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chinese Science Bulletin 2008年第5期53卷 681-686页

作者： ZHANG Feng1,2, WEI ZhengRong1,2, CAO ZhenZhou1,2, ZHANG ChangHua1,2 & ZHANG Bing1,2 1 State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, chinese academy of sciences, Wuhan 430071, china 2 graduate university of chinese academy of sciences, beijing 100039, china State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics Wuhari Institute of Physics and Mathematics Chinese Academy of Sciences Wuhan 430071 China graduate university of chinese academy of sciences Beijing 100039 China

The photodissociation/photoionization processes of chlorobromomethane (CH_2BrCl) induced by fem- tosecond laser pulses have been investigated using pump-probe scheme combined with the time-of-flight mass spectra. The dominate photoproducts are observed at different delay time of the pump (400 nm) and probe (800 nm) pulses and the corresponding time-dependence of them is obtained. The results show that the decaying time of the molecule CH_2BrCl in the A-band is in the 100 fs. The decaying tendencies of the fragment ions (CH_2Cl^+ and CH_2Br^+) and the parent ion (CH_2BrCl^+) are almost the same and the relative ratios of the yields of them keep constant during the delay time of 0 to 150 fs. These facts suggest that the fragment ions come from the fragmentation of the parent ions in excited electronic states. The probabilities to form CH_2Cl^+ and CH_2Br^+ are obtained from the relative ratio of the ion intensity and are about 71.6% and 14.2%, respectively.

关键词：毫微秒激光氯溴化甲烷激光探针光解作用光化电离作用

Review on the study of entanglement in quantum computation speedup

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chinese Science Bulletin 2007年第16期52卷 2161-2166页

作者： DING ShengChao1,3 & JIN Zhi1,2,1 Institute of Computing Technology,chinese academy of sciences,beijing 100080,china 2 academy of Mathematics and Systems Science,chinese academy of sciences,beijing 100080,china 3 graduate university of chinese academy of sciences,beijing 100080,china Institute of Computing Technology Chinese Academy of Sciences Beijing 100080 China graduate university of chinese academy of sciences Beijing 100080 China academy of Mathematics and Systems Science Chinese Academy of Sciences Beijing 100080 China

The role the quantum entanglement plays in quantum computation speedup has been widely disputed. Some believe that quantum computation's speedup over classical computation is impossible if entan-glement is absent,while others claim that the presence of entanglement is not a necessary condition for some quantum algorithms. This paper discusses this problem systematically. Simulating quantum computation with classical resources is analyzed and entanglement in known algorithms is reviewed. It is concluded that the presence of entanglement is a necessary but not sufficient condition in the pure state or pseudo-pure state quantum computation speedup. The case with the mixed state remains open. Further work on quantum computation will benefit from the presented results.

关键词：量子论量子纠缠量子计算加速模拟

Conceptual design and simulation analysis of thermal behaviors of TGR blast furnace and oxygen blast furnace

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Science china(Technological sciences) 2010年第1期53卷 85-92页

作者： ZHANG Hui1,2,LI HuiQuan1,TANG Qing1 & BAO WeiJun1 1 National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology,Institute of Process Engineering,chinese academy of sciences,beijing 100190,china 2 graduate university of chinese academy of sciences,beijing 100049,china National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology Institute of Process Engineering Chinese Academy of Sciences graduate university of chinese academy of sciences

Extensive use of carbon based fuel is the main inducement for global warming and more extreme *** carbon dioxide emission and enhancing energy use is a common subject in steel *** the integrated steel plant,decreasing carbon dioxide emission must consider energy balance in the whole iron and steel works,and secondary energy must be actively *** promising blast-furnaces,top gas recovery blast furnace(TGR-BF) and oxygen blast furnace have been *** this paper,conceptual TGR blast furnace and oxygen blast furnace are *** on the idea of blast furnace gas de-CO2 circulating as reducing agent and the idea of pure oxygen blast decreasing the thermal reserve zone temperature,process modeling is conducted with ASPEN *** is shown that the developed model reasonably describes the energy balance and mass balance feature of the furnace,and provides basic thermodynamic condition for *** effects of changes in different operation conditions are studied by sensitivity analysis and reference data from simulation.

关键词： TGR blast-furnace thermal behavior simulation analysis CO2 emission decreasing

Environmental characteristics of Mid-Holocene recorded by lacustrine sediments from Lake Daihai, north environment sensitive zone, china

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Science china Earth sciences 2006年第9期49卷 968-981页

作者： SUN Qianli1,2, ZHOU Jie1, SHEN Ji3, CHEN Peng1,2, WU Feng1,2 & XIE Xiuping1,2 1. State Key Lab of Loess and Quaternary Geology, Institute of Earth Environment, chinese academy of sciences, Xi’an 710075, china 2. graduate university of chinese academy of sciences, beijing 100039, china 3. Nanjing Institute of Geography and Limnology, chinese academy of sciences, Nanjing 210008, china State Key Lab of Loess and Quaternary Geology Institute of Earth Environment Chinese Academy of Sciences Xi’an China graduate university of chinese academy of sciences Beijing China Nanjing Institute of Geography and Limnology Chinese Academy of Sciences Nanjing China

Climate proxies, such as total organic carbon and nitrogen (TOC, TN), carbonate content (CaCO3), grain-size and pollen of the sediment core retrieved from enclosed Lake Daihai which lies in the north china environment sensitive zone are analyzed to reconstruct the environment evolution of the area based on high-resolution radiocarbon chronology. The results reveal that the TOC and TN contents of the sediments correlate well with pollen percentage and pollen flux variations during the Holocene, and both reach their peak values simultaneously at 6.7―3.5 ka BP (calendar age, 7.6―3.6 ka BP). Since 6.7 ka BP, both the CaCO3 and organic matter contents of the core have simultaneous variations, and their high values also occur during 6.7―3.5 ka BP. While during 9.0―6.7 ka BP (calendar age, 10―7.6 ka BP) relatively lower level of organic matter content and pollen flux corre- spond to the higher level of carbonate content. The above relations suggest that during 6.7―3.5 ka BP, the productivity and effective precipitation were greatly improved in the lake drainage area, and this would probably strengthen the hydrodynamic conditions, enhancing organic matter, pollen and carbonate inputs from terrestrial sources. Such processes would account for the enrichment of both organic matter and carbonate in the sediments. While during 9.0―6.7 ka BP, the lower level of or- ganic matter, pollen flux but high carbonate content show depressed productivity and declined vege- tation coverage. The higher carbonate content at this stage would have probably resulted from the higher evaporation ratio of the lake water under relatively drier climate conditions. Therefore, it is in- ferred that during 6.7―3.5 ka BP, the climate was more humid with abundant rainfalls and vegetation was more flourishing in the Lake Daihai area. This can be seen as Holocene Climate Optimum (HCO). As a result, this has evident discrepancies with the traditional notion that the HCO occurs at Early Holocene or early Mid

关键词： Lake Daihai, Mid-Holocene, lacustrine sediments, environmental characteristics.

Thermal analysis of the baffle structure of the Solar Space Telescope

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Science china(Physics,Mechanics & Astronomy) 2010年第9期53卷 1755-1764页

作者： LI Rong1,2,3 & WANG Sen1,3 1 National Astronomical Observatories,chinese academy of sciences,beijing 100012,china 2 graduate university of chinese academy of sciences,beijing 100049,china 3 Key Laboratory of Solar Activity,National Astronomical Observatories of chinese academy of sciences,beijing 100012,china chinese academy of sciences National Astronomical Observatories Beijing China (GRID:grid.9227.e) (ISNI:***) graduate university of chinese academy of sciences Beijing China (GRID:grid.458514.9) National Astronomical Observatories of chinese academy of sciences Key Laboratory of Solar Activity Beijing China (GRID:grid.450302.0) (ISNI:***) chinese academy of sciences National Astronomical Observatories Beijing China (GRID:grid.9227.e) (ISNI:***) National Astronomical Observatories of chinese academy of sciences Key Laboratory of Solar Activity Beijing China (GRID:grid.450302.0) (ISNI:***)

The SST(Space Solar Telescope) is an astronomical telescope with a primary mirror of 1 m in *** observes the sun with a small view field to ensure that its high spatial resolution imaging has 0.1″-0.15″ and high SNR(signal to noise ratio).Surrounding the small view field is still the sun,which is an intense source of both heat and stray *** baffles(the main baffle,the aperture,and the outer baffle),which are used to eliminate the stray light,will change the thermal flux in the SST and will weaken the effect of the thermal control *** this study,the compatibility analysis of the thermal effect of baffle structures in SST is *** GCF(Geometry Composing Function) and BRDF(Bidirectional Reflectance Distribution Function),which are two inherent related parameters in the compatibility analysis,are *** objective and method of the compatibility analysis are *** the thermal analysis software,the temperature fields are calculated for different lengths of the main baffle,different radii of apertures,different lengths of the outer baffle with a 3' tilt angle and 16' tilt angle,and different tilt angles of the outer baffle with a 200 mm length.A series of configurations and sizes of the baffles are studied with the goals of both thermal control and elimination of stray *** design of the baffle structure of SST is achieved:the main baffle of length 4100 mm,the internal shield of radius 494 mm,the outer baffle of length 200 mm,and the outer baffle of tilt angle 3' are successfully *** paper presents the relationship between the thermal control design and stray light elimination plan in the *** aims of the optimal design of the baffle structure of SST are *** thoughts and methods of the optimal analysis are also useful for similar optical telescopes designed for solar observation.

关键词： baffle the main baffle the outer baffle GCF BRDF

Effects of diatoms on reproduction and growth of marine copepods

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Progress in Natural Science:Materials International 2004年第10期14卷 1-7页

作者： ZHANG Guangtao 1,2 and SUN Song 1 (1.Key Laboratory of Marine Ecology&Environment sciences,Institute of Oceanology,chinese academy of sciences,Qingdao266071,china 2.graduate School,chinese academy of sciences,beijing100039,china) Key Laboratory of Marine Ecology & Environment sciences Institute of Oceanology Chinese Academy of Sciences Qingdao 266071 China. graduate School Chinese Academy of Sciences Beijing 100039 China

Two hot spots in marine ecology,deleterious effects of diatoms and feeding selectivity of copepods,as well as new progress on these two issues achieved in the recent ten years,are *** two issues are considered correlated *** and their metabolites can induce deleterious effects on growth,reproduction and development of copepods,including increase of mortality and decrease of egg production,hatching and growth *** negative effects,resulting from either chemical toxin or nutritional defi-ciency,can be conquered in natural environments by diverse *** is therefore concluded that deleterious effects of diatoms observed in laboratory or during blooming period are only a special case that accommodation of feeding strategy of copepods is *** under-stand their feeding strategy in natural environments is a prerequisite to explaining the mechanisms of deleterious effects caused by diatoms,and makes it possible to re-evaluate the energy flow in marine ecosystems.

关键词： diatoms copepod feeding strategy reproduction deleterious effects

Research on applying physical chaos generator to spacecraft information security

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Science china(Technological sciences) 2009年第5期52卷 1463-1470页

作者： ZHAO HePing State Key Laboratory of Information Security,graduate university of chinese academy of sciences,beijing 100049,china china academy of Space Technology,beijing 100094,china State Key Laboratory of Information Security Graduate University of Chinese Academy of Sciences china academy of Space Technology

The effectiveness of a short-length message extension method based on physical chaos generator was analyzed and the entropy of the extended message was calculated in this *** analysis demon-strated that with the mentioned method the entropy of short-length messages,which are repeatedly used in spacecraft data systems,is obviously increased,and the security of transmission is enhanced as *** paper also presented an improvement of the protocol for secret key agreement presented by *** and *** of depending on characteristics of communication channel,this method takes advantage of the random data produced by physical chaos generator to preset the initial parameters of the procedure on both sides of communication,so that the procedure and quantity of cipher key can be precisely *** method can be used to cipher key management of se-cure communication between long life-span spacecraft and ground system.

关键词： physical chaos generator spacecraft information security message extension cipher key management

The solid lubricating material experiment device for Shenzhou-7 Spaceship

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Science china(Technological sciences) 2010年第9期53卷 2521-2527页

作者： WANG Ke1,2,REN WeiJia1,WANG ShiDa1 & WENG LiJun3 1 academy of Opto-Electronics,chinese academy of sciences,beijing 100190,china 2 graduate university of chinese academy of sciences,beijing 100049,china 3 Lanzhou Institute of Chemical Physics,chinese academy of sciences,Lanzhou 730000,china academy of Opto-Electronics Chinese Academy of Sciences graduate university of chinese academy of sciences

A solid lubricating material exposure experiment in space is one of the missions during the seventh manned spaceflight of china,and the key is to develop a device which can be fixed reliably outside of the orbital module and can be fetched conveniently by an astronaut during space *** solid lubricating material experiment device needs to be locked reliably in a vibrating and impacting environment during the launch phase,and should meet the requirement that it can be unlocked and fetched reliably by the astronaut wearing an extravehicular spacesuit via simple operations in orbit in an environment of high and low *** for the device we developed,the environmental characteristic of the mission was analyzed,the mechanical analysis and thermal analysis were carried out,and then a mechanism with functions of mechanical locking,structural self-locking and manual unlocking was *** device was verified by a sequence of experiments and was fetched by the astronaut during the flight of the Shenzhou-7 Spaceship.

关键词： manned spaceflight exposure experiment mechanism unlock

Contributions of phosphatase and microbial activity to internal phosphorus loading and their relation to lake eutrophication

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Science china Earth sciences 2006年第z1期49卷 102-113页

作者： SONG Chunlei, CAO Xiuyun, LI Jianqiu, LI Qingman, CHEN Guoyuan & ZHOU Yiyong Institute of Hydrobiology, chinese academy of sciences, Wuhan 430072, china graduate School of the chinese academy of sciences, beijing 100039, china Institute of Hydrobiology Chinese Academy of Sciences Wuhan China graduate School of the chinese academy of sciences Beijing China

Phosphatase may accelerate the process of lake eutrophication through improving phosphorus bioavailability. This mechanism was studied in three chinese eutrophic shallow lakes (Lake Taihu, Lake Longyang and Lake Lianhua). Phosphatase activity was related to the concentration of soluble reactive phosphorus (SRP) and chlorophyll a. Stability of dissolved phosphatase in reverse micelles may be attributed to molecular size, conformation and active residues of the *** the site with Microcystis bloomed in Lake Taihu, dissolved phosphatase activity was higher and more stable in micelles, SRP concentrations were lower in interstitial water, the contents of different forms of phosphorus and the amounts of aerobic bacteria were lower while respiration efficiency was higher in sediments. Phosphobacteria, both inorganic and organic and other microorganisms were abundant in surface water but rare in sediments. Therefore, internal phosphorus may substantially flux into water column by enzymatic hydrolysis and anaerobic release, together with mobility of bacteria,thereby initiating the bloom. In short, biological mechanism may act in concert with physical and chemical factors to drive the internal phosphorus release and accelerate lake eutrophication.

关键词： dissolved phosphatase, reverse micelle, internal loading, phosphorus form of sediment, microbiology, eutrophication, Microcystis bloom.

Study on the atmospheric photochemical reaction of CF_3 radicals using ultraviolet photoelectron and photoionization mass spectrometer

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Science china Chemistry 2008年第4期51卷 316-321页

作者： YAO Li1,2, DU Lin1,2, YIN Shi1,2 & GE MaoFa1 1 beijing National Laboratory for Molecular sciences (BNLMS), State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, chinese academy of sciences, beijing 100080, china 2 graduate university of chinese academy of sciences, beijing 100080, china beijing National Laboratory for Molecular sciences (BNLMS) State Key Laboratory for Structural Chemistry of Unstable and Stable Species Institute of Chemistry Chinese Academy of Sciences Beijing China graduate university of chinese academy of sciences Beijing China

A study of the atmospheric photochemical reaction of CF3 radical with CO and O2 was performed by using a homemade ultraviolet photoelectron spectrometer-photoionization mass spectrometer (PES- PIMS). The electronic structures and mechanism of ionization and dissociation of CF3OC(O)OOC(O)- OCF3 were investigated. It was indicated that the two bands on the photoelectron spectrum of CF3OC(O)OOC(O)OCF3 are the result of ionization of an electron from a lone pair of oxygen and a fluo- rine lone pair of CF3 group. The outermost electrons reside in the oxygen lone pair. The experimental and theoretical first vertical ionization energy is 13.21 and 13.178 eV, respectively, with the PES and OVGF method. They are in good agreement. The photo ionization and dissociation processes were discussed with the help of theoretical calculations and PES-PIMS experiment. After ionization, the parent ions prefer the dissociation of the C-O bond and giving the fragments CF3OCO+ and CF3+. It demonstrated that the ultraviolet photoelectron and photoionization mass spectrometer could be ap- plied widely in the study of atmospheric photochemical reaction.

关键词： photochemical reaction CF3 radical ultraviolet photoelectron and photoionization mass spectroscopy transient species