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Polymer-assisted nanoparticulate contrast-enhancing materials

science china Chemistry 2010年第3期53卷 479-486页

作者： DING Yin1,3,HU Yong2,WU Wei1 & JIANG XiQun1 1laboratory of Mesoscopic Chemistry and department of Polymer science and engineering,College of Chemistry & Chemical engineering,nanjing university,nanjing 2.0093.china 2national laboratory of solid state microstructure,department of material science and engineering,nanjing university,nanjing 2.0093.china 3Key laboratory of Analytical Chemistry for Life science,Ministry of Education,School of Chemistry and Chemical engineering,nanjing university,nanjing 2.0093.china laboratory of Mesoscopic Chemistry and department of Polymer science and engineering College of Chemistry & Chemical Engineering Nanjing University Nanjing China Key laboratory of Analytical Chemistry for Life science Ministry of Education School of Chemistry and Chemical Engineering Nanjing University Nanjing China national laboratory of solid state microstructure Department of Material Science and Engineering Nanjing University Nanjing China

The application of nanotechnology in medicine research has significant potential in modern biomedical research,disease diagnosis and *** fluorophore-based detection techniques have been widely used as imaging and signal transduction tools for the detection of trace levels of *** photosensitivity of the fluorophores,however,limits their application in such complex environments as living bio-systems where degradation or photobleaching *** nanoparticles have unique and stable optical,electrical,magnetic and catalytic properties because of their various shapes,sizes and *** potential of the nanoparticles as novel imaging agents has been studied as a possible solution to this *** modification of inorganic nanoparticles could enhance their biostability in physiological conditions and ability of targeting bioactive molecules.

关键词： contrast agent cell image gold nanoparticles iron oxide nanoparticles carbon nanotubes polymeric-inorganic hybrid nanoparticles

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Analysis of variance for testing method of cement in determination of strength

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Progress in Natural science:materials International 2011年第4期21卷 341-346页

作者： Hong HUANG,Xiao-dong SHEN state Key laboratory of materials-Oriented Chemical engineering,College of material science and engineering, nanjing university of Technology,nanjing 210009,china state Key laboratory of materials-Oriented Chemical engineering College of Material Science and Engineering Nanjing University of Technology Nanjing 210009 China

The statistical tools such as descriptive statistics,full factorial design and analysis of source of variation were used to identify the potential factors that impact the validity of testing method for determining the strength of *** results showed that personal error impacted both accuracy and precision of test *** time associated with temperature fluctuation resulted in strength variation but did not impact the precision of test in all curing *** compactions did not impact the precision of test but resulted in the strength variation on 3 d and 28 d *** methods for the initial moist air curing significantly impacted the precision of testing method and resulted in the strength variation of cement on 1 d.

关键词： testing method of cement analysis of variance strength accuracy precision

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Statistical study of cement additives with and without chloride on performance modification of Portland cement

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Progress in Natural science:materials International 2011年第3期21卷 246-253页

The effectiveness of cement additives with and without chloride on the fluidity and the strength development of Portland cement was compared by using statistical full factorial *** experimental results show that the cement additive containing CaCl2and Ca(NO3)2can enhance early strength of cement ***,Ca(NO3)2is less effective than CaCl2even if it is combined with other organic chemicals such as alkanolamine and *** significant difference is found between CaCl2and Ca(NO3)2influencing the fluidity and 28 d strength of *** fluidity is determined by saccharide and its interaction with *** 28 d strength enhancement is determined by *** fluidity as well as the mechanical performance of treated cement can be significantly improved by combining Ca(NO3)2with TIPA and saccharide.

关键词： Portland cement cement additive accelerator type fluidity strength development full factorial design

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FERROELECTRIC CHARACTERISTICS OF SrBi_2Ta_2O_9 THIN FILMS ANNEALED IN FORMING GAS

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Acta Metallurgica Sinica(English Letters) 2001年第6期14卷 517-519页

作者： D.S. Wang, T. Yu and A. Hu (department of Physics & national laboratory of solid state microstructures, nanjing university, nanjing 2.0093, china) D. Wu, A.D. Li, Z.G. Liu and N.B. Ming (department of material science and engineering & national laboratory Dept. of Phys. Nanjing Univ. Nanjing 210093 China

The degradation behavior of SrBi2Ta2O9 (SBT) thin films annealed in forming gas (5%H2+95%N2) was investigated. The ferroelectric remnant polarization Px of SBT had a severe decrease in the containing H2 atmosphere at 400°C. SEM results showed that Bi could be reduced from SBT thin films for the effect of H2. The reduction role increased with a rise of annealing temperature. SBT thin films lost their ferroelectricity when the annealing temperature was above 450°C. It implied that the degradation of Pr value or the disappearance of ferroelectricity in SBT thin, films had the relationship with the reductive amounts of Bi in SBT. H2 played an important role in degradation of ferroelectric SBT thin films. This role could be attributed to its strong reduction activity during forming gas annealing.

关键词： Annealing Degradation Ferroelectricity Thermal effects

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Influences of low-Ti substitution for La and Mg on the electrochemical and kinetic characteristics of AB_3-type hydrogen storage alloy electrodes

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science china(Technological sciences) 2010年第1期53卷 242-247页

作者： DONG ZhenWei1,2,WU YaoMing1,MA LiQun2,SHEN XiaoDong2 & WANG LiMin1 1 state Key laboratory of Rare Earth Resource Utilization,Changchun Institute of Applied Chemistry,Chinese Academy of sciences,C hangchun 130022,china 2 College of material science and engineering,nanjing university of Technology,nanjing 210009,china state Key laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun China College of material science and engineering Nanjing University of Technology Nanjing China

The(La0.67Mg0.33)1-xTixNi2.75Co0.25(x = 0,0.05,0.10,0.15 and 0.20,at%) alloys were synthesized by arc melting and subsequent heat solid-liquid diffusing *** structure,electrochemical properties and kinetic characteristics of the alloys were investigated *** results showed that all the alloys mainly consisted of the(La,Mg)Ni3,LaNi5 phases,and the lattice parameters and the cell volumes of the(La,Mg)Ni3 and LaNi5 phases decreased with increasing Ti *** alloy electrodes could be activated to reach their maximum discharge capacity within five *** cycle life after 100 charge/discharge cycles(C100/Cmax) and the high-rate dischargeability at a discharge current density of 1200 mA/g first increased and then *** the results showed that low-Ti content in AB3-type hydrogen storage alloys was beneficial to improvements of the overall electrochemical properties,and the optimum overall electrochemical performance of the alloy electrodes was obtained when x = 0.05.

关键词： AB3-type alloy metal hydride electrode microstructure electrochemical property kinetic characteristic

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Characteristics of Li diffusion on silicene and zigzag nanoribbon

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Chinese Physics B 2016年第1期25卷 742-745页

作者：郭艳华曹觉先徐波 College of materials science and engineering Nanjing Tech UniversityNanjing 210009China department of Physics Xiangtan UniversityXiangtan 411105China department of materials science and engineering and national laboratory of solid state microstructures Nanjing UniversityNanjing 210093China

We perform a density functional study on the adsorption and diffusion of Li atoms on silicene sheet and zigzag nanoribbons. Our results show that the diffusion energy barrier of Li adatoms on silicene sheet is 0.25 eV, which is much lower than on graphene and Si bulk. The diffusion barriers along the axis of zigzag silicene nanoribbon range from0. 1 to 0.25 eV due to an edge effect, while the diffusion energy barrier is about 0.5 eV for a Li adatom to enter into a silicene nanoribbon. Our calculations indicate that using silicene nanoribbons as anodes is favorable for a Li-ion battery.

关键词： Li diffusion silicene sheet silicene nanoribbons density functional theory

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Progress and development in thermodynamic theory of friction and wear

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science china(Technological sciences) 2009年第4期52卷 844-849页

作者： DAI ZhenDong1 & XUE QunJi2 1 Institute of Bio-inspired Structure and Surface engineering, nanjing university of Aeronautics and Astronautics, nanjing 210016, china 2 state Key laboratory of solid Lubrication, Chinese Academy of sciences, Lanzhou 710000, china Institute of Bio-inspired Structure and Surface engineering Nanjing University of Aeronautics and Astronautics Nanjing China state Key laboratory of solid Lubrication Chinese Academy of Sciences Lanzhou China

Tribology theory lags well behind engineering needs because of those complex and multi-dimensional characteristics associated with friction and wear. The mechanism of friction is reviewed and discussed from a static thermodynamics perspective; research methods on the process of friction and wear and thermodynamic studies within the field of tribology are also reviewed. We propose that entropy can be a critical parameter in describing the evolution of friction and wear, and the entropy balance equation could be considered as a fundamental cornerstone for a systematic tribology theory. Applications of irreversible thermodynamic theory of tribology to various fields are reviewed.

关键词： friction and wear irreversible thermodynamics entropy generation multi-factor coupling

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Damage and progressive failure of concrete structures using non-local peridynamic modeling

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science china(Technological sciences) 2011年第3期54卷 591-596页

作者： HUANG Dan1,2, ZHANG Qing1,2 & QIAO PiZhong1,3 1 state Key laboratory of Hydrology-Water Resources and Hydraulic engineering, Hohai university, nanjing 210098, china 2 department of engineering Mechanics, Hohai university, nanjing 210098, china 3 department of Civil and Environmental engineering, Washington state university, Pullman, WA 99164-2910, USA state Key laboratory of Hydrology-Water Resources and Hydraulic engineering Hohai University Nanjing China department of engineering Mechanics Hohai University Nanjing China department of Civil and Environmental engineering Washington State University Pullman USA

Peridynamics (PD), a recently developed theory of solid mechanics, which employs a non-local model of force interaction and makes use of integral formulation rather than the spatial partial differential equations used in the classical continuum mechanics theory, has shown effectiveness and promise in solving discontinuous problems at both macro and micro scales. In this paper, the peridynamics theory is used to analyze damage and progressive failure of concrete structures. A non-local peridynamic model for a rectangular concrete plate is developed, and a central pairwise force function is introduced to describe the interior interactions between particles within some definite distance. Damage initiation, evolution and crack propagation in the concrete model subject to in-plane uni-axial tension, in-plane uni-axial compression and out-of-plane impact load are investigated respectively. The numerical results show that discontinuities appear and grow spontaneously as part of the solution to the peridynamic equations of motion, and no special failure criteria or re-meshing techniques are required, which proves the potential of peridynamic modeling as a promising technique for analyzing the progressive failure of concrete materials and structures.

关键词： concrete damage progressive failure peridynamic model discontinuities

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Formulation Design of the Multi-component Cement Additive by Using engineering Statistics

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Journal of Wuhan university of Technology(materials science) 2010年第3期25卷 538-544页

作者：黄弘沈晓冬 state Key laboratory of materials-oriented Chemical engineering College of Material Science and EngineeringNanjing University of Technology

A novel methodology for the formulation design of the multi-component cement additive for the low early strength blend cement was presented by using engineering *** of cement additive such as triethanolamine,chloride,saccharide and a kind of divalent alcohol were simultaneously tested according to the arrangement of response surface *** models were established to express the quantitative relationship between the chemical components of cement additive and the compressive strength of treated blend *** effectiveness and the possible interactions of these four chemicals contributing to the strength development of blend cement were further explored by the pareto chart and the contour *** according the performance analysis of four chemicals,the optimized formulations were brought forward and were validated in practical trials by Turkey＇s multiple comparison.

关键词： cement additive blend cement effectiveness interaction engineering statistics

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The birhythmicity increases the diversity of p53 oscillation induced by DNA damage

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Chinese Physics B 2017年第12期26卷 68-75页

作者：王道光周春红张小鹏 national laboratory of solid state microstructure and department of Physics Nanjing University Nanjing 210093 China School of Physics and Electronic engineering Jiangsu Normal University Xuzhou 221116 China Kuang Yaming Honors School Nanjing University Nanjing 210023 China

The tumor suppressor p53 mediates the cellular response to various stresses. It was experimentally shown that the concentration of p53 can show oscillations with short or long periods upon DNA damage. The underlying mechanism for this phenomenon is still not fully understood. Here, we construct a network model comprising the ATM-p53-Wip1 and p53-Mdm2 negative feedback loops and ATM autoactivation. We recapitulate the typical features of p53 oscillations including p53 birhythmicity. We show the dependence of p53 birhythmicity on various factors such as the phosphorylation status of ATM. We also perform stochastic simulation and find the noise-induced transitions between two modes of p53 oscillation, which increases the p53 variability in both the amplitude and period. These results suggest that p53 birhythmicity enhances the responsiveness of p53 network, which may facilitate its tumor suppressive function.

关键词： p53 birhythmicity oscillation

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