solutions of (0.1).

关键词： Neutral delay differential equations (A,B,C)-method RK method Parallel diagonally-implicit iteration RK method.

X-ray spectra induced in highly charged 40Ar^q+ interacting with Au surface

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Science china(phys.cs,Mechanics & Astronomy) 2006年第2期49卷 203-212页

作者： ZHANG Xiao’an1,2, XIAO Guoqing1, YANG Zhihu1, CHEN Ximeng3. ZHAO Yongtao1, LI Fuli4, ZHANG Yinping1, CUI Ying3. ZHANG Hongqiang3. XU Xu3. SHAO Jianxiong3.& ZHAN Wenlong11. Institute of modern phys.cs, Chinese Academy of Sciences, lanzhou 730000,{3. 2. department of phys.cs, Xianyang Normal university, Xianyang 712000,{3. 3. department of modern phys.cs, lanzhou university, lanzhou 730000,{3. 4. department of Applied phys.cs, Xi’an Jiaotong university, Xi’an 710049,{3. 1. Institute of modern phys.cs Chinese Academy of Sciences Lanzhou 730000 China 2. department of phys.cs Xianyang Normal University Xianyang 712000 China 3. department of modern phys.cs Lanzhou University Lanzhou 730000 China 4. department of Applied phys.cs Xi’an Jiaotong University Xi’an 710049 China

By use of optical spectrum technology, the spectra of X-ray induced by highly charged 40Arq+ ions interacting with Au surface have been studied. The results show that the argon Kα X-ray were emitted from the hollow atoms formed below the surface. There is a process of multi-electron exciting in neutralization of the Ar16+ion, with electronic con-figuration 1s2 in its ground state below the solid surface. The yield of the projectile Kα X-ray is related to its initial electronic configuration, and the yield of the target X-ray is related to the projectile kinetic energy.

关键词： highly charged ion hollow multi-electron excitation X- ray.

Syntheses,characterization,crystal structure and magnetic properties of copper(Ⅱ) α,β-unsaturated carboxylate complexes with trimethyl phosphate

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Chinese Science Bulletin 2001年第12期46卷 987-991页

作者： WANG Yaoyu, LIU Ping, SHI Qian, GAO Yici & SHI Qizhen1. department of Chemistry, Northwest university, Xi’an 710069, china 2. department of Chemistry, Wenzhou Teachers College, Wenzhou 3.5003. china 3. department of Chemistry, lanzhou university, lanzhou 730000, china department of Chemistry Northwest University Xi’an China department of Chemistry Wenzhou Teachers College Wenzhou China department of Chemistry Lanzhou University Lanzhou China

Two ternary complexes Cu2A4[OP(OCH3.3.2 (A represents CH2=CH-COO- and CH2=C(CH3.-COO-) have been synthesized, and elemental analyses, IR, ESR, electronic reflectance spectra and magnetic studies were carried out. The single crystal X-ray diffraction shows that Cu2[CH2=C(CH3.-COO]4[OP(OCH3.3.2 is triclinic, with space group P1, a = 1.05128(13., b = 1.7559(5), c = 1.94479(3. nm, α =91.263.14)°,(β = 102.559(6)°,γ= 106.3.9(13.°, Z = 4 and R = 0.0668. Two copper(Ⅱ) atoms are bridged by four (a-methacrylate groups, and each copper(Ⅱ) atom is coordinated with a trimethyl phosphate molecule in the axial position, forming a distorted square pyramidal configuration. The symmetric center is between the two copper(Ⅱ) atoms, and the Cu-Cu bond distance is 0.26098(6) nm. The Cu-Cu distance and magnetic studies suggest that there exist anti-ferromagnetic interactions between the two copper(Ⅱ) atoms.

关键词： copper(Ⅱ ) complex α β-unsaturated carboxylate trimethyl phosphate magnetic property crystal structure.

X-ray spectra induced by ^(129)Xe^(q+) impacting the metal surface

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Science china(phys.cs,Mechanics & Astronomy) 2008年第1期51卷 82-89页

作者： ZHANG XiaoAn 1,2 ,XIAO GuoQing 1 ,YANG ZhiHu 1 ,CHEN XiMeng 3.,ZHAO YongTao 1 , LI FuLi 4 ,WANG Li 1,2 ,CUI Ying 3.,ZHANG HongQiang 3.&ZHAN WenLong 1 1Institute of modern phys.cs,Chinese Academy of Sciences,lanzhou {3.,china 2department of phys.cs,Xianyang Normal university,Xianyang 712000,china 3.5} of modern phys.cs,lanzhou university,lanzhou {3.,china 4department of Applied phys.cs,Xi’an Jiaotong university,Xi’an 710049,china 1. Institute of modern phys.cs Chinese Academy of Sciences Lanzhou 730000 China 2. department of phys.cs Xianyang Normal University Xianyang 712000 China 3. department of modern phys.cs Lanzhou University Lanzhou 730000 China 4. department of Applied phys.cs Xi’an Jiaotong University Xi’an 710049 China

Using the slow highly charged ions 129 Xe q+ (q=25,26,27;initial kinetic T0≤4.65 keV/a.u.)to impact Au surface,the Au atomic Mαcharacteristic X-ray spectrum is *** result shows that as long as the charge state of projectile is high enough,the heavy atomic characteristic X-ray can be effectively excited even though the incident beam is very weak(nA magnitude),and the X-ray yield per ion is in the order of 10-8and increases with the kinetic energy and potential energy of *** measuring the Au Mα-X-ray spectra,Au atomic N-level lifetime is estimated at about 1.3.×10-18s based on Heisenberg uncertainty relation.

关键词： slow highly charged ions characteristic X-ray level lifetime

Synthesis of 6-aryl substituted 3.(5'-phenyl-2H-tetrazole-2'-methylene)-S-triazolo[3.4-b]-1,3.4-thiadiazoles

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Chinese Journal of Chemistry 1995年第5期13卷 448-453页

作者： ZHANG, Zi-Yi ZOU, NingNational Laboratory of Applied Organic Chemistry, department of Chemistry, lanzhou university, lanzhou, Gansu {3., china National Laboratory of Applied Organic Chemistry Department of Chemistry Lanzhou University Lanzhou Gansu 730000 China

In this paper , 10 novel 6-aryl-3.(5'-phenyl-2H-tetrazole-2'-methylene)-S-triazolo[3. 4-b]-1,3.4-thiadiazoles have been synthesized by the condensation of 3.(5'-phenyl-2H-tetrazole-2'-methylene)-4-amino-5-mercapto-1,2,4-triazole with various aromatic carboxylic acids in the presence of phosphorus oxychloride. The structure of these compounds was determined by elemental analysis , UV, IR, 1H NMR and MS. Their spectral properties were also discussed.

关键词： S-triazolo[3.4-b]-1,3.4-thiadiazole synthesis spectral analysis

Synthesis and Efficiency of a SphericalMacroporous Epoxy-dicyandiamide ChelateResin for Preconcentrating and SeparatingTrace Au, Hg, Pd and Ru from Samples

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Chemical Research in Chinese Universities 2001年第2期17卷 168-174页

作者： GONG Bo-lin, LI Xue-qiang and WANG Feng-rong (department of Chemistry, Ningxia university, Yinchuan 750021, china) CHANG Xi-jun (department of Chemistry, lanzhou university, lanzhou 730000, china) Ningxia Univ Dept Chem Yinchuan 750021 Peoples R China lanzhou Univ Dept Chem Lanzhou 730000 Peoples R China

A novel spherical macroporous epoxy-dicyandiamide chelate resin was synthesized simply and rapidly from epoxy resin and used for the preconcentration and separation of trace amounts of Au (Ⅲ ), Hg (Ⅱ ), Pd (Ⅳ) and Ru (Ⅲ) ions from solution samples. The analyzed ions can be quantitatively concentrated by the resin at a flow rate of 2. 0 mL/min at pH 4, and can also be desorbed with 15 mL of 4 mol/L HCl + 0. 3.g thiourea from the resin column with recoveries of 96. 5%-99. 0%. After the chelate resin was reused for 7 times, the recoveries of these ions were still over 92%, and 400-1 000 times of excess of Fe(Ⅲ ), Al(Ⅲ ), Ni( II), Mn( Ⅱ ), Cr (Ⅲ ), Cu ( Ⅱ ), Cd (Ⅱ ) and Pb (Ⅱ ) caused little interference with the determination of these ions by an inductively coupled plasma optical emission spectrometer (ICP-OES ). The capacities of the resin for the analytes are in the range of 0. 3.~0. 92 mmol/g. The RSDs of the proposed method are in the range of 1. 1 % ~4. 0% for each kind of the analyzed ions. The recoveries of a standard added in real solution samples are between 96. 5% and 98. 5%, and the results for the analyzed ions in a powder sample are in good agreement with their reported values.

关键词： Concentration Separation Macroporous epoxy-dicyandiamide chelate resin Gold Mercury Palladium and ruthenium.

Discovery of bipinnatifid fronds of Protoblechnum contractum(Gu et Zhi)

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Chinese Science Bulletin 1999年第4期44卷 381-383页

作者： SUN Bainian and SHEN Guanglong department of Geology, lanzhou university, lanzhou 730000,{3. department of Geology, Northwest university, Xi’an 710069,{3. department of Geology Lanzhou University Lanzhou China department of Geology Northwest University Xi’an China

IN Permian floras of china, a dispute over the relationship among the Protoblechnum and other similar plants such as Compsopteris, Glenopteris and Supaia has been existing for a long time, and moreover it has not been completely solved up to now. Halle placed a few simple pinnate fronds from the Shihhotze Formation in the genus Protoblechnum and named them Protoblechnum Wongii Halle 70 years ago when he was studying the fossil plants from the Late Palaeozoic strata in Shanxi, china. He did not think forked or unforked fronds as an important dividing genus condition in discussing the distinction among Protoblechnum and other relative fossils. Zalessky alSO found some specimens similar to Chinese Protoblechnum while he studied the Permian fossil plants from Russia. However, he did not approve of

关键词： very over Discovery of bipinnatifid fronds of Protoblechnum contractum Gu et Zhi

A NEW CHARACTERIZATION OF NBU CLASS OF LIFE DISTRIBUTIONS WITH APPLICATION

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Journal of Systems Science & Complexity 2003年第2期16卷 222-228页

作者： LI Xiaohu (department of Mathematics, lanzhou university, lanzhou 730000,{3.) department of Mathematics Lanzhou University Lanzhou 730000 China

Assume an unreliable workstation performing jobs with a random service time, namely, it occasionally breaks down because of unexpected interruptions. As an interruption really occurs, the station is instantaneously repaired and the uncompleted job is restarted again from the beginning till a job is completed without being interrupted. The total service time is shown to be NBU if and only if the total time it takes to finish each job with interruptions is stochastically larger than that without them, irrespective of when and how the breakdowns occur. As an application, a nonparametric procedure is developed to test for the strict NBU property of the service time. Finally, some numerical simulations are presented as well.

关键词： NBU interruptions stochastically larger L-statistic