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Identification of marine natural gases with different origin sources

Science china Earth Sciences 2008年第S1期51卷 148-164页

作者： WANG YunPeng 1 ,ZHAO ChangYi 2.,WANG ZhaoYun 2.,WANG HongJun 2.,TIAN Jin 1 ,ZOU YanRong 1 &LIU JinZhong1 1State Key Laboratory of Organic Geochemistry,Guangzhou Institute of Geochemistry,Chinese Academy of Sciences,Guangzhou 510640,china 2.nstitute of Geology,research Institute of {2. Exploration and Development,Petrochina,beijing 100083,china State Key Laboratory of Organic Geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China Institute of Geology Research Institute of Petroleum Exploration and Development PetroChina Beijing 100083

Kinetic experiments of gas generation for typical samples of marine gas precursors including low-maturity kerogen,residual kerogen and oil as well as dispersed liquid hydrocarbon(DLH)in source rocks were performed by closed system,and the evolution trends of molecular and isotopic compositions of natural gases from different precursors against the maturity(R0%)at laboratory conditions were *** diagrams of gas origin were calibrated by using the experimental data.A diagram based on the ratio of normal and isomerous butane and pentane(i/nC4-i/nC5)was proposed and used to identify the origins of the typical marine natural gases in the Sichuan basin and the Tarim basin, *** the maturities of natural gases were estimated by using the statistical relationships between the gaseous molecular carbon isotopic data and maturities(δ13C-R 0 %)with different *** results indicate that the molecular and isotopic compositions of simulated gases from different precursors are different from each *** example,the dryness index of the oil-cracking gas is the lowest;the dryness indices of gases from DLH and kerogen in closed system are almost the same;and the dryness index of gases from residual kerogen is extremely high,indicating that the kerogen gases are very dry;the contents of non-hydrocarbon gases in kerogen-cracking gases are far higher than those in oil-cracking and DLH-cracking *** molecular carbon isotopes of oil-cracking gases are the lightest,those of kerogen in closed system and GLH-cracking gases are the second lightest,and those of cracking gases from residual kerogen are the *** calibration results indicate that the diagrams of ln(C1/C2.-ln(C2.C3)andδ13C2.δ13C3-ln(C2.C3)can discriminate primary and secondary cracking gases,but cannot be used to identify gas origin sources,while the diagram of i/nC4-i/nC5 can differentiate the gases from different *** application results of these diagrams show that gas mixtures ext

关键词： marine organic matter gas origin sources kerogen oil-cracking gas origin identification carbon isotope

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Multi-origin alkanes related to CO_2.rich, mantle-derived fluid in Dongying Sag, Bohai Bay basin

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Chinese Science Bulletin 2002年第20期47卷 1756-1760页

作者： JIN Zhijun, ZHANG Liuping, ZENG Jianhui & YANG Leibasin & reservoir {2. center, University of petroleum, beijing 102.49, china Key Laboratory for Hydrocarbon Accumulation Mechanism of Chinese Ministry of Education, University of petroleum, beijing 1 basin and reservoir {2. center University of Petroleum Beijing 102249 China Key Lab. Hydrocarbon Accumul. Mech. University of Petroleum Beijing 102249 China

With the newly obtained carbon isotope data for the natural gas, a pilot study of multiple-sourced alkanes related to the mantled-derived fluid is presented. The carbon isotope values of alkanes in the Dongying Sag possess the features indicating a general organic origin. However, there are two sub-populations in the isotopic data set, which reflect two specific types of origins. In general, the sub-population with high δ13CCH4 values is related to the CO2.rich, mantle-derived fluid, and it is distributed in the belts where mantle-derived fluid flow and basic volcanic activities have occurred. Geological and geochemical studies demonstrate that this variation of methane carbon isotope values in the Dongying Sag is unrelated with the basin bury and thermal histories, types of source rocks, and reactions between basin fluid and rocks. Mixing of mantle-derived fluid and organic sourced hydrocarbons is probably the cause for the variation.

关键词： mantle-derived fluid organic origin hydrocarbons in-teraction carbon isotope.

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Potential recoverable natural gas resources in china

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petroleum Science 2008年第1期5卷 83-86页

作者： Liu Chenglin Zhu Jie Che Changbo Liu Guangd School of Resource and Information China University of Petroleum Beijing 102249 China Oil and Gas Resource Strategy research center of the Ministry of Land and resource Beijing China

Natural gas resources in china are abundant. The undiscovered recoverable natural gas resources in china are estimated to be 19.2. ×10^12.m^3. Natural gas is mainly distributed in the middle and west china and offshore areas of china. The Tarim basin, Sichuan basin, Ordos basin, East china Sea basin, Tsaidam basin, Yinggehai basin, and Qiongdongnan basin are the main gas-bearing basins. The natural gas resources are not distributed evenly and are under-explored in china. The deeper horizons in east china, foreland basins and craton paleo-uplifts in the middle and west china, and the offshore basins are the main exploration areas in the future.

关键词： Natural gas resources exploration area china

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Origin and controlling factors of chlorite coatings—an example from the reservoir of T_3x Group of the Baojie area,Sichuan basin,{2.

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petroleum Science 2009年第4期6卷 376-382页

作者： Peng Jun1,Liu Jinku2.Wang Yan2.and Liu Jianfeng2.1 Scientific research Department,Southwest petroleum University,Chengdu,Sichuan 610500,{2. 2.Graduate School,Southwest petroleum University,Chengdu,Sichuan 610500,{2. Scientific research Department Southwest Petroleum University Chengdu Sichuan China Graduate School Southwest Petroleum University Chengdu Sichuan China

The study of the chlorite coatings always attracts scholars in china and other countries because the chlorite coatings play an important role in the preservation of residual primary pores in sandstone *** present,the study of the origin and the controlling factors is relatively *** occurrence,time of formation,genesis,controlling factors,and the mechanism of chlorite coatings inhibiting quartz overgrowths were studied in detail with thin section and SEM *** were from the sandstone reservoirs of the T3x Group in the Baojie area,the transitional zone from the middle to the south of Sichuan *** results indicate that the chlorite coatings on the walls of the pore spaces are oriented perpendicular to grain surfaces in the form of isopachous(even-thickness) grain-coating,while the chlorite coatings at the contacts between adjacent detrital grains are arranged with a preferred orientation tangential to the surface of detrital *** chlorite coatings were formed in the eogenetic *** were formed by recrystallization of Fe-rich clay films during the syndepositional period,and chlorite cements would be recrystallized after the coatings’ *** formation of chlorite coatings was mainly controlled by the depositional environment,provenance conditions,and diagenetic *** presence of chlorite coatings could result in the preservation of primary pores in deeply buried sandstone reservoirs by effectively inhibiting quartz overgrowths and the development of compaction and pressure solution.

关键词： Chlorite coatings occurrence time of formation origin controlling factor quartz overgrowths T3x Group

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Diagenesis and Restructuring Mechanism of Oil and Gas reservoir in the Marine Carbonate Formation,Northeastern Sichuan:A Case Study of the Puguang Gas reservoir

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Acta Geologica Sinica(English Edition) 2009年第6期83卷 1173-1181页

作者： DU Chunguo1, 2. WANG Jianjun1, ZOU Huayao2. ZHU Yangming3 and WANG Cunwu4 1 research Institute of petroleum Exploration and Development, {2. 100034, china 2.petroleum University of china, beijing 102.49, china 3 Department of Earth Science, Zhejiang University, Hangzhou 31002., china 4 Faculty of Earth Resources, china University of Geosciences, Wuhan 430074, china Faculty of Earth Resources China University of Geosciences Wuhan 430074 China

Based on the technology of balanced cross-section and physical simulation experiments associated with natural gas geochemical characteristic analyses, core and thin section observations, it has been proven that the Puguang gas reservoir has experienced two periods of diagenesis and restructuring since the Late Indo-Chinese epoch. One is the fluid transfer controlled by the tectonic movement and the other is geochemical reconstruction controlled by thermochemical sulfate reduction (TSR). The middle Yanshan epoch was the main period that the Puguang gas reservoir experienced the geochemical reaction of TSR. TSR can recreate the fluid in the gas reservoir, which makes the gas drying index higher and carbon isotope heavier because C2. (ethane and heavy hydrocarbon) and 12. (carbon 12.isotope) is first consumed relative to CH4 and 13C (carbon 13 isotope). However, the reciprocity between fluid regarding TSR (hydrocarbon, sulfureted hydrogen (H2.) , and water) and reservoir rock results in reservoir rock erosion and anhydrite alteration, which increases porosity in reservoir, thereby improving the petrophysical properties. Superimposed by later tectonic movement, the fluid in Puguang reservoir has twice experienced adjustment, one in the late Yanshan epoch to the early Himalayan epoch and the other time in late Himalayan epoch, after which Puguang gas reservoir is finally developed.

关键词： diagenesis and restructuring mechanism marine carbonate formation thermochemical sulfate reduction Puguang gas reservoir

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Present geotemperature and its suggestion to natural gas generation in Xujiaweizi fault-depression of the northern Songliao basin

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Science china Earth Sciences 2008年第S1期51卷 207-220页

作者： ZHOU QingHua 1,2.,FENG ZiHui 3 &MEN GuangTian 3 1 research Institute of petroleum Exploration and Development,Petro{2.,beijing 100083,{2. 2.Geological Logging Subcompany of Daqing Oil Field Company Ltd.,Daqing 163411,{2. 3 research Institute of petroleum Exploration and Development of Daqing Oil field Company Ltd.,Daqing 163732.{2. Petrochina Res Inst Petr Explorat & Dev Beijing 100083 Peoples R China Daqing Oil Field Co Ltd Geol Logging Subco Daqing 163411 Peoples R China Daqing Oil field Co Ltd Res Inst Petr Explorat & Dev Dacling 163732 Peoples R China

According to stastistic of present geotemperatures at the depths of 1000,2.00,3000 and 4000 m,respectively in the Xujiaweizi fault-depression of the north Songliao basin,the result indicates that Xujiaweizi fault-depression falls in the high geotemperature area,with the higher geothermal gradient in the depression layer than that in the fault-depression *** geothermal gradient decreases with the increasing of the *** thermal conductivity of rock greatly controls the geothermal *** main factors constraining the current geotemperature include thermal configuration of the earth's crust, deep faults,distribution and abundance of *** high geotemperature is in favour of generation of deep gas.

关键词： Xujiaweizi fault-depression geotemperature geothermal gradient thermal conductivity of rock deep layer natural gas

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Anisotropic characteristics of electrical responses of fractured reservoir with multiple sets of fractures

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petroleum Science 2009年第2期6卷 127-138页

作者： Shen Jinsong Su Benyu Guo Naichuan Department of Geophysics School of Resource and Information Technology China University of Petroleum Beijing 102249 China Key Laboratory of CNPC Geophysical Exploration China University of Petroleum Beijing 102249 China State Key Laboratory of petroleum Resource and Prospecting China University of Petroleum Beijing 102249 China

In fractured reservoirs, the fractures not but also form the main flow channels which connect productivity of reservoirs. However, because of the only provide the storage space for hydrocarbons, the pores of the matrix, so fractures dominate the heterogeneity and randomness of the distribution of fractures, exploration and evaluation of fractured reservoirs is still one of the most difficult problems in the oil industry. In recent years, seismic anisotropy has been applied to the assessment of fractured formations, whereas electrical anisotropy which is more intense in fractured formations than seismic anisotropy has not been studied or used so extensively. In this study, fractured reservoir models which considered multiple sets of fractures with smooth and partly closed, rough surfaces were established based on the fractures and pore network, and the vertical and horizontal electrical resistivities were derived as a function of the matrix and fracture porosities according to Ohm＇s law. By using the anisotropic resistivity equations, variations of the electrical anisotropy of three types of fractured models under the conditions of free pressure and confining pressure were analyzed through the variations of the exerted pressure, matrix porosity, fracture aperture and formation water resistivity. The differences of the vertical and horizontal resistivities and the anisotropy between the connected and non-connected fractures were also analyzed. It is known from the simulated results that an increase of the confining pressure causes a decrease of electrical anisotropy because of the elasticity of the closed fractures and the decrease of the fracture aperture. For a fixed fracture porosity, the higher the matrix porosity, the weaker the electrical anisotropy in the rock formation.

关键词： Fractured reservoir partly closed fracture electrical anisotropy fracture roughness

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Control of neotectonic movement on hydrocarbon accumulation in the Kuqa Foreland basin,west china

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petroleum Science 2010年第1期7卷 49-58页

作者： Jiang Zhenxue Li Lianxia Song Yan Tian Fenghua Zhao Mengjun Wang Haijiang Zhao Zhenxing State Key Laboratory of petroleum Resources and Prospecting China University of Petroleum Beijing 102249 China basin and reservoir {2. center China University of Petroleum Beijing 102249 China Exploration and Development research Institute PetroChina Beijing 100083 China Department of Exploration ＆ Development PetroChina CBM Limited Company Beijing 100013 China Exploration Department Tarim Oilfield Company PetroChina Kuerle Xinjiang 841000 China No.8 Oil Production Plant Changqing Oilfield Company PetroChina Xi＇an Shaanxi 710018 China

Neotectonic movement refers to the tectonic movement that has happened since the Cenozoic, which is the latest movement. It has the most important influence on the basins in west china, especially on the hydrocarbon accumulation in the western foreland basins. We determined the time of neotectonic movement in the Kuqa Foreland basin, which began from the Neogene, and analyzed the patterns of movement, which were continuous and fast subsidence in the vertical direction and intense lateral compression. The structure styles are that the faulting is weakened and the folding is strengthened gradually from north to south. We studied the control of neotectonic movement on the hydrocarbon accumulation process and model in the Kuqa Foreland basin with basin simulation technique. The largest subsidence rate of the Kuqa Foreland basin reached 1,2.0 m/Ma during the neotectonic movement, leading to rapid maturing of source rock within 5 Ma and a large quantity of hydrocarbon being generated and expelled. The thick neotectonic strata can form high quality reservoirs with the proved gas and oil reserves accounting for 5% and 2.% of the total reserves, respectively. 86% of the structural traps were formed in the neotectonic movement period. The faults formed during the neotectonic movement serve as important migration pathways and they exist in the region where the hydrocarbon reservoirs are distributed. Abnormally high pressure caused by the intense lateral compression, thick neotectonic strata deposition and rapid hydrocarbon generation provide driving force for hydrocarbon migration. The accumulation elements match each other well over a short period, leading to many large gas fields formed later in the Kuqa Foreland basin.

关键词： Kuqa Foreland basin neotectonic movement accumulation element accumulation process accumulation model

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Tectonic Evolution of the Junggar Foreland basin in the Late Carboniferous-Permian

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Acta Geologica Sinica(English Edition) 2001年第4期75卷 398-408页

作者： CHEN Shuping, ZHANG Yiwei, TANG Liangjie and BAI Guoping basin and reservoir {2. Centre, University of petroleum, Changping, beijing 102.49 basin and reservoir {2. Centre University of Petroleum Changping Beijing 102249 [?]2.hen Shuping Born in 1965 earned his B. Engr. from the University of petroleum in 1985 and M.Sc. from china University of Geosciences ({2.) in 1988. Now he is a Ph.D student in the basin and reservoir research Centre University of Petroleum Beijing. His research interest lies in tectonic analysis of basins.

A comprehensive study has been carried out to subdivide and correlate the Upper Carboniferous and Permian sedimentary successions in the Junggar basin based on outcrops and drilling and geophysical data. The study results, combined with geological analyses of the basin's periphery and the basement, as well as studies of the sedimentary rocks within the basin, the unconformities, tectonic geometry, kinematics and geodynamics, lead to the conclusion that the Junggar basin was characterized by the development of foreland basin systems during the Late Carboniferous and Permian. During that period, three foreland basin systems were developed: (1) the northwest foreland basin system, which trended nearly north-south from Mahu to the Chepaizi Palaeo-mountain during its early stage of development and thus it was also referred to as the west foreland basin system; (2. the Karamaili foreland basin system in the east and (3) the Northern Tianshan foreland basin system in the south. These systems are different in size, development stage and time of formation. The first two are developed earlier than the third, but they are smaller in size. All the structures in the Junggar basin have resulted from the integration and superposition of structural elements in the above three systems. In general, the development of the Junggar basin can be divided into four stages. Stage I was marked by the creation and evolution of the marginal western foreland and the peripheral Karamaili foreland basin systems during the Late Carboniferous-early Early Permian (C3P1ja). Stage II was characterized by the development of complicated foreland basin systems during the middle-late Early Permian (P1jb-P1f) when the three foreland basin systems took their shapes. Stage III was the integration stage of peripheral foreland basin systems during the Middle Permian (P2. in which steady and slow tectonic subsidence prevailed. Stage IV coincided with the shrinking of foreland basin development during the Late P

关键词： Junggar basin foreland basin system tectonic evolution

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Layer structure,petroleum accumulation system and characteristic of subtle reservoir of continental {2.s in eastern china:Taking Jiyang depression for example

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Science china Earth Sciences 2008年第S2期51卷 146-155页

作者： XU HuaiMin1,XU ZhaoHui1,ZHANG ShanWen2.WANG ZhiGao2.& WANG YongShi2.1 Faculty of Resource and Information Technology,china University of petroleum,{2.,china 2.Shengli Oil Field Ltd. Co.,SINOPEC,Dongying 2.7015,china 1. Faculty of Resource and Information Technology China University of Petroleum Beijing 102249 China 2. Shengli Oil Field Ltd. Co. SINOPEC Dongying 257015 China

The concept and division method for petroleum accumulation system,based on layer structure,are presented according to characteristics of layer structure and reservoirs. The petroleum accumulation system of Jiyang depression can be divided into four levels,namely petroleum accumulation system combination,petroleum accumulation system,oil-gas reservoir combination and reservoir. The petro-leum accumulation system combination includes three types of genetic pattern: other-source bur-ied-ridge accumulation system combination in pre-Paleogene,medium-deep layer self-source accu-mulation system combination in Paleogene,and shallow layer other-source accumulation system combination in Neogene. This paper also describes the reservoir types and their distribution charac-teristics of different petroleum accumulation system combinations and their interior units.

关键词： accumulation system Jiyang depression basin structure reservoir genetic pattern

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