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Volumetric lattice Boltzmann method for pore-scale mass diffusionadvection process in geopolymer porous structures

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Journal of Rock Mechanics and Geotechnical engineering 2024年第6期16卷 2126-2136页

作者： Xiaoyu Zhang Zirui Mao Floyd W.Hilty Yulan Li Agnes Grandjean Robert Montgomery Hans-Conrad zur Loye Huidan Yu shenyang Hu Purdue university IndianapolisIN46202USA Pacific Northwest National Laboratory RichlandWA99352USA CEA DESISECDMRCUniv.MontpellierMarcouleFrance Department of Chemistry and Biochemistry University of South CarolinaColumbiaSC29208USA

Porous materials present significant advantages for absorbing radioactive isotopes in nuclear waste *** improve absorption efficiency in nuclear waste treatment,a thorough understanding of the diffusion-advection process within porous structures is essential for material *** this study,we present advancements in the volumetric lattice Boltzmann method(VLBM)for modeling and simulating pore-scale diffusion-advection of radioactive isotopes within geopolymer porous *** structures are created using the phase field method(PFM)to precisely control pore *** our VLBM approach,we introduce a concentration field of an isotope seamlessly coupled with the velocity field and solve it by the time evolution of its particle population *** address the computational intensity inherent in the coupled lattice Boltzmann equations for velocity and concentration fields,we implement graphics processing unit(GPU)*** of the developed model involves examining the flow and diffusion fields in porous ***,good agreement is observed for both the velocity field from VLBM and multiphysics object-oriented simulation environment(MOOSE),and the concentration field from VLBM and the finite difference method(FDM).Furthermore,we investigate the effects of background flow,species diffusivity,and porosity on the diffusion-advection behavior by varying the background flow velocity,diffusion coefficient,and pore volume fraction,***,all three parameters exert an influence on the diffusion-advection *** background flow and diffusivity markedly accelerate the process due to increased advection intensity and enhanced diffusion capability,***,increasing the porosity has a less significant effect,causing a slight slowdown of the diffusion-advection process due to the expanded pore *** comprehensive parametric study provides valuable insights into the kinetics of isotope

关键词： Volumetric lattice Boltzmann method(VLBM) Phase field method(PFM) Pore-scale diffusion-advection Nuclear waste treatment Porous media flow Graphics processing unit(GPU) parallelization

Influence of nanometric CeO2 coating on high temperature oxidation of Cr

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Progress in Natural Science:Materials International 2007年第5期17卷 601-606页

作者： Jin Huiming , Zhang Linnan and Liu Xiaojun (Materials research center, Department of Mechanical engineering, Yangzhou university, Yangzhou 225009, china College of Materials Science and engineering, North-East university, shenyang 110014, china) [a]Materials research center Department of Mechanical Engineering Yangzhou University Yangzhou China [b]College of Materials Science and engineering North-East University Shenyang China

Isothermal and cyclic oxidation behavior of chromium and its superficially applied nanometric CeO2 samples were studied at 900℃in air. Scanning electronic microscopy (SEM), transmission electronic microscopy (TEM) and high resolution electronic microscopy (HREM) were used to examine the morphology and micro-structure of oxide films. It was found that ceria addition greatly improved the anti-oxidation ability of Cr both in isothermal and cyclic oxidizing experiments. Acoustic emission (AE) technique was used in situ to monitor the cracking and spalling of oxide films, and AE signals were analyzed in time-domain and number-domain according to the related oxide fracture model. Laser Raman spectrometer was also used to study the stress status of oxide films formed on Cr with and without ceria. The main reason for the improvement in anti-oxidation of chromium was that ceria greatly reduced the growing speed and grain size of Cr2O3. This fine-grained Cr2O3 oxide film might have better high temperature plasticity and could relieve parts of compressive stress by means of creeping, and maintained the ridge character and relatively low internal stress level. Meanwhile, ceria application reduced the size and the number of interfacial defects, while remarkably enhanced the adhesive property of Cr2O3 oxide scale formed on Cr substrate.

关键词： oxidation stress CeO2 nanoparticle coating chromium.

Bipolar charged aerosol agglomeration and collection by a two-zone agglomerator

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Journal of environmental Sciences 2001年第3期13卷 276-279页

作者： XIANG Xiao dong 1, CHEN Bao zhi 1, COLBECK I 2 (1. School of Resource and Civil engineering, Northeastern university, shenyang 110006, china. 2. Institute for environmental research, Department of Biological and Chemical Sciences, university of Es School of Resource and Civil engineering Northeastern University Shenyang 110006 China.

In older to collect fine particles more efficiently, a new-type electrostatic agglomerator with two zones was developed. The distinguishing feature of this electrostatic agglomerator is that the particles are bipolarly charged and coagulated in the same alternating electric field simultaneously. The silica flour with 2 fun mass median diameter and the smoke from burning wood powder were used as test aerosol. The comparison experimental results have shown that when the mean electric field is 4 kV/cm the collection efficiency of the new electrostatic agglomerator was 98.2% for silica flour and 67.4% for wood powder smoke, Under the same experimental condition. the collection efficiency of the electrostatic agglomerator with three zones was 97.4% for collecting silica flour and the collection efficiency of the electrostatic precipitator was 56.3% for wood powder smoke.

关键词： charged particle agglomeration alternating electric field electrostatic agglomerator (EA) electrostatic precipitator (ESP) collection efficiency

Evaluation of Changes and Stability on the Surroundings Adjacent to Exhaust-Gas Emitting Port

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沈阳建筑大学学报(自然科学版) 2011年第3期27卷 541-546页

作者： AO Yong′an1,Marc A.Rosen2,WANG Yueren1(1.School of municipal and environmental engineering,shenyang jianzhu university,shenyang,china,110168 2.Faculty of engineering and Applied Science,university of Ontario Institute of Technology,2000Simcoe Street North,Oshawa,Ontario,Canada,L1H7K4) School of municipal and environmental engineering Shenyang Jianzhu University Shenyang 110168 China Faculty of engineering and Applied Science University of Ontario Institute of Technology 2000 Simcoe Street North Oshawa Ontario L1H 7K4 Canada

The exergy and entropy changes of the surroundings adjacent to exhaust-gas emitting ports,and the probable effects on the atmosphere,are investigated and the current stable state changing point of atmosphere is determined and compared in the *** potential of doing work is described and the effects of the amount of exhaust gas on the atmosphere are studied through exergy and entropy change *** exergy change function accounts for the flow direction of the exhaust gas without local *** appears that exergy can be used as a state function to describe the change,the stability and the order of a system.

关键词： exergy entropy exhaust gas nonlinear dynamic atmosphere change

Temperature-controlled ionic liquid dispersive liquid phase microextraction combined with ultra-high-pressure liquid chromatography for the rapid determination of triclosan,triclocarban and methyl-triclosan in aqueous samples

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Science china Chemistry 2010年第12期53卷 2600-2607页

作者： GUO JieHong 1,2,LI XingHong 2,CAO XueLi 1,QU Lei 2,3,HOU DeKun 2 & XU XiaoBai 2 1 School of Chemical and environmental engineering,Beijing Technology and Business university,Beijing 100048,china 2 State Key Laboratory of environmental Chemistry and Eco-toxicology research center of Eco-environmental Sciences,Chinese Academy of Sciences,Beijing 100085,china 3 Zhengzhou university,Zhengzhou 450001,china 1. School of Chemical and environmental engineering Beijing Technology and Business University Beijing 100048 China2. State Key Laboratory of Environmental Chemistry and Eco-toxicology research center of Eco-environmental Sciences Chinese Academy of Sciences Beijing 100085 China3. Zhengzhou University Zhengzhou 450001 China

As extraction solvents,ionic liquids have green *** this study,an environmentally benign analytical method termed temperature-controlled ionic liquid dispersive liquid phase microextraction (TIL-DLME) combined with ultra-highpressure liquid chromatography (UHPLC)-tunable ultraviolet detection (TUV) was developed for the pre-concentration and determination of triclosan (TCS),triclocarban (TCC) and methyl-triclosan (M-TCS) in water *** parameters that may affect extraction efficiencies were examined and optimized,including the types and amount of ionic liquids,volume of the diluent,heating temperature,cooling time,salt effect and pH *** the optimum conditions,linearity of the method was observed in the ranges of 0.0100-100 μgL-1 for TCS and M-TCS,and 0.00500-50.0 μgL-1 for TCC with correlation coefficients (r2) > *** limits of detection (LODs) ranged from 1.15 to 5.33 *** in domestic water and TCC in reclaimed water were detected at the concentrations of 1.01 and 0.126 μgL-1,*** spiked recoveries of the three target compounds in reclaimed water,irrigating water,waste water and domestic water samples were obtained in the ranges of 68.4%-71.9%,61.6%-87.8%,58.9%-74.9% and 64.9%-92.4%,*** with the previous dispersive liquid-liquid microextraction method (DLLME) about the determination of TCS,TCC and M-TCS,this method is not only more environmentally friendly but also more sensitive.

关键词： ionic liquid temperature-controlled ionic liquid dispersive liquid phase microextraction UHPLC aqueous samples

Performance comparison and parametric study on spiral groove gas film face seals

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Science china(Physics,Mechanics & Astronomy) 2004年第z1期47卷 29-36页

作者： LIU Yuchuan, SHEN Xinmin, XU Wanfu & WANG ZhiliState Key Laboratory of Tribology, Tsinghua university, Beijing 100084, china School of Mechanical engineering and Automation, Beijing university of Aeronautics and Astronautics, Beijing 100083, china Lubrication Technology research center, shenyang Institute of Technology, shenyang 110015, china Tsing Hua Univ State Key Lab Tribol Beijing 100084 Peoples R China Beijing Univ Aeronaut & Astronaut Sch Mech Engn & Automat Beijing 100083 Peoples R China shenyang Inst Technol Lubricat Technol Res Ctr Shenyang 110015 Peoples R China

Several spiral groove gas film face seals (SGFS) with different layouts are compared quantitatively to analyze their merits and faults and application behaviors. In addition, a parametric study on downstream mode SGFS is conducted to determine its optimal parameters under certain working conditions. In tne computation of gas film pressure on the face, finite element method (FEM) is applied to adapt to complicated geometrical boundary.

关键词： spiral groove, gas film face seals, parameter study, performance comparison, finite element method.

Integral ear elimination and virtual point-based updating algorithms for constrained Delaunay TIN

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Science china(Technological Sciences) 2008年第S1期51卷 135-144页

作者： WU LiXin1,2,WANG YanBing2,3 & SHI WenZhong2,4 1 Institute for Geo-informatics & Digital Mine research,Northeastern university,shenyang 110004,china 2 Institute for GIS/RS/GPS & Subsidence engineering research,china university of Mining & Technology,Beijing 100085,china 3 Laboratory of 3D Information Acquisition & Application,Capital Normal university,Beijing 100037,china 4 center for Advanced GIS research,LSGI,Polytechnic university Hong Kong,Hong Kong,china Northeastern Univ Inst Geoinformat & Digital Mine Res Shenyang 110004 Peoples R China china Univ Mining & Technol Inst GIS RS GPS & Subsidence Engn Res Beijing 100085 Peoples R China Capital Normal Univ Lab Informat Acquisit & Applicat Beijing 100037 Peoples R China Hong Kong Polytech Univ LSGI Ctr Adv GIS Res Hong Kong Hong Kong Peoples R China

Constrained Delaunay Triangular Irregular Networks (CD-TIN),a kind of special data structure,have many practical applications in Geoinformatics,especially in the representation of linear constrained triangulation for DTM and DSM,such as in digital city and digital mine. Past researches on D-TIN mainly focused on point in-sertion and deletion without consideration of constraint,and that on CD-TIN usu-ally paid more attention to the insertion algorithms for points and edges,but little to the deletion algorithms. The presented algorithms are far insufficient for the dy-namic updating of CD-TIN. In this paper,the constraint edge in CD-TIN is consid-ered to be any set of broken lines,i.e.,polygon edges,broken lines and simple segments. The constraint edge may be composed of one or more constraint seg-ments,and it is allowed to be in any form: Open or close,intersection or self-in-tersection. By improving to present insertion and deletion algorithms for D-TIN,two new algorithms for CD-TIN updating are presented. According to the polymorphism of the constraints in CD-TIN,virtual point is adopted to represent the crossing node between constraint edges when a constraint edge is inserted in CD-TIN. Two new algorithms named as Integral Ear Elimination (IEE) and Influence Domain Retrian-gulation for Virtual Point (IDRVP) are presented,the former is for constraint point deletion,while the later is for the insertion and deletion of constraint edge. The principle of IDRVP is that to divide the influence domain of a virtual point into some parts by the constraint-keeping edges,and to retriangulate each part of the influ-ence domain individually referring to the constraint visible property and constraint empty circle (CEC) criterion. Finally,a prototype system is developed with VC++,one case on the integration of 3D terrain and buildings is demonstrated to test the correctness of new algorithms. It shows that the new algorithms are effective for the updating of CD-TIN.

关键词： Delaunay TIN spatial constraint data updating spatial modeling polymorphism digital mine

Cytotoxicity of lambda-cyhalothrin on the macrophage cell line RAW 264.7

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Journal of environmental Sciences 2010年第3期22卷 428-432页

作者： Quan Zhang, Cui Wang, Liwei Sun, Ling Li, Meirong Zhao research center of environmental Science, College of Biological and environmental engineering, Zhejiang university of Technology, Hangzhou 310032, china. [a] research center of environmental Science College of Biological environmental engineering Zhejiang University of Technology Hangzhou 310032 China

The wide use and wide-spectrum toxicity of synthetic pyrethroids （SPs） insecticides make them an emerging ecotoxicological concern. Some previous studies showed that SPs possessed cytotoxicity in some immune cells such as human lymphocytes and rat bone marrow. However, the cytotoxicity of SPs to macrophages, which are crucial to innate immunity, has not been explored. In the present report, we investigated a new pyrethroid insecticide, lambda-cyhalothrin （LCT）, which may increase the generation of reactive oxygen species （ROS） and DNA damage levels and cause cytotoxicity in RAW 264.7 cells in dose- and time-dependent manners. The results for the first time implicated increased endogenous ROS and DNA damage as co-mediators of LCT-induced cytotoxicity in macrophages. Our results also suggested that macrophages were involved in synthetic pyrethroid-induced adverse immune effects. Considering the ubiquitous environmental presence of SPs, this study provided new information relative to the potential long-term physiological and immunological effects associated with chronic exposure to SPs. Hence, the potential immunotoxicity of SPs should be considered in assessing the safety of these compounds in sensitive environmental compartments.

关键词： lambda-cyhalothrin macrophage reactive oxygen species cytotoxicity

Enantioselective separation and zebrafish embryo toxicity of insecticide beta-cypermethrin

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Journal of environmental Sciences 2010年第5期22卷 738-743页

作者： Chao Xu,Wenqing Tu,Chun Lou,Yingying Hong,Meirong Zhao research center of environmental Science,College of Biological and environmental engineering,Zhejiang university of Technology,Hangzhou 310032,china. [a] research center of environmental Science College of Biological environmental engineering Zhejiang University of Technology Hangzhou 310032 China

Enantioselectivity of chiral pollutants is receiving growing concern due to the difference in toxicology and environment fate between *** this study,enantiomers of insecticide beta-cypermethrin （beta-CP） were separated on selected chiral column by HPLC,and the toxicity of enantiomers was evaluated using the zebrafish embryo-larval *** enantiomers of beta-CP were baseline separated on Chiralcel OD and Chiralpak AD columns and detected by circular dichroism （CD） at 236 *** separation could be achieved at lower temperature （e.g.,20°C） and with lower levels of polar *** enantiomers were obtained on Chiralcel *** CD spectra of enantiomers were *** comparing the elution order with a previous similar study,the absolute configuration of beta-CP enantiomers was *** individual enantiomers were used in zebrafish embryo test,and the results showed that beta-CP enantioselectively induced yolk sac edema,pericardial edema and crooked *** 1R-cis-αS and 1R-trans-αS enantiomers showed strong developmental toxicities at concentration of 0.1 mg/L,while the 1S-cis-αR and 1S-trans-αR induced no malformations at higher concentration （e.g.,0.3 mg/L）.The results suggest that the enantioselective toxicological effects of beta-CP should be considered when evaluating its ecotoxicological effects.

关键词： beta-cypermethrin enantioselectivity zebrafish embryo chiral separation