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Indian Ocean-MORB-type isotopic signature of Yushigou ophiolite in North Qilian Mountains and its implications

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Science china Earth Sciences 2006年第6期49卷 561-572页

作者： HOU Qingye1,2, ZHAO Zhidan1,2, ZHANG Hongfei3. ZHANG Benren3.& CHEN Yuelong2 1. state key Laboratory of geological {3. and mineral resources, china university of geosciences, Beijing 100083. china 2. School of Earth Science and mineral resources, china university of geosciences, Beijing 100083. china 3. Faculty of Earth Sciences, china university of geosciences, {13., china state key Laboratory of geological {3. and mineral resources China University of Geosciences Beijing China School of Earth Science and mineral resources China University of Geosciences Beijing China Faculty of Earth Sciences China University of Geosciences Wuhan China

In order to explore the disputed issue concerning the tectonic affinity ofthe ancient ocean mantle of North Qilian Mountains (NQM), geochemical and Sr, Nd, Pb isotopiccompositions of pillow basalts of the Yushigou Ophiolite (YSGO) suite from NQM have been analyzedsystematically. The pillow basalts exhibit tholeiitic characteristics, with flatchondrite-normalized REE patterns ((La/Yb)_N = 0.98—1.27). They display no Nb, Ta, Zr, Hf negativeanomalies, and show MORB features in 2Nb-Zr/4-Y and Ti/100-Zr-YX3.tectonic discrimination *** results indicate that the Yushigou ophiolite is most likely to be formed in a mid-ocean ridgeor mature back-arc basin. Their isotopic data show a relatively broad and enriched ^(87)Sr/^(86)Sr(0.70509 — 0.70700), restricted ^(143.Nd/^(144)Nd (0.512955-0.512978). Pb isotopes are in the rangeof ^(206)Pb/^(204)Pb (18.054-20.562), ^(207)Pb/^(204)Pb (15.53.-15.743. and ^(208)Pb/^(204)Pb(3..068-3..53.). These isotopic data imply that the basalts originated from the depleted mantle(DMM), with the involvement of enriched mantle components (mainly EMII). Geochemical comparisonsbetween the basalts in YSGO and the MORB-type basalts of ophiolite suites occurring in the knownancient Tethyan tectonic domain indicate that the ancient oceanic mantle represented by YSGO suiteforming in early Paleozoic in the North Qilian Moutains is very similar to the Tethyan mantle inboth trace elements and isotopic compositions. The North Qilian Mountains should be a part of theTethyan tectonic domain in early Paleozoic. This further implies that the Tethyan tectonic domaincan be deduced to early Paleozoic in the study area, which will be helpful to discussing thetectonic affinity and evolution of the North Qilian Mountains.

关键词： geochemistry, Indian Ocean-MORB-type isotopic signatures, Tethyan tectonic domain, Yushigou ophiolite, North Qilian Mountains.

Multistage evolution of continental collision orogen:A case study for western Dabie orogen

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Chinese Science Bulletin 2009年第15期54卷 2568-2579页

作者： WU YuanBao state key Laboratory of geological {3. and mineral resources, Faculty of Earth Sciences, china university of geosciences, wuhan 43.074, china state key Laboratory of Continental Dynamics, Department of Geology, Northwest university, Xi’an 710069, china state key Laboratory of geological {3. and mineral resources Faculty of Earth Sciences China University of Geosciences Wuhan China state key Laboratory of Continental Dynamics Department of Geology Northwest University Xi’an China

The foramtion and evolution of collisional orogen is a prominent feature along convergent plate margins, and is generally a complex process. This article presents an integrated study of zircon genesis, U-Pb age and Lu-Hf isotope composition as well as geological characteristics for the western Dabie orogen to constrain its multi-stage evolution history. The results suggest that the formation of oceanic crust in the Huwan area was constrained at ca. 400―43. Ma, which was slightly later than the collision of the northern Qinling with the North china Block. It formed in a marginal basin in the northern margin of the Yangtze Block. The peak metamorphism of eclogite in the Huwan area occurred at ca. 3.0 Ma, and the timing of the initial exhumation of oceanic eclogite was about 270 Ma. The high to ultrahigh pressure (HP-UHP) metamorphic rocks in the Xinxian and the Hong'an metamorphic zones have the same ages and natures as those of the HP-UHP metamorphic rocks in the other Dabie-Sulu terrains, and also have experienced multi-stage exhumation, and thus can be taken as a coherent part of the Dabie-Sulu orogen. Therefore, the Qinling-Dabie-Sulu orogen is a typical multi-stage continental collision orogen, with an amalgamation process extending more than 200 Ma.

关键词：大别造山带大陆碰撞西部演变超高压变质岩碰撞造山带苏鲁造山带变质岩区

Spatio-temporal carbon isotope variation during the Ediacaran period in South china and its impact on bio-evolution

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Science china Earth Sciences 2009年第10期52卷 1520-1528页

作者： WANG XinQiang1 & SHI XiaoYing1,2 1 School of Earth Science and mineral resources, china university of geosciences, Beijing 100083. {3. 2 state key Laboratory of geological processes and mineral resources, Beijing 100083. {3. School of Earth Science and mineral resources China University of Geosciences Beijing China state key Laboratory of geological {3. and mineral resources Beijing China

The Ediacaran period is characterized by the extremely negative carbon isotope anomalies and great biotic evolution in Earth history. At least four negative carbon isotope anomalies have been reported from this interval in South china so far. It is traditionally argued that the isotope variations can be used as a useful tool for global correlation of Ediacaran succession; however, more and more researches argued against this idea. We reviewed the previously published carbon isotope data in South china, and distributed the mean values of a certain time to the paleogeographic maps. The results show that the carbon isotope values (δ13.) vary greatly in different environments, but a clear tendency of becoming lighter from shallow platform to deep basin, with a maximum variation up to 1‰ Moreover, the important changes in Ediacaran biota, marked by the introducing of new taxa or ecologic groups, seemed to always postdate the negative anomalies but coincide with the positive shift. If the negative excursions represented the oxidation of a large dissolved organic carbon (DOC) reservoir in the ocean, the diverse Ediacaran organisms and the carbon isotope anomalies may suggest totally different environments: oxic and anoxic/euxinic. We also suggest that the elimination of euxinic state through precipitation of pyrites is one of the important environment factors in prompting the Ediacaran bio-evolution.

关键词： Ediacaran South china carbon isotope spatio-temporal variations bio-evolution

The equilibrium between diagenetic calcites and dolomites and its impact on reservoir quality in the sandstone reservoir of Kela 2 gas field

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Progress in Natural Science:Materials International 2007年第9期17卷 1051-1058页

作者： Gao Zhiqian1,Yu Bingsong2,3.and Lai Xingyun2,3.1.School of Energy resources,china university of geosciences,Beijing 100083.china 2.{3. key Laboratory of geological processes and mineral resources,china university of geosciences,Beijing 100083.china 3.Ministry of Education key Laboratory of Lithosphere Structure,Deep processes and Exploration Technique,china university of geosciences,Beijing 100083.china) School of Energy resources China University of Geosciences Beijing 100083 China state key Laboratory of geological {3. and mineral resources China University of Geosciences Beijing 100083 China Ministry of Education key Laboratory of Lithosphere Structure Deep Processes and Exploration Technique China University of Geosciences Beijing 100083 China

Based on the equilibrium theory of chemical reactions between water and rocks,this paper establishes a thermodynamic phase relationship diagram among calcites,dolomites and water solution under the condition of diagenesis based on the thermodynamic database of related minerals and fluids and dolomite's degree of order *** has been discovered that the equilibrium between calcites and dolomites in the diagenetic environment is strongly impacted by temperature and the Ca/Mg ratios in groundwater,and that the dolomite's degree of order in the diagenetic environment is a function of crystallization temperature and time,not controlled by water ***,the authors make a further analysis of the close relationship of chemical reaction between carbonate cements and pore water in the sandstone reservoirs of Kala 2 gas field in Kuche *** can be seen that there are different impacts on sandstone reservoir quality among the equilibrium system of calcites,dolomites and pore water at different depths of reservoirs.

关键词： diagenesis equilibrium between calcites and dolomites secondary pores Kela 2 gas field

Mechanism for calcite dissolution and its contribution to development of reservoir porosity and permeability in the Kela 2 gas field,Tarim Basin,china

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Science china Earth Sciences 2008年第4期51卷 567-578页

作者： YU BingSong1,3. DONG HailLiang2,3.& RUAN Zhuang1,3.1 state key Laboratory of geological {3. and mineral resources, china university of geosciences, Beijing 100083. china 2 Department of Geology, Miami university,Oxford, OH 45056, USA 3.Geomicrobiology Laboratory, china university of geosciences, Beijing, 100083. china state key Laboratory of geological {3. and mineral resources China University of Geosciences Beijing China Geomicrobiology Laboratory China University of Geosciences Beijing China Department of Geology Miami University Oxford USA

This study is undertaken to understand how calcite precipitation and dissolution contributes to depth-related changes in porosity and permeability of gas-bearing sandstone reservoirs in the Kela 2 gas field of the Tarim Basin, Northwestern china. Sandstone samples and pore water samples are col-lected from well KL201 in the Tarim Basin. Vertical profiles of porosity, permeability, pore water chem-istry, and the relative volume abundance of calcite/dolomite are constructed from 3.00 to 4000 m below the ground surface within major oil and gas reservoir rocks. Porosity and permeability values are in-versely correlated with the calcite abundance, indicating that calcite dissolution and precipitation may be controlling porosity and permeability of the reservoir rocks. Pore water chemistry exhibits a sys-tematic variation from the Na2SO4 type at the shallow depth (3.00-3.3. m), to the NaHCO3.type at the intermediate depth (3.3.―3.95 m),and to the CaCl2 type at the greater depth (3.28―3.3. m). The geochemical factors that control the calcite solubility include pH, temperature, pressure, Ca2+ concen-tration, the total inorganic carbon concentration (ΣCO2), and the type of pore water. Thermodynamic phase equilibrium and mass conservation laws are applied to calculate the calcite saturation state as a function of a few key parameters. The model calculation illustrates that the calcite solubility is strongly dependent on the chemical composition of pore water, mainly the concentration difference between the total dissolved inorganic carbon and dissolved calcium concentration (i.e., [ΣCO2] -[Ca2+]). In the Na2SO4 water at the shallow depth, this index is close to 0, pore water is near the calcite solubility. Calcite does not dissolve or precipitate in significant quantities. In the NaHCO3.water at the intermedi-ate depth, this index is greater than 0, and pore water is supersaturated with respect to calcite. Massive calcite precipitation was observed at this depth interval and

关键词： calcite dissolution porosity thermodynamic Tarim Basin

Genomics,metagenomics,and microbial oceanography—A sea of opportunities

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Science china Earth Sciences 2011年第4期54卷 473-480页

作者： FANG JiaSong 1,2 &ZHANG Li 3.1 state key Laboratory of Marine Geology,Tongji university,Shanghai 200092,{3. 2 College of Natural and Computational Sciences,Hawaii Pacific university,Kaneohe,HI 96744,USA 3.0} key Laboratory of geological processes and mineral resources,Faculty of Earth Sciences,china university of geosciences,wuhan 43.074,{3. state key Laboratory of Marine Geology Tongji University Shanghai China College of Natural and Computational Sciences Hawaii Pacific University Kaneohe USA state key Laboratory of geological {3. and mineral resources Faculty of Earth Sciences China University of Geosciences Wuhan China

Microbial oceanography is an emerging discipline resulted from the interaction,cross-fertilization and integration of life science and ocean *** oceanography integrates the principles of marine microbiology,microbial ecology and oceanography to study the role of microorganisms in the biogeochemical dynamics of natural marine *** application of genomics tools to study marine microbes is resulting in rapid advancements in microbial oceanography that has important implications in global carbon cycle,climate change,and ecosystem *** we review the application of genomics and metagenomics in microbial oceanography and suggest future directions in microbial oceanography research.

关键词： microbial oceanography genomics metagenomics genes biomass bacteria archaea eukarya phylogeny physiology metabolism ecology biogeochemistry microbiology ecosystem function

Carbon isotope composition of the Lower Triassic marine carbonates, Lower Yangtze Region, South china

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Science china Earth Sciences 2006年第3期49卷 225-241页

作者： ZUO Jingxun1,2, TONG Jinnan3. QIU Haiou4 & ZHAO Laishi3.1. Nanjing Institute of Geology and Palaeontology, Chinese Academy of Sciences, Nanjing 210008, china 2. Henan Institute of geological Survey, Zhengzhou 450007, china 3. {3. key Laboratory of geological processes and mineral resources at china university of geosciences, wuhan 43.074, china 4. Faculty of Material Sciences and Chemical Engineering, china university of geosciences, wuhan 43.074, china Nanjing Institute of Geology and Palaeontology Chinese Academy of Sciences Nanjing China Henan Institute of geological Survey Zhengzhou China state key Laboratory of geological {3. and mineral resources at china university of geosciences Wuhan China Faculty of Material Sciences and Chemical Engineering China University of Geosciences Wuhan China

Studies on three Lower Triassic sections located on the shallow water platform, the deep water slope and in the deep water basin in the Lower Yangtze Region, South china, show the similar trend of carbon isotope evolution. Biostratigraphic correlations among the Lower Triassic sections on the basis of standard conodont zones indicate that three negative shifts occurred in the Griesbachian, the Smithian and the late Spathian stages respectively, and one distinctly positive shift occurred in the early Spathian stage. Trend of carbon isotope evolution of the Lower Triassic reflects some significant changes in the global carbon cycle. Moreover, δ 13. background values are intensively controlled by palaeogeographic environment. In general, δ 13. values from deep-water slope carbonates are lighter than those from carbonate platform and heavier than those from deep-water basin carbonates. The positive carbon isotope excursion may be induced by a significant amount of organic carbon burial in marine sediments and increase in primary productivity. The large negative carbon isotope excursions during the Early Triassic in Lower Yangtze Region are interpreted to relate to volcano eruptions based on tuffaceous claystone interlayers observed near the Permian-Triassic boundary, the Induan- Olenekian boundary and the Lower Triassic-Middle Triassic boundary.

关键词： Lower Triassic, carbon isotope compositions, palaeogeography, volcanic eruptions, Lower Yangtze Region.

Exploring the deep biosphere

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Science china Earth Sciences 2011年第2期54卷 157-165页

作者： FANG JiaSong1,2 & ZHANG Li3.1 state key Laboratory of Marine Geology, Tongji university, Shanghai 200092, {3. 2 College of Natural and Computational Sciences, Hawaii Pacific university, Kaneohe, HI 96744, USA 3.state key Laboratory of geological processes and mineral resources, Faculty of Earth Sciences, china university of geosciences, wuhan 43.074, {3. state key Laboratory of Marine Geology Tongji University Shanghai China College of Natural and Computational Sciences Hawaii Pacific University Kaneohe USA state key Laboratory of geological {3. and mineral resources Faculty of Earth Sciences China University of Geosciences Wuhan China

Over the past two decades, scientific drilling into sediments and rocks in the ocean and the continent has revealed the presence of physiologically and phylogenetically complex microbial life in the deep subsurface. Microorganisms, most of which have no cultured or known relatives in the surface biosphere, have been discovered in sediments and rock at depth as deep as 1 km below the seafloor and more than 3.km deep in the continent. The deep biosphere probably represents the most voluminous part of the global biosphere and may constitute as much as 50% of the Earth’s biomass. In this article, we review the current knowledge of and most recent advances in studying the deep biosphere and suggest directions in future research.

关键词： deep biosphere Thomas Gold microorganism biomass DNA ribosome ODP CARD-FISH dark energy lipids serpentinization

Petrogenesis of Indosinian volcanic rocks in Songpan-Garze fold belt of the northeastern Tibetan Plateau:New evidence for lithospheric delamination

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Science china Earth Sciences 2010年第9期53卷 1316-1328页

作者： CAI HongMing1,2, ZHANG HongFei1,2, XU WangChun1,2, SHI ZhangLiang1,2 & YUAN HongLin3.1 state key Laboratory of geological {3. and mineral resources, wuhan 43.074, china 2 Faculty of Earth Sciences, china university of geosciences, wuhan 43.074, china 3.state key Laboratory of Continental Dynamics, Northwest {13., Xi’an 710069, china state key Laboratory of geological {3. and mineral resources Wuhan China Faculty of Earth Sciences China University of Geosciences Wuhan China state key Laboratory of Continental Dynamics Northwest University Xi’an China

In the Songpan-Garze fold belt of the northeastern Tibetan Plateau, an Indosinian lithospheric delamination model has been proposed, based on previous investigation of widespread granitoids. However, this model lacks comparable information from volcanism in the area. During the Indosinian delamination in the Songpan-Garze fold belt, whether partial melting of litho- spheric mantle taken place is debated. This paper reports U-Pb zircon LA-ICP-MS ages, geochemical and Sr-Nd-Hf isotopic compositions from the Aba and Wasai calc-alkaline volcanic rocks in the central Songpan-Garze fold belt. Obtained magma crystallization ages are 210±3.Ma for the Aba andesite and 205±1 Ma for the Wasai andesite. These are consistent with magma crystallization ages of the late Indosinian granitoids in the Songpan-Garze fold belt that formed in a post-collisional tectonic setting. The Aba and Wasai andesites have distinct geochemical singnatures. The former has higher Al2O3. K2O, Rb but lower Na2O, Ba and Sr contents, suggesting differences in their magmatic evolution. The Aba andesites have ISr values of 0.7070-0.7076 and εNd(t) values of -3.9 to -5.3. and the Wasai andesites have ISr values of 0.7075-0.7077 and εNd(t) values of -3.6 to -3.9. Zircons show εHf(t) values of -3.7 to 0.3.for the Aba andesites and -2.7 to 5.5 for the Wasai andesites. Geochemical and Sr-Nd-Hf isotopic compositions indicate that fractional crystallization and crustal assimilation processes are not key roles for their magma evolution, implying that their chemical compositions are those of primary melts. We suggest that the magma of the Aba andesites originated predominantly from a crustal source, with a minor mantle-derived component. The source region of the magma was likely at the crust-mantle boundary. The magma of the Wasai andesites resulted from partial melting of lithospheric mantle, which was probably metasomatized by fluids so that it was amphibole bearing. The petrogenesis of the Aba and Wasai andesite

关键词： volcanism U-Pb dating geochemistry petrogenesis lithospheric delamination Songpan-Garze fold belt