检索结果-南通市图书馆

Journal of Environmental sciences 2003年第3期15卷 423-432页

作者： ZHANG Dai-jun 1,2.(1. Department of Environmental science, Chongqing university, Campus A, Chongqing 400044,{2. 2. Key Laboratory for the Southwest{2. Resources Exploitation and Environmental Disaster Control Engineering, Ministry of Education,{2..) Department of Environmental science Chongqing University Campus A 重庆 400044

The integration of methanogenesis with denitrification and anaerobic ammonium oxidation(ANAMMOX) was studied in an expanded granular sludge bed(EGSB) reactor in this work. Experimental results from the continuous treatment of wastewater with nitrite and ammonium, which lasted for 107 days, demonstrated that wastewater with high nitrite and ammonium could be anaerobically treated in an expanded granular sludge bed reactor. More than 91% to 97% of COD were removed at up to about 3.9 g COD/(L·d) of COD volumetric loading rate. More than 97% to 100% of nitrite was denitrified at up to about 0.8 g NO -_2.N/(L·d), which is 16 times higher than that in a conventional activated sludge system with nitrification/denitrification(0.05 gN/(L·d)). No dissimilatory reduction of nitrite to ammonium occurred in the process. However, maximum of about 40% ammonium was found to be lost. Batch tests of 15 days with sludge from the reactor showed that 100% of nitrite was denitrified completely, and about 3% of ammonium was removed when only ammonium (34.3 mg/L) and nitrite(34.3 mg/L) were added into the sludge suspension medium. Furthermore, about 15% of ammonium amounts were lost with organic COD addition. It suggested that the methanogenesis in the system could enhance ANAMMOX because of intermediate hydrogen produced during methanogenesis.

关键词： methanogenesis denitrification ANAMMOX EGSB reactor

Potential energy surfaces for low-lying electronic states of SO_2

在线全文

学校读者我要写书评

暂无评论

science china Chemistry 2006年第4期49卷 289-295页

作者： LI Anyang1, SUO Bing2. WEN Zhenyi2.& WANG Yubin2.1. Shanxi Key Laboratory of Physico-inorganic Chemistry, Department of Chemistry, Northwest university, Xi’an 710069, china 2. Institute of Modern Physics, Northwest university, Xi’an 710069, china Shanxi Key Laboratory of Physico-inorganic Chemistry Department of Chemistry Northwest University Xi’an China Institute of Modern Physics Northwest University Xi’an China

The potential energy surfaces for the nine low-lying electronic states of SO2.have been constructed by using the multi-reference second order perturbation theory (MRPT2. with the basis set cc-pVTZ. The optimized geometries and the adiabatic excitation energies of these states are in good agreement with experiments and previous calculations. The crossings and avoided crossings dis- played in the potential energy surfaces are expounded.

关键词： cross of PES, MRPT2. SO2 (sulfur dioxide).

Pioneer organisms after F-F mass extinction in Dushan region,Guizhou Province,and their significance in establishing new ecosystem

在线全文

学校读者我要写书评

暂无评论

science china Earth sciences 2006年第5期49卷 449-460页

作者： WANG Yue1, 2. WANG Xunlian1 & SHI Xiaoying1 1. school of Earth sciences and Resources,{2. university of Geosciences, Beijing 100083,{2. 2. school of Resources and Environment, Guizhou university, Guiyang 550003,{2. school of Earth sciences and Resources China University of Geosciences Beijing China school of Resources and Environment Guizhou University Guiyang China

After mass extinctions, most areas became “ecologically barren areas” lacking or even without ecosystem over an extensive region. Studying the pioneer organisms and the reconstruction process of a new ecosystem in the “ecologically barren area” is very important for revealing the evo- lution after bio-mass extinctions. In the Dushan region, Guizhou Province, china, the trace fossils appeared and flourished evidently earlier than body fossils after Frasnian-Famennian (F-F) mass extinction. The pioneer organisms and pathfinders in the “ecologically barren areas” are the trace-makers that are deposit-feeders with relatively simple structure and conformation on or near the deposit surface. The trace-makers have undergone an evolutionary process that their trace structures changed from simple to complex, and their living and moving areas and spaces enlarged from linear to planar and then to three-dimension spaces. Those characters show that the ability of the trace-makers to deposits and their efficiency of looking for food have been enhanced gradually and that those trace-makers constructed gradually a base for the new ecosystem. This process is similar to that of the trace fossils near the Precambrian-Cambrian boundary. In the Dushan area, only the recovery intervals have been identified for the Famennian body fossils, with no eminent radiation interval recognizable due to the Devonian-Carboniferous (C-D) mass ex- tinction. However, both the recovery and radiation intervals may be clearly recognized in the Famen- nian trace fossils based on their conformation and diversity. The evolution and diversification of the trace fossils in the “ecologically barren area” is considered to have played a role of necessary foun- dation for the recovery of body fossils in the ecological chain. With the gradual disappearance of the unfavourable environment factors resulting in the F-F mass extinction, a new ecosystem was reconstructed in the “ecologically barren area” through a three-

关键词： pioneer organisms, reconstruction of ecosystem, trace fossils, F-F mass extinction, Later Devonian, Dushan region, Guizhou Province, china.

Studies on the microstructure,optical and electrical properties of organic microcavity devices based on a porous silicon reflector

在线全文

学校读者我要写书评

暂无评论

science china(Technological sciences) 2005年第2期48卷 191-201页

作者： XIONG Zuhong1, FAN Yongliang2. ZHAN Yiqiang2. ZHANG Songtao2. DING Xunmin2.& HOU Xiaoyuan2.1. school of Physics, Southwest china-Normal {2., Chongqing 400715, china 2. Surface Physics Laboratory (National Key Laboratory), Fudan {2., Shanghai 2.0433, china school of Physics Southwest China-Normal University Chongqing China Surface Physics Laboratory (National Key Laboratory) Fudan University Shanghai China

A novel type of microcavity organic light-emitting diode based on a porous silicon distributed Bragg reflector (PS-DBR) has first been achieved and its microstructure, optical, and electrical properties have also been investigated in detail. The microcavity is made up of the central active organic multilayer sandwiched between a top silver film and a bottom PS-DBR, formed by electrochemical etching of p++-Si substrate. The field- emission scanning electron microscopy cross-section images show the nanometer-scale layered structure and flat interfaces inside the microcavity. The reflectivity (relative to an Al mirror) of the PS-DBR is up to 99%, and the stopband is about 160 nm wide. Resonant cavity mode appears as a tip in the reflectivity spectrum of the Si-based organic multilayer films, which is a symbol that the Si-based organic multilayer structure is indeed a microcavity. The peak widths of the electroluminescence (EL) spectra from the cavities emitting green and red light are greatly reduced from 85 nm and 70 nm to 8 nm and 12.nm, respectively, as compared with those measured from non-cavity structures. Note that the EL emission from the cavity devices is single-mode, and the off-resonant optical modes are highly suppressed. Moreover, increases of a factor of about 6 and 4 of the resonant peak intensity from the cavities emitting green and red light are also observed, respectively. In addition, the current-brightness-voltage characteristics and effect parameters on the lifetime of the cavity devices are also discussed. The present technique for obtaining enhanced EL emission from Si-based organic microcavity may also be another novel effective method for realizing Si-based optoelectronics device integration.

关键词： electrochemical etching, Si-based microcavity, electroluminescence, organic light-emitting diodes.

Effects of Al on Microstructure and High-Temperature Wear Properties of Austenitic Heat-Resistant Steel

在线全文

学校读者我要写书评

暂无评论

Journal of Iron and Steel Research International 2012年第3期19卷 62-66页

作者： ZHANG Yan1, SUN Yu-fu2. ZHAO Jing-yu2. GUAN Shao-kang2.(1. school of Materials Engineering, Nanjing Institute of Technology, Nanjing 2.1167, Jiangsu, china 2. school of Materials science and Engineering, Zhengzhou university, Zhengzhou 450002. Henan, china) school of Materials Engineering Nanjing Institute of Technology Nanjing Jiangsu China school of Materials science and Engineering Zhengzhou University Zhengzhou Henan China

Microstructure and high-temperature dry sliding wear at 600 ~C in ambient air of austenitic heat-resistant steel ZG40Cr2.Ni2. with different contents （mass percent） of AI （0 to 7.10~） have been investigated. The results show that microstructures of 4.68% and 7.10% A1 addition content consist of the matrix and reinforcement of inter- metallic compound y＇ and carbide, while microstructures of ZG40Cr2.Ni2. without A1 and with A1 of 1.68% are ab- sent of y＇. Higher wear resistance than the original ZG40Cr2.Ni2. alloy is achieved in alloys with higher content of A1 under the same high-temperature wear test condition. The wear rates of Fe-2.Cr-2.Ni-7.10A1 and Fe-2.Cr-2.Ni- 4.68A1 are only 2..83% and 45.83% of that of Fe-2.Cr-2.Ni, respectively. Heat-resistant steels with higher con- tents of AI （4.72. and 7.10%） have higher hardness than those with lower contents of AI （1.68% and 0）. Wear mechanisms of ZG40Cr2.Ni2. are considered as severe plough plastic deformation and slight adhesive. However, wear mechanisms of Fe-2.Cr-2.Ni 4.68A1 are light micro-cutting and oxidation-wear, while that of Fe-2.Cr-2.Ni- 7. 10A1 are severe adhesive transfer and oxidation-wear_

关键词： austenitic heat resistant steel Al microstructure high-temperature sliding wear mechanism

Research progress in synthesis and catalysis of polyoxometalates

在线全文

学校读者我要写书评

暂无评论

Progress in Natural science:Materials International 2005年第5期15卷 385-394页

作者： GONG Yun1, HU Changwen1* and LIANG Hong2.1. Department of Chemistry, school of science, the Institute for Chemical Physics, Beijing Institute of Technology, Beijing 100081,{2. 2. Chemical Industry Press, Beijing 10002.,{2.) Sch. of Sci Inst. for Chem. Phys. Beijing Inst. of Technol. Beijing 100081 China Chem. Indust. Press Beijing 100029 China

Recent progress in the synthetic chemistry and catalysis of polyoxometalates (POMs) is reviewed. The novel POMs and their derivatives emerging in nearly three years (2.02.2.04) are introduced, including POMs with novel structure, POMs-organic hybrid compounds and host-guest complexes. Our review is focused on the elaboration of POMs' supramolecular chemistry.

关键词： polyoxometalates hybrid host-guest structure supramolecule catalysis.

Effect of Excipients on Stability and Structure of rhCuZn-SOD Encapsulated in PLGA Microspheres

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Chemical Research in Chinese Universities 2004年第3期20卷 323-327页

作者： LIU Ling 1,2.,GE Yu 1 and YUAN Qin-sheng 1 1. State Key Laboratory of Bioreactor Engineering and Institute of Biochemistry,East china university of {2. and Technology,Shanghai 2.02.7,P. R. china 2. Public Health school,Nanjing Medical university,Nanjing 2.002.,P. R. china State Key Laboratory of Bioreactor Engineering and Institute of Biochemistry East China University of Science and Technology 生物反应器工程国家重点实验室上海 200237

When a protein is encapsulated into poly( DL -lactide-co-glycolide)(PLGA) microspheres by means of the double-emulsion method,the harsh microspheres formation process including ultrasonification,exposure to an organic solvent and a polymer may cause the denaturation of the protein. In this study,we investigated the enzymatic activity change and the effect of the excipients on the stability of recombinant human Cu,Zn-superoxide dismutase(rhCu,Zn-SOD) during the emulsification. The specific activity recovery was found to be concentration dependent and the excipients involved such as PEG 600 and Tween 2.,and trehalose were shown to increase the stability of rhCu,Zn-SOD. The protein structural integrity within the microspheres was analyzed by FTIR. The structure of rhCu,Zn-SOD within PLGA microspheres containing trehalose was found to be similar to that of the native solid state,whereas the protein encapsulated during the preparation in the absence of any excipient changed due to the possible hydrophobic interaction with the polymer. The results suggest that a rational stability strategy for protein to be encapsulated into microspheres should aim at different processes.

关键词： Poly( DL -lactide-co-glycolide)(PLGA) microsphere Recombinant human Cu Zn-superoxide dismutase(rhCu Zn-SOD) Fourier transform infrared(FTIR) spectroscopy Protein stability Excipient

An efficient quantum secret sharing protocol with orthogonal product states

在线全文

学校读者我要写书评

暂无评论

science china(Physics,Mechanics & Astronomy) 2007年第3期50卷 331-338页

作者： YANG YuGuang1,2. WEN QiaoYan3 & ZHU FuChen4 1 school of Computer, Beijing university of Technology, Beijing 10002.,{2. 2.State Key Laboratory of Information Security, Graduate university of Chinese Academy of sciences, Beijing 10002.,{2. 3 school of science, Beijing university of posts and telecommunications, Beijing 100876,{2. 4 National Key Laboratory for Modern Communications, Chengdu 610041,{2. school of Computer Beijing University of Technology Beijing China State Key Laboratory of Information Security Graduate University of Chinese Academy of Sciences Beijing China school of science Beijing University of Posts and Telecommunications Beijing China National Key Laboratory for Modern Communications Chengdu China

An efficient quantum secret sharing protocol with orthogonal product states in the 33 Hilbert space is presented. The particles in the orthogonal product states form two particle sequences. One sequence is sent to Bob and the other is sent to Charlie after rearranging the particle orders. With the help of Alice, Bob and Charlie make the corresponding local measurement to obtain the information of the or- thogonal product states prepared. This protocol has many distinct features such as great capacity and high efficiency.

关键词： quantum secret sharing orthogonal product state orthogonal measurement

Automorphisms with order three of affine Lie algebras

在线全文

学校读者我要写书评

暂无评论

Chinese science Bulletin 1998年第21期43卷 1793-1798页

作者： JIN Quanqin 1,2.and HOU Zixin 2.1. Department of Mathematics, Hebei university, Baoding 071002. china 2. Department of Mathematics, Nankai university, Tianjin 300071, china Department of Mathematics Hebei University Baoding China Department of Mathematics Nankai University Tianjin China

Some properties of automorphisms of affine Lie algebras are presented. Automorphisms with order three are classified up to conjugacy, and their fixed point sets are also computed. As a corollary, it is proved that two... 详细信息

关键词： affine Lie algebra automorphism of order three first (second) kind of automorphism.

A study of constraints on the constitutive relationships of electromagnetic medium based on generally acknowledged truths

在线全文

学校读者我要写书评

暂无评论

science china(Physics,Mechanics & Astronomy) 2005年第5期48卷 541-548页

作者： GUO Huiping1, LIU Xueguan1,2. YIN Hongcheng2. CHAO Zengming2.& HUANG Peikang2.1. school of Electronics and Information Engineering, Soochow university, Suzhou 2.502.,{2. 2. National Electromagnetic Scattering Laboratory, Beijing 100854,{2. school of Electronics and Information Engineering Soochow University Suzhou China National Electromagnetic Scattering Laboratory Beijing China

The study of constraints on the constitutive relationships of electromagnetic media is of great importance in the aspects of the medium characteristics analysis, the new article material synthesis and the medium parameters reconstruction, etc. According to the fact that the constitutive relationships should not conflict with the general physical laws, the constraints that the constitutive relationships of electromagnetic medium must satisfy have been summarized in this paper. These constraints include determinacy principle, objectivity principle, causality principle and permission principle. And the parameter constraints of the arbitrary linear homogenous time-invariant medium are obtained following the minimum energy consumption principle. This work provides a new way of ascertaining the constitutive relationships of the electromagnetic medium.

关键词： electromagnetic medium, medium parameter constraint, generally acknowledged truths, energy conservation principle, minimum energy consumption principle.