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Laboratory research on Tahe AR Fluid Coking on Weak Acid Catalysts

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china Petroleum Processing & Petrochemical Technology 2011年第2期13卷 9-13页

作者： Wu Zhiguo Li Yanjun Shen Haiping(sinopec research {2. of Petroleum Processing,beijing 100083) sinopec Res Inst Petr Proc Beijing 100083 Peoples R China

Fluid coking on micro-spherical particles with acid sites on them could produce more light oils from Tahe *** conversion rate could increase by about 2.% on the catalyst B compared to that obtained on the catalyst A and the light oil yield could increase by about 12..The yield of gasoline and diesel was more than 50% from Tahe AR over the catalyst *** on acidity of the catalyst B by pyridine FT-IR spectrometry showed that the total acid content and the ratio of weak acid number to total acid number were higher than other catalysts.

关键词： fluid coking weak acid catalyst fixed fluidized bed Tahe AR

Carbon and hydrogen isotopic characteristics of natural gases from the Luliang and Baoshan basins in Yunnan Province, china

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Science china Earth Sciences 2006年第9期49卷 938-946页

作者： XU Yongchang1, LIU Wenhui2. SHEN Ping1, WANG Wanchun1, WANG Xiaofeng1, Tenger1, YAN Yaomin3 & LIU Ruobin3 1. Lanzhou Center of Oil & Gas Resources, institute of Geology and Geophsics, Chinese Academy of Sciences, Lanzhou 730000, china 2. {2. institute of Petroleum Exploration and production, sinopec, beijing 100083, china 3. South Branch of Petroleum Exploration and production Company, sinopec, Kuming 650000, china 1. Lanzhou Center of Oil & Gas Resources Institute of Geology and Geophsics Chinese Academy of Sciences Lanzhou 730000 China 2. research institute of Petroleum Exploration and {2. SINOPEC Beijing 100083 China 3. South Branch of Petroleum Exploration and production Company SINOPEC Kuming 650000 China

The Luliang and Baoshan basins of Yunnan Province are two small-sizedcontinental oil/gas-bearing sedimentary basins, which were developed at the bases of theCarboniferous and Devonian systems during the Late Tertiary, covering an area of 32. km^2.and 2.4km^2. respectively. Since the 1990s, there have been discovered small-sized natural gas pools inthese two basins. The natural gases are composed mainly of hydrocarbon gases, with nonhydrocarbonsaccounting for less than 2.. Of the hydrocarbon gases, methane accounts for more than 99%, and thecomponents above C_2.account for less than 0.2.. On the basis of previous studies of geologicalbackground, the composition of natural gases and their carbon isotopic composition, it has beendefined that these two gas pools are of bacterial origin. In this work we have comprehensivelymeasured the carbon and hydrogen isotopic composition of natural gases from these two basins andhave gone into the details of the mechanism of gas generation. The δ^(13)C_1 values of naturalgases from the Luliang Basin are within the range of -72.1 per thousand - -73.3 per thousand, andthe δD_(CH_4) values, -2.2.per thousand - -2.4 per thousand, indicating that the bacterial gasgeneration is dominated by the way of CO_2.reduction. It has been evidenced that undercontinental-facies fresh water conditions there did occur the CO_2.reduction as a process ofbacterial gas generation. The δ^(13)C_1 values of natural gases from the Baoshan Basin are withinthe range of - 62.5 per thousand - -63.5 per thousand, and the δD_(CH_4) values, -2.2.per thousand- -2.0 per thousand. These isotopic characteristics are fallen into transitional phase of acetatefermentation and CO_2.reduction as defined by Whiticar et al. (1986). An important discovery in theLuliang Basin is the carbon isotopic composition of ethane of purely biogenetic origin, i.e., itsδ^(13)C_2.values are within the range of - 61.2.per thousand - - 66.0 per thousand. These carbonisotopic values have been r

关键词： bacterial gas, carbon and hydrogen isotope, CO2 reduction, acetate fermentation.

research on C—C Bond Length Distribution in Hydrocarbon Molecules

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china Petroleum Processing & Petrochemical Technology 2010年第3期12卷 6-11页

作者： Liu Jun Long Jun He Zhenfu Dai Zhenyu (research institute of Petroleum Processing,{2.,beijing 100083) sinopec Res Inst Petr Proc Beijing 100083 Peoples R China

The C--C bond dissociation energy （BDE） is a very important data in research of hydrocarbon cracking reactions, because it reflects the difficulty level of chemical reactions. But it is very difficult to obtain the C--C bond dissociation energy （BDE） by experiments, so using quantum chemistry calculation such as density functional theory （DFT） to study the C--C bond dissociation energy is a very useful means. The impact of acceptor substituents and donor substituents on the C--C bond length distribution was studied.

关键词： hydrocarbon molecules bond dissociation energy (BDE) density functional theory (DFT) acceptor substituent donor substituent

research on Determination of Nitrogen Content in Petroleum Using Mid-infrared Spectroscopy

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china Petroleum Processing & Petrochemical Technology 2011年第4期13卷 1-7页

作者： Li Jingyan Chu Xiaoli Tian Songbai Lu Wanzhen (sinopec research {2. of Petroleum Processing, beijing 100083) sinopec Res Inst Petr Proc Beijing 100083 Peoples R China

Nitrogen content is an important parameter for petroleum refining processes. The combined use of mid-infrared attenuated total reflection spectroscopy and multivariate calibration allows accurate determination of nitrogen content in petroleum and its products. The calibration models of nitrogen content in crude oils have been established by partial least squares (PLS) method. The results predicted by this method were very close to those determined by standard methods. Compared with standard methods, this method is provided with advantages such as high-speed, simplicity and good-repeat- ability without any needs for pretreatment.

关键词： petroleum mid-infrared spectroscopy partial least square nitrogen

A research on the Joining of SiC Composite to 40 Cr Steel

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Journal of University of Science and Technology beijing 2001年第4期8卷 280-282页

作者： Chengchang Jia, Jianxin Chu, Qingshan Zhao 1) Materials Science and Engineering, University of Science and Technology beijing, beijing 100083, {2. 2. beijing Nonferrous Metals research institute, beijing 100081, {2. Univ Sci & Technol beijing Beijing 100083 Peoples R China beijing Nonferrous Met Res Inst Beijing 100081 Peoples R China

SiC composites and 40 Cr Steels were joined with Ag-Cu-Ti solder in order to develop a new method of joining ceramics to metal. Effects of solder component and process parameters on the joining strength were investigated. The results show that some chemical reactions occur on the jointing interface between ceramics and metal. Higher joining strength is achieved when titanium is 0.2. (mass fraction) in the solder. The thickness of solder also affects the joining characteristics, and 0.2.0.3 mm. thickness of solder is the most suitable.

关键词： ceramics metal joint sintering SiC composites Ag-Cu-Ti solder

research progress in synthesis and catalysis of polyoxometalates

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Progress in Natural Science:Materials International 2005年第5期15卷 385-394页

作者： GONG Yun1, HU Changwen1* and LIANG Hong2.1. Department of Chemistry, School of Science, the institute for Chemical Physics, beijing institute of Technology, beijing 100081, china 2. Chemical Industry Press, beijing 10002., china) Department of Chemistry School of Science the Institute for Chemical Physics Beijing Institute of Technology Beijing 100081 China Chemical Industry Press Beijing 100029 China

Recent progress in the synthetic chemistry and catalysis of polyoxometalates (POMs) is reviewed. The novel POMs and their derivatives emerging in nearly three years (2.02.2.04) are introduced, including POMs with novel structure, POMs-organic hybrid compounds and host-guest complexes. Our review is focused on the elaboration of POMs' supramolecular chemistry.

关键词： polyoxometalates hybrid host-guest structure supramolecule catalysis.

Natural gas geochemistry and its origins in Kuqa depression

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Science china Earth Sciences 2008年第S1期51卷 174-182页

作者： LIU QuanYou 1 ,QIN ShengFei 1 ,LI Jian 2.,LIU WenHui 3 ,ZHANG DianWei 3 ,ZHOU QingHua 1 &HU AnPing 1 1 research institute of Petroleum Exploration and Development,Petro{2.,beijing 100083,{2. 2.Langfang Branch of research institute of Petroleum Exploration and Development,Petro{2.,Langfang 065007,{2. 3 Exploration and production research institute,{12.,beijing 100083,{2. Petrochina Res Inst Petr Explorat & Dev Beijing 100083 Peoples R China Petrochina Langfang Branch Res Inst Petr Explorat & Dev Langfang 065007 Peoples R China sinopec Explorat & Prod Res Inst Beijing 100083 Peoples R China

According to gas compositional and carbon isotopic measurement of 114 gas samples from the Kuqa depression,accumulation of the natural gases in the depression is dominated by hydrocarbon gases, with high gas dryness(C1/C1-4)at the middle and northern parts of the depression and low one towards east and west sides and southern *** carbon isotopes of methane and its homologues are relatively enriched in 13 C,and the distributive range ofδ13C 1 ,δ13C 2.andδ13C 3 is-32.―-36‰,-2.‰―-2.‰and-2.‰―-2.‰,*** general,the carbon isotopes of gaseous alkanes become less negative with the increase of carbon ***δ13C CO2.value is less than-10‰in the Kuqa depression,indicating its organogenic *** distributive range of 3 He/ 4 He ratio is within n×10-8 and a decrease in 3 He/ 4 He ratio from north to south in the depression is *** on the geochemical parameters of natural gas above,natural gas in the Kuqa depression is of characteristics of coal-type gas *** possible reasons for the partial reversal of stable carbon isotopes of gaseous alkanes involve the mixing of gases from one common source rock with different thermal maturity or from two separated source rock intervals of similar kerogen type,multistages accumulation of natural gas under high-temperature and over-pressure conditions,and sufficiency and diffusion of natural gas.

关键词： Kuqa depression natural gas stable carbon isotope gas origin

Propagation characteristics of converted refracted wave and its application in static correction of converted wave

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Science china Earth Sciences 2008年第S2期51卷 226-232页

作者： LIU Yang1,2.& WEI XiuCheng3 1 State Key Laboratory of Petroleum Resource and Prospecting,china University of Petroleum,beijing 102.49,china 2.CNPC Geophysical Exploration Key Laboratory,china University of Petroleum,beijing 102.49,china 3 Exploration and production research institute,sinopec,beijing 100083,china china Univ Petr State Key Lab Petr Resource & Prospecting Beijing 102249 Peoples R China china Univ Petr CNPC Geophys Explorat Key Lab Beijing 102249 Peoples R China sinopec Explorat & Prod Res Inst Beijing 100083 Peoples R China

Three-component seismic exploration through P-wave source and three-component geophone is an effective technique used in complicated reservoir exploration. In three-component seismic exploration data processing,one of the difficulties is static correction of converted wave. This paper analyzes propagation characteristics of non-converted and converted refracted waves,and discovers a favor-able condition for the formation of converted refracted wave,i.e. the velocity of overlaying medium S wave is much lower than that of underlying medium S wave. In addition,the paper proposes the static correction method of converted wave based on PPS converted refracted wave,and processes the real three-component seismic data with better results of static correction of converted wave.

关键词： PPS converted refracted wave converted wave static correction

research progress in the inner surface modification of metal tubes by plasma processing

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Progress in Natural Science:Materials International 2006年第11期16卷 1119-1126页

作者： ZHANG Guling~ 1,2.**, WU Xingfang~1, GU Weichao~2. CHEN Guangliang~2. FENG Wenran~2. NIU Erwu~2. LI Li~2. L Guohua~2. CHEN Huan~2. FAN Songhua~2. LIU Chizi~2.and YANG Size~2.1. School of Material Science and Engineering, University of Science and Technology beijing, beijing 100083, {2. 2. beijing National Laboratory for Condensed Matter Physics, institute of Physics, Chinese Academy of Sciences, beijing 100080, {2.) School of Material Science and Engineering University of Science and Technology Beijing Beijing 100083 China beijing National Laboratory for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences Beijing 100080 China

The recent progress in inner surface hardening of tubes by plasma processing is summerized. Several techniques of inner surface plasma source ion implantation and deposition are introduced, and their advantages and disadvantages are discussed. The basic principles, technical features and new progress of inner surface plasma source ion implantation methods for metal tubes, which were developed in our laboratory, are described in detail. And perspectives of the future technical development for inner surface ion implantation of tubes are presented.

关键词： PSII metal tubes inner surface surface modification.