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Experimental study on interaction between simulated sandstone and acidic fluid

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Petroleum Science 2009年第1期6卷 8-16页

作者： Zhang Yongwang Zeng Jianhui Yu Bingsong State key laboratory of Petroleum Resource and Prospecting China University of Petroleum Beijing 102249 China Basin and Reservoir Research Center China University of Petroleum Beijing 102249 China State key laboratory of Geological Processes and Mineral Resources China University of Geosciences Beijing 100083 China

In order to investigate the controlling mechanism of temperature, fluid and other factors on water-rock interaction in the diagenetic process, we performed a series of simulated experiments on the interaction between two kinds of fluids with different salinity and a composite mineral system （simulated sandstone）, which contains albite, K-feldspar and other minerals. The experimental results showed that acidity was the most important factor that affected the dissolution of minerals in the composite mineral system. The lower the pH value, the more easily the minerals dissolved. At the same pH value, the dissolution abilities of different acids for various mineral components were also different. Compared to hydrochloric acid （inorganic acid）, oxalic acid （organic acid） was more able to dissolve aluminosilicate minerals. However, the dissolution ability of oxalic acid for carbonate minerals was lower than that of hydrochloric acid. In the process of fluid-rock interaction, dissolution of feldspar was relatively complicated. Increase of temperature would accelerate the dissolution of feldspar. Under acidic conditions, albite had a higher dissolution rate than K-feldspar. K-feldspar could dissolve and convert into montmorillonite and kaolinite, while albite could dissolve and convert into kaolinite both at 40℃ and 80℃. Presence of organic acid, and decrease of pH value and water salinity were all favorable for the dissolution of feldspar, but weakened the ability to form clay minerals.

关键词： Fluid simulated sandstone dissolution static experiment

Application of C5-C13.light hydrocarbons in depositional environment diagnosis

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Progress in Natural Science:Materials International 2008年第9期18卷 1129-1137页

作者： Peirong Wanga,b,, Guanjun Xu a,c, Tingrong Xiaoc, Dajiang Zhanga,c, Bin Zhanga,c a key laboratory of Petroleum geochemistry, {3. National Petroleum Corporation, beijing 100083, {3. b Department of Organic geochemistry, Yangtze University, Jingzhou 43.023. {3. c Central laboratory of Petroleum Geology, Research Institute of Petroleum Exploration and Development, Petro{3., beijing 100083, {3. key laboratory of Petroleum geochemistry China National Petroleum Corporation Beijing 100083 China Department of Organic geochemistry Yangtze University Jingzhou 434023 China Central laboratory of Petroleum Geology Research Institute of Petroleum Exploration and Development PetroChina Beijing 100083 China

Based on the geological background and Gammacerane/C3.H(S + R) ratios, source rock depositional environments of the studied oil samples (194) from 13.oilfields were classified into three groups according to salinity:saline-lacustrine facies, fresh to brackish lacustrine facies (including limnetic facies), and semi-saline to saline facies (including marine facies of the Tarim Basin).C5-C13.compound groups in the crude oils were separated by GC, and about 286 compounds were qualitatively *** geochemical application of the C6-C13.compound groups and their ratios between each group with individual carbon number was *** studies show that (1) C6-C13.compound groups and their ratios in the crude oils could serve as new reliable parameters for oil-oil correlation because the C6-C13.light fractions are the major oil component, especially in light oil or condensate, in which they account for almost 90% of the whole oil;(2) the compound groups of C7 light hydrocarbons in oils derived from difierent depositional environments with difierent salinity have difierent characteristics;(3. C6-C13.compound groups and ratios may be afiected by other factors such as maturity, but they are mainly controlled by salinity of depositional waters.

关键词： Light hydrocarbons Crude oil Depositional environment Salinity

Inertial theory of the mean Hadley circulation under the condition of nonstatic equilibrium

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Science china Earth Sciences 2006年第5期49卷 546-553页

作者： CHAO Jiping1 & LIU Fei2,3.1. National Marine Environmental Forecasting Center, beijing 100081, china 2. key {3.oratory Regional Climate-Environment for Temperate East Asia, Institute of Atmospheric Physics, Chinese Academy of Sciences, beijing 100029, china 3. Graduate University of Chinese Academy of Sciences, beijing 100049, china 1. National Marine Environmental Forecasting Center Beijing 100081 China 2. key laboratory Regional Climate-Environment for Temperate East Asia Institute of Atmospheric Physics Chinese Academy of Sciences Beijing 100029 China 3. Graduate University of Chinese Academy of Sciences Beijing 100049 China

Tropical atmosphere is divided into two layers, the layer near the ground is the planet boundary layer, where the motion is linear, if the radiation equilibrium temperature is given at the top of the boundary layer, the vertical motion there can be obtained. It is the non-viscous ideal atmos- pheric layer above the boundary one, where the motion is nonlinear. After getting the conservation laws of angular momentum, potential temperature and potential vortex, the inertial theory of the Hadley circulation driven by the vertical motion of the boundary layer is established, followed by sev- eral examples of its application.

关键词： Hadley circulation, inertial theory, conservation laws of angular momentum, potential temperature and potential vortex.

Parameter identification theory of a complex model based on global optimization method

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Science china(Physics,Mechanics & Astronomy) 2008年第11期51卷 1722-1732页

作者： QU Jie1, JIN QuanLin2 & XU BingYe3.1 College of Automotive Engineering, South china University of Technology, Guangzhou 510640, china 2 beijing Research Institute of Mechanical and Electrical Technology, beijing 100083, china 3.Department of Engineering Mechanics, Tsinghua University, beijing 100084, china 1. College of Automotive Engineering South China University of Technology Guangzhou 510640 China 2. beijing Research Institute of Mechanical and Electrical Technology Beijing 100083 China 3. Department of Engineering Mechanics Tsinghua University Beijing 100084 China

With the development of computer technology and numerical simulation technology, computer aided engineering (CAE) technology has been widely applied to many fields. One of the main obstacles, which hinder the further application of CAE technology, is how to successfully identify the parameters of the selected model. An elementary framework for parameter identification of a complex model is provided in this paper. The framework includes the construction of objective function, the design of the optimization method and the evaluation of the identified results, etc. The parameter identification process is described in this framework, taking the parameter identification of the superplastic constitutive model considering grain growth for Ti-6Al-4V at 927°C as an example. The objective function is the weighted quadratic sums of the difference between the experimental and computational data for the stress-strain relationship and the grain growth relationship; the designed optimization method is a hybrid global optimization method, which is based on the feature of the objective function and incorporates the strengths of genetic algorithm (GA), the Levenberg-Marquardt algorithm and the augmented Gauss-Newton algorithm. The reliability evaluation of parameter identification result is made through the comparison between the calculated and experimental results and between the theoretical values of the parameters and the identified ones.

关键词： constitutive model parameter identification theory inverse analysis global optimization

Numerical simulation of non-Archie electrophysical property of saturated rock with lattice Boltzmann method

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Petroleum Science 2009年第1期6卷 24-28页

作者： Yue Wenzheng Tao Guo Liu Dongming Yang Wendu State key laboratory of Petroleum Resource and Prospecting China University of Petroleum Beijing 102249 China key laboratory of Earth Prospecting and Information Technology China University of Petroleum Beijing 102249 China Research Centre of Well Logging CNPC Key Laboratory of Well Logging China University of Petroleum Beijing 102249 China cnpc Logging Changqing Business Division Xi＇an Shaanxi 710201 China Sichuan Petroleum Administration Logging Company Ltd. CNPC Chongqing 401147 China

The electrophysical property of saturated rocks is very important for reservoir identification and evaluation. In this paper, the lattice Boltzmann method （LBM） was used to study the electrophysical property of rock saturated with fluid because of its advantages over conventional numerical approaches in handling complex pore geometry and boundary conditions. The digital core model was constructed through the accumulation of matrix grains based on their radius distribution obtained by the measurements of core samples. The flow of electrical current through the core model saturated with oil and water was simulated on the mesoscopic scale to reveal the non-Archie relationship between resistivity index and water saturation （I-Sw）. The results from LBM simulation and laboratory measurements demonstrated that the I-Sw relation in the range of low water saturation was generally not a straight line in the log-log coordinates as described by the Archie equation. We thus developed a new equation based on numerical simulation and physical experiments. This new equation was used to fit the data from laboratory core measurements and previously published data. Determination of fluid saturation and reservoir evaluation could be significantly improved by using the new equation.

关键词： Non-Archie relation digital core model lattice Boltzmann method numerical simulation rock physical experiment

Complex conforming Delaunay triangulation

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Science china(Information Sciences) 2010年第6期53卷 1130-1140页

作者： MENG XianHai 1, LI JiGang 1, YANG Qin 1, CAI Qiang 2 & CHEN QiMing 3.1 NLSDE, School of Computer Science and Engineering, BeiHang University, beijing 100083, china 2 School of Computer Sciences, beijing Technology and Business University, beijing 10003., china 3.School of Mechanical Engineering and Automation, BeiHang University, beijing 100083, china 1. NLSDE School of Computer Science and Engineering BeiHang University Beijing 100083 China2. School of Computer Sciences Beijing Technology and Business University Beijing 100037 China3. School of Mechanical Engineering and Automation BeiHang University Beijing 100083 China

A novel algorithm of conforming Delaunay triangulation for curved geometry is presented in the paper.A progress has been made for the problem puzzled Delaunay refinement where curved constraints cannot be accepted as input *** algorithm is based on a new sufficient condition for the existence of constraints in *** requires computing only the intersection between constraints and Voronoi edges or faces instead of the circum-sphere of curved *** the termination of the algorithm when small input angles exist in constraints, a weighted method is applied to ensure that the algorithm can terminate under any *** two-dimensional and three-dimensional results are also *** is shown that the algorithm has the capability of dealing with both linear and nonlinear constraints in a consistent way, without the need of maintaining triangular meshes on face constraints.

关键词： mesh generation Delaunay triangulation conforming curved constraints tetrahedralization weight

Compression behavior of Zr_(41)Ti_(14)Cu_(12.5)Ni_(10)Be_(22.5) bulk metallic glass up to 24 GPa

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Science china(Physics,Mechanics & Astronomy) 2005年第3期48卷 319-324页

作者： LI Gong 1, 2 , ZHAN Zaiji 2 , LIU Jing 3., YUN Jinku 1 , SUN Liling 2 , LIU Riping 1 , ZHANG Jun 2 & WANG Wenkui 1, 2 1. key laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, china 2. Center for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, {3. 100080, china 3. BSRF, Institute of High Energy Physics, Chinese Academy of Sciences, {3. 10003., china 1. key laboratory of Metastable Materials Science and Technology Yanshan University 066004 Qinhuangdao China 2. Center for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences 100080 Beijing China 3. BSRF Institute of High Energy Physics Chinese Academy of Sciences 100039 Beijing China

The compression of a Zr41Ti14Cu12.5Ni10Be22.5 bulk metallic glass (BMG) is investigated at room temperature up to 24 GPa using in-situ high pressure energy dispersive X-ray diffraction with a synchrotron radiation source. The pressure-induced structural relaxation is exhibited. It is found that below about 8 GPa, the existence of excess free volume contributes to the rapid structural relaxation, which gives rise to the rapid volumetric change, and the structural relaxation results in the structural stiffness under higher pressure.

关键词： bulk metallic glass, high pressure, structural relaxation, synchrotron radiation.

Influence of Ordovician carbonate reservoir beds in Tarim Basin by faulting

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Science china Earth Sciences 2008年第S2期51卷 53-60页

作者： L XiuXiang1,2,YANG Ning1,2,ZHOU XinYuan3.YANG HaiJun3.& LI JianJiao1,2 1 Faculty of Natural Resource & Information Technology,china University of Petroleum,beijing 102249,china 2 State {3. laboratory of Petroleum Resource and Prospecting,china University of Petroleum,beijing 102249,china 3.Tarim Oilfield,Petrochina,Korla 841000,china china Univ Petr Fac Nat Resource & Informat Technol Beijing 102249 Peoples R China china Univ Petr State Key Lab Petr Resource & Prospecting Beijing 102249 Peoples R China Petrochina Tarim Oilfield Korla 841000 Peoples R China

The quality of the Ordovician carbonate reservoir beds in the Tarim Basin is closely related to the development of secondary pores,fractures and cavities. Karstification is important in improving the properties of reservoir beds,and karstification related to unconformity has caught wide attention. Compared with the recent research on the unconformity karst reservoir bed improvement,this paper shows a new way of carbonate reservoir bed transformation. Based on field survey,core and slices observation,transformation of Ordovician carbonate reservoir beds by faulting can be classified into three types: (1) Secondary faults and fracturs generated by faulting improved carbonate reservoir bed properties,which were named the Lunnan or Tazhong82 model; (2) upflow of deep geothermal fluids caused by faulting,with some components metasomatizing with carbonate and forming some secon-dary deposit,such as fluorite. It can improve carbonate reservoir bed properties obviously and is named the Tazhong 82 model; and (3. the faulting extending up to the surface increased the depth of supergene karstification and the thickness of reservoir bed. It is named the Hetianhe model. Trans-formation effect of carbonate reservoir beds by faulting was very significant,mainly distributed on the slopes or on the edge or plunging end of the uplift.

关键词： carbonate faulting reservoir transformation Ordovician Tarim Basin

Distribution,formation and evolution of sand ridges on the East china Sea shelf

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Science china(Technological Sciences) 2010年第3期53卷 822-828页

作者： ZHAO RenBao 1,2,SUN HaiTao 3.WU YaSheng 3.&ZHAO ChuanFeng 1,2 1MOE key laboratory of Petroleum Engineering,china University of Petroleum,{3. 102249,china 2 Enhanced Oil Recovering Research Center,china University of Petroleum,{3. 102249,china 3.aculty of Natural Resource&Information Technology,china University of Petroleum,{3. 102249,china 1. MOE key laboratory of Petroleum Engineering China University of Petroleum Beijing 102249 China2. Enhanced Oil Recovering Research Center China University of Petroleum Beijing 102249 China3. Faculty of Natural Resource & Information Technology China University of Petroleum Beijing 102249 China

Influence of CO2 corrosion on reservoir mineralogical composition,pore structure and their mechanical characteristics was studied using XRD,SEM,rock tri-axial machine and core flow experimental *** was found that the corrosion effect was mainly attributed to rock texture and structure,fluid composition and external dynamical conditions in the experimental *** cores with bedding structures,their bedding surfaces were the preferential corrosion regions,because micro-cracks would evolve at these surfaces in the pressure-releasing ***,for cores with massive structures controlled by stable water environment,the CO2 corrosion would result in pore enlargement and secondary pore *** gas velocity from outlet showed sharp increase in the injection process of CO2-H2O *** could be explained by two changes caused by *** was the opening and closure of *** other was particle *** the corrosion time increased,both tensile strength and compressive strength decreased,which confirmed decrease of cementation *** should also be noted that permeability increase and micro-cracks generation would pose damage to the capacity of CO2 geological storage.

关键词： carbon dioxide geological storage mineralization enhanced oil recovery corrosion