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Effect of solution concentration on the structured order and optical properties of short-chain polyene biomolecules

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Science china(Physics,Mechanics & Astronomy) 2010年第9期53卷 1646-1650页

作者： OUYANG ShunLi1,2,SUN ChengLin1,2,ZHOU Mi1,2,LI DongFei2,WANG WeiWei1,2,QU GuanNan1,LI ZuoWei1,2,GAO ShuQin1 & YANG JianGe3 1 State Key Laboratory of Superhard Materials,jilin university,changchun 130012,china 2 college of Physics,jilin university,changchun 130023,china 3 The ordnance engineering Department,Air Force Aviation university,changchun 130022,china 1. State Key Laboratory of Superhard Materials Jilin University Changchun 130012 China2. College of Physics Jilin University Changchun 130023 China3. The ordnance Engineering Department Air Force Aviation University Changchun 130022 China

We have measured the Raman spectra and UV-Vis absorption spectra of linear polyene biomolecules(β-carotene and lycopene) in CS2 at low concentrations(10-6-10-10 mol/L).With decreasing concentration,all the carbon-carbon vibrations form a coherent mode in ordered β-carotene and lycopene due to extended π-conjugation that gives strong electron-phonon coupling,which leads to an anomalous experimental *** observed an extremely high Raman scattering cross section(RSCS) and the Raman activities in β-carotene and lycopene are characterized by intensive overtones and ***,the UV-Vis absorption bands become narrower.

关键词： molecular structured order Raman spectroscopy Raman scattering cross section

A two-dimensional study on natural convection and heat transfer in the enclosure with heat transfer and radiation coupled in natural convection

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Science china(Technological Sciences) 2010年第4期53卷 991-999页

作者： ZHAN NaiYan1,2,YANG Mo1 & XU PeiWei2 1 college of power engineering,university of Shanghai for Science and Technology,Shanghiai 200093,china 2 Department of Environmental engineering,jilin Architectural and Civil engineering Institute,changchun 130021,china 1. college of power engineering University of Shanghai for Science and Technology Shanghiai 200093 China2. Department of Environmental Engineering Jilin Architectural and Civil Engineering Institute Changchun 130021 China

Numerical investigation using SIMPLE algorithm with QUICK scheme for natural convection and heat transfer in the enclosure bounded by a solid wall and with heat transfer and radiation coupled in natural convection has been *** various parameters are:Rayleigh number(from 103 to 105),dimensionless conductivity of bounding wall(from 0 to 100),dimensionless wall thickness(from 0 to 0.6) and radiation emissivity of all surfaces(from 0 to 1).The results suggest that flow and heat transfer are influenced by *** is a dominant action on flow and heat *** increase of the thermal conductivity of wall,flow and heat transfer turn *** temperature distribution changes *** the thermal conductivity of wall is over a certain critical number,the increasing trend of flow and heat transfer may *** increase of enclosure wall thickness,flow and heat transfer turn *** the enclosure wall thickness is over a certain critical number,the flow and heat transfer will turn slow.

关键词： conduction natural convection radiation couple numerical simulation

Complete quantum circuit of Haar wavelet based MRA

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Chinese Science Bulletin 2005年第16期50卷 1796-1798页

作者： HE Yuguo1,2 & SUN Jigui1,3 1. college of Computer Science and Technology, jilin university, changchun 130012, china 2. Department of Computer Science and engineering, Beijing Institute of Technology, Beijing 100081, china 3. Key Laboratory of Computation and Knowledge engineering of Min-istry of Education, jilin university, changchun 130012, china college of Computer Science and Technology Jilin University Changchun 130012 China

Wavelet analysis has applications in many ar- eas, such as signal analysis and image processing. We pro- pose a method for generating the complete circuit of Haar wavelet based MRA by factoring butterfly matrices and con- ditional perfect shuffle permutation matrices. The factoriza- tion of butterfly matrices is the essential part of the design. As a result, it is the key point to obtain the circuits of I 2t ⊕ W ⊕ I 2n ? 2t ?2. In this paper, we use a simple means to de- velop quantum circuits for this kind of matrices. Similarly, the conditional permutation matrix is implemented entirely, combined with the scheme of Fijany and Williams. The cir- cuits and the ideas adopted in the design are simple and in- telligible.

关键词：量子计算量子算法量子电路 Haar微波 MRA

Preparation and Electrochemical Behaviors of AA-PEGMA Copolymer Film Electrode

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Chemical Research in Chinese Universities 2012年第1期28卷 156-161页

作者： Lü Xue and LIU Feng-qi college of Chemistry, jilin university, changchun 130012, P. R. china jilin Univ Coll Chem Changchun 130012 Peoples R China

A new kind of comblike copolymer film composed of acrylic acid-polyethylene glycol monomethyl ether acrylate copolymer（AA-PEGMA copolymer） was successfully synthesized to immobilize hemoglobin（Hb）. FTIR, UV-Vis and CD spectra suggest that Hb kept its original structure in the AA-PEGMA copolymer film without denaturation. A pair of well-defined, quasi-reversible cyclic voltammetric peaks at around –270 mV vs. saturated calomel electrode（SCE） for the Hb Fe（III）/Fe（II） redox couple was observed on the film-modified electrode in phos phate buffer solution（PBS, pH=7.0）. The formal potential of Hb/AA-PEGMA copolymer film-modified electrode is linearly dependent on solution pH with a slope of –46.3 mV/pH, illustrating that one-proton transfer was accompa nied with each electron transfer. Furthermore, the modified electrode displayed electrocatalytic response to the reduc tion of H2O2 with a linear range of 3.5―126 μmol/L and a detection limit of 1.17 μmol/L. In conclusion, the AA-PEGMA copolymer film was proved to be an excellent matrix for the immobilization and electrochemistry of proteins.

关键词： Copolymer film Hemoglobin Comblike polymer Electrochemical behavior

Using multi-matching system based on a simplified deformable model of the human iris for iris recognition

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Journal of Bionic engineering 2004年第3期1卷 183-190页

作者： MING Xing , XU Tao , WANG Zheng-xuan 1 2 3 1. college of Computer Science and Technology, Nanling Campus,jilin university, 5988 Renmin Street,changchun 130022, P. R. china 2. college of Mechanical Science and engineering, Nanling Campus,jilin university, 5988 Renmin Street, changchun 130022, P. R. china 3. college of Computer Science and Technology, Qianwei Campus,jilin university, 10 Qianwei Road, changchun 130012, P. R. china. jilin university jilin university jilin university

A new method for iris recognition using a multi-matching system based on a simplified deformable model of the human iris was proposed. The method defined iris feature points and formed the feature space based on a wavelet transform. In the matching stage it worked in a crude manner. Driven by a simplified deformable iris model, the crude matching was refined. By means of such multi-matching system, the task of iris recognition was accomplished. This process can preserve the elastic deformation between an input iris image and a template and improve precision for iris recognition. The experimental results indicate the va- lidity of this method.

关键词： iris recognition wavelet transform feature points deformable model

Investigation on Vibrational Spectra and Structures of 4-Mercaptopyridine Monomer and Its Dihydrate

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Chemical Research in Chinese Universities 2006年第1期22卷 90-93页

作者： CHENG Jian-bo 1,2 , XUE Wei-qing 1 , ZHAO Bing 1** , ZHANG Gang 3 and GONG Bao-an 2 1. Key Laboratory for Supramolecular Structure and Material of Ministry of Education, jilin university, changchun 130012, P. R. china 2. Science and engineering college of Chemistry and Biology, Yantai university, Yantai 264005, P. R. china 3. State Key Laboratory of Theoretical and Computational Chemistry, jilin university, changchun 130023, P. R. china [a]Key Laboratory for Supramolecular Structure and Material of Ministry of Education Jiln University Changchun 130012 P. R. China[b]Science and Engineering College of Chemistry and Biology Yantai University Yantai 264005 P. R. China[c]State Key Laboratory of Theoretical and Computational Chemistry Jiln University Changchun 130023 P. R. China

The optimized molecular structures and vibrational frequencies of 4-mercaptopyridine(4MPY) monomer and its dihydrate were studied by means of the density functional theory(DFT), viz. B3LYP method with the 6-311++G(d,p) basis set. On the basis of the calculations, the assignments of the vibrational spectra of the monomer and the dihydrate were performed, and so were investigated the changes in the structure and the vibrational spectrum of the dihydrate as well as the intermolecular force resulting in the formation of the dihydrate. The calculated results show that each of the water molecule planes is vertical to the pyridine ring plane in the dihydrate that is formed via the H-bonds between 4MPY and water molecules. Furthermore, the structure and the vibrational spectrum of 4MPY can be consi- derably affected by the water molecules.

关键词： 4MPY Dihydrate Vibrational spectra DFT Molecular structure

Properties of meso-tetrakis (4-n-alkanoyloxyphenyl) porphyrin liquid crystal Co and Ni complexes

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Science china Chemistry 2007年第4期50卷 488-493页

作者： LIU Wei1,2 & SHI TongShun2 1 college of Materials Science and engineering, Shandong university of Technology, Zibo 255049, china 2 Department of Chemistry, jilin university, changchun 130023, china 1. college of Materials Science and engineering Shandong University of Technology Zibo 255049 China 2. Department of Chemistry Jilin University Changchun 130023 China

Six series of meso-tetrakis (4-n-alkanoyloxyphenyl) porphyrin Co and Ni complexes (12 kinds) were reported. Nine of the compounds were found to exhibit liquid crystal properties and display a hexagonal columnar discotic columnar (Colh) phase. Molecular structure of all synthesized compounds was confirmed by IR, UV, MS, 1H NIVR, and elemental analysis. These liquid crystalline compounds have been studied by cyclic voltammetry, luminescence, and surface photovoltage spectroscopy.

关键词： porphyrin liquid crystal cyclic voltammetry luminescence surface photovoltage spectroscopy

Canonical Huffman code based full-text index

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Progress in Natural Science:Materials International 2008年第3期18卷 325-330页

作者： Yi Zhang a,b, Zhili Pei a, Jinhui Yanga, Yanchun Liang a, a college of Computer Science and Technology, jilin university, Key Laboratory of Symbol Computation and Knowledge engineering of the Ministry of Education, changchun 130012, china b Department of Computer Science, jilin Technology and Business college, changchun 130062, china college of Computer Science and Technology Jilin University Key Laboratory of Symbol Computation and Knowledge Engineering of the Ministry of Education Changchun 130012 China Department of Computer Science Jilin Technology and Business College Changchun 130062 China

Full-text indices are data structures that can be used to find any substring of a given string. Many full-text indices require space larger than the original string. In this paper, we introduce the canonical Huffman code to the wavelet tree of a string T[1. . .n]. Compared with Huffman code based wavelet tree, the memory space used to represent the shape of wavelet tree is not needed. In case of large alphabet, this part of memory is not negligible. The operations of wavelet tree are also simpler and more efficient due to the canonical Huffman code. Based on the resulting structure, the multi-key rank and select functions can be performed using at most nH0 + jRj(lglgn + lgn lgjRj)+O(nH0) bits and in O(H0) time for average cases, where H0 is the zeroth order empirical entropy of T. In the end, we present an efficient construction algorithm for this index, which is on-line and linear.

关键词： Full-text index Su?x automaton Canonical Hu?man code

NUMERICAL SIMULATION OF SLOSHING IN RECTANGULAR TANK WITH VOF BASED ON UNSTRUCTURED GRIDS

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Journal of Hydrodynamics 2010年第6期22卷 856-864页

作者： MING Ping-jian DUAN Wen-yang college of power and Energy engineering Harbin Engineering University Harbin 150001 China college of Shipbuilding engineering Harbin Engineering University Harbin 150001 China

A new method for sloshing simulation in a sway tank is present, in which the two phase interface is treated as a physical discontinuity, which can be captured by a well-designed high order scheme. Based on Normalized Variable Diagram （NVD）, a high order discretization scheme with unstructured grids is realized, together with a numerical method for free surface flow with a fixed grid. This method is implemented in an in-house code General Transport Equation Analyzer （ GTEA ） which is an unstructured grids finite volume solver. The present method is first validated by available analytical solutions. A simulation for a 2-D rectangular tank at different excitation frequencies of the sway is carried out. A comparison with experimental data in literature and results obtained by commercial software CFX shows that the sloshing load on the monitor points agrees well with the experimental data, with the same grids, and the present method gives better results on the secondary peak. It is shown that the present method can simulate the free surface overturning and breakup phenomena.

关键词： sloshing numerical simulation unstructured grid Volume Of Fluid (VOF)