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Photogeneration of the free radicals and singlet oxygen by chrysophanol from rheum

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Science china Chemistry 2004年第5期47卷 381-387页

作者： RAO Jing1,2. XIE Jie1, ZHAO Jingquan1 & ZHU Teng2.1. key {3. of Photochemistry, Center for Molecular Science, {2. of Chemistry, The chinese academy of sciences, beijing 100080, china 2. University of Science and Technology beijing, beijing 10083. china 1. key laboratory of Photochemistry Center for Molecular Science Institute of Chemistry The Chinese Academy of Sciences 100080 Beijing China 2. University of Science and Technology beijing 10083 Beijing China

In the current work, chryosphanol (MHAQ) was isolated and purified from rheum, and the photosensitization activities were studied. In nitrogen-saturated DMSO solution, irradia- tion of chryosphanol (MHAQ) with visible light (>43. nm) produced the semiquinone radical anions (MHAQ??), which was intensified significantly by an electron donor NADH, suggesting electron transfer between the excited and ground state photosensitizer molecules. In an air-saturated DMSO solution, superoxide radical anions (O2.), trapped by DMPO, were detected. ?? It was proved that O2.was not originated from the singlet oxygen (1O2. but dependent on DMPO, ?? chrysophanol, oxygen and the irradiation time. The singlet oxygen and OH could also be pro- ? duced by the photosensitization of the photosensitizer. These suggest that chrysophanol pos- sesses the photosensitization activity via Type I mechanism and Type II mechanism. To evaluate the photosensitization activities of MHAQ, emodin and mixed anthraquinone derivatives ex- tracted from rheum, the relative productivities of O2.were estimated to be 1.8, 1.1 and 1.0 re- ?? spectively and the quantum yields for singlet oxygen to be 0.3., 0.53.and 0.14 respectively. Therefore, these low-cost pigments may be potentially used as phototherapeutic medicine for some kind of vascular diseases or photo-activated pesticides.

关键词： chrysophanol, ESR, semiquinone radical anions, superoxide radical anions, hydroxyl radical, singlet oxygen.

DMTB:A comprehensive online resource of 16S rRNA genes,ecological metadata,oligonucleotides,and magnetic properties of magnetotactic bacteria

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chinese Science Bulletin 2011年第6期56卷 476-478页

作者： LIN Wei1,2. LI Bi1,2.& PAN YongXin1,2.1 Paleomagnetism and Geochronology {3., key {3. of the Earth’s Deep Interior, institute of Geology and geophysics, chinese academy of sciences, beijing 10002., china 2.France-china Bio-Mineralization and Nano-Structures {3., institute of Geology and geophysics, chinese academy of sciences, beijing 10002., china Paleomagnetism and Geochronology laboratory Key Laboratory of the Earth"s Deep Interior Institute of Geology and Geophysics Chinese Academy of Sciences France-china Bio-Mineralization and Nano-Structures laboratory Institute of Geology and Geophysics

Magnetotactic bacteria (MTB) are of interest in microbiology, biomineralization, advanced magnetic materials, and bio-geo-sciences because of their ability to form highly ordered intracellular magnetic minerals. Great strides for MTB studies have been made in the past four decades. In this paper we complied the first internet-accessible database for MTB, Database of Magnestotactic Bacteria (DMTB). It contains information of 16S rRNA gene sequences, corresponding ecological metadata, oligonucleotides, and magnetic properties of MTB. The comprehensive information contained in DMTB will provide a very useful data resource for researchers from different disciplines. The website of DMTB is at http://***/.

关键词： rRNA基因序列趋磁细菌 16S 网上资源寡核苷酸磁学性质生态磁性材料

The gravitational gradient tensor’s invariants and the related boundary conditions

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Science china Earth sciences 2010年第5期53卷 781-790页

作者： YU JinHai1,2.3.& ZHAO DongMing4 1 College of Earth Science, Graduate University of chinese academy of sciences, beijing 100049, {2. 2.institute of Geodesy and geophysics, chinese academy of sciences, Wuhan 43.077, {2. 3.State key laboratory of Astronautic Dynamics, Xi’an 710043. {2. 4 Zhengzhou institute of Surveying and Mapping, Zhengzhou 450052. {2. 1. College of Earth Science Graduate University of Chinese Academy of Sciences Beijing 100049 China2. Institute of Geodesy and Geophysics Chinese Academy of Sciences Wuhan 430077 China3. State Key Laboratory of Astronautic Dynamics Xi’an 710043 China4. Zhengzhou Institute of Surveying and Mapping Zhengzhou 450052 China

Here we report new approaches of recovering the Earth gravitational field from GOCE (Gravity field and steady-state Ocean Circulation Explorer) gradiometric data with the help of the gradient tensor’s invariants. Our results only depend on GOCE satellite’s position and gradiometry, in other words, they are completely independent of the satellite attitude. First, starting from the invariants, linearization models are established, which can be referred as the general boundary conditions on the satellite’s orbit. Then, the spherical approximation expressions for the models are derived, and the corresponding solving methods for them are discussed. Furthermore, considering effects of J2.term, the spherical approximation models are improved so that the accuracies of the boundary conditions can be theoretically raised to O ( J 2.2.T), which is approximately equivalent to O(T2.. Finally, some arithmetic examples are constructed from EGM96 model based on the derived theories, and the computational results illustrate that the spherical models have accuracies of 10-7 and the order recovering the gravitational field can reach up to 2.0, and the models with regard to effect of J2.term have accuracies of 10-8 and the order can reach up to 2.0.

关键词： the Earth’s gravitational field gravitational gravidiometry tensor’s invariant

Sporopollen analysis of Core B10 in the southern Yellow Sea and the reflected characteristics of climate changes

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chinese Science Bulletin 2003年第B06期48卷 42-48页

作者： FU Mingzuo~(1,2.3., LI Zhen~1, XU Xiaowei~1 & SHl Xuefa~1 1. key laboratory of Marine Sedimentology and Environmental Geology, First {2. of Oceanography. State Oceanic Administration, Qingdao 2.6061. china 2. {2. of Oceanology, chinese academy of sciences, Qingdao 2.6071. china 3. Graduate School, chinese academy of sciences, beijing 10003.. china 1. key laboratory of Marine Sedimentology and Environmental Geology First institute of Oceanography State Oceanic Administration 266061 Qingdao China 2. institute of Oceanology Chinese Academy of Sciences 266071 Qingdao China 3. Graduate School Chinese Academy of Sciences 100039 Beijing China

Eight sporopollen zones have been divided based on the results of high-resolution sporopollen analysis of Core B10 in the southern Yellow Sea. Based on the results along with ^14C datings and the subbottom profiling data,climatic and environmental changes since the last stage of late Pleistocene are discussed. The main conclusions are drawn as follows: (1) the vegetation evolved in the process of coniferous forest-grassland containing broad-leaved trees→coniferous and broad-leaved mixed forest→coniferons and broad-leaved mixed forest-grassland prevailed by coniferous trees→coniferous and broad-leaved mixed forest-grassland containing evergreen broad-leaved trees→coniferons and broad-leaved mixed forest-grassland prevailed by broadleaved trees→deciduous broad-leaved forest-meadow containing evergreen broad-leaved trees→coniferous and broadleaved mixed forest-grassland prevailed by broad-leaved trees→coniferous and broad-leaved mixed forest containing evergreen broad-leaved trees; (2. eight stages of climate changes are identified as the cold and dry stage, the temperate and wet stage, the cold and dry stage, the warm and dry stage, the temperate and wet stage, the hot and dry stage, the temperate and dry stage, then the warm and dry stage in turn; (3. the sedimentary environment developed from land,to littoral zone, to land again, then to shore-neritic zone; and (4) the Yellow Sea Warm Current formed during early-Holocene rather than Atlantic stage.

关键词：中国黄海气候变化碳14年代测定底基压型数据更新世沉积环境大西洋

A zooarchaeological study of bone assemblages from the Ma'anshan Paleolithic site

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Science china Earth sciences 2010年第3期53卷 395-402页

作者： ZHANG Yue1,2.3. WANG ChunXue1,2. ZHANG ShuangQuan1,2.& GAO Xing1,2.1 institute of Vertebrate Paleontology and Paleoanthropology, chinese academy of sciences, {2. 100044 2.Joint laboratory of Human Evolution and Archaeometry, chinese academy of sciences, {2. 100044 3.State key laboratory of Palaeobiology and Stratigraphy, Nanjing 2.0008 1. institute of Vertebrate Paleontology and Paleoanthropology Chinese Academy of Sciences Beijing 100044 China2. Joint Laboratory of Human Evolution and Archaeometry Chinese Academy of Sciences Beijing 100044 China3. State Key Laboratory of Palaeobiology and Stratigraphy Nanjing 210008 China

Ten thousands of bone fragments were recovered from the Ma’anshan Paleolithic site, of which 43.8 pieces can be identified to skeletal elements or species. In this research, the bone assemblages are quantified based on elements of MNI, MNE, and MAU. Then bone surface modifications and skeletal element profiles of the bone assemblages are studied to understand shlepping behaviors and reveal the technique of disarticulating and defleshing the animals’ bodies, etc. Based on the analyses of bone assemblages and the comparative study with the ethnoarchaeological as well as experimental data, it is assumed that later hominids at the site made fuller use of the game animals than the earlier hominids. Incorporating the lines of evidence from chronological dating, paleoenvironment, and polished bone tools between the two cultural layers, here we propose three hypotheses suggesting that the changes of environment, the migrations of the hominids from the North, or the demographic pulses may cause such a behavioral difference. However, it is yet to be determined which hypothesis can better explain the changes.

关键词： Ma’anshan site zooarchaeology Paleolithic hominid behavior

Biodegradable amphiphilic block copolymers containing functionalized PEO blocks:Controlled synthesis and biomedical potentials

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Science china Chemistry 2010年第3期53卷 519-527页

作者： ZHANG Yu1,2.SUN PeiJian1,2.& GAN ZhiHua1 1CAS key {3. of Engineering Plastics,{2. of Chemistry,chinese academy of sciences,beijing 100190,china 2.raduate University of chinese academy of sciences,beijing 10003.,china 1. CAS key laboratory of Engineering Plastics Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China2. Graduate University of Chinese Academy of Sciences Beijing 100039 China

A series of controllable amphiphilic block copolymers composed of poly(ethylene oxide)(PEO) as the hydrophilic block and poly(ε-caprolactone)(PCL) as the hydrophobic block with the amino terminal group at the end of the PEO chain(PCL-b-PEO-NH2. were *** on the further reaction of reactive amino groups,diblock copolymers with functional carboxyl groups(PCL-b-PEO-COOH) and functional compounds RGD(PCL-b-PEO-RGD) as well as the triblock copolymers with thermosensitive PNIPAAm blocks(PCL-b-PEO-b-PNIPAAM) were *** well-controlled structures of these copolymers with functional groups and blocks were characterized by gel permeation chromatography(GPC) and 1H NMR *** copolymers with functionalized hydrophilic blocks were fabricated into microspheres for the examination of biofunctions via cell culture experiments and in vitro drug *** results indicated the significance of introducing functional groups(e.g.,NH2.COOH and RGD) into the end of the hydrophilic block of amphiphilic block copolymers for biomedical potentials in tissue engineering and controlled drug release.

关键词： amphiphilic block copolymers biodegradable polymers functional terminal group cell growth drug release

The establishment of crystal position look-up table for positron emission tomography with block detectors

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Science china(Technological sciences) 2009年第8期52卷 2418-2423页

作者： CHAI Pei1,2.& SHAN BaoCi1 1 key laboratory of Nuclear Analytical Techniques, {2. of High Energy Physics, chinese academy of sciences, beijing 100049, china 2.Graduate University of chinese academy of sciences, beijing 100049, china key laboratory of Nuclear Analytical Techniques Institute of High Energy Physics Chinese Academy of Sciences Beijing 100049 China Graduate University of chinese academy of sciences Beijing 100049 China

A method has been developed to establish the crystal position look-up table for positron emission tomography with block detectors. It is based on the principle that the counts in crystal position histogram obey the Gaussian mixture model (GMM). This method has taken full consideration of the characteristics of the GMM and the detector itself. The experimental results have proved that it is simple, reliable, and universal.

关键词： positron emission tomography position look-up table 2.D position histogram

A 12.bit multichannel ADC for pixel detectors in particle physics and nuclear imaging

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Science china(Technological sciences) 2010年第5期53卷 1208-1214页

作者： WEI Wei1,2.3.WANG Zheng1,3.& ZHAO JingWei1,3.1 institute of High Energy Physics,chinese academy of sciences,{2. 100049,china 2.Graduate University of chinese academy of sciences,{2. 100049,china 3.key Lab of Nuclear Detection Technology and Nuclear Electronics of chinese academy of sciences,{2. 100049,china 1. institute of High Energy Physics Chinese Academy of Sciences Beijing 100049 China2. Graduate University of Chinese Academy of Sciences Beijing 100049 China3. Key Lab of Nuclear Detection Technology and Nuclear Electronics of Chinese Academy of Sciences Beijing 100049 China

Modern pixel detectors in nuclear and particle physics experiments and also in nuclear imaging,starve for highly integrated application specified integrated circuit(ASIC),whereas in china the study of ASIC still stays far away from practical *** lack of ASIC strictly limits the research and development of domestic high energy physics field.A 12.bit multichannel ADC designed for high density readout is introduced as a major candidate for solution.A precise model is discussed and the simulation fully agrees with the model,which indicates a key principle of *** is performed according to the given rule,and novel layout techniques are carried *** results in all aspects are also obtained,showing an excellent real performance,which satisfies the practical requirement.

关键词： application specified integrated circuit high density readout Wilkinson ADC multi-channel ADC

Persistent anomalous flows over the subtropical western Pacific insummer

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chinese Science Bulletin 1998年第8期43卷 672-675页

作者： ZHUANG Shiyu\+1 and JI Liren\+2.1. National Meteorological Centre, china Meteorological Administration, beijing 100081, china 2. LASG, institute of Atmospheric Physics, chinese academy of sciences, beijing 100080, china National Meteorological Ccntre China Meteomlcgical Administration Beijing China LASG Institute of Atmospheric Physics Chinese Academy of Sciences Beijing China

The distribution of global persistent anomalies shows that the subtropical western Pacific is a key region with high_frequency occurrence of persistent anomalies. Analyses of streamfunction anomalies, OLR anomalies etc. suggest that the convective heating related to Indian monsoon might be responsible for the development of WPA. The results of numerical experiment by two linear barotropic models support the observation.

关键词： persistent anomalies subtropical high Indian monsoon anomalous forcing.