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Geomorphologic evidence of phased uplift of the northeastern Qinghai-Tibet Plateau since 14 million years ago

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science china Earth sciences 2004年第9期47卷 822-833页

作者： LU Huayu1, WANG Xiaoyong1, AN Zhisheng1, MIAO Xiaodong1, ZHU Rixiang3. MA Haizhou2. LI Zhen4, TAN Hongbing2.& WANG Xianyan1 1. state Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, chinese {2. of sciences, Xi’an 710075 china 2. Qinghai Institute of {3. lakes, chinese {2. of sciences. xining 810008, china 3. Institute of Geology and Geophysics, chinese {2. of sciences, Beijing 10002., china 4. Department of Geography, Qinghai Normal University, xining 810008, china chinese Acad sci Inst Earth Environm State Key Lab Loess & Quaternary Geol Xian 710075 Peoples R China chinese Acad sci Qinghai Inst Salt Lakes Xining 810008 Peoples R China chinese Acad sci Inst Geol & Geophys Beijing 100029 Peoples R China Qinghai Normal Univ Dept Geog Xining 810008 Peoples R China

A typical sequence of fluvial terraces and aeolian deposits overlying these ter- races were multidisciplinary investigated. New evidences for uplift process of the northeastern Qinghai-Tibetan Plateau in the past 14 million years were obtained. At least 11 river terraces along Huangshui, the first-class tributary of Yellow River, at the xining-Huzhu region are identi- fied. While the first one (T1) is classified as an accumulation terrace, the others are all basement river terraces, which consist of the Tertiary sandstone and siltstone bedrock, fluvial gravel and pebbles and the overlying aeolian loess-Red Clay deposit. samples from the aeolian deposits were examined for paleomagnetic stratigraphic reconstruction (103. samples), luminescence dating (16 samples), magnetic susceptibility and grain-size distribution (more than 4000 sam- ples). The luminescence dating and stratigraphic correlation suggest that terraces of Tll, T10, T8, T7, T3. T2. T1 were formed at 14, 11.3. 1.55, 1.2. 0.15, 0.07 and 0.01 million years ago, re- spectively. sedimentological analysis and geomorphological observation indicate that formation and evolution of these terraces were mainly driven by tectonic uplift. Therefore, the terrace se- quence provides an ideal geological record, of the uplift process of the northeastern during the past 14 million years, and the timings of the terraces formation are regarded as the timings of tectonic uplift. The significant uplifting events took place at 14, 11.3. 1.2.and 0.15 mil- lion years ago, respectively. The fluvial incision at the xining-Huzhu region is less than 100 m during a period of ~12.million years in the Miocene era (between the Tll and T9), while the Huangshui River had incised 43. m during the past 1.2.million years (from T7 to the present floodplain). The river incision process clearly demonstrates that accelerated rising of the north- eastern Qinghai-Tibet Plateau during the late Cenozoic, and provides new evidence of previous thoughts

关键词： river terrace, tectonic uplift, loess-Red Clay, the past 14 million years, northeastern Qinghai-Tibet Plateau.

Characteristics of chlorine isotope distribution and analysis on sylvinite deposit formation based on ancient salt rock in the western Tarim Basin

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science china Earth sciences 2005年第11期48卷 1913-1920页

作者： TAN Hongbing1,2. MA Haizhou1, XIAO Yingkai1, WEI Haizhen1,2. ZHANG Xiying1 & MA Wandong1 1. Institute of salt lakes, {2. {3. of sciences, xining 810008, china 2. Graduate school of the {2. {3. of sciences, Beijing 10003., china 1. Institute of salt lakes Chinese Academy of Sciences 810008 Xining China 2. Graduate school of the chinese academy of sciences 100039 Beijing China

During formation of the Tarim Basin, there repetitively happened seawater invasion for it was ever connected with wide Paleo-mediterranean sea. At the same time, for the applica-tion of tectonic and paleoenvironmental condition, the basin deposits many sequences of thick strata of evaporites, especially in its two largest subbasins of Kuqa in the north and shaqa in the southwest. Therefore, the western Tarim Basin has been considered to be a favorable location to prospect ancient sylvinite deposit. But it is unfortunate that the Br×103.Cl ratio, as a common geochemical index to uncover clues of sylvinite deposit, is almost invalid to indicate the stage of ancient brine condensation for very low content of bromine in salt rock samples (less than 10?6 commonly) in the western Tarim Basin evaporites. Fortunately, we noticed recently that the val-ues of chlorine isotope (δ 3.Cl value) for salt rock samples follow some clear laws from place to place, which in the shaqa subbasin, all δ 3.Cl values of salt rock samples behaved negatively and on the contrary, they all surprisingly showed positive values in the Kuqa subbasin. Based on conclusions of previous research and referring to the ratios of Br×103.Cl for salt rock or brine samples, we proved that the chlorine isotope (δ 3.Cl) could be used as an effective index to find ancient sylvinite deposit in those evaporites rock basin with low content of Br element back-ground, such as the Tarim Basin. Thus according to the new index of chlorine isotope, we con-clude that the concentration of ancient brines formed ancient salt rocks is much more concen-trated in the shaqa subbasin than that in the Kuqa subbasin. Particularly, the δ 3.Cl value of salt rock in Kashi depression of the western shaqa subbasin is greatly negative (s been concentrated to the terminal stage of salt deposit or even the later stage of sylvinite deposit. Then it is possible to find sylvinite-bearing d

关键词： the Tarim Basin, chlorine isotope, ancient salt rock, ancient sylvinite deposit, deposit stage

study on phase diagrams and properties of solutions in ternary systems Li+,K+(Mg2.)/sO42.-H2. at 2.℃

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chinese Journal of Chemistry 1995年第2期13卷 112-117页

作者： LI,Bing LI, Jun FANG, Chun-Hui WANG, Qing-Zhong sONG, Peng-shengQinghai Institute of salt lakes, {2. {3. of sciences, xining, Qinghai 810008, china sU.EDU Qinghai Institute of salt lakes Chinese Academy of Sciences Xining Qinghai 810008 China

solubilities of ternary systems Li+,K+/sO42.-H2. (1) and Li+,Mg2./sO42.H2. (2. were investigated by isothermal method at 2.℃. Physico-chemical properties of solutions, such as density, refractive index, viscosity, conductivity and pH, were determined. Phase diagram of the system (1) consists of three solubility branches and three crystallization fields corresponding to K2.O4, Li2.O4.H2. and LiKsO4. LiKsO4 is an incongruent compound, and its transition point is estimated graphically to be 45.5-46.0℃. No solid solution of LiKsO4 with Li2.O4.H2. was found in the system. The system (2. is a simple eutonic type. Pitzer model of electrolyte solution was used to check the obtained solubilities. Data comparison gives good agreement. Two equations were used to correlate density, refractive index of the solution with its composition. Differences between measured and calculated values are less than 0.6% for density, 0.15% for the latter.

关键词： salt-water system solubility of Li salt phase diagram.

Influence of Fly Ash and silica Fume on Water-resistant Property of Magnesium Oxychloride Cement

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Journal of Wuhan University of Technology(Materials science) 2010年第4期25卷 721-724页

作者：李成栋于红发 Qinghai Institute of salt lakes Chinese Academy of Sciences Graduate school of chinese academy of sciences Nanjing University of Aeronautics and Astronautics Department of Civil Engineering

By incorporation of fly ash or silica fume into magnesium oxychloride （MOC） cement, a high water resistance material can be formed for successful industrial applications. The influences of fly ash and silica fume on water-resistant property were investigated by sEM and EDs. It is found that the incorporation of fly ash or silica fume can improve the water-resistance of the MOC. The improvement of the water resistance of the MOC incorporated with fly ash or silica fume may be attributed to the alumino-silicate 5·1·8 gel or silicate 5·1·8 gel.

关键词： magnesium oxychloride cement fly ash silica fume water resistance

Thermodynamics of mixture of boric acid with lithium borate and chloride

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chinese Journal of Chemistry 1994年第2期12卷 97-104页

作者： WANG, Dong-Bao sONG, Peng-sheng The Institute of salt lakes, {2. {3. of sciences, xining, Qinghai 810008, chinaYANG, Jia-ZhenDepartment of Chemistry, Liaoning University, shenyang, Liaoning 11003., china 1The Institute of salt lakes Chinese Academy of Sciences Xining Qinghai 810008 China2Department of Chemistry Liaoning University Shenyang Liaoning 110036 China

The first thermodynamic dissociation constants of boric acid in aqueous solution of lithium chloride with borate at five different temperatures from 2.8.15 to 3.8.15 K were evaluated from emf values of the cell without liquid junction potential with the improved extrapolation and polynomial approximation on the basis of Pitzer's theory. Values obtained from both methods are in good agreement with each other. Pitzer's parameters β(0) and β(1) of LiB(OH)4 and other thermodynamic quantities of dissociation process of boric acid are obtained. Results have been discussed.

关键词： Thermodynamics boric aicd Pitzer's parameters.

An unusual isotopic fractionation of boron in synthetic calcium carbonate precipitated from seawater and saline water

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science china Chemistry 2006年第5期49卷 454-465页

作者： XIAO Yingkai1,2.LI shizhen1,WEI Haizhen1,sUN Aide1,ZHOU Weijian2.& LIU Weiguo2.1. Qinghai Institute of salt lakes,{2. {3. of sciences,xining 810008,china 2. state Key Laboratory of Loess and Quaternary Geology,Institute of Earth Environment,{2. {3. of sciences,Xi’an 710075,china 1. Qinghai Institute of salt lakes Chinese Academy of Sciences Xining 810008 China 2. state Key Laboratory of Loess and Quaternary Geology Institute of Earth Environment Chinese Academy of Sciences Xi’an 710075 China

Inorganic calcium carbonate precipitation from natural seawater and salinewater at various pH values was carried out experimentally. The results show the clear positiverelationships between boron concentration and δ^(11)B of inorganic calcium carbonate with the pH ofnatural seawater and saline water. However, the variations of boron isotopic fractionation betweeninorganic calcite and seawater/saline water with pH are inconsistent with the hypothesis thatB(OH)_4^- is the dominant species incorporated into the biogenic calcite structure. The isotopicfractionation factors a between synthetic calcium carbonate precipitate and parent solutionsincrease systematically as pH increases, from 0.9884 at pH 7.60 to 1.0072.at pH 8.60 for seawaterand from 0.982. at pH 7.60 to 1.0178 at pH 8.75 for saline water. An unusual boron isotopicfractionation factor of larger than 1 in synthetic calcium carbonate precipitated fromseawater/saline water at higher pH is observed, which implies that a substantial amount of theisotopically heavier B(OH)_3.species must be incorporated preferentially into synthetic inorganiccarbonate. The results propose that the incorporation of B(OH)_3.is attributed to the formation ofMg(OH)_2.at higher pH of calcifying microenvironment during the synthetic calcium carbonateprecipitation. The preliminary experiment of Mg(OH)_2.precipitated from artificial seawater showsthat heavier ^(11)B is enriched in Mg(OH)_2.precipitation, which suggests that isotopically heavierB(OH)_3.species incorporated preferentially into Mg(OH)_2.precipitation. This result cannot beapplied to explain the boron isotopic fractionation of marine bio-carbonate because of thepossibility that the unusual environment in this study appears in formation of marine bio-carbonateis infinitesimal. We, however, must pay more attention to this phenomenon observed in this study,which accidentally appears in especially natural environment.

关键词： boron, isotopic fractionation, calcium carbonate precipitate, seawater, saline water.

^(11)B and ~7Li NMR Investigations of the Oxysulfide Glasses in Li_2.-B_2._3.(-LiBr) systems

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chinese Chemical Letters 1998年第12期9卷 0-0,0-0页

作者： Hat Chun GAO Chan Gmin sUN and Yan HUO(Institute of salt lakes, {2. {3. of sciences, xining 810008)Zi Rong LI (Institute of Physics, {2. {3. of sciences, Beijing 100080) Institute of salt lakes Chinese Academy of Sciences Xining 810008 China Institute of Physics Chinese Academy of Sciences Beijing 100080 China

Phosphopeptides were synthesized with bis-alkyloxy-N,N-dialkylphosphorfollowed by oxidation. Many hydroxyl groups in oligopeptides can be O-phosphorylated in onestep.

关键词： Phosphopeptide phosphoramidite

Boron isotopic fractionation in laboratory inorganic carbonate precipitation:Evidence for the incorpora-tion of B(OH)_3.into carbonate

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science china Earth sciences 2008年第12期51卷 1776-1785页

作者： XIAO YingKai1,2. LI HuaLing1,3. LIU WeiGuo4, WANG XiuFang1 & JIANG shaoYong5 1 Qinghai Institute of salt {2., chinese {3. of sciences, xining 810008, china 2.state Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, chinese {3. of sciences, Guiyang 550002. china 3.Nanjing Institute of Geology and Mineral Resources, Nanjing 2.0016, china 4 state Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, chinese {3. of sciences, Xi’an 710075, china 5 state Key Laboratory for Mineral Deposits Research, Department of Earth sciences, Nanjing University, Nanjing 2.0093. china 1. Qinghai Institute of salt lakes Chinese Academy of Sciences Xining 810008 China 2. state Key Laboratory of Environmental Geochemistry Institute of Geochemistry Chinese Academy of Sciences Guiyang 550002 China 3. Nanjing Institute of Geology and Mineral Resources 210016 Nanjing China 4. state Key Laboratory of Loess and Quaternary Geology Institute of Earth Environment Chinese Academy of Sciences Xi’an 710075 China 5. state Key Laboratory for Mineral Deposits Research Department of Earth Sciences Nanjing University Nanjing 210093 China

A laboratory inorganic carbonate precipitation experiment at high pH of 8.96 to 9.3. was conducted, and the boron isotopic fractionations of the precipitated carbonate were measured. The data show that boron isotopic fractionation factors (αcarb-3. between carbonate and B(OH)3.in seawater range 0.93. and 0.965, with an average value of 0.953. Our results together with those reported by sanyal and collabo-rators show that the αcarb-3.values between carbonate and B(OH)3.in solution are not constant but are negatively correlated with the pH of seawater. The measured boron isotopic compositions of carbonate precipitation (δ11Bcarb) do not exactly lie on the best-fit theoretical δ 11B4-pH curves and neither do they exactly parallel any theoretical δ 11B4-pH curves. Therefore, it is reasonable to argue that a changeable proportion of B(OH)3.with pH of seawater should also be incorporated into carbonate except for the dominant incorporation of B(OH)4- in carbonate . Hence, in the reconstruction of the paleo-pH of sea-water from boron isotopes in marine biogenic carbonates, the use of theoretical boron isotopic frac-tionation factor (α4-3. between B(OH)4- and B(OH)3.is not suitable. Instead, an empirical equation should be established.

关键词： boron isotopic fractionation biogenic carbonate B(OH)3 incorporation

On-line parallel reversed phase two-dimensional liquid chromatography for high-throughput analysis of complex proteomic samples

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science china Chemistry 2006年第6期49卷 527-533页

作者： WANG Zhicong1,3. ZHANG Qinghe2. LI Tong2. ZHAO Zhongyi3.& ZHANG Weibing1 1. Dalian Institute of Chemical Physics, {2. academy of sciences, Dalian 116011, china 2. Dalian Elite Analytical Instrument Co., Ltd., Dalian 116011, china 3. Faculty of Material science and Chemical Engineering, china University of Geosciences, Wuhan 43.074, china 1. Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian 116011 China 3. Faculty of Material science and Chemical Engineering China University of Geosciences Wuhan 430074 China 2. Dalian Elite Analytical Instrument Co. Ltd. Dalian 116011 China

A comprehensive two-dimensional liquid chromatographic system (2. sCX/RP) is con- structed with a 10-port-2.way valve using strong cation exchange chromatography (Hypersil sCX, 100 mm×4.6 mm I.D.) followed by reversed phase chromatography (Hypersil BDs C18, 15 mm×4.6 mm I.D.) to separate the complex peptides from globin peptic hydrolysate. After the sample was loaded on the sCX column, the phosphate buffer (pH 4.0) was used to elute the peptides. Then, elutes flowed through the interface and the peptides focused on the head of the trapping columns (Hypersil BDs C18, 15 mm×4.6 mm I.D.) but salt passed into the waste. After the valve was switched, the samples were flushed with a backward flow into the RP analytical column. The peptides on the sCX were eluted with 12.discontinuous steps linearly increasing salt concentrations. The peptides enriched on the trapping column were desalted and separated by the RP columns. The resolution and the resolved peaks of the 2. sCX/RP system were greatly increased and the total peak capacity reached as high as 2.80.

关键词： two-dimensional liquid chromatography, interface, trapping column, proteomics, globin.