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Transient species and its properties of melatonin

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Science china Chemistry 2006年第4期49卷 308-314页

作者： ZHU Hongping1,2. ZHANG Zhaoxia1,2. ZHAO Hongwei1, WANG Wenfeng1 & YAO Side1 1. Shanghai Institute of Applied Physics, chinese academy of {2., Shanghai 2.1800, china 2. graduate university of the chinese academy of {2., Beijing 10004., china 1. Shanghai Institute of Applied Physics Chinese Academy of Sciences Shanghai 201800 China 2. graduate university of the {2. academy of sciences Beijing 100049 China

The photo-physical and photo-chemical properties of melatonin (ML) werestudied by 2.6 nm laser flash photolysis (LFP). ML undergoes photo-ionization to produce radicalcation of ML (ML^(·+))and hydrated electrons (e_(aq)^-), while excited triplet state ~3ML~* is alsoformed during photolysis. The oxidation via one electron transfer from ML to SO_4^(·+) and thetriplet state of riboflavin (~3RF~*) has been also investigated and the rate constants for theprocess have been determined to be 8.0x10^9 and 1.4x10^9 L·mol^(-1)·s^(-1) respectively. Theradical cation of 2.2.'-azinobis(3-ethylbenzothiazoline-6-sulfonic acid)(ABTS^(·+)) scavengingcapacities of melatonin and other antioxidants are compared in this paper.

关键词： melatonin, laser flash photolysis, photoionization, triplet state.

Strengthening of the boreal winter Hadley circulation and its connection with ENSO

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Progress in Natural Science:Materials International 2007年第11期17卷 1327-1333页

作者： Ma Jie1,2.and Li Jianping2.1. College of Atmospheric sciences, Lanzhou university, Lanzhou 730000, {2. 2. LASG, Institute of Atmospheric Physics, chinese academy of sciences, Beijing 10002., {2.) College of Atmospheric sciences Lanzhou University Lanzhou 730000 China LASG Institute of Atmospheric Physics Chinese Academy of Sciences Beijing 100029 China

Empirical orthogonal function (EOF) analysis is carried out for the year-to-year variability of the boreal winter (DJF) mass stream function of the mean meridional circulation (MMC) during the period 1948—2.05. The results demonstrate that it is dominated by the equatorially asymmetric and symmetric modes. Further analysis shows that the former mode is linked with the boreal winter Hadley cell mainly on the decadal time-scale, and the latter on the interannual time-scale. The asymmetric mode index (AMI) with a clear upward trend contributes to the decadal strengthening of the boreal Hadley circulation, and is closely correlated with the tropical SST warming, especially in the region of Indo-west Pacific warm pool (INWP). Furthermore, the AMI also contributes to the abrupt change of the correlation coefficient between the boreal Hadley circulation and ENSO after 1976. The symmetric mode index (SMI) with robust and stable linkage with ENSO shows a significant interannual variability, suggesting that the variability of the Hadley circulation is mainly associated with ENSO on the interannual time-scale.

关键词： the Hadley circulation interannual time-scale decadal time-scale

Architecture and application of integrated spatial information service platform for digital mine

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中国有色金属学会会刊：英文版 2011年第S3期21卷 706-711页

作者： ZHANG Jin1, XIAO Jie2.1. College of Mining, Taiyuan university of Technology, Taiyuan 03002., china 2. Institute of Geodesy and Geophysics, {2. academy of sciences, Wuhan 430077, china Taiyuan Univ Technol Coll Min Taiyuan 030024 Peoples R China chinese Acad Sci Inst Geodesy & Geophys Wuhan 430077 Peoples R China

Using enterprise GIS platform, spatial databases and modern information technology, building geo-spatial information service platform of digital mine which has the features of the data exchange service, enterprise GIS services, directory services, logging services, is key technology and application infrastructure for digital mine. Based on the support of geospatial information service platform of digital mine, the professional GIS application service adapter can be developed and the application supports related to mining application system can be realized. Using high-resolution satellite remote sensing data, the mine functional partition map and geographic grids can be divided, and the geographic grid parts, status and events of important features of the surface object were investigated and defined. The system architecture and technical characteristics of integrated spatial information service platform were analyzed firstly, which guarantee service ability of digital mine. The methods and applications of functional partition map for integrated management service platform were discussed which are the services scheme of digital mine. The application results indicated that digital mine upgrades and enhances the capability and range of mine surveying and mapping, and is of great significance for guarantee of efficient, green and intensive exploitation of mine.

关键词： platform architecture web services application services digital mine

The solid lubricating material experiment device for Shenzhou-7 Spaceship

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Science china(Technological sciences) 2010年第9期53卷 2521-2527页

作者： WANG Ke1,2.REN WeiJia1,WANG ShiDa1 & WENG LiJun3 1 academy of Opto-Electronics,chinese academy of sciences,Beijing 100190,china 2.graduate university of chinese academy of sciences,Beijing 10004.,china 3 Lanzhou Institute of Chemical Physics,chinese academy of sciences,Lanzhou 730000,china 1. academy of Opto-Electronics Chinese Academy of Sciences Beijing 100190 China2. Graduate University of Chinese Academy of Sciences Beijing 100049 China3. Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China

A solid lubricating material exposure experiment in space is one of the missions during the seventh manned spaceflight of china,and the key is to develop a device which can be fixed reliably outside of the orbital module and can be fetched conveniently by an astronaut during space *** solid lubricating material experiment device needs to be locked reliably in a vibrating and impacting environment during the launch phase,and should meet the requirement that it can be unlocked and fetched reliably by the astronaut wearing an extravehicular spacesuit via simple operations in orbit in an environment of high and low *** for the device we developed,the environmental characteristic of the mission was analyzed,the mechanical analysis and thermal analysis were carried out,and then a mechanism with functions of mechanical locking,structural self-locking and manual unlocking was *** device was verified by a sequence of experiments and was fetched by the astronaut during the flight of the Shenzhou-7 Spaceship.

关键词： manned spaceflight exposure experiment mechanism unlock

A novel operation mode for spaceborne polarimetric SAR

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Science china(Information sciences) 2011年第4期54卷 884-897页

作者： QI WeiKong 1,2.& YU WeiDong 1 1 Institute of Electronics,chinese academy of {2.,Beijing 100190,china 2.graduate School of chinese academy of {2.,Beijing 100039,china 1. Institute of Electronics Chinese Academy of Sciences Beijing 100190 China2. Graduate School of Chinese Academy of Sciences Beijing 100039 China

A novel operation mode for spaceborne polarimetric SAR,named polarization space-division adding polarization code-division (PSD-PCD) operation mode,is proposed in this paper through combining polarimetric SAR with elevation digital beam-forming (DBF) on *** a pulse repetition interval the up-chirp LFM sub-pulse is transmitted with horizontal polarization antenna,and with some delay the down-chip LFM subpulse is transmitted with vertical polarization antenna to realize code *** every sub-aperture receives returns from ground,SAR system uses range DBF to separate echoes relative to different sub-pulses in order to realize space *** system PRF is equal to that of single-polarization SAR,and elevation DBF help reduce range ambiguity ***,the main system parameters,including PRF,delay between two sub-pulses,radar equation and ambiguity are analyzed and compared with those of single-polarization *** results demonstrate the feasibility and validity of PSD-PCD operation mode.

关键词： spaceborne synthetic aperture radar (SAR) polarimetry digital beamforming (DBF) operation mode ambiguity ratio polarization space-division polarization code-division

Preparation and characterization of a novel adsorbent for removing lipophilic organic from water

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Science china Chemistry 2005年第6期48卷 600-604页

作者： LIU Huijuan1, DAI Ruihua1, QU Jiuhui1 & RU Jia1,2.1. State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental sciences, chinese {2. of sciences, Beijing 100085, china 2. graduate School of the chinese {2. of sciences, Beijing 100039, china 1. State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental Sciences Chinese Academy of Sciences 100085 Beijing China 2. graduate School of the chinese {2. of sciences 100039 Beijing China

A novel composite adsorbent containing a kind of lipid-triolein is studied. The ad-sorbent is prepared by embedding triolein into cellulose acetate (CA) sphere. The preparation method, the physical-chemical properties of the adsorbent and the removal efficiency of two or-ganochlorinated pesticides are studied. The adsorbent is stable in water and no triolein leaks into water for 465 h soaking. The adsorbent has high adsorption capacity for organochlorinated pes-ticides such as dieldrin and aldrin. The results suggest that triolein-containing adsorbent could serve as a good adsorbent for lipophilic organic pollutants. The adsorption rate for lipophilic pol-lutants is very fast and has relation with the logKow of the compounds.

关键词： triolein, cellulose acetate, adsorbent, lipophilic organic, drinking water.

Validating global hydrological models by ground and space gravimetry

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chinese Science Bulletin 2009年第9期54卷 1534-1542页

作者： ZHOU JiangCun1,2.3, SUN HePing1,2.& XU JianQiao1,2.1 Institute of Geodesy and Geophysics, chinese academy of {2., Wuhan 430077, china 2.Key Laboratory of dynamic geodesy, chinese academy of {2., Wuhan 430077, china 3 graduate university of chinese academy of {2., Beijing 10004., china Institute of Geodesy and Geophysics Chinese Academy of Sciences Wuhan 430077 China Key Laboratory of dynamic geodesy Chinese Academy of Sciences Wuhan 430077 China graduate university of {2. academy of sciences Beijing 100049 China

The long-term continuous gravity observations obtained by the superconducting gravimeters (SG) at seven globally-distributed stations are comprehensively analyzed. After removing the signals related to the Earth's tides and variations in the Earth's rotation, the gravity residuals are used to describe the seasonal fluctuations in gravity field. Meanwhile, the gravity changes due to the air pressure loading are theoretically modeled from the measurements of the local air pressure, and those due to land water and nontidal ocean loading are also calculated according to the corresponding numerical models. The numerical results show that the gravity changes due to both the air pressure and land water loading are as large as 100×10-9 m s-2.in magnitude, and about 10×10-9 m s-2.for those due to the nontidal ocean loading in the coastal area. On the other hand, the monthly-averaged gravity variations over the area surrounding the stations are derived from the spherical harmonic coefficients of the GRACE-recovered gravity fields, by using Gaussian smoothing technique in which the radius is set to be 600 km. Com-pared the land water induced gravity variations, the SG observations after removal of tides, polar mo-tion effects, air pressure and nontidal ocean loading effects and the GRACE-derived gravity variations with each other, it is inferred that both the ground- and space-based gravity observations can effec-tively detect the seasonal gravity variations with a magnitude of 100×10-9 m s-2.induced by the land water loading. This implies that high precision gravimetry is an effective technique to validate the re-liabilities of the hydrological models.

关键词：重力测量水文模型模型验证和空间地面重力变化季节性波动空气压力

A puzzle of the radio-quiet quasar PG 1407+2.5:Are optical and X-ray emissions produced from a relativistic jet?

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Science china(Physics,Mechanics & Astronomy) 2011年第1期54卷 183-186页

作者： CHEN Liang 1,2.3 & BAI JinMing 1,2.1 National Astronomical Observatories/Yunnan Observatory,chinese academy of {2.,Kunming 650011,china 2.Key Laboratory for the Structure and Evolution of Celestial Objects,chinese academy of {2.,Kunming 650011,china 3 graduate university of chinese academy of {2.,Beijing 10004.,china 1. National Astronomical Observatories/Yunnan Observatory Chinese Academy of Sciences Kunming 650011 China2. Key Laboratory for the Structure and Evolution of Celestial Objects Chinese Academy of Sciences Kunming 650011 China3. Graduate University of Chinese Academy of Sciences Beijing 100049 China

PG 1407+2.5 is a radio quiet quasar that has a relativistic *** this report,we show some peculiar properties of its optical and X-ray emissions,which indicate possible non-thermal origins produced from the *** use a simple synchrotron + synchrotron self Compton (SSC) model to fit the emissions with different ratios of energy densities between the magnetic field and electrons (η≡U B/U e),which predicts a different γ-ray *** First LAT AGN Catalog (1LAC) did not include PG 1407+2.5,which indicates an upper limit of γ-ray *** upper limit constrains the ratio to be unreasonably large (η≥10 4-5).This inversely indicates that the optical and X-ray emissions may not be produced from the beaming *** discuss the physical implications of these results.

关键词： active galactic nuclei jet non-thermal emission PG 1407+2.5

Testing local realism in P → VV decays

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Science china(Physics,Mechanics & Astronomy) 2010年第5期53卷 870-875页

作者： LI JunLi1 & QIAO CongFeng1,2.1Department of Physics,graduate university of {2. academy of sciences,Beijing 10004.,china 2.heoretical Physics Center for Science Facilities(TPCSF),{2. academy of sciences,Beijing 10004.,china 1. Department of Physics Graduate University of Chinese Academy of Sciences Beijing 100049 China2. Theoretical Physics Center for Science Facilities (TPCSF) Chinese Academy of Sciences Beijing 100049 China

It was found that the vector meson pair from the pseudoscalar decays can form an entangled *** this work we give out detailed explanations on the polarization correlation of the two entangled vector *** is demonstrated that an experimental test of the Clauser-Horne inequality can be carried out through measuring the azimuthal distribution of four pseudoscalars in the cascade decay ηc→ VV →(PP)(PP),and the measurement of this process is feasible with the current running experiments in tau-charm ***,a brief discussion on the polarization correlation of the two vector mesons from B → VV decays is also presented.

关键词： nonlocality test high energy experiment meson decays