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Geochemical Characteristics and Origin of Natural Gases in the Qaidam Basin,china

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Acta Geologica Sinica(English Edition) 2003年第1期77卷 103-115页

作者： ZHANG Xiaobao, HU Yong, DUAN Yi, MA Liyuan, MENG Zifang, HE Peng,ZHOU Shixin and PENG DehuaState Key Laboratory of Gas Geochemistry, Lanzhou institute of Geology, Chinese Academy ofSciences, Lanzhou, Gansu 730000 research institute of petroleum exploration and development, Qinghai petroleum Company,cnpc, Dunhuang, Gansu 736200 Chinese Acad Sci Lanzhou Inst Geol State Key Lab Gas Geochem Lanzhou 730000 Gansu Peoples R China Qinghai Petr Co Res Inst Petr Explorat & Dev CNPC Dunhuang 736200 Gansu Peoples R China

Sixty-five natural gas samples were collected from 19 oil-gasfields in theQaidam basin, china. The chemical composition and carbon isotope values of the samples weremeasured, and the geochemical characteristics and origin of the natural gases were studied. Thegases can be divided into biogenic gases, sapropelic oil-type gases, mixed type oil-type gases,coal-type gases and mixed gas. The delta^(13)C_1 values of the biogenic gases are very small and theC_2^+ contents of them are very low, ranging from -68.2 per thousand to -61 .8 per thousand and0.06 percent to 0.20 percent respectively. They have heavy delta D and delta^(13)C_(CO_2), showing aCO_2 reduction pathway. They ,are distributed in the East depression region and derived from theQuaternary source rocks. The sapropelic oil-type gases have small delta^(13)C_2 values and highC_2^+ ranging from -36.6 per thousand to -28.6 per thousand and from 33.01 percent to 47.15 percentrespectively. The mixed type oil-type gases have delta^(13)C_2 values and C_2^+ contents varyingfrom -28.6 per thousand to -24.8 per thousand and from 4.81 percent to 26.06 percent *** sapropelic oil-type gases and mixed type oil-type gases are associated with oil-type oils,distributed in the West depression region and derived from the Tertiary saltwater lacustrinesapropelic source rocks and humic source rocks respectively. The delta^(13)C_2 values of thecoal-type gases are extremely high and the C_2^+ contents are very low, changing from -23.3 perthousand to -12.5 per thousand and from 0.06 percent to 18.07 percent respectively. The coal-typegases in the Nanbaxian gasfield and the Lenghu oil-gasfields in the North fault block belt arederived from the Middle Jurassic coal-measures source rocks, whereas those in the West depressionregion are derived from the Tertiary saltwater lacustrine humic source rocks. Compared with someother basins in china, the natural gases there have obviously heavier delta^(13)C due to the heavierdelta^(1

关键词： natural gas geochemical characteristics origin Qaidam basin

Seismic multi-arch structures in East china

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Science china Earth Sciences 2006年第2期49卷 133-146页

作者： YANG Wencai1 & CHEN Zhide2 1.institute of Geology, Chinese Academy of Geological Sciences, beijing 100037, china 2.Daqing institute of petroleum exploration and Production, Daqing 163712, china institute of Geology Chinese Academy of Geological Sciences Beijing China Daqing institute of petroleum exploration and Production Daqing China

In previous papers (Wencai, 2002, 2003), the author has analyzed the deep seismic reflection profiles along some of the Mesozoic plutons in East china, and has pointed out that the crustal structures around these intrusions usually correlate with a special seismic fabric called the seismic multi-arch structure. This paper will continue to show main characteristics of the seismic multi-arch structures and discuss their relationship with mantle-origin magmatism and the lithospheric thinning process. Calibration of seismic reflectors in Chinese continental drilling sites shows that small-scale arch-like reflectors can be generated by fractured eclogites or other plutons, they do not belong to the multi-arch structure specially discussed in the paper. The multi-arch structure is char-acterized by several arch-like reflectors distributed in both the upper and lower crust with granitoid plutons or stocks exposed on the surface, which do not have obvious negative Europium anomalies. Based on the distribution pattern of arch reflectors, the multi-arch magmatic structures can be divided into three main types, namely the simple vertical combination type, the spread arch magmatic struc-ture and the arch-bouquet structure. All of them correlate to mantle-origin magmatism, but occur in different places. The spread arch magmatic structures occur within a Mesozoic/Cenozoic rift zone with very thin and hot lithosphere. The vertical combination type of the multi-arch structures occurred near the rift zones where lithosphere was thin and hot. The arch-bouquet magmatic structures occur far from the rift zones where the lithosphere is not hot. The continental rifting acted as the late episode of the lithospheric thinning process seeing that the rift zones usually coincide with the thinnest parts of the lithosphere in East china. In different locations within the lithospheric thinning areas, mantle-origin magmatic activities have different characteristics, which might generate different

关键词： deep seismic reflection, multi-arch structure, eclogite bodies, mantle-origin magmatism, East china.

A NEW METHOD FOR PREDICTION OF PRODUCTIVITY OF FRACTURED HORIZONTAL WELLS BASED ON NON-STEADY FLOW

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Journal of Hydrodynamics 2007年第4期19卷 494-500页

作者： LEI Zheng-dong CHENG Shi-qing LI Xiang-fang XIAO Hua-ping research institute of petroleum exploration and development Beijing 100083 China CMOE Key Laboratory of petroleum Engineering China University of Petroleum Beijing 102249China beijing Huayou Natural Gas Co. Itd Beijing 100100 China

Hydraulic fracturing technologies of horizontal well are important ways to develop oil-gas field with low permeability. Productivity forecast of fractured horizontal wells is a difficult problem of hydraulic fracturing technologies. Basing on non-steady flow of fractures fluid during production, applying potential function principles, superposition principle and mathematical method for solving, coupling of seepage flow in the formation and pipe flow in the well bore, a new model on multi-fracture interference productivity forecast of fractured horizofltal well is established in this article. The results indicate the coincidence rate between this model and practice is high. The pressure loss in the horizontal well bore has definite influence on the production status of fractured horizontal wells. The productions of different fractures in horizontal well bore are unequal, the productions of outer fractures are higher than middle fractures; the pressure in the well bore shows an uneven distribution, the pressure declines gradually from finger tip to heel end. Asymmetry of fractures may make productivity of fractured horizontal wells decline. The conclusions are instructive in designing fractured horizontal well for low permeability reservoir.

关键词： horizontal well fracturing productivity couple non-steady flow

Effects of Light Olefins Formation during Catalytic Pyrolysis of n-Heptane

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china petroleum Processing & Petrochemical Technology 2011年第4期13卷 8-14页

作者： Cheng Xiaojie Xie Chaogang Wei Xiaoli (SINOPEC research institute of petroleum Processing, beijing 100083) SINOPEC research institute of petroleum Processing Beijing 100083 China

The influence of zeolite structure and process parameters (including reaction temperature and catalyst/oil ratio) on rules for formation of ethylene and propylene in the course of catalytic pyrolysis of n-heptane was studied in a small- scale fixed fluid catalytic cracking unit. Test results have revealed that compared to the USY zeolite and Beta zeolite, the catalytic pyrolysis of n-heptane in the presence of the ZRP zeolite catalyst can result in higher yield and selectivity of ethyl- ene and propylene, while a higher reaction temperature and a higher catalyst/oil ratio can promote the formation of ethylene and propylene during catalytic pyrolysis of n-heptane. The ethylene formation reaction is more sensitive to the changes in reaction temperature, whereas the changes in catalyst/oil ratio are more influential to the propylene formation reaction. This paper has made a preliminary exploration into the different reaction pathways for formation of ethylene and propylene on zeolites with different structures.

关键词： n-heptane catalytic pyrolysis light olefins reaction pathway

Preliminary study on the origin identification of natural gas by the parameters of light hydrocarbon

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Science china Earth Sciences 2008年第S1期51卷 131-139页

作者： HU GuoYi 1,2,3 ,LI Jian 1,2 ,LI Jin 1,2 ,LI ZhiSheng 1,2 ,LUO Xia 1,2 ,SUN QingWu 1,2 &MA ChengHua 1,2 1 research institute of petroleum exploration and development(Langfang Branch),Petrochina,Langfang 065007,china 2 The Key Laboratory of Gas Formation and development,Petrochina,Langfang 065007,china 3 College of Geo-Resources and Information,china University of petroleum,beijing 102200,china research institute of petroleum exploration and development (Langfang Branch) Petrochina Langfang China The Key Laboratory of Gas Formation and development Petrochina Langfang China College of Geo-Resources and Information China University of Petroleum Beijing China

The light hydrocarbon composition of 209 natural gas samples and individual light hydrocarbon carbon isotopes of 53 natural gas samples from typical humic-sourced gas and sapropelic-sourced gas in the four basins of china have been determined and *** identification parameters for humic-sourced gas and sapropelic-sourced gas are proposed or *** differences of compound-specificδ13C value of individual light hydrocarbon between humic-sourced gas and sapropelic-sourced gas have been *** humic-sourced gas has the distribution ofδ13C benzene > -24‰,δ13C toluene >-23‰,δ13C cyclohexane >-24‰andδ13C methyl cyclohexane >-24‰,while the sapropelicsourced gas has the distribution ofδ13C benzene 24‰,δ13C toluene 24‰,δ13C cyclohexane 24‰and δ13C methyl cyclohexane 24‰.Among the components of C7 light hydrocarbon compound,such as normal heptane(nC7),methyl cyclohexane(MCH)and dimethyl cyclopentane(ΣDMCP),etc,relative contents of nC7 and MCH are influenced mainly by the source organic matter type of natural ***,it is suggested that the gas with relative content of nC7 of more than 30%and relative content of MCH of less than 70%is sapropelic-sourced gas,while gas with relative content of nC7 of less than 35%and relative content of MCH of more than 50%is humic-sourced *** components of C5-7 aliphatics, the gas with relative content of C5-7 normal alkane of more than 30%is sapropelic-sourced gas,while the gas with relative content of C5-7 normal alkane of less than 30%is humic-sourced *** paremeters have been suggested to identify humic-sourced gas and sapropelic-sourced gas.

关键词： natural gas humic-sourced gas sapropelic-sourced gas carbon isotope light hydrocarbon parameters

Major factors controlling the formation of middle and large marine carbonate stratigraphic fields

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Science Bulletin 2007年第S1期 44-53页

作者： ZOU CaiNeng & TAO ShiZhen research institute of petroleum exploration and development, Petrochina, beijing 100083, china

Marine carbonate oil and gas fields have become an important exploration area in china and even across the world. Their formation, distribution and enrichment are special owing to the complexity of the deposition, diagenesis and accumulation, which is caused by the multiplicity of the carbonate depositional environments and facies, huge extensions of formation time and burial depth, complication of diagenetic evolution, heterogeneity as well as the development of pores, caves and fractures affected by various factors. Oil and gas accumulations in carbonate rocks are not strictly controlled by the second-order structure belt. Most of them, under certain structural settings, are controlled by sedimentary diagenesis and its favorable facies. The hydrocarbon reservoir type is predominantly stratigraphic. Based on the worldwide researches of carbonate fields, the paper concludes that 7 main factors control the formation and distribution of middle-large marine carbonate stratigraphic fields.

关键词： carbonates stratigraphic reservoir accumulation condition main controlling factors

Abnormal high pressure in Kuqa foreland thrust belt of Tarim basin: Origin and impacts on hydrocarbon accumulation

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Progress in Natural Science:Materials International 2006年第12期16卷 1307-1314页

作者： ZENG Lianbo~1** and LIU Benming~ 1,2 (1. Key Laboratory of Hydrocarbon Accumulation in china petroleum University, Ministry of Education, beijing 102249, china 2. The institute of Oil and Gas exploration and development, Tarim Oilfield Company, Petrochina Company Limited, Korla 841000, china) Key Laboratory of Hydrocarbon Accumulation in china Petroleum University Ministry of Education Beijing 102249 China The institute of Oil and Gas exploration and development Tarim Oilfield Company PetroChina Company Limited Korla 841000 China

Following analyses of the abnormal high pressure distribution characteristics, based on the geological characteristics, tectonic stress field and physical simulation, we investigated the formation mechanisms of abnormal high pressure and its impacts on hydrocarbon accumulation in the Kuqa foreland thrust belt. The abnormal high pressure appears at the bottom of the Paleogene and obviously exists in the Triassic and Jurassic. However, the pressure coefficient in the Triassic and Jurassic is lower than that in the Cretaceous and at the bottom of the Paleogene. Horizontally, the abnormal high pressure distribution is characterized by E-W orientation zoning. The maximum pressure coefficient lies in the Kelasu-Dongqiu-Dina tectonic zones in the center of the Kuqa foreland thrust belt and decreases away from the tectonic zones. The formation of abnormal high pressure was mainly related with the intense tectonic compression in the Early Pleistocene time, and tectonic uplifting, undercompaction and hydrocarbon generation were secondary factors contributing to abnormal high pressure. Under the rapid and intense tectonic compression in the Early Pleistocene, the rock framework firstly undertook 1/4 of the compression stress and the other was borne by the pore fluids. Due to the presence of great seal of gypsum-salt or gypsum-mudstone beds in the Paleogene, the pressure of pore fluids increased rapidly and led to the abnormal high pressure in the Kuqa foreland thrust belt. The abnormal high pressure has important impacts on hydrocarbon accumulation. It is one of the necessary conditions for formation of large oil and gas fields in the Kuqa foreland thrust belt.

关键词： abnormal high pressure formation mechanism oil and gas reservoir Kuqa foreland thrust belt Tarim basin.

Formation and evolution of the Chinese marine basins

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Science Bulletin 2007年第S1期 1-11页

作者： JIA ChengZao1, LI BenLiang2, 3, ZHANG XingYang3 & LI ChuanXin1 1 research institute of petroleum exploration and development, Petrochina, beijing 100083, china 2 Resources and Information institute, china University of petroleum, beijing 102249, china 3 Central Laboratory of petroleum Geology research, research institute of petroleum exploration and development, beijing 100083, china

There are plenty of petroleum resources in the Chinese marine basins, which will be the potential exploration regions of petroleum in the 21st century. The formation and evolution of the Chinese marine basins have mainly undergone two major tectonic epochs and five tectonic evolution stages. The first major tectonic epoch is the early Paleozoic plate divergence and drifting epoch during which the marine basins were formed, and the second one is the late Paleozoic plate convergence and collision epoch during which the pre-existent marine basins were superimposed and modified. The five tectonic evolution stages include: ① the drifting of micro-continental plates in Oceans and the formation of marine basins mainly filled with carbonate rocks during Proterozoic-Middle Carboniferous; ② the northward collage and convergence of continental plates and the development of the paralic sedimentary basins during Late Carboniferous-Middle Triassic; ③ the tectonically stabilized stage after the plate collage and the superimposition of lacustrine basins controlled by the inland subsidence during Late Triassic-Early Cretaceous; ④ the stage of the inland deformation and successive deep burial, uplifting, erosion or breakage of marine basins influenced by the plate tectonic activities of Neo-Tethys Ocean and the West Pacific developed in Late Cretaceous-Paleocene; ⑤ the stage of the foreland compression and basin-range coupling in the margin of the marine basins caused by the collision between India and Eurasia Plates and its long-distance effect since Neocene. The process of the tectonic evolution has controlled the petroleum geologic characteristics of Chinese marine basins, and a material foundation for the formation of oil and gas reservoirs has been built up via the formation of Paleozoic ma- rine basins, and the Mesozoic-Cenozoic tectonic superimposition and modification have controlled the key conditions of hydrocarbon accumulation and preservation. From the Late Proterozoic to

关键词： marine basin plate tectonics tectonics evolution petroleum exploration

Potential risks of spectrum whitening deconvolution——compared with well-driven deconvolution

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petroleum Science 2009年第2期6卷 146-152页

作者： Li Guofa Zhou Hui Zhao Chao State Key Laboratory of petroleum Resource and Prospecting China University of Petroleum Beijing 102249 China Key Laboratory of cnpc Geophysical exploration China University of Petroleum Beijing 102249 China

Deconvolution is widely used to increase the resolution of seismic data. To compare the resolution ability of conventional spectrum whitening deconvolution to thin layers with that of welldriven deconvolution, a complex sedimentary geological model was designed, and then the simulated seismic data were processed respectively by each of the two methods. The amplitude spectrum of seismic data was almost white after spectrum whitening, but the wavelet resolution was low. The amplitude spectrum after well-driven deconvolution deviated from white spectrum, but the wavelet resolution was high. Further analysis showed that if an actual reflectivity series could not well satisfy the hypothesis of white spectrum, spectrum whitening deconvolution had a potential risk of wavelet distortion, which might lead to a pitfall in high resolution seismic data interpretation. On the other hand, the wavelet after well- driven deconvolution had higher resolution both in the time and frequency domains. It is favorable for high resolution seismic interpretation and reservoir prediction.

关键词： Well-driven high resolution spectrum whitening deconvolution seismic wavelet