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Science china Chemistry 2007年第3期50卷 308-317页

作者： ZHANG Wen, ZHAO Fei, LIU Tao & GAO Song beijing National Laboratory for Molecular sciences, State Key Laboratory of Rare earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, peking university, beijing 100871, china beijing National Laboratory for Molecular sciences State Key Laboratory of Rare Earth Materials Chemistry and Applications College of Chemistry and Molecular Engineering Peking University Beijing China

A series of 1D nickel(II)/zinc(II)-lanthanide(III) coordination polymers, [M(μ-L)2Ln(NO3)3]n·solvents (HL = bis(2-pyridylcarbonyl)amine; M = Ni, Ln = Gd (1·NiGd), Tb (2·NiTb), Dy (3·NiDy), Ho (4·NiHo), Y (5·NiY); M = Zn, Ln = Gd (6·ZnGd), Tb (7·ZnTb), Dy (8·ZnDy), Ho (9·ZnHo); solvents = H2O or H2O-ethanol), was synthesized and characterized. All of the complexes are isostructural at 293 K and crystallize in the orthorhombic space group Fddd. Magnetic measurements were performed on 1―9, where weak ferromagnetic interaction is found in 1·NiGd, ferromagnetic interaction in 2·NiTb and 3·NiDy, and antiferromagnetic interaction in 4·NiHo. A remarkable dc magnetic field dependence of ac susceptibilities was found in this series of complexes.

关键词： nickel lanthanide 3d-4f coordination polymer magnetic property

Mantle xenoliths from Late Cretaceous basalt in eastern Shandong Province: New constraint on the timing of lithospheric thinning in eastern china

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Chinese Science Bulletin 2003年第19期48卷 2139-2144页

作者： YAN Jun, CHEN Jiangfeng, XIE Zhi & ZHOU Taixi school of earth and space sciences, university of Science and Technology of china, Hefei 230026, china school of earth and space sciences University of Science and Technology of China Hefei China

The age of the alkali basalt from Daxizhuang in Jiaozhou, eastern Shandong, was determined to be 73.5±0.3 Ma by 40Ar-39Ar technique. The basalt gave high eNd(t) values of +7.5 and +7.6, suggesting that the primitive magma was derived from depleted asthenospheric mantle with a formation depth of about 65—95 km. Spinel-lherzolite xenoliths have been discovered in the basalt. The Fo values of olivine from the xenoliths range from 88 to 89. The estimated equilibrium P-T conditions of spinel-lherzolite xenoliths are about 2.0 GPa and 1010—1140℃, suggesting an equilibrium depth of about 65 km. Geochemical characteristics of the Late Mesozoic (125—115 Ma) mantle-derived rocks in Shandong Province suggest an enriched lithospheric mantle along the southern margin of the North china block. However, geochemical characteristics of the Late Cretaceous basalts in Daxizhuang and the equilibrium P-T condition estimated from the xenoliths suggest that the lithosphere at 73 Ma ago was as thick as that of the Cenozoic in the region. Additionally, the xenoliths are rich in basaltic-component, suggesting a derivation from a newly-formed lithosphere. Therefor, lithospheric thinning took place at a time interval between about 120 and 73 Ma along the southern margin of the North china block.

关键词：覆盖捕虏岩白垩纪玄武岩山东东部地区岩石圈稀释化 ^40Ar-^39Ar技术

Sm-Nd and zircon SHRIMP U-Pb dating of Huilanshan mafic granulite in the Dabie Mountains and its zircon trace element geochemistry

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Science china earth sciences 2005年第12期48卷 2081-2091页

作者： HOU Zhenhui1, LI Shuguang1, CHEN Nengsong2, LI Qiuli1 & LIU Xiaoming3 1. school of earth and space sciences, university of Science and Technology of china, Hefei 230026, china 2. The Key Laboratory of Continental Dynamics of the Ministry of Education, Northwest university, Xi’an 710069, china 3. Faculty of earth sciences, china university of Geosciences, Wuhan 430074, china school of earth and space sciences University of Science and Technology of China Hefei China The Key Laboratory of Continental Dynamics of the Ministry of Education Northwest University Xi’an China Faculty of earth sciences China University of Geosciences Wuhan China

The mafic granulites from Huilanshan are outcropped on the center of the Luotian dome in the northern Dabie Mountains. The Sm-Nd isochron defined by granulite-facies meta-morphic minerals (garnet + clinopyroxene + hypersthene) yields an age of 136 ± 18 Ma indicating the early Cretaceous granulite-facies metamorphism. The cathodoluminescence (CL) images of zircons from the granulite show clearly core-mantle-rim structures. The zircon cores are charac-terized by typical oscillatory zoning and highly HREE enriched patterns, which suggests their magma origin. Some zircon cores among them with little Pb loss give SHRIMP U-Pb ages rang-ing from 753 to 780 Ma, which suggests that the protolith of Huilanshan granulite is Neopro-terozoic mafic rocks. The zircon mantles usually cut across the oscillatory zone of the zircon cores have 3―10 times lower REE, Th, U, Y, Nb and Ta contents than the igneous zircon cores but have high common Pb contents. These characteristics suggest that they were formed by hydrothermal alteration of the igneous zircons. The part of zircon mantles with little Pb loss give a similar SHRIMP U-Pb age (716―780 Ma) to the igneous zircon cores, which implies that the hydrothermal events occurred closely to the magmatic emplacement. In view of the strong early Cretaceous magmatism in the Luotian dome, consequently, the Huilanshan mafic granulite was formed by heating of the Neoproterozoic mafic rocks in mid-low crust, which caused the granu-lite-facies metamorphism underneath the Dabie Mountains. The similarity between the granulite metamorphic age (136 ± 18 Ma) defined by Sm-Nd isochron and K-Ar age of 123―127 Ma given by amphible from the gneiss in Luotian dome suggests a rapid uplifting of the Luotian dome, which may result in further exhumation of the ultrahigh pressure metamorphic rocks in the Dabie Mountains.

关键词： Dabie orogen, granulite, zircon U-Pb ages, Sm-Nd age.

The April 14th, 2010 Yushu earthquake, a devastating earthquake with foreshocks

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Science china earth sciences 2010年第6期53卷 791-793页

作者： NI SiDao1, WANG WeiTao2 & LI Li3 1 school of earth and space sciences, university of Science and Technology of china, Hefei 230026, china 2 Institute of Geophysics, china earthquake Administration, beijing 100081, china 3 National earthquake Infrastructure Service, china earthquake Administration, beijing 100036, china school of earth and space sciences University of Science and Technology of China Hefei China Institute of Geophysics China Earthquake Administration Beijing China National earthquake Infrastructure Service China Earthquake Administration Beijing China

In the early morning of April 14th, 2010, a strong earth- quake (Ms7.1, http://***; Mw6.9, http://neic. ***) occurred in Yushu district, Qinghai Province, china. More than 2000 lives were lost and over 100000 injured,

关键词： Figure Yushu earthquake a devastating earthquake with foreshocks The April 14th 2010 very than

A tentative study for the prediction of the CME related geomagnetic storm intensity and its transit time

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Science china(Technological sciences) 2005年第6期48卷 648-668页

作者： ZHAO Xinhua1,2 & FENG Xueshang1,3 1. SIGMA Weather Group, Key Laboratory of space Weather, Center for space Science and Applied Re-search, Chinese Academy of sciences, beijing 100080, china 2. Graduate school of the Chinese Academy of sciences, beijing 100039, china 3. school of Geophysics and Geoinformation Systems, china university of Geosciences, beijing 100083, china SIGMA Weather Group Key Laboratory of Space Weather Center for Space Science and Applied Research Chinese Academy of Sciences Beijing China Graduate school of the Chinese Academy of sciences Beijing China school of Geophysics and Geoinformation Systems China University of Geosciences Beijing China

Using 80 CME-ICME events during 1997.1―2002.9, based on the eruptive source locations of CMEs and solar magnetic field observation at the photosphere, a current sheet magnetic coordinate (CMC) system is established in order to study the propagation of CME and its geoeffectiveness. In context of this coordinate system, the effect of the eruptive source location and the form of heliospheric current sheet (HCS) at the eruptive time of CME on the geomagnetic storm intensity caused by CME and the CME’s transit time at the earth is investigated in detail. Our preliminary conclusions are: 1) The geomagnetic disturbances caused by CMEs tend to have the so-called “same side-opposite side effect”, i.e. CMEs erupt from the same side of the HCS as the earth would be more likely to arrive at the earth and the geomagnetic disturbances associated with them tend to be of larger magnitude, while CMEs erupting from the opposite side would arrive at the earth with less probability and the corresponding geomagnetic disturbance magnitudes would be relatively weaker. 2) The angular separation between the earth and the HCS affect the corresponding disturbance intensity. That is, when our earth is located near the HCS, adverse space weather events occur most probably. 3) The erupting location of the CME and its nearby form of HCS will also affect its arrival time at the earth. According to these conclusions, in this context of CMC coordinate we arrive at new prediction method for estimating the geomagnetic storm intensity (Dstmin) caused by CMEs and their transit times. The application of the empirical model for 80 CME-ICME events shows that the relative error of Dst is within 30% for 59% events with Dstmin≤?50 nT, while the averaged absolute error of transit time is lower than 10 h for all events.

关键词： coronal mass ejections, current sheet magnetic coordinate system, geomagnetic storm intensity, transit time, prediction method.

Re-Os(ICP-MS)dating of the massive sulfide ores from the Jinchuan Ni-Cu-PGE deposit

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Science china earth sciences 2005年第10期48卷 1672-1677页

作者： YANG Gang1,2, DU Andao1, LU Jiren3, QU Wenjun1 & CHEN Jiangfeng2 1. National Research Center of Geoanalysis, beijing 100037, china 2. Laboratory for earth Material Cycling, school of earth and space sciences, university of Science and Technology of china, Hefei 230026, china 3. Institute of Mineral Resource, Chinese Academy of Geological sciences, beijing 100037, china National Research Center of Geoanalysis university of Science and Technology of china Chinese Academy of Geological sciences

Massive sulfide ore from the Jinchuan Ni-Cu-PGE deposit was dated by Re-Os technique using Carius Tube digestion, Os distillation, Re extraction by acetone and ICP-MS measurement. An isochron giving an age of 833 ± 35 Ma, initial 187Os/188Os ratio of 0.279 ± 0.018 (MSWD = 1.7) and γOs = 130 ± 15 is obtained. The Re-Os age obtained agrees, within analytical uncertainties, with previous SHRIMP zircon U-Pb age of 827 ± 8 Ma (n=5, MSWD = 4.3). The result suggests that the deposit was formed at Neoproterozoic and that the formation of the Jinchuan Ni-Cu-PGE sulfide deposit may be closely related to the plume activity, which were attributed to the breakup of the Rodinia supercontinent. The high γOs of the massive ores sug-gests that crustal material was involved in the formation of the Jinchuan deposit, however, the quantity of the added crustal material is less than 10%.

关键词： Jinchuan Ni-Cu-PGE deposit, Re-Os dating, ICP-MS.

Neoproterozoic magmatic activity and global change

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Chinese Science Bulletin 2003年第16期48卷 1639-1656页

作者： ZHENG Yongfei school of earth and space sciences, university of Science and Technol-ogy of china, Hefei 230026, china (e-mail: yfzheng@***) school of earth and space sciences University of Science and Technology of China Hefei China

Neoproterozoic is a very important time in the history of the earth, during which occurred supercontinent breakup, low-latitude glaciation, and biotic diversification. These concern a series of interdisciplinary studies involving ancient plate motion, climate change and life evolution, re-sulting in many forefront topics of general interest in the earth sciences. These include exact ages bracketing the Cryogenian System and glaciations, initial age and lasted duration of supercontinent breakup, dynamic reconstruction of china continents in supercontinental configurations, the nature of rift magmatism and extent of hydrothermal altera-tion, paleoclimatic implication of water-rock interaction and low-18O magmatism, and relationship between superconti-nental evolution and global change. A number of outstanding advances in the above aspects have being made by Chinese scientists, leaving many important issues to be resolved: (1) did the Cryogenian start at either 800 to 820 Ma or 760 to 780 Ma? (2) was South china in the supercontinental con-figuration located in either southeast to Australia or north to India? (3) are Paleoproterozoic to Archean ages of crustal rocks a valid parameter in distinguishing North china from South china? Available observations suggest that Neopro-terozoic mantle superwelling occurred as conspicuous mag-matism in South china but as cryptical magmatism in North china. Mid-Neoproterozoic mantle superplume event and its derived rift-magmatism would not only result in the supercontinental demise, but also play a very important role in the generation and evolution of the snowball earth event by initiating the global glaciation, causing the local degla-ciation and terminating the snowball earth event.

关键词：原生代大陆断裂低纬度地区生物多样性板块运动气候变化生物进化大陆构架全球变化冰川

Framework and development of digital china

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Science china(Technological sciences) 2008年第S1期51卷 1-5页

作者： WU Lun & TONG QingXi Institute of Remote Sensing and Geographical Information Systems,peking university,beijing 100871,china Institute of Remote Sensing and Geographical Information Systems Peking University

Digital china (DC) has recently drawn much attention. It is a strategic project for china in response to the challenge of sustainable development of population,re-source,and environment. Intending to establish the national information infra-structure (NⅡ),the DC project forms a solid foundation for Chinese informatization. In such an NⅡ,multi-sourced spatial data are integrated. They focus on various themes and have different space and time features. Based on the NⅡ,numerous applications and services can be developed so that spatial information will benefit everyone. Since lots of organizations,such as governments,universities,and en-terprises,are involved in the implementation of DC,the DC project will significantly prompt the relevant scientific research as well as economic progress in china.

关键词： Digital earth Digital china spatial information sciences and technology

Commutators of pseudo-differential operators

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Science china Mathematics 2008年第3期51卷 453-460页

作者： LIN Yan school of Mathematical sciences, beijing Normal university, beijing 100875, china school of Mathematical sciences Beijing Normal University Beijing China

In this paper, the boundedness of commutators generated by pseudo-differential operators and BMO functions is discussed on Lebesgue spaces.

关键词： pseudo-differential operator BMO function commutator Lebesgue space 42B20 35S05 47G30

Numerical study of the role played by magnetic reconnection in solar wind origin

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Numerical study of the role played by magnetic reconnection ...