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Sedimentary geochemistry of the Cambrian-Ordovician cherts: Implication on archipelagic ocean of North Qilian orogenic belt

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Science china Earth Sciences 2007年第11期50卷 1628-1644页

作者： DU YuanSheng1,2, ZHU Jie1, GU SongZhu1, 2, XU YaJun1 & YANG JiangHai1 1 Faculty of Earth Sciences, china university of geosciences, wuhan 430074, china 2.key laboratory of biogeology and Environment geology of education ministry, wuhan 430074, china Faculty of Earth Sciences China University of Geosciences Wuhan China key laboratory of biogeology and Environment geology of education ministry Wuhan China

The Caledonian North Qilian orogenic belt lies between the North china plate and the Qaidam mi-croplates, and resulted from the collision among the Qaidam microplate, mid-Qilian block and the North china plate. The orogen initiated from the rifting of the Late Proterozoic Rodinia, and then it experi-enced stages of Cambrian rift basin and Ordovician archipelagic oceanic basin, and foreland basin during Silurian to Early-Middle Devonian. The average ratios of Al/(Al+Fe+Mn), Al/(Al+Fe), δ Ce, Lan/Ybn and Lan/Cen from cherts of Cambrian Heicigou Formation are 0.797, 0.627, 1.114, 0.994 and 1.034 re-spectively. In the NAS standardized REE distribution pattern, the cherts from Xiangqianshan is slightly HREE enriched, and the cherts from Ganluci and Shiqingdong are plane. All of these features indicated that Cambrian cherts of the Heicigou Formation originated from a continental margin rift background. On the contrary, the average ratios of Al/(Al+Fe+Mn), Al/(Al+Fe), δ Ce, Lan/Ybn, Lan/Cen of the Ordovician chert from Dakecha, Cuijiadun, Shihuigou, Laohushan, Heicigou, Maomaoshan, Bianmagou, Da-chadaban, Baiquanmen, Jiugequan and Angzanggou, are respectively 0.72, 0.58, 0.99, 1.09 and 0.96 respectively. Their NAS standardized REE distribution patterns of most Ordovician cherts are plane mode or slightly HREE enriched. The REE distribution pattern of few samples of cherts are slightly LREE enriched. Characteristics of sedimentary geochemistry and tectonic evolution demonstrated that the Cambrian-Ordovician cherts, associated with rift, oceanic, island arc and back-arc volcanic rocks, was not formed in a typical abyssal oceanic basin or mid-oceanic ridge. On the contrary, they formed in a deepwater basin of continental margin or a archipelagic ocean tectonic setting. Several Early Paleo-zoic ophiolite belts in North Qilian and adjacent periphery Qaidam microplate imply that an archipelagic ocean during Ordovician existed in the east of Pro-Tethys.

关键词： North Qilian orogenic belt,Cambrian-Ordovician,cherts sedimentary geochemistry,archipelagic ocean

Analytical method of Cr stable isotope and its application to water pollution survey

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Chinese Science Bulletin 2010年第7期55卷 664-669页

作者： GAO YongJuan 1,2,3,MA Teng 4,5,LING WenLi 1,2,LIU CunFu 4,5 & LI Li 4,5 1Faculty of Earth Science,china university of geosciences,wuhan 430074,china 2State key laboratory of Geological Processes and Mineral Resources,china university of geosciences,wuhan 430074,china 3 Graduate School,china university of geosciences,wuhan 430074,china 4 Biogeological and environmental geology laboratory of ministry of education(china university of geosciences) ,wuhan 430074,china 5 Sino-Hungary Joint laboratory of environmental Sciences and Health,china university of geosciences,wuhan 430074,china Faculty of Earth Science China University of Geosciences Wuhan China State key laboratory of Geological Processes and Mineral Resources China University of Geosciences Wuhan China Graduate School China University of Geosciences Wuhan China Biogeological and environmental geology laboratory of ministry of education (china university of geosciences) Wuhan China Sino-Hungary Joint laboratory of environmental Sciences and Health China University of Geosciences Wuhan China

High Cr(VI) concentration is a potential serious risk to environment and ecologic ***,it is essential to effectively monitor Cr contamination in water systems and scientifically evaluate its evolution trend.A new method of in-situ tracer technique by Cr isotopic analysis for quantitatively estimating Cr-contamination and its regional evolution in natural waters as well as a case application are reported in this *** on documented literatures,an experimental procedure for chemical separation and purification of Cr in water samples and its analytical method for Cr isotopic measurement by thermal ionization mass spectrometry(TIMS) are *** samples collected around a chemical factory in Hubei Province were analyzed by this *** samples showδ53Cr values ranging from-1.7‰to 7.3‰and an elevating trend with an increasing in distance from the sampling site to pollution source.A functional correlation following Rayleigh fractionation law was established between sample'sδ53Cr value and its extent of Cr *** study suggests that Cr isotopic analysis is an effective method to reveal the spatial distribution and its evolution trend of Cr contamination in the regional water *** is thus helpful to assessing the self-purifying ability of local water system according to Cr isotopic fractionation.

关键词：铬(VI) 水污染调查稳定同位素应用同位素分析供水系统演变趋势示踪技术

Arsenic Biomobilization from Aquifer Sediments by Indigenous Bacteria at Datong Basin and Hetao Plain,Northern china

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地学前缘 2009年第S1期16卷 4-5页

作者： Zuoming Xie,Yanxin Wang School of environmental Studies & MOE key laboratory of biogeology and environmental geology,china university of geosciences(wuhan),wuhan 430074,china.

High arsenic groundwater is widely distributed at Datong Basin and Hetao Plain,northern *** investigate the effects of microbial activities on arsenic mobilization in the two high arsenic regions,the microcosm experiments were performed under various conditions of two bacterial strains(XZM001 and YH001,isolated from the two shallow aquifer sedi-

关键词： biomobilization indigenous bacteria As

Ostracod fauna across the Permian-Triassic boundary at Chongyang, Hubei Province, and its implication for the process of the mass extinction

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Science china Earth Sciences 2010年第6期53卷 810-817页

作者： LIU Hao1, WANG YongBiao1, YUAN AiHua2, YANG Hao1, SONG HaiJun1 & ZHANG SuXin21 key laboratory of biogeology and environmental geology of ministry of education, wuhan 430074, china 2 State key laboratory of Geological Processes and Mineral Resources, wuhan 430074, china key laboratory of biogeology and environmental geology of ministry of education Wuhan China State key laboratory of Geological Processes and Mineral Resources Wuhan China

Thirty species of 10 ostracod genera were identified from 440 fossil specimens isolated through the hot acetolysis of the rock samples collected across the Permian-Triassic boundary at Chongyang section. Twenty species of 6 genera are found to occur in the limestone of Changxing Formation, and 11 species of 7 genera above the main faunal mass extinction horizon. The os-tracod assemblages identified at the Chongyang section are obviously different from those previously reported in the contem-poraneous microbialites in Guangxi and Chongqing regions, not only in the ostracod components but also in the abundance of filter-feeding ostracods relative to the deposit-feeding ostracods, an indicator of the oxygen level of the seawater. This spatial difference in ostracod assemblages might reflect the diversity of oceanic environmental conditions after the end-Permian mass extinction. Ostracods disappear at 200 cm below and near the main mass extinction horizon, and on the top of the microbialites, respectively, showing an episodic and gradual collapse process at the Chongyang section. The carbon isotope composition is found to appear at 200 cm below the main mass extinction horizon, indicating the initial deterioration of oceanic environment. Fluctuation of the carbon isotope composition is obviously related with the episodic evolution of ostracod species, but not with the abundance of ostracods.

关键词： ostracod microbialite Permian-Triassic mass extinction Chongyang

A Technique for Carbon and Chlorine Isotope Analyses of Chlorinated Aliphatic Hydrocarbons in Groundwater

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Journal of Earth Science 2013年第2期24卷 274-281页

作者：甘义群余婷婷周爱国刘运德刘存富 School of environmental Studies China University of Geosciences State key laboratory of biogeology and environmental geology China University of Geosciences

Chlorinated aliphatic hydrocarbons （CAHs）, significant contaminants in groundwater, can be characterized by stable isotopic compositions of carbon and chlorine. Previously published methods were of low analytical sensitivity or not ideal for natural samples with low concentrations of CAHs. This method is reported here to carry out simultaneously carbon and chlorine isotope analyses for mieromolar concentrations of dissolved CAHs. It was executed by extracting and converting CAHs to carbon dioxide and methyl chloride （CH3CI）. Specially, a continuous-flow interface GasBench Ⅱ was used to extract CH3CI for online chlorine isotope analysis. As a result, it greatly enhances the efficiency for isotope analysis by eliminating procedures for offline CH3CI preparation and separation. Sample size requirement was reduced to approximately 11 pmol chlorine. The standard deviation of δ^＋3C and δ^37CI for both TCE solvents and water samples was better than 0.30‰ and 0.20%0 （1σ）, *** and chlorine isotope analyses can be used as an important tool to study the sources of organic contaminants in groundwater and their behaviors in the aquifers. The method is applicable to manufacturers＇ products as well as a sample from a polluted site in principle, which will be validated in our field studies.

关键词： chlorine isotope carbon isotope chlorinated aliphatic hydrocarbon (CAH) groundwater organic contamination.

Endolithic fungi:A possible killer for the mass extinction of Cretaceous dinosaurs

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Science china Earth Sciences 2008年第6期51卷 801-807页

作者： GONG YiMing1,2, XU Ran1 & HU Bi2 1 key laboratory of biogeology and environmental geology of ministry of education, State key laboratory of Geological Processes and Mineral Resources, china university of geosciences, wuhan 430074, china 2 Institute of Resources and Environment key laboratory of Biogenic Traces & Sedimentary Minerals of Henan Province, Henan Polytechnic university, Jiaozuo 454003, china key laboratory of biogeology and environmental geology of ministry of education State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Wuhan China Institute of Resources and Environment key laboratory of Biogenic Traces & Sedimentary Minerals of Henan Province Henan Polytechnic University Jiaozuo China

Mycelium-like structures found under ESEM within radial sections of fragmental dinosaur eggshells would be the endolithic fungi coexistent with dinosaur eggs in the upper part of the Late Cretaceous Hugang Formation from the Wenjiaping section of Wenxian, Danjiangkou, northwestern Hubei, Central china. The endolithic fungi selectively occurred in the bad biomineral zone within the columnar layer of the eggshells, where the crowded endolithic fungi penetrated the columnar layer at near-vertical or near-horizontal angles. The endolithic fungi are needle-like, ribbon-like and silk-like, and 5-18 μm long, 0.3-0.5 μm wide at their base, with pointed tip, and are unbranched. The hyphae are mainly composed of oxygen, carbon and calcium, and are with minor sodium, potassium, chlorine and sulfur. The en-dolithic fungi and host have the same characters in lithification, fracture and main chemical composi-tion. We suggested that the episode endolithic fungi invading dinosaur eggs may have taken place in the interval between after formation of dinosaur eggshells and before their petrifaction and that dino-saur eggs invaded by endolithic fungi would not be normally incubated or would only be incubated into venerable and pathologic baby dinosaurs to be easily to aborted and contributed to the mass extinction of the dinosaurs at the end of Cretaceous.

关键词： endolithic fungi dinosaur eggs mass extinction Cretaceous

Geochemical Evidence of Gas Sources of CO_2-Rich Cold Springs from Wudalianchi,Northeast china

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Journal of Earth Science 2009年第6期20卷 959-970页

作者：毛绪美王焰新 Oleg V Chudaev 王逊 key laboratory of biogeology and environmental geology of ministry of education China University of GeosciencesWuhan Far East Geological Institute Russian Academy of Science Institute of Hydrogeology and Engineering geology of Heilongjiang Province

CO2-rich cold springs occur near the active volcanoes at Wudalianchi （五大连池）, Northeast china. The springs are rich in CO2, with HCO3-as the predominant anion and have elevated contents of total dissolved solid （TDS）（〉1 000 mg/L）, Fe^2＋（〉20 mg/L）, Sr （〉1 mg/L）, and dissolved Si （〉20 mg/L）. The compositions of escaped and dissolved gases of the springs are similar. The δ^13C values of escaped gases and dissolved gases in mineral springs at Wudalianchi vary from -8.77‰ to -4.53‰ and -8.24‰ to -5.26‰, while δ^18O values vary from -10.68‰ to -7.65‰ and -10.30‰ to -8.84‰, respectively, indicating the same upper mantle origin of CO2 of escaped gases and dissolved gases in the springs. Carbon and oxygen isotope fractionations and water-CO2 exchange were weak in the process of groundwater flow. The 4He content exceeds 5 000×10-6 cm^3·STP/mL in escaped gases of the mineral springs, and the 3He/4He ratios of the escaped and dissolved gases vary from 2.64Ra to 3.87Ra and 1.18Ra to 3.30Ra, respectively. It can be postulated that the CO2 of mineral springs deriving from the magma chamber of the upper mantle moves upward to the surface, to increase the content of 4He in the mineral springs and decrease the ratio of 3He/4He. The helium origin of escaped gases in springs can be calculated with the MORB-crust mixing model, but that in the north spring can be better explained with the MORB-crust-air mixing model due to the effect of mixing with surface water. However, dissolved helium in springs, except the north spring, is better explained with the MORB-crust-ASW mixing model.

关键词： δ^13C δ^18O, ^3He/^4He mineral spring CO2 Wudalianchi Northeast china.

Ce Anomalies of the Yangtze Region,South china,through the Ordovician and Silurian Transition

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Journal of Earth Science 2009年第6期20卷 941-948页

作者：严德天张丽琴李双建 key laboratory of Tectonics and Petroleum Resources of ministry of education China University of GeosciencesWuhan Institute of geology and Geophysics Chinese Academy of Sciences School of Geodesy and Geomatics Wuhan University key laboratory of Geospace Environment & Geodesy of ministry of education Wuhan University Petroleum Exploration and Production Institute of SINOPEC

Systematic Ce anomalies for whole-rock have been obtained from the shale-dominated, continuous, and pelagic sedimentary sequences spanning the Ordovician/Silurian （O/S） boundary at the Tieshui （铁水） of Xiushan （秀山）, Chongqing （重庆）, South china. Ce anomalies across the O/S boundary are recognized in three intervals, Wufeng （五峰）, Guanyinqiao （观音桥） and Longmaxi （龙马溪）. The calculated Ce/Ce＊ values of Wufeng Formation range from 0.84 to 0.96 （avg. 0.90）. In the Guanyinqiao Formation, the values of calculated Ce/Ce＊ range from 0.73 to 0.85 （avg. 0.79）. The Ce/Ce＊ values of uppermost Longmaxi Formation range from 0.87 to 0.96 （avg. 0.91）. All along the section, the magnitude of the Ce anomaly is always negative, but is more significant in the Guanyinqiao Formation. The relatively higher Ce/Ce＊ values in the Wufeng and Longmaxi shales are likely to be due to the sediments deposited under rather reducing conditions. The Ce anomaly apparently does play some regular roles in the anoxic events that accompany prominent mass extinctions, and this work provides new data of critical importance for constraining models on the end-Ordovician anoxic events and mass extinctions.

关键词： Ce anomaly redox mass extinction Ordovician/Silurian boundary Yangtze platform.

Megaripples from the Mesoproterozoic of the Kimberley region,northwestern Australia and its geological implications

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Journal of Palaeogeography 2012年第1期1卷 15-25页

作者： Lan Zhongwu 1,2,3,,Zhong-Qiang Chen 2,4,1.State key laboratory of Lithospheric Evolution,Institute of geology and Geophysics,Chinese Academy of Sciences,Beijing 100029,china 2.School of Earth and Environment,The university of Western Australia,Australia 3.key Lab of Petroleum Resources Research,Institute of geology and Geophysics,Chinese Academy of Sciences,Beijing 100029,china 4.State key laboratory of biogeology and environmental geology,china university of geosciences (wuhan),wuhan 430074,china State key laboratory of Lithospheric Evolution Institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China School of Earth and Environment The University of Western Australia Australia key Lab of Petroleum Resources Research Institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China State key laboratory of biogeology and environmental geology China University of Geosciences (Wuhan) Wuhan 430074 China

Large ripples are described from the Mesoproterozoic Hilfordy Formation in the Kimberley region,northwestern *** ripple index (RI) and ripple symmetry index (RSI) suggest the Kimberley ripples were likely generated by storm *** wave height is up to 15 23 cm and wave length is up to 70 90 *** features,incorporated with other morphological characteristics such as symmetry,steepness,ripple spacing,and compositions,agree well with the megaripples previously reported from the intertidal-nearshore settings of modern seas and the geological *** Mesoproterozoic ripples were likely generated by the storm-induced *** survey of the global record of megaripples reveals that such structures have occurred through the geological past from the Archean to present *** were particularly common in the Neoproterozoic and had the largest ripple length and ripple height among the modern and geological *** is probably because extreme storms prevailed at that *** frequent occurrence in present day beach is probably due to the prevalence of extreme storms caused by the monsoon or tsunami/earthquake influenced climatic regimes.

关键词： megaripples palaeohydrodynamics extreme storms Mesoproterozoic Hilfordy Formation Kimberley northwestern Australia