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Science china Chemistry 2010年第3期53卷 519-527页

作者： ZHANG Yu1,2,SUN PeiJian1,2 & GAN ZhiHua1 1CAS Key Laboratory of Engineering Plastics,Institute of Chemistry,chinese academy of sciences,beijing 100190,china 2graduate university of chinese academy of sciences,beijing 100039,china 1. CAS Key Laboratory of Engineering Plastics Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China2. Graduate University of Chinese Academy of Sciences Beijing 100039 China

A series of controllable amphiphilic block copolymers composed of poly(ethylene oxide)(PEO) as the hydrophilic block and poly(ε-caprolactone)(PCL) as the hydrophobic block with the amino terminal group at the end of the PEO chain(PCL-b-PEO-NH2) were *** on the further reaction of reactive amino groups,diblock copolymers with functional carboxyl groups(PCL-b-PEO-COOH) and functional compounds RGD(PCL-b-PEO-RGD) as well as the triblock copolymers with thermosensitive PNIPAAm blocks(PCL-b-PEO-b-PNIPAAM) were *** well-controlled structures of these copolymers with functional groups and blocks were characterized by gel permeation chromatography(GPC) and 1H NMR *** copolymers with functionalized hydrophilic blocks were fabricated into microspheres for the examination of biofunctions via cell culture experiments and in vitro drug *** results indicated the significance of introducing functional groups(e.g.,NH2,COOH and RGD) into the end of the hydrophilic block of amphiphilic block copolymers for biomedical potentials in tissue engineering and controlled drug release.

关键词： amphiphilic block copolymers biodegradable polymers functional terminal group cell growth drug release

Highly stereospecific polymerization of isoprene with homogeneous binary Ziegler-Natta catalysts based on NCN-pincer neodymium precursor

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Science china Chemistry 2010年第8期53卷 1641-1645页

作者： LIU DongTao1,2,CUI DongMei1 & GAO Wei3 1State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry,chinese academy of sciences,Changchun 130022,china 2graduate university of chinese academy of sciences,beijing 100039,china 3School of Chemistry,Jilin university,Changchun 130012,china 1. State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun 130022 China2. Graduate University of Chinese Academy of Sciences Beijing 100039 China3. School of Chemistry Jilin University Changchun 130012 China

The aryldiimine NCN-pincer stabilized neodymium dichloride combined with aluminum alkyls established a new type of homogeneous binary neutral Ziegler-Natta catalyst *** system exhibited high activity and high cis-1,4 selectivity for the polymerization of isoprene (Tp=20 °C,98.2%;Tp=-20 °C,> 99%).Such catalytic performances remained under a broad range of polymerization temperatures and monomer-to-neodymium ratios (from 500 to 8000),reaching high number-average molecular weight (Mn=1582 kg/mol) and relatively narrow molecular weight distribution (PDI=1.68),which was,however,influenced by the amount and bulkiness of aluminum *** investigation of the polymerization was performed,which showed the number-average molecular weight of the resultant polyisoprene had an almost linear correlation with the conversion,suggesting,in some degree,the polymerization with this catalytic system was controllable.

关键词： neodymium cis-1 4 selectivity NCN-pincer complex polyisoprene

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森林生态系统的水源涵养功能及其计量方法

生态学杂志 2009年第3期28卷 529-534页

作者：张彪李文华谢高地肖玉中国科学院地理科学与资源研究所北京100101 中国科学院研究生院北京100039

为全面认识与正确评价森林生态系统的水源涵养功能,本文探讨了其概念、表现形式及其计量方法,认为:1)森林的水源涵养功能是一个动态、综合的概念,随着人们对森林水文作用认识的不断深入,其内涵不断丰富扩大,因此森林的水源涵养功能概念... 详细信息

为全面认识与正确评价森林生态系统的水源涵养功能,本文探讨了其概念、表现形式及其计量方法,认为:1)森林的水源涵养功能是一个动态、综合的概念,随着人们对森林水文作用认识的不断深入,其内涵不断丰富扩大,因此森林的水源涵养功能概念存在狭义和广义之分;2)森林的水源涵养功能(广义)有多种表现形式,包括拦蓄降水、调节径流、影响降雨和净化水质等,不过其具体表现形式与研究对象、研究目的以及研究尺度有关;3)目前森林拦蓄降水功能的计量方法主要有土壤蓄水能力法、水量平衡法、年径流量法和多因子回归法等8种,不过这些方法都存在一定的局限性,实际应用中需要综合考虑。

关键词：森林生态系统水源涵养功能表现计量方法

伊乐藻(Elodea nuttallii)对高浓度氮磷营养盐的耐受性

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生态学杂志 2009年第12期28卷 2561-2566页

作者：王小冬秦伯强高光杨桂军王洪艳宋玉芝冯胜中国科学院南京地理与湖泊研究所湖泊与环境国家重点实验室南京210008 中国科学院研究生院北京100039 南京信息工程大学南京210044

通过5个相对恒定的TN、TP浓度梯度下伊乐藻(Elodea nuttallii)的生长实验,探讨了伊乐藻对高浓度氮磷营养盐的耐受性,比较了各营养盐浓度下水体的pH值、DO、浮游藻类叶绿素a和附着藻类叶绿素a以及伊乐藻的株高、湿质量、干质量和叶绿素a... 详细信息

通过5个相对恒定的TN、TP浓度梯度下伊乐藻(Elodea nuttallii)的生长实验,探讨了伊乐藻对高浓度氮磷营养盐的耐受性,比较了各营养盐浓度下水体的pH值、DO、浮游藻类叶绿素a和附着藻类叶绿素a以及伊乐藻的株高、湿质量、干质量和叶绿素a含量。结果表明:在实验条件下,伊乐藻能耐受TN=10mg·mL-1,TP=0.4mg·mL-1的胁迫,且在该营养盐水平下水体中没有出现大量的浮游藻类;而在TN=50mg·mL-1、TP=2mg·mL-1和TN=100mg·mL-1、TP=4mg·mL-1的高营养盐条件下,伊乐藻的生长受到了明显的抑制,同时水体中的浮游藻类明显增多,而附着藻类则明显减少;在高营养盐水平下,一方面水体中的某些营养盐可能对伊乐藻产生了直接伤害,另一方面水体中浮游藻类的增多,所导致的遮光作用也可能限制了其生长;对水体中营养盐的平均水平低于TN=10mg·mL-1,TP=0.4mg·mL-1的太湖而言,沉水植被的消亡可能不是由于氮磷营养盐所产生的直接伤害和胁迫。

关键词：营养盐胁迫伊乐藻生长耐受性

Effects of cosmological constant on motion of UHECR particles

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Science china(Physics,Mechanics & Astronomy) 2005年第1期48卷 44-56页

作者： CHEN Shaoxia & CHANG Zhe Institute of High Energy Physics, chinese academy of sciences, beijing 100039, china graduate School of chinese academy of sciences, beijing 100039, china Institute of High Energy Physics Chinese Academy of Sciences Beijing 100039 China graduate School Chinese Academy of Sciences Beijing 100039 China

Recent astronomical observations manifest that about two-thirds of the whole energy in the Universe is contributed by a small positive cosmological constant A (> 0). Then, an asymptotically de Sitter spacetime is premised naturally. However, physics in the de Sitter spacetime is very different from that in the Minkowski spacetime. As the first step, a covariant formalism of the kinematics in the de Sitter spacetime is presented here. By solving exactly the equations of motion for a field, we obtain the dispersion relation of a free particle. It is noticed that the dispersion relation is dependent on the degree of freedom of angular momentum of the particle. We show the threshold anomaly of the ultra high energy cosmic ray disappears naturally in the framework of the de Sitter kinematics.

关键词： ultrahigh energy cosmic ray, cosmological constant, curved spacetime.

A new class of symmetric periodic solutions of the spatial elliptic restricted three-body problem

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Science china(Physics,Mechanics & Astronomy) 2009年第9期52卷 1404-1413页

作者： XU XingBo1,2 & FU YanNing1 1 Purple Mountain Observatory, chinese academy of sciences, Nanjing 210008, china 2 graduate university of chinese academy of sciences, beijing 100039, china 1. Purple Mountain Observatory Chinese Academy of Sciences Nanjing 210008 China 2. graduate university of chinese academy of sciences Beijing 100039 China

We show that there exists a new class of symmetric periodic solutions of the spatial elliptic restricted three-body problem. In such a solution, the infinitesimal body is confined to the vicinity of a primary and moves on a nearly circular orbit. This orbit is almost perpendicular to the orbital plane of the primaries, where the line of symmetry of the orbit lies. The existence is shown by applying a corollary of Arenstorf's fixed point theorem to a periodicity equation system of the problem. And this existence doesn't require any restriction on the mass ratio of the primaries, nor on the eccentricity of their relative elliptic orbit. Potential relevance of this new class of periodic solutions to real celestial body systems and the follow-up studies in this respect are also discussed.

关键词： periodic orbits spatial restricted three-body problem symmetric orbits averaging

Observation results of relativistic electrons detected by Fengyun-1 satellite and analysis of relativistic electron enhancement (REE) events

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Science china(Physics,Mechanics & Astronomy) 2008年第12期51卷 1947-1956页

作者： YANG XiaoChao1,2↑ & WANG ShiJin1 1 Center for Space Science and Applied Research, chinese academy of sciences, beijing 100190, china 2 graduate university of chinese academy of sciences, beijing 100049, china 1. Center for Space Science and Applied Research Chinese Academy of Sciences Beijing 100190 China 2. graduate university of chinese academy of sciences Beijing 100049 China

The space particle component detector on Fengyun-1 satellite which works at the sun-synchronous orbit of about 870 km altitude has detected relativistic electrons for a long time. In comparison with the SAMPEX satellite observations during 1999–2004, the relativistic electron data from Fengyun-1 satellite from June 1999 to 2005 are used to analyze the relativistic electron enhancement (REE) events at the low earth orbit, and the possible correlation among REE events at the low earth orbit, high-speed solar wind and geomagnetic storms is discussed. The statistical result presents that 45 REE events are found in total during this time period, and the strong REE events with the maximum daily average flux > 400 cm?2·srt-1·s?1 occur mostly during the transition period from solar maximum to solar minimum. Among these 45 REE events, four strong REE events last a longer time period from 26-to 51-day and correlate closely with high speed solar wind and strong geomagnetic storms. Meanwhile, several strong geomagnetic storms occur continuously before these REE events, and these continuous geomagnetic storms would be an important factor causing these long-lasting strong REE events. The correlation analysis for overall 45 events indicates that the strength of the REE events correlates with the solar wind speed and the strength of the geomagnetic storm, and the correlation for strong REE events is much stronger than that for weak REE events.

关键词： relativistic electron enhancement low earth orbit high-speed solar wind geomagnetic storm

The deep thermal characteristic of continental margin of the northern South china Sea

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chinese Science Bulletin 2000年第18期45卷 1717-1722页

作者： ZHANG Jian & WANG Jiyang1. graduate School, university of Science and Technology of china, chinese academy of sciences, beijing 100039, china 2. Institute of Geology, chinese academy of sciences, beijing 100029, china graduate School University of Science and Technology of China Chinese Academy of Sciences Beijing China Institute of Geology Chinese Academy of Sciences Beijing China

Heat flow plays an important role in the study ot thermal structure and thermal evolutionof continental margin of the northern South china Sea. The analysis of heat flow value shows that margin heat flow in the northern South china Sea is relatively high setting, but the percentage of crustal heat flow is lower than 35% in terrestrial heat flow. The terrestrial heat flow exhibited a current of rise from the Northern Continental Margin to the Southern Central Basin. However, the proportion of crustal heat flow in terrestrial heat flow slowly dropped down in the same direction. It is suggested that the main factor causing high heat flow setting is the moving up of hot material from asthenosphere.

关键词： margin of northern South china Sea terrestrial heat flow thermal structures.

Ionization state of cosmic hydrogen by early stars and quasars

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Research in Astronomy and Astrophysics 2009年第6期9卷 665-681页

作者： Xiao-Chun Mao1,2 1 National Astronomical Observatories, chinese academy of sciences, beijing 100012, china 2 graduate university of chinese academy of sciences, beijing 100049, china National Astronomical Observatories Chinese Academy of Sciences Beijing 100012 China graduate university of chinese academy of sciences Beijing 100049 China

Cosmic hydrogen is reionized and maintained in its highly ionized state by the ultraviolet emission attributed to an early generation of stars and quasars. The Lyα opacity observed in absorption spectra of high-redshift quasars permits more stringent constraints on the ionization state of cosmic hydrogen. Based on density perturbation and structure formation theory, we develop an analytic model to trace the evolution of the ionization state in the post-overlap epoch of reionization, in which the bias factor is taken into account. For quasars, we represent an improved luminosity function by utilizing a hybrid approach for the halo formation rate that is in reasonable agreement with the published measurements at 2 ≤ z ≤ 6. Comparison with the classic Press-Schechter mass function of dark matter halos, we demonstrate that the biased mass distribution indeed enhances star formation efficiency in the overdense environment by more than 25 per cent following the overlap of ionized bubbles. In addition, an alternative way is introduced to derive robust estimates of the mean free path for ionizing photons. In our model, star-forming galaxies are likely to dominate the ionizing background radiation beyond z = 3, and quasars contribute equally above a redshift of z ～ 2.5. From 5 ≤ z ≤ 6, the lack of evolution in photoionization rate can thus be explained by the relatively flat evolution in star formation efficiency, although the mean free path of ionizing photons increases rapidly. Moreover, in the redshift interval z ～ 2 - 6, the expected mean free path and Gunn-Peterson optical depth obviously evolve by a factor of ～ 500 and ～50 respectively. We find that the relative values of critical overdensities for hydrogen ionization and collapse could be 430% at z ≈2 and 2% at z ≈6, suggesting a rapid overlap process in the overdense regions around instant quasars following reionization. We further illustrate that the absolute estimates of the fraction of neutral hydrogen computed fr

关键词： cosmology theory -- formation galaxies -- quasars general -- diffuse radiation -- intergalactic medium

Recent advances in the data analysis method of functional magnetic resonance imaging and its applications in neuroimaging

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Progress in Natural Science:Materials International 2006年第8期16卷 785-795页

作者： TIAN Jie, YANG Lei and HU Jin (Institute of Automation, chinese academy of sciences, beijing 100080, china graduate School of chinese academy of sciences, beijing 100039, china) [a]chinese academy of sciences Institute of Automation Beijing China [b]graduate School of chinese academy of sciences Beijing China

Functional magnetic resonance imaging (fMRI) has opened a new area to explore the human brain. The fMRI can reveal the deep insights of spatial and temporal changes underlying a broad range of brain function, such as motor, vision, memory and emotion, all of which are helpful in the clinical investigation. In this paper, we introduce some recent-developed algorithms for fMRI signal detection such as model-driven method (general linear model, deconvolution model, non-linear model, etc. ) and data-driven method (principle component analysis, independent component analysis, self-organization mapping, clustered constrained non-negative matrix factorization, etc. ). We also propose several important applications of neuroimaging and point out their shortcomings and future perspectives.

关键词： fMR1 data analysis neuroimaging.