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Polymer-assisted nanoparticulate contrast-enhancing materials

science china Chemistry 2010年第3期53卷 479-486页

作者： DING Yin1,3,HU Yong2.WU Wei1 & JIANG XiQun1 1laboratory of Mesoscopic Chemistry and department of Polymer {2. and engineering,College of Chemistry & Chemical engineering,nanjing University,nanjing 2.0093,china 2.ational laboratory of solid state microstructure,department of material science and engineering,nanjing University,nanjing 2.0093,china 3Key laboratory of Analytical Chemistry for Life {2.,Ministry of Education,School of Chemistry and Chemical engineering,nanjing University,nanjing 2.0093,china laboratory of Mesoscopic Chemistry and department of Polymer {2. and engineering College of Chemistry & Chemical Engineering Nanjing University Nanjing China Key laboratory of Analytical Chemistry for Life science Ministry of Education School of Chemistry and Chemical Engineering Nanjing University Nanjing China National laboratory of {2. state microstructure Department of Material Science and Engineering Nanjing University Nanjing China

The application of nanotechnology in medicine research has significant potential in modern biomedical research,disease diagnosis and *** fluorophore-based detection techniques have been widely used as imaging and signal transduction tools for the detection of trace levels of *** photosensitivity of the fluorophores,however,limits their application in such complex environments as living bio-systems where degradation or photobleaching *** nanoparticles have unique and stable optical,electrical,magnetic and catalytic properties because of their various shapes,sizes and *** potential of the nanoparticles as novel imaging agents has been studied as a possible solution to this *** modification of inorganic nanoparticles could enhance their biostability in physiological conditions and ability of targeting bioactive molecules.

关键词： contrast agent cell image gold nanoparticles iron oxide nanoparticles carbon nanotubes polymeric-inorganic hybrid nanoparticles

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Influences of low-Ti substitution for La and Mg on the electrochemical and kinetic characteristics of AB_3-type hydrogen storage alloy electrodes

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science china(Technological sciences) 2010年第1期53卷 242-247页

作者： DONG ZhenWei1,2.WU YaoMing1,MA LiQun2.SHEN XiaoDong2.& WANG LiMin1 1 state Key laboratory of Rare Earth Resource Utilization,Changchun Institute of Applied Chemistry,Chinese Academy of {2.s,C hangchun 13002.,china 2.College of material {2. and engineering,nanjing University of Technology,nanjing 2.0009,china state Key laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun China College of material science and {2. Nanjing University of Technology Nanjing China

The(La0.67Mg0.33)1-xTixNi2.75Co0.2.(x = 0,0.05,0.10,0.15 and 0.2.,at%) alloys were synthesized by arc melting and subsequent heat solid-liquid diffusing *** structure,electrochemical properties and kinetic characteristics of the alloys were investigated *** results showed that all the alloys mainly consisted of the(La,Mg)Ni3,LaNi5 phases,and the lattice parameters and the cell volumes of the(La,Mg)Ni3 and LaNi5 phases decreased with increasing Ti *** alloy electrodes could be activated to reach their maximum discharge capacity within five *** cycle life after 100 charge/discharge cycles(C100/Cmax) and the high-rate dischargeability at a discharge current density of 12.0 mA/g first increased and then *** the results showed that low-Ti content in AB3-type hydrogen storage alloys was beneficial to improvements of the overall electrochemical properties,and the optimum overall electrochemical performance of the alloy electrodes was obtained when x = 0.05.

关键词： AB3-type alloy metal hydride electrode microstructure electrochemical property kinetic characteristic

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Organic thin-film solar cells:Devices and materials

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science china Chemistry 2012年第4期55卷 553-578页

作者： LI ZhiGang1, ZHAO XinYan2. LI Xin1,2. GAO ZhiQiang1, MI BaoXiu1 & HUANG Wei2.1Jiangsu engineering Centre for Flat-Panel Displays & solid-{2. Lighting and School of materials science & engineering, nanjing University of Posts & Telecommunications, nanjing 2.0046, china 2.ey laboratory for Organic Electronics & Information Displays (KLOEID) Institute of Advanced materials (IAM), nanjing University of Posts & Telecommunications, nanjing 2.0046, china Jiangsu engineering Centre for Flat-Panel Displays & solid-{2. Lighting and School of materials science & engineering Nanjing University of Posts & Telecommunications Nanjing China Key laboratory for Organic Electronics & Information Displays (KLOEID) Institute of Advanced materials (IAM) Nanjing University of Posts & Telecommunications Nanjing China

In recent years, the performance of organic thinfilm solar cells has gained rapid progress, of which the power conversion efficiencies （r/p） of 3%-5% are commonly achieved, which were difficult to obtain years ago and are improving steadily now. The r/p of 7.4% was achieved in the year 2.10, and r/p of 9.2. was disclosed and confirmed at website of Mitsubishi Chemical in April, 2.11. The promising future is that the r/p of 10% is achievable according to simulation results. Apparently, these are attributed to material innovations, new device structures, and also the better understanding of device physics. This article summarizes recent progress in organic thinfilm solar cells related to materials, device structures and working principles. In the device functioning part, after each brief summary of the working principle, the methods for improvements, such as absorption increment, organic/electrode interface {2., morphological issues, are addressed and summarized accordingly. In addition, for the purpose of increasing exciton diffusion efficiency, the benefit from triplet exciton, which has been proposed in recent years, is highlighted. In the active material parts, the chemical nature of materials and its impact on device performance are discussed. Particularly, emphasis is given toward the insight for better understanding device physics as well as improvements in device performance either by development of new materials or by new device architecture.

关键词： organic – solar cell – photovoltaic – devices – materials

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FERROELECTRIC CHARACTERISTICS OF SrBi_2.a_2._9 THIN FILMS ANNEALED IN FORMING GAS

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Acta Metallurgica Sinica(English Letters) 2001年第6期14卷 517-519页

作者： D.S. Wang, T. Yu and A. Hu (department of Physics & National {2. of solid state microstructures, nanjing University, nanjing 2.0093, china) D. Wu, A.D. Li, Z.G. Liu and N.B. Ming (department of material science and engineering & National {2. Dept. of Phys. Nanjing Univ. Nanjing 210093 China

The degradation behavior of SrBi2.a2.9 (SBT) thin films annealed in forming gas (5%H2.95%N2. was investigated. The ferroelectric remnant polarization Px of SBT had a severe decrease in the containing H2.atmosphere at 400°C. SEM results showed that Bi could be reduced from SBT thin films for the effect of H2. The reduction role increased with a rise of annealing temperature. SBT thin films lost their ferroelectricity when the annealing temperature was above 450°C. It implied that the degradation of Pr value or the disappearance of ferroelectricity in SBT thin, films had the relationship with the reductive amounts of Bi in SBT. H2.played an important role in degradation of ferroelectric SBT thin films. This role could be attributed to its strong reduction activity during forming gas annealing.

关键词： Annealing Degradation Ferroelectricity Thermal effects

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Two-dimensional thermoelasticity solution for functionally graded thick beams

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science china(Physics,Mechanics & Astronomy) 2006年第4期49卷 451-460页

作者： Lü Chaofeng1, CHEN Weiqiu1 & ZHONG Zheng2.1. department of Civil engineering, Zhejiang University, Hangzhou 31002., {2. 2. Key laboratory of solid Mechanics of Ministry of Education, School of Aerospace engineering and Ap- plied Mechanics, Tongji University, Shanghai 2.0092. {2. department of Civil engineering Zhejiang University Hangzhou China Key laboratory of solid Mechanics of Ministry of Education School of Aerospace Engineering and Applied Mechanics Tongji University Shanghai China

Two-dimensional thermoelasticity analysis of functionally graded thick beams is presented using the state space method coupled with the technique of differential quadrature. material properties vary continuously and smoothly through the beam thickness, leading to variable coefficients in the state equation derived from the elasticity equations. Approximate laminate model is employed to translate the state equation into the one with constant coefficients in each layer. To avoid numerical instability, joint coupling matrices are introduced according to the continuity conditions at interfaces in the approximate model. The differential quadrature procedure is applied to discretizing the beam in the axial direction to make easy the treatment of arbitrary end conditions. A simply-supported beam with exponentially varying material properties is considered to validate the present method. Numerical examples are performed to investigate the influences of relative parameters.

关键词： state equation differential quadrature approximate laminate model joint coupling matrices thermal stresses.

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Effects of NaNbO_3-Co_2._3 Co-additive on the Properties of PZN-PZT Ceramics

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Journal of Wuhan University of Technology(materials science) 2007年第4期22卷 722-724页

作者：邓毅华 College of material science and {2. South China University of Technology department of Electronic science and Technology Huazhong University of Science and TechnologyWuhan 430074China

NaNbO3-Co2.3 co-added PZN-PZT （PZCNNT） ceramics were prepared using conventional solid state reaction. The piezoelectric and dielectric properties were measured. The experimental results show that the addition of 0.3mo1% Co2.3 leads to low dielectric loss （tgδ） in PZCNNT ceramics and the proper addition of NaNbO3 not only improves piezoelectric properties but also decreases intensively dielectric loss and mechanical loss. The optimal ceramic having d33=310 pC/N, kp=0.59, εr=985, tgδ=0.0034, Qm=1380 was obtained.

关键词： PZN-PZT piezoelectric constant dielectric constant dielectric loss

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Numerical simulation of the transient multiphase field during plasma deposition manufacturing composite materials

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science china(Physics,Mechanics & Astronomy) 2009年第4期52卷 508-517页

作者： KONG FanRong1,2.ZHANG HaiOu1 & WANG GuiLan3 1 state Key laboratory of Digital Manufacturing Equipment and Technology,Huazhong University of {2. and Technology,Wuhan 430074,china 2.Research Center for Advanced Manufacturing,Southern Methodist University,3101 Dyer Street,Dallas,Texas 752.5,USA 3 College of material {2. and engineering,Huazhong University of {2. and Technology,Wuhan 430074,china state Key laboratory of Digital Manufacturing Equipment and Technology Huazhong University of Science and Technology Wuhan China Research Center for Advanced Manufacturing Southern Methodist University Dallas USA College of material science and {2. Huazhong University of Science and Technology Wuhan China

A solid/liquid/gas unified model has been developed to investigate the gradient composition formation during the plasma deposition manufacturing(PDM) composite materials process. In this model,an enthalpy porosity model was applied to deal with the melting and solidification of the deposited layer,and a level-set approach was introduced to track the evolution of the free surface of the molten pool and the deposited layer. Moreover,complicated physical phenomena occurring at the liquid/gas interface,including forced convection heat loss,heat emission and plasma heat source,have been incorporated into the governing equations by source terms. In this study,the numerical experiment of nickel base alloy powder deposited on the medium steel substrate by PDM technique was implemented based on the staggered grid and SIMPLEC algorithm. Concentration gradient distribution of the solute material at the composite material interface,fluid flow and temperature distribution in the molten pool and the deposited layer have been investigated in detail.

关键词： plasma deposition manufacturing composite material solid/liquid/gas unified model level-set approach

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Nonlinear Theory on Dynamic Controlling Interface Patterns Duringsolidification of a Dilute Binary Alloy

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International Journal of Minerals,Metallurgy and materials 1999年第4期13卷 253-258页

作者： Zidong Wang Hanqi Hu(material science and {2. School, University of science and Technology Beijing, Beijing 100083, china) material science and {2. School University of Science and Technology Beijing Beijing 100083 China

In non-equilibrium nonlinear region, the nonlinear equations of time dependence of perturbation amplitude at the solid/liquidinterface during solidification of a dilute binary alloy are established on the base of assuming that there is local equilibrium at the solid/liquid interface and considering that curvature, temperature and composition at the solid/liquid interface which are related to the perturbation amplitude are nonlinear. As a result, patterns at the solid/liquid interface during solidification process, which is from nonsteadystate to steady state can be controlled by these nonlinear equations.

关键词： nonlinearity solidification, dilute binary alloy, dynamic control

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Ⅱ类超导体制冷效应的热力学分析

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同济大学学报（自然科学版） 2002年第6期30卷 705-709页

作者：俞建群徐政单磊金新同济大学材料科学与工程系上海200092 南京大学固体微结构国家实验室南京210093

以超导热力学唯象理论为基础 ,讨论了Ⅱ类超导体样品当外场从 0增加到临界场Hc2.(T)过程中的制泠效应 .结果表明 :样品从Meissner态到低场混合态和从高场混合态到正常态相变为二级相变 ,无制冷效应 ,但是样品处在混合态区域时因外场增... 详细信息

以超导热力学唯象理论为基础 ,讨论了Ⅱ类超导体样品当外场从 0增加到临界场Hc2.(T)过程中的制泠效应 .结果表明 :样品从Meissner态到低场混合态和从高场混合态到正常态相变为二级相变 ,无制冷效应 ,但是样品处在混合态区域时因外场增加有可能产生制冷效应 ,因而该区域是超导制冷实验研究的重点 .

关键词：热力学 Ⅱ类超导体制冷效应

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稀土Gd_5Ge_2.Si_(2.x)Al_x)合金系的晶体结构和磁卡效应研究

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中国稀土学报 2003年第Z1期21卷 114-116页

作者：黄军平罗广圣唐少龙吴小山南昌大学材料科学与工程学院江西南昌330047 南京大学国家固体微结构实验室江苏南京210093

用磁控电弧炉在氩气气氛下熔炼了Gd5Ge2.Si2.xAlx)(x=0,0.1,0.2.0.5,1.0)系样品。X射线粉末衍射分析表明,样品基本为单相结构,其晶体对称性不会随Al含量的增加而改变。用振动样品磁强计测量了样品的M T曲线和不同温度下的M H曲线。居里... 详细信息

用磁控电弧炉在氩气气氛下熔炼了Gd5Ge2.Si2.xAlx)(x=0,0.1,0.2.0.5,1.0)系样品。X射线粉末衍射分析表明,样品基本为单相结构,其晶体对称性不会随Al含量的增加而改变。用振动样品磁强计测量了样品的M T曲线和不同温度下的M H曲线。居里温度随Al含量x的增加略有减小,当x=0.2.Gd5Ge2.Si2.xAlx)有最大-ΔSM值。退火对样品的居里温度和磁卡效应影响不大,退火前后的居里温度和磁卡效应基本保持一致。

关键词：磁热效应磁熵变晶体结构居里温度稀土

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