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Mn content of reservoir calcite cement: A novel inorganic geotracer of secondary petroleum migration in the tectonically complex Junggar Basin (NW china)

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Science china Earth Sciences 2007年第12期50卷 1796-1809页

作者： CAO Jian1,HU WenXuan1,YAO SuPing1,ZHANG YiJie2,WANG XuLong3,ZHANG YueQian3,TANG Yong3 & SHI XinPu3 1 State Key Laboratory for Mineral Deposit research,Department of Earth Sciences,Nanjing University,Nanjing 210093,china 2 research institute of exploration and development,petrochina,Beijing 100083,china 3 research institute of exploration and development,petrochina xinjiang oilfield company,karamay 834000,china State Key Laboratory for Mineral Deposit research Department of Earth Sciences Nanjing University Nanjing China research institute of exploration and development PetroChina Beijing China research institute of exploration and development PetroChina Xinjiang Oilfield Company Karamay China

Electronic probe microanalysis(EPMA) results of reservoir calcite cement from fourteen core samples in the Junggar Basin show that Mn-content varies largely between different samples from below the detect limitation to 4.14%,while it displays a generally good correlation with oil-gas ***,therefore,likely indicates that concentration of the Mn-content of the calcite cement has a close rela-tion to the intensity of petroleum fluid charging during hydrocarbon secondary *** order to assess this hypothesis,oxygen and strontium isotopic measurements on sixteen calcite veins host in source sequences were carried out to investigate the feature of the oil-source petroleum *** results imply that during hydrocarbon generation and migration,deep hot fluid has dissolved volcanic minerals interlined between mudstone source *** Mn is a kind of typical trace element enriched in volcanic rocks,it is reasonable to conclude that the petroleum fluid formed in the source sequences would be ***,calcite cements precipitated from such Mn-rich petroleum fluid would be Mn-rich *** to the geologic chromatographic effect during migration along reservoir rocks,the decreasing of the Mn-content of the reservoir calcite cements indicates the migration ***,this novel geotracer was further successfully applied in the study of hydrocarbon migration in the Junggar Basin in combination with organic geochemical analyses during the hydrocarbon *** Mn content of the reservoir calcite cement appears promising as a novel inorganic geotracer for the petroleum *** paper represents a search for novel indicators of secondary petroleum migration in tectonically complex basins based on fundamentals of the reservoir fluid-rock interactions.

关键词： Petroleum migration, inorganic geochemistry, water-rock interaction, reservoir calcite cement, the Junggar Basin

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Detection of water in petroleum inclusions and its implications

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Science Bulletin 2006年第12期51卷 1501-1507页

作者： CAO Jian1, YAO Suping1, HU Wenxuan1, ZHANG Yijie2, WANG Xulong3, ZHANG Yueqian3 & TANG Yong3 1. State Key Laboratory for Mineral Deposit research, Department of Earth Sciences, Nanjing University, Nanjing 210093, china 2. research institute of exploration and development, petrochina, Bei- jing 100083, china 3. research institute of exploration and development, xinjiang oilfield company, petrochina, karamay 834000, china State Key Laboratory for Mineral Deposit research Department of Earth Sciences Nanjing University Nanjing China research institute of exploration and development PetroChina Beijing China research institute of exploration and development Xinjiang Oilfield Company PetroChina Karamay China

FTIR spectra of inclusions sampled from fault-zone reservoirs of the northwestern Junggar Basin show that water, with different abundances, does exist in petroleum inclusions. It is thus implied that petroleum inclusions can seldom form without water. Different inclusions hosted in one single grain, and formed in one oil charging phase, have a largely varied ratio of water to oil and slightly changed CH3/CH2 ratio. This likely provides evidence for fault-related episodic migration and accumulation of hydrocarbons.

关键词： water in petroleum inclusions forming mechanism of inclusions episodic migration and accumulation of hydrocarbons FTIR microspectroscopy Junggar Basin.

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Timing and history of marine hydrocarbon accumulation in Tarim craton

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Chinese Science Bulletin 2002年第S1期47卷 120-127页

作者： ZHAO Jingzhou~(1,2) & LI Qiming~3 1. Department of Petroleum Geology, Xi’an Petroleum institute, Xi’an 710065, china 2. research institute of Petroleum exploration and development, petrochina, Beijing 100083, china 3. Tarim oilfield company, Kuerle, xinjiang 841000, china Department of Petroleum Geology Xi’an Petroleum Institute Xi’an China research institute of Petroleum exploration and development PetroChina Beijing China Tarim oilfield company Kuerle Xinjiang China

Based on the analyses of hydrocarbon inclu-sions, K-Ar dating of authigenic illites and oil/gas-watercontact retrospection as well as other methods, the marineprimary reservoirs in the cratonic region of the Tarim Basinare found to have been formed in the late Caledonian toearly Hercynian, late Hercynian, and Himalayan, and oil andgas adjusted and redistributed in the Yanshanian (Jurassic toCretaceous) and Himalayan (Tertiary). The analyses alsoshow that the remaining primary oil accumulations aremostly formed in the late Hercynian, and the secondary oilreservoirs resulted from the adjustment and redistribution ofthe earlier accumulations during the Yanshanian and Hima-layan (especially late Himalayan), of which the Himalayan isalso the major stage of gas accumulation. The primary oilreservoirs formed in the late Hercynian mostly occur withinthe Paleozoic formation, whereas the secondary reservoirsformed in the Himalayan in the Mesozoic. The late adjust-ment and redistribution of reservoirs in the craton region ofthe Tarim Basin is ubiquitous because of the intensified tec-tonic movements since the Mesozoic, especially Cenozoic andintrusion of the high- to over-mature gas. Furthermore, thelower amplitude of reservoirs in the craton region also makesthem easier to be adjusted and redistributed. Therefore, theremaining paleo-uplift and palaeo-slope developed in rela-tively stable tectonic regions are the main potential areas forthe middle-large marine reservoirs in the Tarim Basin.

关键词： Tarim Basin craton geochronology of hydrocarbon accumulation history of hydrocarbon accumulation marine reservoir primary reservoir secondary reservoir.

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Geochemical characteristics and accumulation of marine oil and gas around Halahatang depression,Tarim Basin,china

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Science china Earth Sciences 2008年第S1期51卷 195-206页

作者： LU YuHong,XIAO ZhongYao,GU QiaoYuan&ZHANG QiuCha research institute of exploration and development,Tarim oilfield company,petrochina,Korla 841000,china research institute of exploration and development Tarim Oilfield Company PetroChina Korla China

There exists a petroleum system rich of oil and gas around Halahatang depression,where the oil and gas possess obvious local distinctions of properties in different *** research proved that the discovered crude oil and natural gas in the region derived mainly from O2+3 source rock,and the differences of its properties were controlled by the oil and gas filling *** comprehensive study result shows the oil and gas reservoirs of the region mainly underwent three important accumulation phases:late Caledonian-Early Hercynian epoch,late Hercynian epoch,and Yanshan-Himalayan epoch. In the first phase,the oil and gas derived mostly from Cambrian source rock,which formed the primary ancient oil reservoirs,then suffered strong degradation and remained a great quantity of pyrobitumen in the high position of Tabei uplift in the *** the second phase,the O2+3 source rock of Manjia'er depression started its generation of hydrocarbon,which accumulated in the high position of Tabei uplift afterwards,and then biodegradated to heavy oil in the late Hercynian *** the last phase,the O2+3 source rock of southern Halahatang depression and margin of Manjia'er depression started its peak of generating liquid hydrocarbon,which mostly accumulated in the trap formed before the Indo-china and Yanshan epoch,and in somewhere the heavy oil suffered dilutions in various degrees or serious gas invading,to lead to obvious crude oil divergence.

关键词： marine facies Mid-Upper Ordovician source rock oil and gas source accumulation stage Halahatang depression Tarim Basin

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Characteristics,genesis and accumulation history of natural gas in Hetianhe gasfield,Tarim Basin,china

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Science china Earth Sciences 2008年第S1期51卷 84-95页

作者： WANG ZhaoMing 1 ,WANG QingHua 1 ,ZHAO MengJun 2 ,LI Yong 1 &XU ZhiMing 3 1 Tarim oilfield company,petrochina,Kuerle 841000,china 2 research institute of Petroleum exploration&development,petrochina,Beijing 100083,china 3 Southwest Petroleum institute,Nanchong 637001,china Tarim oilfield company PetroChina Kuerle China research institute of Petroleum exploration & development PetroChina Beijing China Southwest Petroleum institute Nanchong China

Hetianhe gasfield in Bachu region of the Tarim Basin is mainly composed of three reservoir-caprock assembly,namely regional caprock of upper mudstone,middle mudstone and lower mudstone of the Carboniferous and reservoir of Bachu bioclastic limestone,glutenite and the Ordovician carbonate buried *** gas in Hetianhe gasfield sourced from the Cambrian source *** is thought that gases in Ma4 well block in the east of Hetianhe gasfield are mainly crude-oil cracked gases,while those in Ma3 and Ma8 well blocks in the west are the mixture gases of kerogen cracked gases and crude-oil cracked *** gas is rich in H2S and accumulated in multiply stages as the result of *** accumulation history is divided into three stages,namely accumulation and breakage in the late Caledonian-early Hercynian,migration and dissipation in the late Hercynian and accumulation in Himalayan. The main accumulation of reformed gas reservoir is in Himalayan.

关键词： gas characteristics gas genesis accumulation history Hetianhe gasfield Tarim Basin

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Geochemical characteristics and origin of gases from the Upper,Lower Paleozoic and the Mesozoic reservoirs in the Ordos Basin,china

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Science china Earth Sciences 2008年第S1期51卷 183-194页

作者： HU AnPing 1 ,Li Jian 2 ,ZHANG WenZheng 3 ,LI ZhiSheng 2 ,HOU Lu 4 &LIU QuanYou 5 1 Department of Earth Sciences,Zhejiang University,Hangzhou 310027,china 2 Langfang Branch,Reasearch institute of Petroleum exploration and development,petrochina,Langfang 065007,china 3 institute of exploration and development,petrochina Changqing oilfield company,Xi’an 710021,china 4 University of Petroleum,Beijing102249,china 5 petrochina research institute of Petroleum exploration and development,Beijing 100083,china Department of Earth Sciences Zhejiang University Hangzhou China Langfang Branch Reasearch Institute of Petroleum Exploration and Development PetroChina Langfang China institute of exploration and development PetroChina Changqing Oilfield Company Xi’an China University of Petroleum Beijing China petrochina research institute of Petroleum exploration and development Beijing China

The Ordos Basin,the second largest sedimentary basin in china,contains the broad distribution of natural gas *** far,several giant gas fields have been discovered in the Upper and Lower Paleozoic in this basin,each having over 1000×10 8 m 3 of proven gas reserves,and several gas pools have also been discovered in the *** paper collected the data of natural gases and elucidated the geochemical characteristics of gases from different reservoirs,and then discussed their *** hydrocarbons preserved in the Upper Paleozoic,the elevatedδ13C values of methane,ethane and propane indicate that the gases would be mainly coal-formed gases;the singular reversal in the stable carbon isotopes of gaseous alkanes suggests the mixed gases from humic sources with different *** the Lower Paleozoic,theδ13C 1 values are mostly similar with those in the Upper Paleozoic,but theδ13C 2 andδ13C 3 values are slightly lighter,suggesting that the gases would be mixing of coal-type gases as a main member and oil-type *** are multiple reversals in carbon isotopes for gaseous alkanes,especially abnormal reversal for methane and ethane(i.e.δ13C 1 >δ13C 2 ),inferring that gases would be mixed between high-mature coal-formed gases and oil-type *** the Mesozoic,the δ13Cvalues for gaseous alkanes are enriched in 12C,indicating that the gases are mainly derived from sapropelic sources;the carbon isotopic reversal for propane and butane in the Mesozoic is caused by microbial oxidation and mixing of gases from sapropelic sources with different *** contrast to the Upper Paleozoic gases,the Mesozoic gases are characterized by heavier carbon isotopes of iso-butane than normal butane,which may be caused by gases generated from different kerogen types. Finally,according toδ13C 1 -Ro relationship and extremely low total organic carbon contents,the Low Paleozoic gases would not be generated from the Ordovician source as a main gas source,bycontrast, the Upper Pale

关键词： Ordos Basin natural gas chemical composition carbon isotope genesis

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Depositional characteristics and petroleum geological significance of wetland

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Petroleum Science 2009年第4期6卷 347-353页

作者： Jin Zhenkui Gu Junfeng Su Nina Wang Zhaofeng Huang Xiaoping State Key Laboratory of Hydrocarbon Resources and exploration China University of PetroleumBeijing 102249China research institute of Petroleum exploration and development Xinjiang Oilfield CompanyPetroChinaKaramayXinjiang 834000China

Wetland is a new type of sedimentary facies proposed for the first time in this paper. It is a type of sedimentary environment, transitional between land facies and water (sea or lake) facies. In this paper, wetland is redefined as “a type of sedimentary environments whose ground surface is flat and wet throughout the year, which may be covered with very shallow water (less than 2 m deep), and is covered with lush plant growth”. Wetland is reclassified into two types, swamp wetland (swamp in brief) and wet plain wetland (wet plain in brief). Swamp deposits are coal, while wet plain deposits are dark colored mudstones or silty mudstones rich in plant fossils and carbon debris. The deposits of wet plain are different from those of lake and floodplain in the abundance of plant fossils, color, resistivity well logging curve, and other sedimentary characteristics. In boreholes, resistivity logging can be used to distinguish between wet plain mudstones and lake mudstones. Understanding the sedimentary characteristics of wet plain wetland can help to identify wet plain deposits which were formerly classified as floodplain or lake deposits. This will help to reconstruct the palaeogeography and to understand the history of basin and climate evolution accurately, and is especially important in evaluation of the hydrocarbon generating potential of a basin. With the Jurassic Sangonghe Formation of the Yanqi Basin as an example, the identification characteristics of wetland are described.

关键词： Wetland wet plain Yanqi Basin Sangonghe Formation of Jurassic braided river delta

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欠平衡钻水平井附加套管注气方式及关键技术

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石油学报 2011年第2期32卷 350-354页

作者：杨虎王利国王峥王磊中国石油新疆油田公司勘探开发研究院重庆科技学院中国石油新疆油田公司石油工程监督中心

充气欠平衡钻井技术应用于水平井或大斜度井,将是拓展欠平衡钻井应用领域的重要方向之一。目前注气方式主要是钻柱注气和环空注气。采用钻柱注气方式,常规井下动力钻具和泥浆脉冲随钻测量工具无法正常工作,而现有的环空注气方式(如寄生... 详细信息

充气欠平衡钻井技术应用于水平井或大斜度井,将是拓展欠平衡钻井应用领域的重要方向之一。目前注气方式主要是钻柱注气和环空注气。采用钻柱注气方式,常规井下动力钻具和泥浆脉冲随钻测量工具无法正常工作,而现有的环空注气方式(如寄生套管、双层套管),由于成本高,技术问题多,应用不够广泛。由此,结合欠平衡钻井和水平井的理论和实践,提出了附加套管环空注气方式,并针对其关键技术进行理论分析和论证。该注气技术克服了钻柱注气的特殊问题,形成一套实用的环空注气欠平衡钻水平井技术。

关键词：欠平衡钻井水平井注气方式套管新型套管头

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吐哈盆地台北凹陷水西沟群致密砂岩气成藏条件

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天然气工业 2011年第7期31卷 21-23,103页

作者：范谭广中国石油吐哈油田公司勘探开发研究院

吐哈盆地台北凹陷侏罗系水西沟群钻探发现较大规模的致密砂岩气藏,迫切需要在该区开展天然气成藏条件研究,寻找有利勘探区域。为此,从烃源条件、储层特征及分布等方面分析了该区2套主力产层(下侏罗统三工河组和八道湾组)的成藏条件,结... 详细信息

吐哈盆地台北凹陷侏罗系水西沟群钻探发现较大规模的致密砂岩气藏,迫切需要在该区开展天然气成藏条件研究,寻找有利勘探区域。为此,从烃源条件、储层特征及分布等方面分析了该区2套主力产层(下侏罗统三工河组和八道湾组)的成藏条件,结果认为:①该区煤系烃源岩品质好、厚度大,生气强度大,富气条件优越;②储层分布稳定,厚度大,物性致密,常规气藏形成条件欠佳,但能形成致密砂岩气藏;③气藏类型为"先成型"致密砂岩气藏,存在2种不同的成藏模式。通过评价生烃强度、储层发育程度、源储配置关系等指标,划分出托克逊、苏巴什—连木沁等8个致密砂岩气有利勘探区域,其中的高渗透带及构造有利部位是"甜点"有利分布区,整体勘探潜力大。

关键词：致密砂岩气气藏特点烃源岩储集层特征早侏罗世成藏模式勘探方向吐哈盆地

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Transition from platemargin to intraplate environment: Geochemistry of basalts in Paleogene Liaohe basin, northeastern china

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Science china Earth Sciences 2005年第12期48卷 2069-2080页

作者： WU Changzhi1, GU Lianxing1, REN Zuowei1,2, ZHANG Zunzhong1, CHEN Zhenyan2 & ZHAO Ming1 1. State Key Laboratory of Mineral Deposit research (Nanjing University), Department of Earth Sciences, Nanjing University, Nanjing 210093, china 2. exploration and development research institute of Liaohe oilfield Branch company, petrochina, Panjin 124010, china State Key Laboratory of Mineral Deposit research (Nanjing University) Department of Earth Sciences Nanjing University Nanjing China exploration and development research institute of Liaohe oilfield Branch company PetroChina Panjin China

Paleogene basalts from the Liaohe basin, northeastern china, are dominated by alkaline olivine basalts and olivine basalts. These basalts are generally enriched in high field strength elements (HFSE), depleted in large ion lithophile elements (LILE) and comparable to those of typical ocean island basalts (OIB). Positive anomalies of Ba, Sr and Zr with high Nb/U, U/Pb, Ce/Pb and Zr/Hf ratios imply that materials from an oceanic crust had been added to the mantle sources of the basalts. In addition, the basalts are generally depleted in Sr, Nd and Pb isotopes, indicating that an enriched mantle (EMI) and a depleted mantle (DM) sources were added to the OIB-like resource. Comprehensive research on lithosphere evolution and tectonic setting of the Liaohe basin and surrounding areas suggests that these basalts were derived by variable degrees of partial melt-ing from an upwelling asthenosphere mantle. Materials from an oceanic lithosphere were added to the source in company with Paleogene tectonic transition from platemargin to intraplate envi-ronment. Retreating and steepening of the subducting Pacific oceanic plate could be the main cause for the tectonic environment transition.

关键词： geochemistry, basalt, Paleogene, Liaohe basin, North china Block, eastern china.

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