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Spatio-temporal carbon isotope variation during the Ediacaran period in South china and its impact on bio-evolution

Science china Earth Sciences 2009年第10期52卷 1520-1528页

作者： WANG XinQiang1 & SHI XiaoYing1,2.1 School of Earth Science and mineral resources,{2., Beijing 100083, china 2.state key Laboratory of geological Processes and mineral resources, Beijing 100083, china School of Earth Science and mineral resources China University of Geosciences Beijing 100083 China state key Laboratory of {2. Processes and mineral resources Beijing 100083 China

The Ediacaran period is characterized by the extremely negative carbon isotope anomalies and great biotic evolution in Earth history. At least four negative carbon isotope anomalies have been reported from this interval in South china so far. It is traditionally argued that the isotope variations can be used as a useful tool for global correlation of Ediacaran succession; however, more and more researches argued against this idea. We reviewed the previously published carbon isotope data in South china, and distributed the mean values of a certain time to the paleogeographic maps. The results show that the carbon isotope values (δ13C) vary greatly in different environments, but a clear tendency of becoming lighter from shallow platform to deep basin, with a maximum variation up to 1‰ Moreover, the important changes in Ediacaran biota, marked by the introducing of new taxa or ecologic groups, seemed to always postdate the negative anomalies but coincide with the positive shift. If the negative excursions represented the oxidation of a large dissolved organic carbon (DOC) reservoir in the ocean, the diverse Ediacaran organisms and the carbon isotope anomalies may suggest totally different environments: oxic and anoxic/euxinic. We also suggest that the elimination of euxinic {2. through precipitation of pyrites is one of the important environment factors in prompting the Ediacaran bio-evolution.

关键词： Ediacaran South china carbon isotope spatio-temporal variations bio-evolution

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Exsolution of ilmenite and Cr-Ti magnetite from olivine of garnet-wehrlite

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Science china Earth Sciences 2005年第9期48卷 1368-1376页

作者： LIU Xiangwen1,2. JIN Zhenmin1,3, QU Jing2.& WANG Lu2.1. state key Laboratory of {2. Processes and mineral resources, china university of geosciences, Wuhan 430074, china 2. Graduate School of china university of geosciences, Wuhan 430074, china 3. Faculty of Earth Sciences, china university of geosciences, Wuhan 430074, china 1. state key Laboratory of {2. Processes and mineral resources China University of Geosciences 430074 Wuhan China 2. Graduate School of china university of geosciences 430074 Wuhan China 3. Faculty of Earth Sciences China University of Geosciences 430074 Wuhan China

Exsolution of rod-like ilmenite (Ilm) and Cr-Ti magnetite (Mt) have been found in olivine of garnet-wehrlite from the core of Chinese Continental Sciences Drilling (CCSD). Their composition, morphology, crystal structure and their topotaxies with host olivine have been studied in detail by the transmission electron microscopy (TEM) and electron probe microanaly- sis (EPMA) technique. It shows that rod-like Ilm exsolution reported in this paper has similar characteristic with that of Alpe Arami olivine, while Cr-Ti magnetite exsolution mentioned in this paper has large discrepancy with chromite exsolution in Alpe Arami olivine. These observations suggest that both of the exsolutions found in this paper should be solid solution phases in β-olivine at their first period, then experiencing decomposition of solid solution and therefore forming Ilm and Cr-Ti magnetite exsolution with the pressure decreasing. So, this garnet-wehrlite perhaps had been ever located in mantle transition zone with a minimum depth of 300 km.

关键词： garnet-wehrlite, ilmenite, magnetite, exsolution, CCSD.

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Indian Ocean-MORB-type isotopic signature of Yushigou ophiolite in North Qilian Mountains and its implications

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Science china Earth Sciences 2006年第6期49卷 561-572页

作者： HOU Qingye1,2. ZHAO Zhidan1,2. ZHANG Hongfei3, ZHANG Benren3 & CHEN Yuelong2.1. state key Laboratory of {2. Processes and mineral resources, china university of geosciences, Beijing 100083, china 2. School of Earth Science and mineral resources, china university of geosciences, Beijing 100083, china 3. Faculty of Earth Sciences, china university of geosciences, Wuhan 430074, china 1. state key Laboratory of {2. Processes and mineral resources China University of Geosciences Beijing 100083 China 2. School of Earth Science and mineral resources China University of Geosciences Beijing 100083 China 3. Faculty of Earth Sciences China University of Geosciences Wuhan 430074 China

In order to explore the disputed issue concerning the tectonic affinity ofthe ancient ocean mantle of North Qilian Mountains (NQM), geochemical and Sr, Nd, Pb isotopiccompositions of pillow basalts of the Yushigou Ophiolite (YSGO) suite from NQM have been analyzedsystematically. The pillow basalts exhibit tholeiitic characteristics, with flatchondrite-normalized REE patterns ((La/Yb)_N = 0.98—1.2.). They display no Nb, Ta, Zr, Hf negativeanomalies, and show MORB features in 2.b-Zr/4-Y and Ti/100-Zr-YX3 tectonic discrimination *** results indicate that the Yushigou ophiolite is most likely to be formed in a mid-ocean ridgeor mature back-arc basin. Their isotopic data show a relatively broad and enriched ^(87)Sr/^(86)Sr(0.70509 — 0.70700), restricted ^(143)Nd/^(144)Nd (0.512.55-0.512.78). Pb isotopes are in the rangeof ^(2.6)Pb/^(2.4)Pb (18.054-2..562., ^(2.7)Pb/^(2.4)Pb (15.537-15.743) and ^(2.8)Pb/^(2.4)Pb(38.068-38.530). These isotopic data imply that the basalts originated from the depleted mantle(DMM), with the involvement of enriched mantle components (mainly EMII). Geochemical comparisonsbetween the basalts in YSGO and the MORB-type basalts of ophiolite suites occurring in the knownancient Tethyan tectonic domain indicate that the ancient oceanic mantle represented by YSGO suiteforming in early Paleozoic in the North Qilian Moutains is very similar to the Tethyan mantle inboth trace elements and isotopic compositions. The North Qilian Mountains should be a part of theTethyan tectonic domain in early Paleozoic. This further implies that the Tethyan tectonic domaincan be deduced to early Paleozoic in the study area, which will be helpful to discussing thetectonic affinity and evolution of the North Qilian Mountains.

关键词： geochemistry, Indian Ocean-MORB-type isotopic signatures, Tethyan tectonic domain, Yushigou ophiolite, North Qilian Mountains.

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The equilibrium between diagenetic calcites and dolomites and its impact on reservoir quality in the sandstone reservoir of Kela 2.gas field

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Progress in Natural Science:Materials International 2007年第9期17卷 1051-1058页

作者： Gao Zhiqian1,Yu Bingsong2.3 and Lai Xingyun2.3(1.School of Energy resources,china {2. of geosciences,Beijing 100083,china 2.state key Laboratory of geological Processes and mineral resources,china {2. of geosciences,Beijing 100083,china 3.Ministry of Education key Laboratory of Lithosphere Structure,Deep Processes and Exploration Technique,china {2. of geosciences,Beijing 100083,china) School of Energy resources China University of Geosciences Beijing 100083 China state key Laboratory of {2. Processes and mineral resources China University of Geosciences Beijing 100083 China Ministry of Education key Laboratory of Lithosphere Structure Deep Processes and Exploration Technique China University of Geosciences Beijing 100083 China

Based on the equilibrium theory of chemical reactions between water and rocks,this paper establishes a thermodynamic phase relationship diagram among calcites,dolomites and water solution under the condition of diagenesis based on the thermodynamic database of related minerals and fluids and dolomite's degree of order *** has been discovered that the equilibrium between calcites and dolomites in the diagenetic environment is strongly impacted by temperature and the Ca/Mg ratios in groundwater,and that the dolomite's degree of order in the diagenetic environment is a function of crystallization temperature and time,not controlled by water ***,the authors make a further analysis of the close relationship of chemical reaction between carbonate cements and pore water in the sandstone reservoirs of Kala 2.gas field in Kuche *** can be seen that there are different impacts on sandstone reservoir quality among the equilibrium system of calcites,dolomites and pore water at different depths of reservoirs.

关键词： diagenesis equilibrium between calcites and dolomites secondary pores Kela 2.gas field

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Science china Earth Sciences 2004年第10期47卷 896-911页

作者： ZHANG Changhou1,2. WU Ganguo1,2. WANG Genhou2. ZHANG Weijie2.& SONG Honglin2.1. key Laboratory of Lithospheric Tectonics and Lithoprobing Technology, china university of geosciences, Ministry of Education of{2., Beijing 100083,{2. 2. School of Earth Sciences and mineral resources, china university of geosciences, Beijing 100083,{2. 1. key Laboratory of Lithospheric Tectonics and Lithoprobing Technology China University of Geosciences Ministry of Education of China 100083 Beijing China 2. School of Earth Sciences and mineral resources China University of Geosciences 100083 Beijing China

The northwest trending tectonic belt in the middle part of the Mesozoic intraplate Yanshan Orogenic Belt, northeast Hebei Province, is composed of thrusts, extensional faults, strike-slip faults and syntectonic sedimentations as well. The northeastward basement-involved major thrusting deformation occurred between 174Ma and 168MaBP and was followed by an intrusion of the granitic plutonic rocks. As a part of the post-thrusting extensional deformations a northwest extending volcano-sedimentation system of Late Jurassic and Early Cretaceous formed in the southwest side of the belt. These volcano-sedimentary sequences are divided into Tuchengzi Formation, Zhangjiakou Formation, Yixian Formation and Jiufotang Formation re- spectively. They are characterized by southeastward migration as a result of the increasing down-dip slip displacement along the major extensional fault toward the southeast of the belt. The provenance area of the Jiufotang Formation north to it experienced southwestward thrusting during and after its later sedimentation. The thrusting in this stage resulted in the formation of an asymmetric footwall syncline with vergence to SW in the Jiufotang Formation in the NE side of the basin. Finally a dextral strike-slip deformation occurred along the NW tectonic belt. The striking tectono-geomorphological features and present seismic activities along this belt indicate that it has been being active since Cenozoic era and is still in the active state at present. This northwest extending tectonic belt was following the same direction and location as the existing fault systems within the basement as revealed by former geological and geophysical studies. So it is reasonable to infer the Mesozoic deformation along this belt to be a result of reactivation of the basement structures in a favorable tectonic stress field. The reactivation of basement struc- tures might be taken as one of the mechanisms of intraplate deformation and orogeny.

关键词： Yanshan Orogenic Belt, northwest extending tectonic complex, thrust system, geochronology.

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Nb/Ta variations of mafic volcanics on the Archean- Proterozoic boundary: Implications for the Nb/Ta imbalance

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Science china Earth Sciences 2005年第8期48卷 1106-1119页

作者： LIU Yongsheng1,2. GAO Shan1,2. WANG Xuance1, HU Shenghong1 & WANG Jianqi2.1. state key Laboratory of {2. Processes and mineral resources, china university of geosciences, Wuhan 430074, china 2. key Laboratory of Continental Dynamics, Department of Geology, Northwest university, Xi’an 710069, china 1. state key Laboratory of {2. Processes and mineral resources China University of Geosciences 430074 Wuhan China 2. key Laboratory of Continental Dynamics Department of Geology Northwest University 710069 Xi’an China

The HFSE and REE of the Precambrian mafic volcanics from the North china craton demonstrate obvious A(Archean)-P(Proterozoic) boundary. The Neoarchean mafic vol- canics show weak correlation between HFSE and TiO2. Their superchondritic Nb/Ta ratio (18.8±1.2. could be attributed to partial melting of mantle peridotite in the presence of garnet. Compared with Neoarchean mafic volcanics, the Paleoproterozoic ones have higher HFSE contents and lower Nb/Ta ratio (15.6±2.9). The significantly elevated HFSE and REE contents of Paleoproterozoic mafic volcanics imply metasomatic enrichment of mantle source, in which Ti-rich silicates could be present as suggested by significant positive correlations between TiO2.and HFSE. The global database of Precambrian mafic volcanics shows a similar A-P boundary. 2. Archean mafic volcanic suites yield an average Nb/Ta ratio of 17.8±1.9 higher than or close to the PM value; Proterozoic mafic volcanics from 2. suites yield an average Nb/Ta ratio of 14.7±4.1 close to the bulk continental crust (BCC) value (11―17.5). Thus, we suggest that the Nb/Ta deficit could be mainly formed in post-Archean time. Archean mafic volcanics could be one of the geochemical reservoirs complementing the low Nb/Ta of the post-Archean continental crust and DM.

关键词： Precambrian mafic volcanics, Nb/Ta deficit, Archean-Proterozoic boundary.

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Geochemistry of the high-Mg andesites at Zhangwu, western Liaoning: Implication for delamination of newly formed lower crust

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Science china Earth Sciences 2007年第12期50卷 1773-1786页

作者： HUANG Hua1,GAO Shan1,2.HU ZhaoChu1,LIU XiaoMing2.& YUAN HongLing2.1 state key Laboratory of {2. Processes and mineral resources,china university of geosciences,Wuhan 430074,china 2.state key Laboratory of Continental Dynamics,Department of Geology,Northwest university,Xi’an 710069,china 1. state key Laboratory of {2. Processes and mineral resources China University of Geosciences Wuhan 430074 China 2. state key Laboratory of Continental Dynamics Department of Geology Northwest University Xi’an 710069 China

Ten volcanic samples at Zhangwu,western Liaoning Province,North china were selected for a sys-tematic geochemical,mineralogical and geochronological study,which provides an opportunity to ex-plore the interaction between the continental crust and mantle beneath the north margin of the North china *** one basalt sample(SiO2. 50.2.%),the other nine samples are andesitic with SiO2.contents ranging from 53% to 59%.They have relatively high MgO(3.4%―6.1%,Mg#=50―64) and Ni and Cr contents(Ni 2.×10?6―197×10?6,Cr 51×10?6―478×10?6).Other geochemical characteristics of Zhangwu high-Mg andesites(HMAs) include strong fractionation of light rare earth elements(LREE) from heavy rare earth elements(HREE),and Sr from Y,with La/Yb greater than 15,and high Sr/Y(34― 115).Zircons of andesite YX2.0 yield three age groups with no Precambrian age,which precludes ori-gin of the Zhangwu HMAs from the partial melting of the Precambrian *** oldest age group peaking at 2.3 Ma is interpreted to represent the collision of the Siberia block and the North china block,resulting in formation of the Central Asian orogenic belt by closure of the Mongol-Okhotsk *** intermediate age group corresponds to the basalt underplating which caused the wide-spread coeval granitoids in the North china craton with a peak 2.6Pb/2.8U age of 172.*** youngest age group gives a 2.6Pb/2.8U age of 12.±2.Ma,which is interpreted as the eruption age of the Zhangwu *** high 87Sr/86Sri(12. Ma)>0.706 and low εNd(t)= ?6.36―?13.99 of the Zhangwu HMAs are distinct from slab *** common presence of reversely zoned clinopyroxene phenocrysts in the Zhangwu HMAs argues against the origin of the Zhangwu HMAs either from melting of the water saturated mantle or melting of the lower *** light of the evidence mentioned above,the envisaged scenario for the formation of the Zhangwu HMAs is related to the basaltic underplating at the base of the crust,which led to the thickening of the lower crust and

关键词： Zhangwu HMAs, basalt underplating, newly formed lower crust, delamination, North china craton

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Mechanism for calcite dissolution and its contribution to development of reservoir porosity and permeability in the Kela 2.gas field,Tarim Basin,china

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Science china Earth Sciences 2008年第4期51卷 567-578页

作者： YU BingSong1,3, DONG HailLiang2.3 & RUAN Zhuang1,3 1 state key Laboratory of {2. Processes and mineral resources, china university of geosciences, Beijing 100083, china 2.Department of Geology, Miami university,Oxford, OH 45056, USA 3 Geomicrobiology Laboratory, china university of geosciences, Beijing, 100083, china state key Laboratory of {2. Processes and mineral resources China University of Geosciences Beijing 100083 China Department of Geology Miami University Oxford OH 45056 USA Geomicrobiology Laboratory China University of Geoscien

This study is undertaken to understand how calcite precipitation and dissolution contributes to depth-related changes in porosity and permeability of gas-bearing sandstone reservoirs in the Kela 2.gas field of the Tarim Basin, Northwestern china. Sandstone samples and pore water samples are col-lected from well KL2.1 in the Tarim Basin. Vertical profiles of porosity, permeability, pore water chem-istry, and the relative volume abundance of calcite/dolomite are constructed from 3600 to 4000 m below the ground surface within major oil and gas reservoir rocks. Porosity and permeability values are in-versely correlated with the calcite abundance, indicating that calcite dissolution and precipitation may be controlling porosity and permeability of the reservoir rocks. Pore water chemistry exhibits a sys-tematic variation from the Na2.O4 type at the shallow depth (3600-3630 m), to the NaHCO3 type at the intermediate depth (3630―3695 m),and to the CaCl2.type at the greater depth (372.―3938 m). The geochemical factors that control the calcite solubility include pH, temperature, pressure, Ca2. concen-tration, the total inorganic carbon concentration (ΣCO2., and the type of pore water. Thermodynamic phase equilibrium and mass conservation laws are applied to calculate the calcite saturation state as a function of a few {2. parameters. The model calculation illustrates that the calcite solubility is strongly dependent on the chemical composition of pore water, mainly the concentration difference between the total dissolved inorganic carbon and dissolved calcium concentration (i.e., [ΣCO2. -[Ca2.]). In the Na2.O4 water at the shallow depth, this index is close to 0, pore water is near the calcite solubility. Calcite does not dissolve or precipitate in significant quantities. In the NaHCO3 water at the intermedi-ate depth, this index is greater than 0, and pore water is supersaturated with respect to calcite. Massive calcite precipitation was observed at this depth interval and

关键词： calcite dissolution porosity thermodynamic Tarim Basin

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Petrogenesis of Indosinian volcanic rocks in Songpan-Garze fold belt of the northeastern Tibetan Plateau:New evidence for lithospheric delamination

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Science china Earth Sciences 2010年第9期53卷 1316-1328页

作者： CAI HongMing1,2. ZHANG HongFei1,2. XU WangChun1,2. SHI ZhangLiang1,2.& YUAN HongLin3 1 state key Laboratory of {2. Processes and mineral resources, Wuhan 430074, china 2.Faculty of Earth Sciences, china university of geosciences, Wuhan 430074, china 3 state key Laboratory of Continental Dynamics, Northwest university, Xi’an 710069, china 1. state key Laboratory of {2. Processes and mineral resources Wuhan 430074 China2. Faculty of Earth Sciences China University of Geosciences Wuhan 430074 China3. State Key Laboratory of Continental Dynamics Northwest University Xi’an 710069 China

In the Songpan-Garze fold belt of the northeastern Tibetan Plateau, an Indosinian lithospheric delamination model has been proposed, based on previous investigation of widespread granitoids. However, this model lacks comparable information from volcanism in the area. During the Indosinian delamination in the Songpan-Garze fold belt, whether partial melting of litho- spheric mantle taken place is debated. This paper reports U-Pb zircon LA-ICP-MS ages, geochemical and Sr-Nd-Hf isotopic compositions from the Aba and Wasai calc-alkaline volcanic rocks in the central Songpan-Garze fold belt. Obtained magma crystallization ages are 2.0±3 Ma for the Aba andesite and 2.5±1 Ma for the Wasai andesite. These are consistent with magma crystallization ages of the late Indosinian granitoids in the Songpan-Garze fold belt that formed in a post-collisional tectonic setting. The Aba and Wasai andesites have distinct geochemical singnatures. The former has higher Al2.3, K2., Rb but lower Na2., Ba and Sr contents, suggesting differences in their magmatic evolution. The Aba andesites have ISr values of 0.7070-0.7076 and εNd(t) values of -3.9 to -5.3, and the Wasai andesites have ISr values of 0.7075-0.7077 and εNd(t) values of -3.6 to -3.9. Zircons show εHf(t) values of -3.7 to 0.3 for the Aba andesites and -2.7 to 5.5 for the Wasai andesites. Geochemical and Sr-Nd-Hf isotopic compositions indicate that fractional crystallization and crustal assimilation processes are not key roles for their magma evolution, implying that their chemical compositions are those of primary melts. We suggest that the magma of the Aba andesites originated predominantly from a crustal source, with a minor mantle-derived component. The source region of the magma was likely at the crust-mantle boundary. The magma of the Wasai andesites resulted from partial melting of lithospheric mantle, which was probably metasomatized by fluids so that it was amphibole bearing. The petrogenesis of the Aba and Wasai andesite

关键词： volcanism U-Pb dating geochemistry petrogenesis lithospheric delamination Songpan-Garze fold belt

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Multistage evolution of continental collision orogen:A case study for western Dabie orogen

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Chinese Science Bulletin 2009年第15期54卷 2568-2579页

作者： WU YuanBao state key Laboratory of {2. Processes and mineral resources, Faculty of Earth Sciences, china university of geosciences, Wuhan 430074, china state key Laboratory of Continental Dynamics, Department of Geology, Northwest university, Xi’an 710069, china state key Laboratory of {2. Processes and mineral resources Faculty of Earth Sciences China University of Geosciences Wuhan 430074 China state key Laboratory of Continental Dynamics Department of Geology Northwest University Xi’an 710069 China

The foramtion and evolution of collisional orogen is a prominent feature along convergent plate margins, and is generally a complex process. This article presents an integrated study of zircon genesis, U-Pb age and Lu-Hf isotope composition as well as geological characteristics for the western Dabie orogen to constrain its multi-stage evolution history. The results suggest that the formation of oceanic crust in the Huwan area was constrained at ca. 400―430 Ma, which was slightly later than the collision of the northern Qinling with the North china Block. It formed in a marginal basin in the northern margin of the Yangtze Block. The peak metamorphism of eclogite in the Huwan area occurred at ca. 310 Ma, and the timing of the initial exhumation of oceanic eclogite was about 2.0 Ma. The high to ultrahigh pressure (HP-UHP) metamorphic rocks in the Xinxian and the Hong'an metamorphic zones have the same ages and natures as those of the HP-UHP metamorphic rocks in the other Dabie-Sulu terrains, and also have experienced multi-stage exhumation, and thus can be taken as a coherent part of the Dabie-Sulu orogen. Therefore, the Qinling-Dabie-Sulu orogen is a typical multi-stage continental collision orogen, with an amalgamation process extending more than 2.0 Ma.

关键词：大别造山带大陆碰撞西部演变超高压变质岩碰撞造山带苏鲁造山带变质岩区

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