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Liquid metal biomaterials: translational medicines,challenges and perspectives

National science Review 2024年第2期11卷 264-284页

作者： Hanchi Xu Jincheng Lu Yikuang xi Xuelin Wang Jing Liu Department of Biomedical engineering School of Medicine Tsinghua University Beijing Tsinghua Changgung Hospital School of Clinical Medicine Tsinghua University Shanghai World Foreign Language Academy Beijing Advanced Innovation Center for Biomedical engineering School of Engineering MedicineBeihang University Beijing Key Lab of Cryo-Biomedical engineering and Key Lab of Cryogenics Technical Institute of Physics and Chemistry Chinese Academy of Sciences

Until now, significant healthcare challenges and growing urgent clinical requirements remain incompletely addressed by presently available biomedical materials. This is due to their inadequate mechanical compatibility, suboptimal physical and chemical properties, susceptibility to immune rejection, and concerns about long-term biological safety. As an alternative, liquid metal(LM) opens up a promising class of biomaterials with unique advantages like biocompatibility, flexibility, excellent electrical conductivity,and ease of functionalization. However, despite the unique advantages and successful explorations of LM in biomedical fields, widespread clinical translations and applications of LM-based medical products remain limited. This article summarizes the current status and future prospects of LM biomaterials, interprets their applications in healthcare, medical imaging, bone repair, nerve interface, and tumor therapy, *** to translate LM materials into medicine and obstacles encountered in practices are *** that, we outline a blueprint for LM clinics, emphasizing their potential in making new-generation artificial organs. Last, the core challenges of LM biomaterials in clinical translation, including bio-safety,material stability, and ethical concerns are also discussed. Overall, the current progress, translational medicine bottlenecks, and perspectives of LM biomaterials signify their immense potential to drive future medical breakthroughs and thus open up novel avenues for upcoming clinical practices.

关键词： liquid metal biomaterials translational medicine clinical device healthcare therapeutics

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Microstructure evolution of single crystal copper wires in cold drawing

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science china(technological sciences) 2007年第6期50卷 736-748页

作者： CHEN Jian1,2, YAN Wen1,2, WANG XueYan2 & FAN xinHui2 1 Department of Applied Physics, Northwestern Polytechnical university, xi’an 710072, china 2.school of material science and chemical engineering, xi’an technological university, xi’an 71.032. china 1. Department of Applied Physics Northwestern Polytechnical University Xi’an 710072 China 2. school of material science and chemical engineering Xi’an Technological University Xi’an 710032 China

The deformation microstructure evolution of single crystal copper wires produced by OCC method has been studied with the help of TEM, EBSD; OM. The results show that there are a small number of dendrites; twins in the undeformed single crystal copper wires. However, it is difficult to observe these dendrites in deformed single crystal copper wires. The structure evolution of deformed single crystal copper wires during drawing process can be divided into three stages. When the true strain is lower than 0.94, macroscopic subdivision of grains is not evident,; the microscopic evolution of deformed structure is that the cells are formed; elongated in drawn direction. When the true strain is between 0.94; 1.96, macroscopic subdivision of grains takes place,; the number of microbands located on {111}; cell blocks is much more than that with the true strain lower than 0.94. When the true strain is larger than 1.96, the macroscopic subdivision of grains becomes more evident than that with the true strain between 0.94; 1.96,; S-bands structure; lamellar boundaries will be formed. From EBSD analysis, it is found that part of 100 texture resulting from solidifying is transformed into 111; 112 due to shear deformation, but 100 texture component is still kept in majority. When the true strain is 0.94, the misorientation angle of dislocation boundaries resulting from deformation is lower than 14°. However, when the true strain arrives at 1.96, the misorientation angle of some boundaries will be greater than 50°,; the peak of misorientation angle distribution produced by texture evolution is located in the range between 25°; 30°.

关键词： single crystal copper wires, deformation structure, electron backscattering diffraction, transmission electron microscopy

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Effect of Mn Addition and Heat Treatment on the Corrosion Behaviour of Mg-Ag-Mn Alloy

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Acta Metallurgica Sinica(English Letters) 2024年第4期37卷 665-677页

作者： You Lv Yupeng Zhang xi Liu Zehua Dong xiaorong Zhou xinxin Zhang Key Laboratory of material Chemistry for Energy Conversion and Storage Ministry of EducationHubei Key Laboratory of Material Chemistry and Service FailureSchool of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan430074China Hubei engineering Research Centre for Biomaterials and Medical Protective materials Huazhong University of Science and TechnologyWuhan430074China Corrosion and Protection Centre Department of MaterialsThe University of ManchesterManchesterM139PLUK

The high corrosion sensitivity and the potential bio-toxicity of Mg-Ag alloys limit their wide applications for the production of implanted devices. In the present work, Mn is added into the Mg-Ag alloy to optimize its corrosion behaviour. The corrosion behaviour of Mg-Ag-Mn alloys is investigated with the underlying microstructural factors examined. The Mg-Ag alloy with 2 wt% Mn exhibits the highest corrosion resistance after post-casting heat treatment at 440 ℃. The addition of Mn results in α-Mn phase with the incorporation of Fe, which suppresses the cathodic activity of impurity Fe. Further, heat treatment of the cast alloys homogenizes the distribution of Ag and promotes the precipitation of α-Mn phase. The former removes Ag segregations as potential cathodes;the latter promotes a more uniform distribution of cathodes and, therefore, prevents localized corrosion.

关键词： Mg-Ag alloy Mn addition Post-casting heat treatment Cathodic activity Corrosion mechanism

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Syntheses and properties of associative acrylamide copolymers containing short hydrophobic chains used in a friction reducer for slick-water fracturing

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Petroleum science 2024年第3期21卷 1889-1901页

作者： Ya-xing Dai xian-Li Zhang Si-Yuan Liu Feng-Run-Ze Zhang Yi-xi Zhang Yu-Tong Sang Jing-xi Zheng Zhao-Sheng Liu Peng Zhang College of Chemistry and chemical engineering Chongqing University of Science and TechnologyChongqing401331China College of Ecology and Environment Chongqing Resources and Environmental Protection of UniversityChongqing401331China China china Property Project Department of Dezhou Mining Property Service CenterShengli Oilfield Company of SinopecDezhou253000ShandongChina

Two allyldimethylalkyl quaternary ammonium salt(AQAS)monomers,N,N-dimethylallylphenylpropylammonium bromide(AQAS1)and N,N-dimethylallylnonylammonium bromide(AQAS2),were synthesized and used to prepare modified polyacrylamide *** new drag reducers were synthesized from acrylamide(AM),sodium acrylate(Na AA)and a cationic modified monomer(AQAS1 or AQAS2)via aqueous solution polymerization,and the copolymers were named P(AM/Na AA/AQAS1)and P(AM/Na AA/AQAS2),*** structures of the drag reduction agents were confirmed by IR and1H NMR *** molecular weight(Mw)of P(AM/Na AA/AQAS1)was 1.79×10^(6)g/*** the copolymer concentration was 1000 mg/L and the flow rate was 45 L/min,in fresh water the highest drag reduction rate was 75.8%,in 10,000 mg/L Na Cl solution the drag reduction rate decreased to 72.9%.The molecular weight of P(AM/Na AA/AQAS2)was 3.17×10^(6)g/*** the copolymer concentration was500 mg/L and the flow rate was 45 L/min,the drag reduction rate reached 75.2%,and in 10,000 mg/L Na Cl solution the drag reduction rate was 73.3%,decreased by approximately 1.9%.The drag reduction rate for partially hydrolyzed polyacrylamide(HPAM)was also investigated,and the results showed that the drag reduction rates for 500 and 1000 mg/L HPAM solutions were merely 43.2%and 49.0%in brine,*** with HPAM,both of the above copolymers presented better drag reduction capacities.

关键词： Shale gas Slick water Drag reducer Modified monomer Copolymerization

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Decarboxylative cyanation and thiocyanation via catalytic electron donor-acceptor complex with copper catalysis

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science china Chemistry 2024年第9期67卷 3019-3028页

作者： Hongping Zhao xiaoxiang xi Tianbao Wu Zimin Chen Minyan Wang Weiming Yuan Key Laboratory of material Chemistry for Energy Conversion and Storage Ministry of EducationHubei Key Laboratory of Bioinorganic Chemistry and Materia MedicaSchool of Chemistry and Chemical EngineeringHuazhong University of Science and Technology(HUST)Wuhan 430074China State Key Laboratory of Coordination Chemistry School of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210093China Shenzhen Huazhong university of science and Technology Research Institute Shenzhen 518000China

A new catalytic decarboxylative cyanation and thiocyanation via a synergistic Na I/Cu catalysis is *** photoexcited electron donor-acceptor complex by assembly of Na I,R3P,and N-acyloxy-phthalimide ester(NHPI ester)triggers the generation of alkyl radical species,which then engages in Cu-catalyzed radical coupling *** to success of this dual catalytic transformation is the reliable charge transfer between I·and Cu(I).This dual catalytic platform can eliminate the use of expensive iridium-based photocatalyst or synthetically elaborate organic dyes.A series of primary,secondary,and tertiary alkyl nitriles and thiocyanates are easily ***,an asymmetric decarboxylative cyanation by applying a chiral Cu catalyst is also developed to afford chiral nitriles in high *** mechanistic details and the origin of the high enantioselectivity are further investigated by the mechanistic experiments and the density functional theory calculations.

关键词： electron donor-acceptor catalysis copper catalysis cyanation thiocyanation asymmetric synthesis

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Precisely Control Relationship between Sulfur Vacancy and H Absorption for Boosting Hydrogen Evolution Reaction

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Nano-Micro Letters 2024年第4期16卷 14-24页

作者： Jing Jin xinyao Wang Yang Hu Zhuang Zhang Hongbo Liu Jie Yin Pinxian xi College of Chemistry and chemical engineering Frontiers Science Center for Rare IsotopesState Key Laboratory of Applied Organic ChemistryLanzhou UniversityLanzhou 730000People’s Republic of China

Ef fective and robust catalyst is the core of water splitting to produce ***, we report an anionic etching method to tailor the sulfur vacancy(VS) of NiS_(2) to further enhance the electrocatalytic performance for hydrogen evolution reaction(HER). With the VS concentration change from 2.4% to 8.5%, the H* adsorption strength on S sites changed and NiS_(2)-VS 5.9% shows the most optimized H* adsorption for HER with an ultralow onset potential(68 m V) and has long-term stability for 100 h in 1 M KOH media. In situ attenuated-total-reflection Fourier transform infrared spectroscopy(ATR-FTIRS) measurements are usually used to monitor the adsorption of intermediates. The S-H* peak of the Ni S_(2)-VS 5.9% appears at a very low voltage, which is favorable for the HER in alkaline media. Density functional theory calculations also demonstrate the Ni S_(2)-VS 5.9% has the optimal |ΔG^(H*)| of 0.17 e V. This work offers a simple and promising pathway to enhance catalytic activity via precise vacancies strategy.

关键词： Hydrogen evolution reaction S vacancies Nanosheet H Adsorption

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Thermodynamic Analysis of the Formation of In-situ Reinforced Phases In Cast Al-4.5Cu Alloy

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Journal of Wuhan university of Technology(materials science) 2008年第3期23卷 342-345页

作者：梁艳峰 State Key Laboratory for Mechanical Behavior of materials School of Materials EngineeringXi’an Jiaotong University school of materials&chemical engineering Xi’an Technological UniversityXi'an 710032China

The thermodynamic analysis of the formation of in-situ reinforced phases in （TiB2＋Al3Ti）/Al-4.5Cu composites prepared by mixed salts reaction was conducted, and heat changes of mixed salts system were analyzed by differential thermal analysis（DTA）.The results show that although TiB2 possesses the strongest formation ability in Al-Ti-B ternary system, [Ti] is relatively excessive in the in-situ reaction and it combines with Al to form AlaTi phase. The reinforced phases are TiB2 and AlaTi in the produced composites due to the reaction taking place to form reinforced phase with the addition of mixed salts into Al-4.5Cu melt between 900 ℃ and 1 032 ℃.

关键词： in-situ composites thermodynamic, TiB2 Al3Ti

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Novel strengthening methods for ultralightweight sandwich structures with periodic lattice cores

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science china(technological sciences) 2010年第3期53卷 875-877页

作者： LU TianJian 1 &ZHANG QianCheng 2 1 MOE Key Laboratory for Strength and Vibration,school of Aerospace,xi’an Jiaotong university,xi’an 710049,china 2 State Key Laboratory for Mechanical Behavior of materials,school of material science and engineering,xi’an Jiaotong university,xi’an 710049,china 1. MOE Key Laboratory for Strength and Vibration School of Aerospace Xi’an Jiaotong University Xi’an 710049 China2. State Key Laboratory for Mechanical Behavior of Materials School of Material Science and Engineering Xi’an Jiaotong University Xi’an 710049 China

Recent development of ultralightweight lattice-cored sandwiches is reviewed,with focus placed on various novel fabrication methods introduced to strengthen these structures,covering not only research results published... 详细信息

关键词： cellular metals strengthening method fabrication sandwich panels

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Super-high bed sintering for iron ores: inhomogeneous phenomena and its mechanism during mineralizing

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Journal of Iron and Steel Research International 2024年第8期31卷 1850-1860页

作者： Hui-bo Liu Liang-ping Xu xi-duan Yang Zhong-lin Dong Qiang Zhong Guang-hui Li school of Minerals Processing and Bioengineering Central South UniversityChangsha 410083HunanChina

The inhomogeneous sinter properties in super-high bed sintering have been reported in our previous *** inves-tigate the reasons for the inhomogeneous phenomena,detailed sampling and analysis of mixed material bed and sintered bed in super-high bed sintering plant were *** results indicated that the higher porosity and thinner dendrite of silico-ferrite of calcium and aluminum in the upper layer as well as dense structure and higher secondary hematite content in the lower layer led to the heterogeneities of mechanical strength and reduction properties exceeding 20%and 10%,*** the bed top downward,the basicity of mixed material decreased from 2.13 to 1.68 because the average particle size increased from 2.65 to 4.56 *** and fuels gathered in finer particles(-3 mm)of mixed material,and the-3 mm particles of mixed material generated more liquid phase than+3 mm *** heat input of super-high sintering bed was inhomogeneous due to the heat accumulation effect and unreasonable fuel *** inhomo-geneous sintering heat condition in sintering bed resulted in the different quantities and properties of liquid *** inhomogeneous quantities and properties of liquid phase that were influenced by inhomogeneous distribution of chemical composition,particle size,and heat input led to inhomogeneous mineralizing *** mineralizing condition is the key for homogeneous super-high bed sintering.

关键词： Iron ore Super-high bed sintering Mineralization material segregation Heat accumulation

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The study of adsorption gas sensor based carbon nanotube film

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science china(technological sciences) 2005年第4期48卷 372-384页

作者： LI xin1, LIU Junhua2 & ZHU Changchun1 1. school of Electronic and Information engineering, xi’an Jiaotong university, xi’an 710049, china 2. school of Electric engineering, xi’an Jiaotong university, xi’an 710049, china 1. school of Electronic and Information engineering Xi’an Jiaotong University 710049 Xi’an China 2. school of Electric engineering Xi’an Jiaotong University 710049 Xi’an China

The study of gas sensitivity of multi-wall carbon nanotubes (MWNTs), which is deposited by low press chemical vapor deposition (LPCVD), is presented. The results show that the pure MWNTs are not sensitive to the gases measured, while the composite film consisting of the MWNTs and silicon dioxide is sensitive to the methane, the hydrogen and the acetylene. The MWNTs and silicon dioxide composite film have the capacitance characteristic because of the formation of Schottky junctions within the MWNTs. The chemistry adsorption of the gas measured on the surface of the MWNTs affects the space discharge area of the Schottky junction, so that the dielectric constant changes with the gas concentration. That is why the gas is sensed.

关键词： gas sensor, carbon nanotubes, low press chemical vapor deposition, scatter.

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