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Effect of concentration on surfactant micelle shapes——A molecular dynamics study

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Science china Chemistry 2005年第5期48卷 470-475页

作者： GAO Jian1,2. GE Wei1 & LI Jinghai1 1. Multiphase Reaction Laboratory, Institute of Process Engineering, chinese academy of sciences, beijing 100080, {2. 2. graduate School of The chinese academy of sciences, beijing 100085, {2. 1. Multiphase Reaction Laboratory Institute of Process Engineering Chinese Academy of Sciences 100080 Beijing China 2. graduate School of The chinese academy of sciences 100085 Beijing China

Many aspects of the behavior of surfactants have not been well understood due to the coupling of many different mechanisms. Computer simulation is, therefore, attractive in the sense that it can explore the effect of different mechanisms separately. In this paper, the shapes, structures and sizes of sodium dodecylbenzenesulfonate (SDBS) micelles under different con-centrations in an oil/water mixture were studied via molecular dynamics (MD) simulations using a simplified atomistic model which basically maintains the hydrophile and lipophile properties of the surfactant molecules. Above the critical micellar concentration (cmc), surfactant molecules ag-gregate spontaneously to form a wide variety of assemblies, from spherical to rodlike, wormlike and bilayer micelles. Changes in their ratios of the principle moments of inertia (g1/g3, g2.g3) in-dicated the transition of micelle shapes at different concentrations. The aggregation number of micelle is found to have a power-law dependence on surfactant concentration.

关键词： surfactant, MD simulation, sodium dodecylbenzenesulfonate, micelle shape.

Relationships between tree-ring width index and NDVI of grassland in Delingha

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chinese Science Bulletin 2006年第9期51卷 1106-1114页

作者： HE Jicheng1,3 & SHAO Xuemei1,2.. Institute of Geographical sciences and Natural Resources Research, chinese academy of sciences, {2. 100101, china 2. Institute of Tibetan Plateau Research, chinese academy of sciences, {2. 100085, china 3. graduate School of chinese academy of sciences, beijing 100039, china Institute of Geographical sciences and Natural Resources Research Chinese Academy of Sciences Beijing China graduate School of chinese academy of sciences Beijing China Institute of Tibetan Plateau Research Chinese Academy of Sciences Beijing China

Using five well-replicated Qilian juniper (Sabina przewalskii Kom.) tree-ring width index se- ries, monthly normalized difference vegetation index (NDVI) of grassland, and climatic data from 1982.to 2.01, the relationships between tree-ring width index, NDVI of grassland, and climatic data were analyzed firstly. Then, the relationship between tree-ring width index and NDVI of grassland was explored. The re- sults showed that: (1) Temperature and precipitation in June influenced tree-ring width index and NDVI of grassland deeply in Delingha. (2. There were sig- nificant relationships between five tree-ring width index series (DLH1-DLH5) and monthly NDVI of grassland from June to September, with the most significant relationship being between tree-ring width index series and NDVI of grassland in August. (3) The PC1 (the first principal component derived from DLH1-DLH5 series) exhibited good agreement with monthly NDVI of grassland in the grass growth sea- son (from June to September) and the averaged NDVI in the growth season, which was attributed to their common responses to water-supply limit in Delingha. This study may allow an increase in studying the past dynamics of grassland in Delingha in that the variation of grassland NDVI during the last millennium has been reconstructed from PC1.

关键词：圆柏祁连山 NDVI 草原年轮宽度指数

Characteristics of chlorine isotope distribution and analysis on sylvinite deposit formation based on ancient salt rock in the western Tarim Basin

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Science china Earth sciences 2005年第11期48卷 1913-1920页

作者： TAN Hongbing1,2. MA Haizhou1, XIAO Yingkai1, WEI Haizhen1,2. ZHANG Xiying1 & MA Wandong1 1. Institute of Salt Lakes, chinese academy of sciences, Xining 810008, china 2. {2. School of the chinese academy of sciences, beijing 100039, china 1. Institute of Salt Lakes Chinese Academy of Sciences 810008 Xining China 2. graduate School of the chinese academy of sciences 100039 Beijing China

During formation of the Tarim Basin, there repetitively happened seawater invasion for it was ever connected with wide Paleo-mediterranean Sea. At the same time, for the applica-tion of tectonic and paleoenvironmental condition, the basin deposits many sequences of thick strata of evaporites, especially in its two largest subbasins of Kuqa in the north and Shaqa in the southwest. Therefore, the western Tarim Basin has been considered to be a favorable location to prospect ancient sylvinite deposit. But it is unfortunate that the Br×103/Cl ratio, as a common geochemical index to uncover clues of sylvinite deposit, is almost invalid to indicate the stage of ancient brine condensation for very low content of bromine in salt rock samples (less than 10?6 commonly) in the western Tarim Basin evaporites. Fortunately, we noticed recently that the val-ues of chlorine isotope (δ 37Cl value) for salt rock samples follow some clear laws from place to place, which in the Shaqa subbasin, all δ 37Cl values of salt rock samples behaved negatively and on the contrary, they all surprisingly showed positive values in the Kuqa subbasin. Based on conclusions of previous research and referring to the ratios of Br×103/Cl for salt rock or brine samples, we proved that the chlorine isotope (δ 37Cl) could be used as an effective index to find ancient sylvinite deposit in those evaporites rock basin with low content of Br element back-ground, such as the Tarim Basin. Thus according to the new index of chlorine isotope, we con-clude that the concentration of ancient brines formed ancient salt rocks is much more concen-trated in the Shaqa subbasin than that in the Kuqa subbasin. Particularly, the δ 37Cl value of salt rock in Kashi depression of the western Shaqa subbasin is greatly negative (

关键词： the Tarim Basin, chlorine isotope, ancient salt rock, ancient sylvinite deposit, deposit stage

Synthesis of well-defined functional PE graft copoly-mers via ATRP process

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Science Bulletin 2005年第10期50卷 1048-1051页

作者： CAO Chengang1, 2. DONG Jinyong1 & HU Youliang1 1. CAS Key Laboratory of Engineering Plastics, Joint Laboratory of Polymer Science and Materials, Institute of Chemistry, chinese academy of {2., beijing 100080, china 2. graduate School, chinese academy of sciences, beijing 100039, china CAS Key Laboratory of Engineering Plastics Joint Laboratory of Polymer Science and Materials Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China graduate School Chinese Academy of Sciences Beijing 100039 China

In summary, we have demonstrated a convenient yet highly efficient method forthe preparation of PE-based graft copolymers via ATRP.. By introducing a small amount of styrenegroups into PE chains via the selective copolymerization of ethylene with 1,4-divinylbenzenecatalyzed by Et(Ind)_2.rCl_2.MAO, the multifunctional ATRP initiator of1-chloroethylbenzene-containing PE was readily achieved by a quantitative hydrochlorination reactionand was shown to be very effective for the initiation of graft polymerization of MMA and styrene toprepare structurally well-defined PE-based graft copolymers.

关键词： ATRP Synthesis of well-defined functional PE graft copoly-mers via ATRP process PE well

Simulation of aerodynamic performance affected by vortex generators on blunt trailing-edge airfoils

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Science china(Technological sciences) 2010年第1期53卷 1-7页

作者： YANG Ke1,2.ZHANG Lei1,3 & XU JianZhong1,2.1 Institute of Engineering Thermophysics,chinese academy of sciences,beijing 100190,{2. 2.Key Laboratory of Wind Energy Utilization,chinese academy of sciences,beijing 100190,{2. 3 graduate School of chinese academy of sciences,beijing 100190,{2. 1. Institute of Engineering Thermophysics Chinese Academy of Sciences Beijing 100190 China2. Key Laboratory of Wind Energy Utilization Chinese Academy of Sciences Beijing 100190 China3. Graduate School of Chinese Academy of Sciences Beijing 100190 China

An investigation was carried out by numerical simulation on a wind turbine airfoil and a blunt trailing-edge airfoil with and without vortex generators (VGs), and the performance of the airfoils was analyzed. By the simulation of airfoil DU 91-W2.2.0 it was verified that the numerical method and model were credible. Based on this airfoil, a new one with a blunt trailing edge of 6% chord was blended by symmetrically adding thickness, and its characteristics curves were obtained through computing at key angles of attack. Additionally, the pressure distribution on blended airfoil was analyzed by comparing to the airfoil without blend. The interaction of streamwise vortices induced by VGs with trailing vortex or separation vortex was considered, followed by the uncovery of how VGs can suppress the boundary layer separation.

关键词： vortex generators airfoil blunt trailing-edge

Analysis of tandem repeats in the genome of chinese shrimp Fenneropenaeus chinensis

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chinese Science Bulletin 2005年第14期50卷 1462-1469页

作者： KONG Jie1 & GAO Huan2.3 1. Key Laboratory for Sustainable Utilization of Marine Fisheries Re- sources, Ministry of Agriculture, Yellow Sea Fisheris Research Insti- tute, chinese academy of Fishery {2., Qingdao 2.6071, china 2. Institute of Oceanology, chinese academy of sciences, Qingdao 2.6071, china 3. The graduate School of the chinese academy of sciences, beijing 100039, china Key Laboratory for Sustainable Utilization of Marine Fisheries Resources Ministry of Agriculture Yellow Sea Fisheris Research Institute Chinese Academy of Fishery Sciences Qingdao China Institute of Oceanology Chinese Academy of Sciences Qingdao China The graduate School of the chinese academy of sciences Beijing China

Through random sequencing, we found a total of 884000 base-pairs (bp) of random genomic sequences in the genome of chinese shrimp (Fenneropenaeus chinensis). Using bio-soft Tandem Repeat Finder (TRF) software, 2.59 tandem repeats were found, in which there were 1714 mi- crosatellites and 445 minisatellites, accounting for 79.4% and 2..6% of repeat sequences, respectively. The cumulative length of repeat sequences was found to be 116685 bp, ac- counting for 13.2. of the total DNA sequence; the cumula- tive length of microsatellites occupied 9.78% of the total DNA sequence, and that of minisatellites occupied 3.42.. In decreasing order, the 2. most abundant repeat sequence classes were as follows: AT (557), AC (471), AG (2.4), AAT (92., A (56), AAG (2.), ATC (2.), ATAG (2.), AGG (18), ACT (15), C (11), AAC (11), ACAT (11), CAGA (10), AGAA (9), AGGG (7), CAAA (7), CGCA (6), ATAA (6), AGAGAA (6). Dinucleotide repeats, not only in the aspect of the number, but also in cumulative length, were the preponderant repeat type. There were few classes and low copy numbers of repeat units of the pentanucleotide repeat type, which included only three classes: AGAGA, GAGGC and AAAGA. The classes and copy numbers of heptanucleotide, eleven-nucleotide and thirteen-nucleotide primer-number-composed repeats were distinctly less than that of repeat types beside them.

关键词：虾遗传特性遗传基因 DNA

Compression behavior of Zr_(41)Ti_(14)Cu_(12.5)Ni_(10)Be_(2..5) bulk metallic glass up to 2. GPa

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Science china(Physics,Mechanics & Astronomy) 2005年第3期48卷 319-324页

作者： LI Gong 1, 2., ZHAN Zaiji 2., LIU Jing 3 , YUN Jinku 1 , SUN Liling 2., LIU Riping 1 , ZHANG Jun 2.& WANG Wenkui 1, 2.1. Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, china 2. Center for Condensed Matter Physics, Institute of Physics, chinese academy of sciences, {2. 100080, china 3. BSRF, Institute of High Energy Physics, chinese academy of sciences, beijing 100039, china 1. Key Laboratory of Metastable Materials Science and Technology Yanshan University 066004 Qinhuangdao China 2. Center for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences 100080 Beijing China 3. BSRF Institute of High Energy Physics Chinese Academy of Sciences 100039 Beijing China

The compression of a Zr41Ti14Cu12.5Ni10Be2..5 bulk metallic glass (BMG) is investigated at room temperature up to 2. GPa using in-situ high pressure energy dispersive X-ray diffraction with a synchrotron radiation source. The pressure-induced structural relaxation is exhibited. It is found that below about 8 GPa, the existence of excess free volume contributes to the rapid structural relaxation, which gives rise to the rapid volumetric change, and the structural relaxation results in the structural stiffness under higher pressure.

关键词： bulk metallic glass, high pressure, structural relaxation, synchrotron radiation.

Photodissociation/photoionization processes of chlorobromomethane induced by femtosecond laser pulses with pump-probe scheme

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chinese Science Bulletin 2008年第5期53卷 681-686页

作者： ZHANG Feng1,2. WEI ZhengRong1,2. CAO ZhenZhou1,2. ZHANG ChangHua1,2.& ZHANG Bing1,2.1 State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, chinese academy of sciences, Wuhan 430071, china {2. University of chinese academy of sciences, beijing 100039, china State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics Wuhan Institute of Physics and Mathematics Chinese Academy of Sciences Wuhan China graduate University of chinese academy of sciences Beijing China

The photodissociation/photoionization processes of chlorobromomethane (CH_2.rCl) induced by fem- tosecond laser pulses have been investigated using pump-probe scheme combined with the time-of-flight mass spectra. The dominate photoproducts are observed at different delay time of the pump (400 nm) and probe (800 nm) pulses and the corresponding time-dependence of them is obtained. The results show that the decaying time of the molecule CH_2.rCl in the A-band is in the 100 fs. The decaying tendencies of the fragment ions (CH_2.l^+ and CH_2.r^+) and the parent ion (CH_2.rCl^+) are almost the same and the relative ratios of the yields of them keep constant during the delay time of 0 to 150 fs. These facts suggest that the fragment ions come from the fragmentation of the parent ions in excited electronic states. The probabilities to form CH_2.l^+ and CH_2.r^+ are obtained from the relative ratio of the ion intensity and are about 71.6% and 14.2., respectively.

关键词：毫微秒激光氯溴化甲烷激光探针光解作用光化电离作用

Overexpression of a tobacco small G protein gene NtRop1 causes salt sensitivity and hydrogen peroxide production in transgenic plants

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Science china(Life sciences) 2008年第5期51卷 383-390页

作者： CAO YangRong1,2. LI ZhiGang1,2. CHEN Tao1,2. ZHANG ZhiGang1, ZHANG JinSong1 & CHEN ShouYi1 1 National Key Lab of Plant Genomics, Institute of Genetics and Developmental Biology, chinese academy of sciences, beijing 100101, {2. 2.graduate School of chinese academy of sciences, beijing 100039, {2. 1. National Key Lab of Plant Genomics Institute of Genetics and Developmental Biology Chinese Academy of Sciences Beijing 100101 China 2. graduate School of chinese academy of sciences Beijing 100039 China

The small GTPases of Rop/Rho family is central regulators of important cellular processes in plants. Tobacco small G protein gene NtRop1 has been isolated; however, its roles in stress responses were unknown. In the present study, the genomic sequence of NtRop1 was cloned, which has seven exons and six introns, similar to the Rop gene structure from Arabidopsis. The NtRop1 gene was constitutively expressed in the different organs whereas the other six Rop genes from tobacco had differential expression patterns. The expression of the NtRop1 gene was moderately induced by methyl viologen, NaCl, and ACC treatments, but slightly inhibited by ABA treatment, with no significant induction by NAA treatment. The transgenic Arabidopsis plants overexpressing the NtRop1 showed increased salt sensitivity as can be seen from the reduced root growth and elevated relative electrolyte leakage. The hydrogen peroxide production was also promoted in the NtRop1-trangenic plants in comparison with wild type plants. These results imply that the NtRop1 may confer salt sensitivity through activation of H2.2.production during plant response to salt stress.

关键词： small G protein NtRop1 salt sensitive hydrogen peroxide