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A new principle of synthetic cascade utilization of chemical energy and physical energy

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Science china(Technological sciences) 2005年第2期48卷 163-179页

作者： JIN Hongguang1, HONG Hui1,2. WANG Baoqun1,2. HAN Wei1,2.& LIN Rumou1,2.1. Institute of Engineering Thermophysics, chinese academy of sciences, Beijing 100080, {2. 2. Graduate School of the chinese academy of sciences, Beijing 100039, {2. 1. Institute of Engineering Thermophysics Chinese Academy of Sciences 100080 Beijing China 2. Graduate School of the chinese academy of sciences 100039 Beijing China

We propose a new principle of the cascade utilization of both chemical energy and physical energy in energy systems with the integration of chemical processes and thermal cycles. Particularly, a general equation of energy levels of substance, Gibbs free energy of chemical reaction and physical energy is explicitly founded. On the basis of this equation, a chemical-looping combustion and an indirect combustion are investigated. Furthermore, a mechanism of energy release, with the combination of decreasing the energy level of Gibbs free energy and upgrading the energy level of low or middle- temperature thermal energy, is clarified. The promising results obtained here establish a theoretical basis for the further investigation of multi-function systems in which energy and the environment are compatible, and create a new approach to improve the performance of traditional thermal cycles.

关键词： chemical energy, cascade utilization, exergy, energy conversion.

Friction-reducing and antiwear behavior of metal halide-stabilized linear phosphazene derivatives as lubricants for a steel-on-steel contact

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Science china(Technological sciences) 2005年第3期48卷 282-291页

作者： ZHU Jiamei 1,2., LIU Weimin 2.& LIANG Yongmin 2.1. School of chemical Engineering and Technology, china University of Mining and Technology, Xuzhou 2.1008, china 2. State Key Laboratory of Solid Lubrication, lanzhou Institute of chemical physics, chinese academy of sciences, lanzhou 730000, china 1. School of chemical Engineering and Technology China University of Mining and Technology 221008 Xuzhou China 2. State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences 730000 Lanzhou China

A series of novel metal halide-stabilized linear phosphazene derivatives were synthesized. The friction-reducing and antiwear abilities of the resulting products as the lubricants for a steel-on-steel contact were comparatively investigated on an Optimol SRV oscillating friction and wear tester. The morphology of the worn steel surface was observed on a scanning electron microscope, while the chemical states of some typical elements on the worn steel surface were examined by means of X-ray photoelectron spectroscopy. It was found that both the side branch structures and central metals influenced the friction-reducing and antiwear behaviors of the synthetic derivatives as the lubricants, which was related to the different adsorption activities of the organic compounds composed of different organic ingredients and metallic ions on a nascent metal surface. All the synthetic lubricants except for the iron (III) derivative showed increased antiwear abilities with increasing metallic ionic radius. A protective layer originated from the tribochemical reaction together with the adsorbed boundary lubricating layer containing organic fluorine compounds, nitrogen oxide, and Fe 3 (PO 4 ) 2.plays an important role in improving the friction and wear behavior of the steel-on-steel system.

关键词： metal halide-stabilized linear phosphazene derivatives,lubricant,steel,tribological properties.

chemical and mineralogical characterizations of a copper converter slag

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Rare Metals 2002年第3期21卷 175-181页

作者： DENG Tong and LING YunhanInstitute of chemical Metallurgy, chinese academy of sciences, Beijing 00080, {2. Institute of chemical Metallurgy Chinese Academy of Sciences 北京 100080

A copper converter slag was examined chemically and mineralogically to determine its existing phases, in particular those containing Co and Cu. The slag consists predominantly of fayalite and magnetite, together with some glass, chalcocite, and metallic copper. Copper is entrapped in the slag mostly as chalcocite and metallic copper, as well as trace copper oxide. There was no indication of any independent Co mineral in the slag, but Co was found to be enriched in fayalite and megnetite as solid solution, although Co was detected in all the phases of the slag by SEM-EDX (scanning electron microscopy equipped with model EDAX-9100 energy dispersive spectrometer) and WDS (model WDX-2. X-ray wave-length dispersive spectrometer).

关键词： Cu Co converter slag characterization

The solid lubricating material experiment device for Shenzhou-7 Spaceship

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Science china(Technological sciences) 2010年第9期53卷 2521-2527页

作者： WANG Ke1,2.REN WeiJia1,WANG ShiDa1 & WENG LiJun3 1 academy of Opto-Electronics,chinese academy of sciences,Beijing 100190,{2. 2.Graduate University of chinese academy of sciences,Beijing 100049,{2. 3 lanzhou Institute of chemical physics,chinese academy of sciences,lanzhou 730000,{2. 1. academy of Opto-Electronics Chinese Academy of Sciences Beijing 100190 China2. Graduate University of Chinese Academy of Sciences Beijing 100049 China3. Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China

A solid lubricating material exposure experiment in space is one of the missions during the seventh manned spaceflight of china,and the key is to develop a device which can be fixed reliably outside of the orbital module and can be fetched conveniently by an astronaut during space *** solid lubricating material experiment device needs to be locked reliably in a vibrating and impacting environment during the launch phase,and should meet the requirement that it can be unlocked and fetched reliably by the astronaut wearing an extravehicular spacesuit via simple operations in orbit in an environment of high and low *** for the device we developed,the environmental characteristic of the mission was analyzed,the mechanical analysis and thermal analysis were carried out,and then a mechanism with functions of mechanical locking,structural self-locking and manual unlocking was *** device was verified by a sequence of experiments and was fetched by the astronaut during the flight of the Shenzhou-7 Spaceship.

关键词： manned spaceflight exposure experiment mechanism unlock

Study on the Reaction of Proteins with 5-Nitrosalicylfluorone-molybdenum(Ⅵ) Complex by Spectrophotometry in PVA 12. Microemulsion

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chinese Journal of Chemistry 2004年第7期22卷 714-718,615页

作者：魏琴吴丹杜斌张慧欧庆瑜lanzhou Institute of chemical {2. chinese academy of sciences lanzhou Gansu 730000 china School of Chemistry & chemical Engineering Jinan University Jinan Shandong 250022 China Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou Gansu 730000 China School of Chemistry & chemical Engineering Jinan University Jinan Shandong 250022 China

The application of 5'-nitrosalicylfluorone (5'-NSF)-molybdenum(VI) complex as a spectroscopic probe was studied. In the buffer medium of HOAc-NaOAc at 3.45 and in the presence of PVA 12. microemulsion, 5'-NSF-Mo(VI) complex combines protein rapidly to form a stable compound, leading to an absorbance decrease at 52. nm of 5'-NSF-Mo(VI) complex. According to this change, microdetermination of protein has been described. Bovine serum albumin (BSA) could be determined in the linear range of 0—16 g昺L-1 with the detection limit of 11 ngmL-1. Many amino acid and metal ions studied do not interfere with the assay. The method possesses high sensitivity as well as high selectivity. It can be used to determine protein in human urine and milk powder successfully. The relative standard deviations are in all instances less than 4.7%, and the recoveries are between 97.6% and 106.0%. Moreover, the binding number of BSA with the complex, which is determined by using molar ratio, Rosenthanl graphic and slope ratio methods, is in good agreement with each other.

关键词： protein spectrophotometry 5'-NSF-Mo(VI) complex microemulsion

Characterization and Tribological Behavior of Octadecene,Dodecene and Undecenoic Acid Films on Si Substrate

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Journal of Materials Science & Technology 2005年第5期21卷 671-674页

作者： Jinfang ZHOU+ and Shengrong YANGState Key Laboratory of Solid Lubrication, lanzhou Institute of chemical {2., chinese academy of sciences, lanzhou730000, china State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China

The films of octadecene, dodecene, and undecenoic acid were prepared on H-terminated Si surface in the presence of ultraviolet irradiation. The resulted films were characterized with water-contact angle measurement and infrared spectroscopy. The friction-reducing behavior of the prepared films was examined on a static-dynamic friction coefficient measurement apparatus and on an atomic force microscope. It was found that all the reacted films on the Si substrate showed good friction-reducing ability; especially, the film of the octadecene exhibited the best friction-reducing ability. This was attributed to the transfer of the reacted films onto the counter face with formation of a transfer film on the counterpart surface, which led to the transformation of the sliding between the reacted films and the hard ceramic to fiat between the reacted films and its transfer film on the counterpart surface. The macroscopic and microscopic friction behaviors of the prepared films were dependent on their molecular chain lengths. Thus the octadecene reacted film with the highest degree of ordering arrangement showed the best friction-reducing and antiwear abilities in sliding against Si3N4.

关键词： Alkese Reaction film Hydrogen-terminated silicon Tribological behavior

QUANTUM　chemical　STUDY　ON　THE　MECHANISM　OF　PRODUCING　OXYGENATES　IN　FISCHER－TROPSCH　SYNTHESIS　ON　M／SiO＿2.（M＝Ni，　Ru，　Rh，　Pd）　CATALYSTS

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chinese chemical Letters 1994年第6期5卷 511-514页

作者： Zheng Ping HAO Tian Wei ZHU Li Dun AN (lanzhou Institute of chemical {2.. chinese academy of sciences, lanzhou 730000)

EHMO calculations and orbital analysis of fragments were performed for the Synthetic reactions of oxygenates in Fischer-Tropsch synthesis using a butterfly model for four different metals (Nim Ru, Rh, Pd)supported on SiO2.as catalysts. Four processest CO dissociation, coupling of CO and H to produce *** of CO to M-CH3; insertion of CH2.to M-CH3 have been calculated. We compared the degree of CO bond activation and the banters of the foregoing processes for these four catalysts, it can be shown that Ni/SiO2.is a methanation catalyst, Ru/SiO2.and Rh/SiO2.can produce C2.oxygenated compound (acetaldehyde), especially Rh/SiO2.is a good catalyst for producing it, and Pd/SiO2.is a methanol Synthesis catalyst.

关键词： Pd CATALYSTS Ru SiO Rh Ni

N_2. emissions from agricultural soils in the North china Plain: the effect of chemical nitrogen fertilizer and organic manure

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Journal of Environmental sciences 2000年第4期12卷 463-468页

作者： DONG Yun\|she 1,2.3 , Dieter Scharffe 2. Manfred Domroes 3, QI Yu chun 1, ZHANG Shen 1 (1. Institute of Geographic sciences and Natural Resources Research, chinese academy of sciences, Beijing 100101, {2. E\|mail: dongys@*** 2. M 中科院地理科学与资源所北京 1 0 0 1 0 Max- Planck-Institute of Chemistry 德国 Mainz 550 2 0 Mainz University 德国 Mainz 550 99

An enclosed chamber technique was used to measure N 2. emissions from intensively agricultural soils of the North china Plain during the periods of 1995—1996 and 1997—1998, to reflect distinct components of winter wheat and summer maize growing seasons. The results showed that the continuous application of fertilizer in agricultural soils increased N\-2. emissions by a factor of 2..1—2..1, the calculated annual chemical N fertilizer\|transformed N\-2.\|N emissions was 0.67%. Our results indicated that the application of organic manure also had a significant influence on soil N 2. emissions, which combined with the use of chemical N increased about 2.% in a year. It was calculated that there were about 0.11% N of organic manure transformed as N 2. N. Annual mean N 2. emission from our study area of fertilized soils was estimated to be 57.1 μgN 2./(m 2.h). A weak correlation was also found between N 2. emissions and soil available nitrogen content NH + 4.

关键词： N_2. emissions the North china Plain agricultural soils chemical nitrogen organic manure

Organic geochemical studies of sinking particulate material in china sea area Ⅱ——Geochemical significance of compositional features of ketone, aldehyde and alcohol compounds

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chinese Science Bulletin 1997年第22期42卷 1894-1898页

作者： DUAN Yi,CUl Mingzhong, MA Lanhua, SONG Jinming, ZHOU Shixin and LUO Binjie1. lanzhou Institute of Geology, chinese academy of sciences, {2., china 2. Earthquake Research Institute of lanzhou, SSB, {2., china 3. Institute of Oceanology, chinese academy of sciences, Qingdao 2.6071, china lanzhou Institute of Geology Chinese Academy of Sciences Lanzhou China Earthquake Research Institute of lanzhou SSB Lanzhou China Institute of Oceanology Chinese Academy of Sciences Qingdao China

SINKING particulate organic matter of the sea plays an important role in marine environment. Itnot only provides food for marine organisms and takes part in chemical cycling, but also pro-vides sedimentary organic matter for marine sediments. Therefore, researchers always payclose attention to the source and processes of transport and transformation of marine sinkingparticulate organic matter. Its transport process can be understood by measuring the

关键词： marine sinking paniculate material composition of lipid compounds organic matter source and biochemical pro-cesses.