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Large second-order optical nonlinearities of s-triazine derivatives: View from micro molecules to macro crystals

Science china Chemistry 2005年第3期48卷 203-209页

作者： FANG Qi1, LEI Hong2, CUI Yuezhi3. HUANG Zhenli4, XUE Gang1 & YU Wentao1 1. State Key Laboratory of Crystal Materials, shandong University, jinan 250100, china 2. School of Information Science and {3., shandong University, jinan 250100, china 3. department of chemical engineering, light industry college of shandong, jinan 250100, china 4. Key Laboratory of Biomedical Photonics, Ministry of Education, Huazhong University of Science and Technology, Wuhan 43.074, china 1. State Key Laboratory of Crystal Materials Shandong University 250100 Jinan China 2. School of Information Science and engineering Shandong University 250100 Jinan China 3. department of chemical engineering Light Industry College of Shandong 250100 Jinan China 4. Key Laboratory of Biomedical Photonics Ministry of Education Huazhong University of Science and Technology 430074 Wuhan China

Three s-triazine derivatives have been synthesized and their structures been de-termined. These are Compound I: 2,4-dimethyl-6-(p-N,N-dimethylaminostyryl)-s-triazine (abbre-viated to NMe-1), Compound II: 2,4-dimethyl-6-(p-N,N-diethylaminostyryl)-s-triazine (to NEt-1), and Compound III: 2-methyl-4,6-bis(p-N,N-dimethylaminostyryl)-s-triazine (NMe-2). NMe-1 and NEt-1 molecules belong to the D-π-A type with a one-dimensional charge-transfer character. NMe-1 crystallizes to centrosymmetric P1 space group, while NEt-1 to non-centrosymmetric polar Cc space group with all of the molecular charge-transfer axes taking the same orientation. Under the irradiation of 1064 nm fundamental laser, NEt-1 powder crystals radiate a 2-order harmonic light with an intensity 46.8 times that of urea. The Λ typed NMe-2 molecule, which has a two-dimensional charge-transfer character, crystallizes to polar P21 space group. Its powder crystals exhibit a 2-order harmonic intensity 46.2 times that of urea. The quantum chemical cal-culations and tensor analyses have been carried out to reveal the dependence of the macro 2-order nonlinear optical (NLO) efficiency on the micro 2-order NLO coefficients (β) and on the crystalline packing styles.

关键词： s-triazine derivatives, synthesis, structure, SHG intensities of crystals, βvalues of molecules.

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The Isomeric Structures of H_2GeLiF, the Prototype Germylenoid

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Chinese chemical Letters 1999年第6期10卷 511-514页

作者： Hua Yu QIU Wan Yong MA Guan Bin LI Cong Hao DENG (department of chemical engineering. {3. Institute of light industry. jinan 250100 Institute of Theoretical Chemistry. {3. University, jinan 250100) shandong Inst light Ind Dept Chem Engn Jinan 250100 Peoples R China shandong Univ Inst Theoret Chem Jinan 250100 Peoples R China

The structures of four isomeric forms of the model germylenoid, H2GeLiF. have been examined by ah initio MO theory. The most stable structure is suggested to be the p-complex *** other three species. three-membered ring 2, δ-complex 3.and tetrahedron 4. are also local minima on the potential energy surface. but are higher in energy.

关键词： Germylenoid p-complex ab initio

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Sensitized Luminescence of Rare Earths

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chemical Research in Chinese Universities 1996年第1期12卷 10-15页

作者： SI Zhi-kun HU Jing-tian JIANG Wei and ZHU Gui-yun(department of Chemistry, shandong University, jinan, {3.)LI Shu-hua(department of Basic Courses, shandong Institute of light industry, jinan, {3.) shandong UNIV DEPT CHEMJINAN 250100PEOPLES R CHINA shandong INST light IND DEPT BASIC COURSESJINAN 250100PEOPLES R CHINA

The enhancement effect on the fluorescence intensities of an Eu3. (or/and Sm3. )-thenoyltrifluoroacetone (TTA )-dibenzo-18-crown-6 (18-C-6 ) system and Eu 3. (or /and Sm3. ) -benzoyltrifluoroacetone (BTA )-cetyltrimethylammonium bromide (CTMAB) system by dysprosium has been studied. In the presence of enhancing ions, the fluorescence intensities of the above systems were enhanced by a factor of about 40-150, respectively. The above systems were used for the determination of europlum or/and samarium in rare earths oxides and gave satisfactory results.

关键词： Sensitized luminescence Rare earths Fluorescence

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The extension of the first main theorem for π-blocks

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Science china Mathematics 2006年第5期49卷 620-625页

作者： HAI Jinke department of Mathematics, Qingdao University, Qingdao 266071, china college of mathematics ,{3. University, jinan 250100, china department of Mathematics Qingdao University Qingdao 266071 China college of mathematics Shandong University Jian 250100 China

Let π be a set of primes and G a π-separable group. Isaacs defines the Bπ characters, which can be viewed as the "π-modular" characters in G, such that the Bp′ characters form a set of canonical lifts for the p-modular characters. By using Isaacs' work, Slattery has developed some Brauer's ideals of p-blocks to the π-blocks of a finite π-separable group, generalizing Brauer's three main theorems to the π-blocks. In this paper, depending on Isaacs' and Slattery's work, we will extend the first main theorem for π-blocks.

关键词： π-block, π-separable group, π-regular classes, defect group.

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OSCILLATION　FREQUENCY　THEORY　OF　A　PIEZOELECTRIC　SENSOR　INLIQUID　PHASE　WITH　TWO　SEPARATED－ELECTRODES

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Chinese chemical Letters 1996年第2期7卷 169-172页

作者： Da Zhong SHEN Ze Chang LIU Qing KANG Jind Tian HU(Chemistry college, shandong University, jinan, {3.)(chemical engineering department, jinan Branch of shandong Institute of Mining and Technology, jinan, 28003.) shandong UNIV CHEM COLLJINAN 250100PEOPLES R CHINA SHANGHAI INST MIN & TECHNOL DEPT CHEM ENGNJINAN 250031PEOPLES R CHINA

In this paper, an oscillation frequency equation for a pizoelectric sensor with two separated-electrodes is theoretically derived and experimentally verified. The correlatione of the oscillation frequency and the liqu... 详细信息

关键词： SENSOR FREQUENCY INLIQUID OF OSCILLATION PHASE PIEZOELECTRIC ELECTRODES SEPARATED THEORY

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Oscillation Conditions for An Electrode-separated Piezoelectric Sensor in Electrolyte Solution

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chemical Research in Chinese Universities 1996年第1期12卷 22-31页

作者： SHEN Da-zhong(Chemistry college, shandong University, jinan, {3.)KANG Qi(chemical engineering department, jinan Branch of shandong Institute of Mining and Technology, jinan, 25003. )YAO Shou-zhuo(New Material Institute, Hunan University, Changsha, 4100 shandong UNIV COLL CHEMJINAN 250100PEOPLES R CHINA INST MIN & TECHNOL DEPT CHEM ENGNJINAN 250031PEOPLES R CHINA HUNAN UNIV NEW MAT INSTCHANGSHA 410082PEOPLES R CHINA

Based on the needs of the oscillation equation and frequency stability, three oscillation conditions are proposed and have been experimentally verified for an electrode-separated piezoelectric sensor (ESPS ) in electrolyte solutions. The present paper covers the dependence of the minimum cell constant needed for the ESPS on solution conductivity. The oscillation conditions of the classical liquid piezoelectric sensor are discussed. The 'cease-to-oscillate' frequencies of the ESPS were measured.

关键词： Piezoelectric sensor Quartz crystal Cell constant Conductivity

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Mathematic Expression of Kinetic Compensation Effect and Relationship between the Exothermic Decomposition Temperature and Critical Temperature of Thermal Explosion of Eighty-six Energetic Materials

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含能材料 2001年第1期9卷 8-9页

作者： HU Rong zu 1, YANG De suo 2, ZHANG Jiao qiang 3. (1. department of Chemistry,Northwest University, Xi′an 710065, china 2. department of Chemistry and {3. engineering, Baoji college of Arts and Science, Baoji 721007, china 3. department of 西北大学陕西西安 710065 宝鸡文理学院陕西 721007 西北工业大学陕西西安 710072

Two relationships are established using the least squares method,between the kinetic parameters (the apparent activation energy and pre exponential constant),and the exothermic decomposition temperature and ther... 详细信息

关键词： critical temperature of thermal explosion decomposition temperature DSC energetic materials.

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Zeolite－Catalyzed　Friedel－Crafts　Acylation　of　Aromatics．Ⅳ．Nature　of　the　Active　Sites　of　Zeolites

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Chinese chemical Letters 1996年第9期7卷 841-844页

作者： Yu Dao MA Qi Long WANG Wei JIANG Be Jun ZUO and Qin QIU(department of Chemistry,shandong University,jinan {3..)(department of Environmental engineering, shandong University,jinan {3..) department of Chemistry Shandong University Jinan 250100 Dept. of Environmental engineering Shandong University Jinan 250100

For zeolite-catalyzed Friedel-Crafts acylation of aromatic rings,the Lewis acid sites were found to be active;while the Bronsted acid sites with moderate strength were found to be inactive.

关键词： Nature Aromatics the Active

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The Synthesis, Photoconductivity, Photoinduced Charge Transfer, and Other Properties of HEC-TCNQ

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Chinese chemical Letters 1997年第1期8卷 75-78页

作者： Qi FANG Hong LEI Dong XU Duo Rong YUAN(Institute of Crystal Materials, shandong University, jinan 250100department of Electronic {3., shandong University, jinan 250100) shandong UNIV INST CRYSTAL MATJINAN 250100PEOPLES R CHINA shandong UNIV DEPT ELECT ENGNJINAN 250100PEOPLES R CHINA

The donor-acceptor complex HEC-TCNQ (HEC = 9-hydroxyethylcarbazole; TCNQ = tetracyanoquinodimethane) has been synthesized. Under the illumination of Ar+ laser, the photoinduced charge transfer salt HEC(+)TCNQ(-) can b... 详细信息

关键词： HEC The Synthesis Photoconductivity Photoinduced Charge Transfer and Other Properties of HEC-TCNQ

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ZEOLITE－CATALYZED　FRIEDEL－CRAFTS　ACYLATION　OF　AROMATICS：I》．SYNTHESIS　OF　4－ACYL　ANISOLE　WITH　A　HY　CATALYST

引用

Chinese chemical Letters 1996年第2期7卷 99-102页

作者： Qi Long WANG Yu Dao MA Xing Dong JI Hao YAN(department of Chemistry,shandong University,jinan, {3.)and Qin QIU(department of Environmental engineering,shandong University.,jinan, {3.) department of Chemistry Shandong University Jinan 250100 China Dept. of Environmental engineering Shandong University Jinan 250100 China

A series of aromatic ketones 4-acyl anisole were synthesized with high yield by using carboxylic acids as acylating agents and a HY zeolite as catalyst.

关键词： HY CATALYST WITH ANISOLE ACYLATION ACYL

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