检索结果-南通市图书馆

Study on H atoms diffusion and adsorption properties of MgH_2.V systems

science china(Technological sciences) 2008年第7期51卷 979-988页

作者： ZHOU DianWu1,2. LIU JinShui3 & PENG Ping3 1 State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body, Hunan University, changsha 410082. china 2.college of Mechanical and Automatic {2., Hunan University, changsha 410082. china 3 college of materials science and engineering, Hunan University, changsha 410082. china State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body Hunan University college of Mechanical and Automatic engineering Hunan University college of materials {2. and engineering

Based on experimental results that VH0.81/MgH2.interface was found during the process of mechanically milling MgH2.5at.%V nanocomposite, H atoms diffusion and adsorption properties of MgH2.V systems have been investigated by using a first-principles plane-wave pseudopotential method based on the density functional theory. The results are as follows. When VH/MgH2.interface is formed due to V alloying MgH2.phase, the vacancy formed by H atoms near VH phase region is more stable than that without V alloying, while vacancy near MgH2.phase region is less stable than that without V alloying. During the process of H atoms diffusion after V alloying, the max migration barrier energy of H atoms in MgH2.V systems is reduced compared with that of MgH2.phase, which means that H atoms diffuse easily. When H diffuses into VH from MgH2.across VH/MgH2.interface, among three substitutions such as the replacement of H for V vacancy, or interstitial site or V atoms, the replacement of H for V vacancy has the strongest diffusion ability, next interstitial site, and finally V atoms site. As far as H adsorbed on different surfaces of VH phase is concerned, physical adsorption is carried out more easily than chemical adsorption, and the behavior of H atoms adsorbed on the surface near VH phase region can be found more easily than that near MgH2.phase region.

关键词： plane-wave pseudopotential theory magnesium hydride diffusion adsorption

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Formation and evolution mechanisms of large-clusters during rapid solidification process of liquid metal Al

引用

science china(Physics,Mechanics & Astronomy) 2005年第1期48卷 101-112页

作者： LIU Rangsu, DONG Kejun, LIU Fengxiang, ZHENG Caixing, LIU Hairong & LI Jiyong Department of Applied Physics, Hunan University, changsha 410082. china college of {2. science and engineering, Hunan University, changsha 410082. china college of Chemistry and Chemical engineering, Hunan University, changsha 410082. china Department of Applied Physics Hunan University Changsha 410082 China college of materials {2. and engineering Hunan University Changsha 410082 China college of Chemistry and Chemical engineering Hunan University Changsha 410082 China

A molecular dynamics simulation study has been performed for the formation and evolution characteristics of nano-clusters in a large-scale system consisting of 400000 atoms of liquid metal Al. The center-atom method combined with pair-bond analysis technique and cluster-type index method (CTIM) has been applied here to describe the structural configurations of various basic clusters. It is demonstrated that both the 1551 bond-type and the icosahedral cluster (12.0 12.0) constructed by 1551 bond-types are dominant among all the bond-types and cluster-types, respectively, in the system and play a critical role in the microstructure transitions of liquid metal Al. The nano-clusters (containing up to 150 atoms) are formed by the combination of some middle and small clusters with distinctly different sizes, through mutual competition by unceasing annex and evolution in a seesaw manner (in turn of obtaining and losing),which do not occur as the multi-shell structures accumulated with an atom as the center and the surrounding atoms are arranged according to a certain rule. This is the essential distinction of nano-cluster in liquid metal from those obtained by gaseous deposition, ionic spray methods, and so on. Though the nano-clusters differ from each other in shape and size, all of them possess protruding corners that could become the starting points of various dendrite structures in the solidification processes of liquid metals.

关键词： liquid metal, solidification process, large-cluster configuration, evolution mechanism, computer simulation.

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Microstructure and formation mechanism of twins of laths of austenite with high nitrogen

引用

science china(Technological sciences) 2007年第6期50卷 755-764页

作者： WU CuiLan1,2.& LUO ChengPing2.1 Center for High Resolution Electron Microscopy, college of materials {2. and engineering, Hunan University, changsha 410082. china 2.college of Mechanical engineering, South china University of Technology, Guangzhou 510641, china Center for High Resolution Electron Microscopy College of Materials Science and Engineering Hunan University college of Mechanical engineering South China University of Technology

The microstructure of composite diffusion layer of the nitrided and chromized 0.2. carbon steel is investigated using TEM and EDS. It is found that laths of austenite with high nitrogen (γ N) precipitate from α-ferrite matrix in the deeper zone of the diffusion layer. These γ N laths are all twins, with their {111} twinning planes parallel to the lath axis, thus forming a characteristic "back-to-back" morphology. There are two types of γN lath. The first is a genuinely {111} twin, and γ N and α keep the accurate K-S relationship, and each γ N and α form a sharp and smooth γ N/α inter- face of {335}γN//{341}α, namely habit plane {335}fcc. The second is a pseudo-twin, with micro-twins {111} or faults formed within the two twin components. Localized lattice deformation (relaxation) seems to have occurred at the interfaces of the second type of γ N due to the formation of micro-twins or faults within the twin components. These micro-twins or faults make the orientation relationship (OR) between each of the γN and the α-matrix deviate from the accurate K-S OR, and the OR between two γ N twin components deviate from the genuine {111} twin relation- ship. In addition, the γ N/α interface of the second type of γ N is not as sharp or smooth as that of the first one.

关键词： austenite containing nitrogen, twins, steel 2., nitriding, composite chromizing

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Molecular dynamics simulation of thermal stability of nanocrystalline vanadium

引用

science china(Technological sciences) 2006年第4期49卷 400-407页

作者： WEI Mingzhi1, XIAO Shifang1, YUAN Xiaojian2.& HU Wangyu1,2.1. Material science and engineering {2., Hunan University, changsha 410082. china 2. Department of Applied Physics, Hunan University, changsha 410082. china Material science and engineering {2. Hunan University Department of Applied Physics Hunan University

The microstructure and thermal stability of nanocrystalline vanadium with an average grain size ranging from 2.86 to 7.50 nm are calculated by means of the analytic embedded-atom method and molecular dynamics. The grain boundary and nanocrystal- line grain atoms are differentiated by the common neighbor analysis method. The results indicate that the fraction of grain boundary increases with the grain size decreasing, and the mean energy of atoms is higher than that of coarse crystals. The thermal-stable tem- peratures of nanocrystalline vanadium are determined from the evolution of atomic energy, fraction of grain boundary and radial distribution function. It is shown that the stable tem- perature decreases obviously with the grain size decreasing. In addition the reasons which cause the grain growth of nanocrystalline vanadium are discussed.

关键词： nanocrystalline, embedded-atom method, molecular dynamics, thermal stability.

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Optimization of thermomechanical processes in Cu-Cr-Zr lead frame alloy using neural networks and genetic algorithms

引用

science china(Technological sciences) 2005年第5期48卷 510-520页

作者： SU Juanhua1,2. LIU Ping2. DONG Qiming2.& LI Hejun1 1. college of materials {2. and engineering, Northwestern Polytechnical University, Xi’an 710072. china 2. college of materials {2. and engineering, Henan University of {2. and Technology, Luoyang 471003, china college of materials {2. and engineering Northwestern Polytechnical University Xi’an China college of materials {2. and engineering Henan University of Science and Technology Luoyang China

The thermomechanical treatment process is effective in enhancing the properties of the lead frame copper alloy. In this study, an optimal pattern of the thermomechanical processes for Cu-Cr-Zr was investegated using an intelligent control technique consisting of neural networks and genetic algorithms. The input parameters of the artificial neural network (ANN) are the reduction ratio of cold rolling, aging temperature and aging time. The outputs of the ANN model are the two most important properties of hardness and conductivity. Based on the successfully trained ANN model, genetic algorithms (GA) are used to optimize the input parameters of the model and select perfect combinations of thermomechanical processing parameters and properties. The good generalization performance and optimized results of the integrated model are achieved.

关键词： Cu-Cr-Zr alloy, thermomechanical processing optimization, artificial neural network, genetic algorithms.

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

A new orthogonality relationship for orthotropic thin plate theory and its variational principle

引用

science china(Physics,Mechanics & Astronomy) 2005年第3期48卷 371-380页

作者： LUO Jianhui 1 , LONG Yuqiu 2.& LIU Guangdong 1 1. college of Civil engineering, Hunan University,{2. 2. Department of Civil engineering, Tsinghua University, Beijing 100084, china college of Civil engineering Hunan University Changsha China Department of Civil engineering Tsinghua University Beijing China

The thought how dual vectors are constructed in a new orthogonality relationship for theory of elasticity is generalized into orthotropic thin plate bending problems by using the analogy theory between plane elasticity problems and plate bending problems. Dual differential equations are directly obtained by using a mixed variables method. A dual differential matrix to be derived possesses a peculiarity of which principal diagonal sub-matrixes are zero matrixes. Two independently and symmetrically orthogonality sub-relationships are discovered. By using the integral form for elastic bending theory of orthotropic thin plate the orthogonality relationship is demonstrated. By selecting felicitous dual vectors a new orthogonality relationship for theory of elasticity can be generalized into elastic bending theory of orthotropic thin plate. By using the integral form a variational principle which is relative to differential form and a whole function expression are proposed.

关键词： theory of elasticity, thin plate theory, dual vectors, orthogonality relationship, orthotropic, variational principle.

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Research on Uncertainties in Evaluation Indicator System for Ecological Residential Community

引用

湖南大学学报（自然科学版） 2009年第S1期36卷 177-181页

作者： JIAO Sheng1,GUAN Chen-yin2.ZENG Guang-ming3,LIU Jian-long1,Zhou Jian-fei3(1.college of Architecture,Hunan University,changsha,Hunan {2.china 2.Beijin School,Hunan University of Commerce,changsha,Hunan 4102.9,china 3.college of Environmental science and engineering,Hunan University,changsha,Hunan {2.china) college of Architecture Hunan University Changsha 410082 China Beijin School Hunan University of Commerce Changsha 410209 China college of Environmental science and {2. Hunan University Changsha 410082 China

In the process of evaluating,the weights of indicators are firstly determined by AHP and Delphi methods;and the values of indicators are normalized by grey correlative coefficient method.A suit of means were put forward,by which a qualitative and quantitative evaluation indicator system suitable for the situation of china and uncertainties can be *** idiographic and operable methods and process were *** the principle of elasticity,hiberarchy and maneuverability,a three-layer evaluation indicator system was established by AHP in Jiuyi ecological residential community,which includes 5 subsystems and 2. *** weights of indicators are measured by AHP and expert estimate and their best indicators values up to par were determined by fuzzy mathematics and *** whole evaluation indicator system not only has an active and practical effect on estimating ecological residential community,but also guides ecological residential community planning.

关键词： ecological residential community evaluation indicator system ecological risk evaluation uncertainty fuzzy mathematics grey correlative coefficient

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Size distributions and magic number characteristics of cluster configurations formed during solidification processes of liquid metal Al

引用

science china(Technological sciences) 2006年第2期49卷 172-187页

作者： LIU Rangsu1, LIU Fengxiang1, DONG Kejun1, ZHENG Caixing1, LIU Hairong2. PENG Ping2.& LI Jiyong3 1. Department of Physics, Hunan University, changsha 410082. china 2. Department of Material science and {2., Hunan University, changsha 410082. china 3. Department of Chemistry, Hunan University, changsha 410082. china Department of Physics Hunan University

A molecular dynamics simulation study has been performed for a large systemconsisting of 100000 liquid metal Al atoms to investigate the formation and magic numbercharacteristics of the cluster configurations formed during the rapid solidification processes. Thecluster-type index method (CTIM) has been adopted to describe various types of clusterconfigurations. The results indicate that the icosahedral clusters (12.0 12.0) and theircombinations play the most important role in the rnicrostructure transitions during solidificationprocesses; for the cluster configurations of different levels formed by various combinations withdiffering numbers of basic clusters, their size distributions possess obvious magic number sequencewhich is in turn as 13(13), 19(2.), 2.-2.(2.), 32.33(32., 39-40, 43-44, 48..., (those in bracket arethe corresponding value in liquid state); the magic numbers correspond to the peak value positionsof the cluster numbers for corresponding level formed with various combinations by 1, 2. 3, 4, 5, 6,7, ...basic clusters, respectively. This magic number sequence is in good agreement with theexperimental results obtained by Harris et al. At the same time, this simulation study also gives ascientific and reasonable explanation to these experimental results.

关键词： liquid metal, solidification processes, cluster configuration, magic numbers, computer simulation.

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

One-pot synthesis of crystalline SnO_2.nanoparticles and their low-temperature ethanol sensing characteristics

引用

science china(Physics,Mechanics & Astronomy) 2009年第10期52卷 1601-1605页

作者： CHEN YuJin1,2.3,ZHU ChunLing4,WANG LiJiao3 & WANG TaiHong2.1 School of materials science and {2.,Beijing Institute of Technology,Beijing 100081,china 2.Micro-Nano Technologies Research Center,Hunan University,changsha 410082.china 3 college of science,Harbin {2. University,Harbin 150001,china 4 college of Material science and Chemical {2.,Harbin {2. University,Harbin 150001,china School of materials science and {2. Beijing Institute of Technology Beijing China Micro-Nano Technologies Research Center Hunan University Changsha China college of science Harbin Engineering University Harbin China college of Material science and Chemical {2. Harbin Engineering University Harbin China

Crystalline SnO2.nanoparticles(NPs) with a diameter less than 6 nm are synthesized using potassium stannate trihydrate as the precursor in a basic *** synthesized NPs can detect ethanol at a ppm level even at 100℃.Furthermore,the NPs have good selectivity to *** excellent ethanol sensing performances are attributed to the small size effect according to the space-charge model.

关键词： SnO2 nanoparticles sensing characteristics

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Synthesis and magnetic properties of CdS/α-Fe_2._3 hierarchical nanostructures

引用

science china(Physics,Mechanics & Astronomy) 2009年第7期52卷 997-1002页

作者： CHEN YuJin1,2.3, SHI XiaoLing1, CAO MaoSheng1 & ZHU ChunLing4 1 School of materials science and {2., Beijing Institute of Technology, Beijing 100081, china 2.Micro-Nano Technologies Research Center, Hunan University, changsha 410082. china 3 college of science, Harbin {2. University, Harbin 150001, china 4 college of Material science and Chemical {2., Harbin {2. University, Harbin 150001, china School of materials science and {2. Beijing Institute of Technology Beijing China Micro-Nano Technologies Research Center Hunan University Changsha China college of science Harbin Engineering University Harbin China college of Material science and Chemical {2. Harbin Engineering University Harbin China

CdS/α-Fe2.3 hierarchical nanostructures, where the CdS nanorods grow irregularly on the side surface of α-Fe2.3 nanorods, were synthesized via a three-step process. The diameters and lengths of CdS nanorods can be tuned by changing the ethylenediamine (EDA) and Cd ion concentrations. The magnetic investigations by superconducting quantum interference device indicate that the hierarchical nanostructures have an Morin transition at lower temperature (2.0 K) than that of the single bulk α-Fe2.3 materials (2.3 K). Importantly, the hierarchical nanostructures exhibit weakly ferromagnetic characteristics at 300 K. A sharp peak assigned to the surface trap induced emission are observed in room temperature PL spectra. Combining with the optoelectronic properties of CdS, the CdS/ α-Fe2.3 hierarchical nanostructures may be used as multi-functional materials for optoelectronic and magnetic devices.

关键词： α-Fe2.3 CdS hierarchical nanostructures magnetic properties

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：