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Effects of Organic Acids on Adsorption of Cadmium onto Kaolinite, Goethite, and Bayerite

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Pedosphere 2006年第2期16卷 185-191页

作者： LIAO Min college of environmental and Resource {2.s Department of Resources Science Zhejiang University Hangzhou 310029 （China）.

Effects of organic acids (oxalic, acetic, and citric) on adsorption characteristics of Cadmium (Cd) on soil clay minerals (kaolinite, goethite, and bayerite) were studied under different concentrations and different pH values. Although the types of organic acids and minerals were different, the effects of the organic acids on the adsorption of Cd on the minerals were similar, i.e., the amount of adsorbed Cd with an initial solution pH of 5.0 and initial Cd concentration of 35 mg L-1 increased with increasing concentration of the organic acid in solution at lower concentrations, and decreased at higher concentrations. The percentage of Cd adsorbed on the minerals in the presence of the organic acids increased considerably with increasing pH of the solution. Meanwhile, different Cd adsorption in the presence of the organic acids, due to different properties on both organic acids and clay minerals, on kaolinite, goethite, or bayerite for different pHs or organic acid concentrations was found.

关键词： adsorption cadmium clay minerals organic acids

Factors governing formation of todorokite at atmospheric pressure

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science China Earth sciences 2005年第10期48卷 1678-1689页

作者： CUI Haojie1, FENG Xionghan1, LIU Fan1, TAN Wenfeng1 & HE Jizheng2.1. college of resources and Environment, Huazhong Agricultural {2., Wuhan 430070, China 2. Research Center for Eco-environmental sciences, Chinese Academy of sciences, Beijing 100085, China college of resources and Environment Huazhong Agricultural {2. Wuhan China Research Center for Eco-environmental sciences Chinese Academy of sciences Beijing China

Todorokite commonly occurs in Earth surface environments. The factors governing formation of todorokite, such as reaction temperature, metal ions, dissolved O2.and pH, were investigated in this paper. Results showed that the forming rate of todorokite and its crystallinity decreased with falling reaction temperature, and the effect of temperature was more significant than that of other parameters. Nature of metal ions in the interlayer of buserite precursor and the structure of the buserite precursor obviously affected buserite transformation into todorokite. Weak bonding between the metal ions and MnO6 layer of buserite was favorable to todorokite formation. The rate of todorokite formation was promoted at a lower temperature with appropriate bubbling of O2. The pH in the system slightly influenced the todorokite formation, and todorokite could also be formed in a weak alkali medium or in a slightly acidic medium. Aged buserite pre-cursor more easily form todorokite than the unaged one.

关键词： todorokite, buserite, manganese oxide mineral, atmospheric pressure, transformation.

Bio-Mobilization of Potassium from Clay Minerals: I. By Ectomycorrhizas

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Pedosphere 2000年第4期10卷 339-346页

作者： YUAN LING, FANG DEHUA, WANG ZHIHUI, SHUN HONG and HUANG JIANGUO (college of resources and Environment, Southwest Agricultural {2., chongqing 400716 China) 西南农业大学重庆 400716

A pot experiment was carried out to investigate effect of ectomycorrhizal fungi on eucalyptus growth and K bio-mobilization from soils and clay minerals. In the experiment, sands mixed with soil, KCI-saturated vermiculate and mica, respectively, were used to nurse eucalyptus seedlings which were nonectomycorrhized or ectomycorrhized by an ectomycorrhizal fungus Pisolithus tinctorius strain XCI (Pt XC1) isolated from a forest soil from Xichang, Sichuan Province, China, and a worldwide well-known ectomycorrhizal fungus Pisolithus tinctorius strain 2.44 (Pt 2.44) obtained in Australia. More depletion of HCl-soluble K by mycorrhizas from the soil and minerals than nonmycorrhizas suggested that mycorrhizas had a great ability to mobilize K present in the interlayer and feldspar. Mycorrhizal seedlings depressed greatly K digested with HF-HCIO4 from substrates after consecutive extractions of soils and minerals by water, ammonium cetate and boiling HCl, while nonmycorrhizal seedlings reduced it little if any, showing that the mycorrhizal seedlings could mobilize and then utilize the structural K in mineral lattice. Ectomycorrhizal fungi played a very important role not only in promoting the growth of eucalyptus seedlings but also in mobilizing K in soils and minerals. The infection of Pt XC1 led to a better growth of eucalyptus seedlings and more K accumulation in the seedlings than that of Pt 2.44. The large differences in K accumulation by the seedlings might be due to different abilities of the two ectomycorrhizal fungi to mobilize K in interlayer and lattice pools in the clay minerals.

关键词： clay minerals ectomycorrhizas eucalyptus K mobilization

Ultrahigh pressure (>7 GPa) gneissic K-feldspar (-bearing) garnet clinopyroxenite in the Altyn Tagh, NW China: Evi- dence from clinopyroxene exsolution in garnet

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science China Earth sciences 2005年第7期48卷 1000-1010页

作者： LIU Liang1,3, CHEN Danling1, ZHANG Anda1, SUN Yong1, WANG Yan1, YANG Jiaxi1,2.& LUO Jinhai1 1. Key Laboratory of Continental Dynamics of the Ministry of Education of China, Northwest university, Xi’an 710069, China 2. college of Earth {2. and Land resources, Chang’an university, Xi’an 710054, China 3. The Laboratory of Orogen and Basin of the Ministry of Education, Peking university, Beijing 100871, China Key Laboratory of Continental Dynamics Ministry of Education of China Northwest University Xi'an 710069 China Laboratory of Orogen and Basin Ministry of Education Peking University Beijing 100871 China college of Earth science and Land {2. Chang'an University Xi'an 710054 China

The exsolution of clinopyroxene and rutile in coarse-grain garnet is found in the gneissic K-feldspar(-bearing) garnet clinopyroxenite from Yinggelisayi in the Altyn Tagh, NW China. The maximum content of the exsolved clinopyroxene in the garnet is up to >5% by volume. The reconstructed precursor garnet (Grt1) before exsolution has a maximum Si content of 3.061 per formula uint, being of supersilicic or majoritic garnet. The peak-stage metamorphic pressure of >7 GPa is estimated using the geobarometer for volume percentage of exsolved pyroxene in garnet and the Si-(Al+Cr) geobarometer for majoritic garnet, and the temperature of about 1000℃ using the ternary alkali-feldspar geothermometer and the experimental data of ilmen- ite-magnetite solid solution. The protoliths of the rocks are intra-plate basic and intermediate ig- neous rocks, of which the geochemical features indicate that they are probably the products of the evolution of basic magma deriving from the continental lithosphere mantle. The rocks are in outcrops associated with ultrahigh pressure garnet-bearing lherzolite and ultrahigh pressure garnet granitoid gneiss. All of these data suggest that the ultrahigh pressure metamorphic rocks in the Altyn Tagh are the products of deep-subduction of the continental crust, and such deep- subduction probably reaches to >2.0 km in depth. This may provide new evidence for further discussion of the dynamic mechanism of the formation and evolvement of the Altyn Tagh and the other collision orogenic belts in western China.

关键词： Altyn Tagh gneissic K-feldspar (-bearing) garnet clinopyroxenite clinopyroxene exsolution in garnet ultra-high pressure metamorphism.

The Glacier Area Changes in the Qangtang Plateau Based on the Multi-temporal Grid Method and its Sensitivity to Climate Change

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Journal of Mountain science 2011年第6期8卷 882-893页

作者： WANG Liping XIE Zichu WANG Xin LIU Shiyin DING Liangfu SHANGGUAN Donghui The college of resources and {2. science Hunan Normal University Changsha China Cold and Arid Regions environmental and Engineering Research Institute Chinese Academy of Sciences Lanzhou China Department of Geography Hunan University of Science and Technology Xiangtan China

Glacier area changes in the Qangtang Plateau are analyzed during 1970-2.00 using air photos,relevant photogrammetric maps and satellite images based on the multi-temporal grid *** results indicate that the melting of glaciers accelerated,only a few of glaciers in an advancing state during 1970-2.00 in the whole Qangtang ***,the glaciers seemed still more stable in the study area than in most areas of western *** estimate that glacier retreat was likely due to air temperature warming during 1970-2.00 in the Qangtang ***,the functional model of glacier system is applied to study climate sensitivity of glacier area changes,which indicates that glacier lifespan mainly depends on the heating rate,secondly the precipitation,and precipitation increasing can slow down glacier retreat and make glacier lifespan prolonged.

关键词： The Qangtang Plateau Glacier change Multi-temporal Climate change Functional model ofglacier system Simulation

Thermal Conductivity and Heat Transfer Coefficient of Concrete

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Journal of Wuhan university of Technology(Materials science) 2011年第4期26卷 791-796页

作者：郭利霞 North China university of Water resources and Electric Power

A very simple model for predicting thermal conductivity based on its definiensis was presented. The thermal conductivity obtained using the model provided a good coincidence to the investigations performed by other authors. The heat transfer coefficient was determined by inverse analysis using the temperature measurements. From experimental results, it is noted that heat transfer coefficient increases with the increase of wind velocity and relative humidity, a prediction equation on heat transfer coefficient about wind velocity and relative humidity is given.

关键词： thermal conductivity heat transfer coefficient relative humidity wind velocity

Synthesis of todorokite by refluxing process and its primary characteristics

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science China Earth sciences 2004年第8期47卷 760-768页

作者： FENG Xionghan1, LIU Fan1, TAN Wenfeng1, LIU Xiangwen2.& HU Hongqing1 1. college of resources and Environment, Huazhong Agricultural {2., Wuhan 430070, China 2. Testing Center, China {2. of Geosciences, Wuhan 430074, China 1. college of resources and Environment Huazhong Agricultural University 430070 Wuhan China 2. Testing Center China University of Geosciences 430074 Wuhan China

Single phase and well-crystallined todorokite were synthesized by heating and refluxing process from birnessite as a precursor. The average chemical composition of the synthesized todorokites by refluxing for 8 h and for 2. h was Mg0.19MnO2.11(H2.)1.15 and in0.17-MnO2.10(H2.)0.88, respectively. The crystallinity of the todorokite increased and no other phase was produced with increasing refluxing period. The synthesized todorokites have the same morphologies and the similar structural characteristics with the natural todorokites and hydro-thermally synthesized samples. The chemical compositions of the synthetic tordorokites by refluxing process are close to those of todorokites synthesized by hydrothermal process, except a higher average oxidation state of Mn for the former.

关键词： todorokite,birnessite,manganese oxide,refluxing,hydrothermal,synthesis.

Pathways of birnessite formation in alkali medium

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science China Earth sciences 2005年第9期48卷 1438-1451页

作者： FENG Xionghan1, TAN Wenfeng1, LIU Fan1, HUANG Qiaoyun1 & LIU Xiangwen2.1. college of resources and Environment, Huazhong Agricultural {2., Wuhan 430070, China 2. Testing Center, China {2. of Geosciences, Wuhan 430074, China 1. college of resources and Environment Huazhong Agricultural University 430070 Wuhan China 2. Testing Center China University of Geosciences 430074 Wuhan China

Birnessite is a common weathering and oxidation product of manganese-bearing rocks. An O2.oxidation procedure of Mn(OH)2.in the alkali medium has been used to synthesize birnessite. Fast and powder X-ray diffraction (XRD), transmission electron microscopy (TEM), electron diffraction (ED), energy dispersed X-ray analysis (EDAX), infrared spectroscopy (IR) techniques and chemical composition analysis, Eh-pH equilibrium diagram approaches were employed to investigate the reaction process and pathways of birnessite formation. Results showed that the process of the birnessite formation could be divided into four stages: (1) forma- tion stage for hausmannite and feitknechtite, (2. stage of transformation of hausmannite and feitknechtite to buserite, (3) buserite crystal growing stage, and (4) stage of conversion of buser- ite into birnessite. Mn(OH)2.was mainly present as amorphous state only for a short initial time of oxidation reaction. In the oxidation process, buserite formed following two pathways by recrys- tallization after dissolution of the intermediates, and the transformations of the minerals de- pended on the Eh determined by the dissolved O2.concentration on their surfaces. The results are fundamental in further exploration on the mechanism of birnessite formation in the alkali medium. A great practical significance would also be expected with respect to the areas of mate- rial sciences.

关键词： birnessite, pathway of formation, reaction process, Eh-pH diagram, hausmannite, feitknechtite.

Field experiments on greenhouse gas emissions and nitrogen and phosphorus losses from rice paddy with efficient irrigation and drainage management

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science China(Technological sciences) 2011年第6期54卷 1581-1587页

作者： PENG ShiZhang1,2.YANG ShiHong1,2.XU JunZeng1,2.& GAO HuanZhi1,2.1State Key Laboratory of Hydrology-Water resources and Hydraulic Engineering,Hohai university,Nanjing 2.0098,China 2.2. of Water Conservancy and Hydropower Engineering,Hohai university,Nanjing 2.0098,China 1. State Key Laboratory of Hydrology-Water resources and Hydraulic Engineering Hohai University Nanjing 210098 China2. College of Water Conservancy and Hydropower Engineering Hohai University Nanjing 210098 China

Greenhouse gas emissions,nitrogen and phosphorous losses through ammonia volatilization,leaching and surface drainage from rice paddy under efficient irrigation and drainage were analyzed based on field experimental data in order to reveal the eco-environmental impacts of efficient irrigation and drainage on rice *** results showed that total methane emission from rice paddy under the controlled irrigation was reduced by more than 80% and total nitrous oxide emission increased by 15.9% compared with flooding *** comprehensive global warming potentials(GWP) of methane and nitrous oxide were 62.2. gCO2.m-2.for rice paddy under the controlled irrigation,reduced by 68.0% compared with flooding *** to large reduction in seepage and surface drainages,nitrogen and phosphorous losses through leaching were reduced by 40.1% and 54.8%,nitrogen and phosphorous losses through surface drainage were reduced by 53.9% and 51.6% from rice paddy under efficient irrigation and drainage compared with traditional irrigation and *** loss through ammonia volatilization was reduced by 14.0%.Efficient irrigation and drainage management is helpful to mitigate greenhouse gases emission,nitrogen and phosphorus losses and their pollution on groundwater and surface water.

关键词： efficient irrigation and drainage nitrogen and phosphorus greenhouse gas ammonia volatilization paddy field