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Classification and origin of natural gases from Lishui Sag,the East china Sea Basin

Science china Earth Sciences 2008年第S1期51卷 122-130页

作者： CHEN JianPing 1,2 ,GE HePing 3.,CHEN XiaoDong 3.,DENG ChunPing 1,2 &LIANG DiGang 1,2 1 Research Institute of Petroleum Exploration&Development,Petrochina,beijing 100083.china 2.key {3. of Petroleum geochemistry,cnpc,beijing 100083.china 3.Shanghai Division,CNOOC,Shanghai 20003.,china Research Institute of Petroleum Exploration & Development PetroChina Beijing China key lab of Petroleum geochemistry CNPC Beijing China Shanghai Division CNOOC Shanghai China

Natural gases discovered up to now in Lishui Sag,the East china Sea Basin,differ greatly in gaseous compositions,of which hydrocarbon gases amount to 2%―94%while non-hydrocarbon gases are dominated by *** hydrocarbon gases,without exception,contain less than 90%of methane and over 10%of C2 + heavier hydrocarbons,indicating a wet *** isotopic analyses on these hydrocarbon gases showed thatδ13. 1 ,δ13. 2 andδ13. 3.are basically lighter than-44‰,-29‰and-26‰, *** difference in carbon isotopic values between methane and ethane is great,suggesting a biogenic oil-type gas produced by the mixed organic matter at peak generation.δ13. CO2 values of nonhydrocarbon gases are all heavier than-10‰,indicating a typical abiogenic *** simulation experiment on hydrocarbon generation of organic matter in a closed gold-tube system showed that the proportion of methane in natural gases produced by terrigenous organic matter in the Lingfeng Formation marine deposit is obviously higher than that in natural gases derived from the aquatic and terrigenous mixed organic matter in the Yueguifeng Formation lacustrine deposit,consequently the proportion of heavier hydrocarbons of the former is remarkably lower than that of the ***, δ13. 1 values of natural gases produced by terrigenous organic matter in the Lingfeng Formation marine deposit are about 5‰heavier than those of natural gases derived from the aquatic and terrigenous mixed organic matter in the Yueguifeng Formation lacustrine deposit whileδ13. 2 andδ13. 3.values of the former are over 9‰heavier than those of the *** the LS3.-1 oil-gas pool is the only commercial oil-gas reservoir in Lishui Sag,where carbon isotopic compositions of various hydrocarbon components differ greatly from those of natural gases produced by the Lingfeng Formation organic matter but are very similar to those of natural gases derived from the Yueguifeng Formation organic matter,therefore,natural gases in the

关键词： Lishui Sag natural gas biogenesis abiogenesis lacustrine source rock marine source rock coal-measures source rock

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Petrogenesis of Songshugou dunite body in the Qinling orogenic belt, Central china: Constraints from geochemistry and melt inclusions

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Science china Earth Sciences 2005年第8期48卷 1146-1157页

作者： SU Li1,2, SONG Shuguang3.& ZHOU Dingwu1 1. key laboratory of Continental Dynamics of the Ministry of Education, Department of Geology, Northwestern University, Xi’an 710069, china 2. The Geological lab Center, china University of Geosciences (beijing), beijing 100083, china 3. key laboratory of Orogenic Belts of the Ministry of Education, Department of Geology, Peking University, beijing 100871, china key laboratory of Continental Dynamics of the Ministry of Education Department of Geology Northwestern University Xi’an China The Geological lab Center China University of Geosciences (Beijing)Beijing China key laboratory of Orogenic Belts of the Ministry of Education Department of Geology Peking University Beijing China

The Songshugou dunite body, which occupies an area of about 20 km2, is the largest ultramafic massif in the eastern Qinling orogenic belt, Central china. The major compo-nent of this body is dunitic rocks including mylonitic dunite and coarse-grained dunite; they oc-cupy about 95 vol% of the total body. Petrography, mineral composition, major and trace ele-ments and primitive melt inclusions have been investigated in this paper; all revealed that this dunite body is the product of melt-rock interaction by porous percolation flow. In comparison with dunite sills or veins in harzburgite from the basal part of Oman ophiolite, this dunite body is characterized by lower contents of Al2O3. CaO and HREE but higher content of highly incom-patible elements and Zr and Hf. The LREE enriched patterns and primitive mantle normalized spidergrams of trace elements are also different from the Oman dunite. Combining with melt in-clusions observed in olivines, we conclude that this dunite body is the product of large- scale porous percolation flow of high-MgO melts within depleted mantle peridotites. The high-MgO magma, in essence, was most probably produced at the hot head of an upwelling mantle plume. The occurrence of the Songshugou dunite body is closely associated with the activity of mantle super-plume in Neo-Proterozoic era in the Yangtze Craton.

关键词： Songshugou dunite body, geochemistry, melt inclusion, mantle plume, Qinling orogenic belt.

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Propagation characteristics of converted refracted wave and its application in static correction of converted wave

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Science china Earth Sciences 2008年第S2期51卷 226-232页

作者： LIU Yang1,2 & WEI XiuCheng3.1 State key laboratory of Petroleum Resource and Prospecting,china University of Petroleum,{3. 102249,china 2 cnpc Geophysical Exploration key laboratory,china University of Petroleum,{3. 102249,china 3.Exploration and Production Research Institute,SINOPEC,beijing 100083.china State key laboratory of Petroleum Resource and Prospecting China University of Petroleum Beijing China cnpc Geophysical Exploration key laboratory China University of Petroleum Beijing China Exploration and Production Research Institute SINOPEC Beijing China

Three-component seismic exploration through P-wave source and three-component geophone is an effective technique used in complicated reservoir exploration. In three-component seismic exploration data processing,one of the difficulties is static correction of converted wave. This paper analyzes propagation characteristics of non-converted and converted refracted waves,and discovers a favor-able condition for the formation of converted refracted wave,i.e. the velocity of overlaying medium S wave is much lower than that of underlying medium S wave. In addition,the paper proposes the static correction method of converted wave based on PPS converted refracted wave,and processes the real three-component seismic data with better results of static correction of converted wave.

关键词： PPS converted refracted wave converted wave static correction

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Progress and review of the studies on the end-Triassic mass extinction event

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Science china Earth Sciences 2005年第12期48卷 2049-2060页

作者： DENG Shenghui1,2, LU Yuanzheng1,2,3.& XU Daoyi4 1. Research Institute of Petroleum Exploration and Development, beijing 100083, china 2. {3. laboratory of Oil and Gas Reservoir of Petrochina, beijing 100083, china 3. china University of Geosciences, beijing 100083, china 4. Institute of Geology, china Earthquake Administration, beijing 100029, china Research Institute of Petroleum Exploration and Development Beijing China key laboratory of Oil and Gas Reservoir of Petrochina Beijing China china University of Geosciences Beijing China Institute of Geology China Earthquake Administration Beijing China

The mass extinction at the end-Triassic is one of the five biggest in the Phanerozoic. However,it is the least well understood among these five events, and only till last decade it became a great academic interesting subject to geologists. The evidences for this event come obviously from bivalves, brachiopods, ammonites, corals, radiolaria, ostracods and foraminifera of marine habitats, and plants and tetrapods of terrestrial realm. By contrast, for some of other groups, such as marine gastropods and marine vertebrates, no mass extinction has been recog-nized yet. The extinction event is strongly marked at specific level but shown a complicated situa-tion at generic and family levels. Dramatic changing of the environment, such as the temperature raise due to the greenhouse effect, the marine anoxic habitats caused by a sudden transgression after the regression at the end of Triassic, has been claimed to be the main cause of the extinction. Many hypotheses have been suggested to demonstrate the mechanisms of the environment changing, among which two popular ones are the bolide impact and volcanic eruption. The Triassic-Jurassic (Tr-J) boundary mass extinction event is still poorly understood because no enough data have been obtained from the Tr-J boundary successional sections of both marine and terrestrial sediments, and most of these studies were regionally restricted. The basic aspects of the event and its associated environmental conditions remain poorly characterized and the causal mechanism or mechanisms are equivocal. Some authors even doubt its occurrence. china has many successionally developed terrestrial and marine Tr-J sections. Detailed studies of these sections may be important and significant for well understanding of the event.

关键词： progress, review, end-Triassic, mass extinction, mechanism, Tr-J boundary.

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Study on attribute characterization for reservoir dynamic monitoring by seismic

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Science china Earth Sciences 2008年第S2期51卷 218-225页

作者： CHEN XiaoHong1,3.LI JingYe2,3.& ZHAO Wei4 1 key lab of Geophysical Exploration of cnpc,{3. Petroleum University,beijing 102249,{3. 2 Basin & Reservoir Research Center,{3. Petroleum University,beijing 102249,{3. 3.State key laboratory of Petroleum Resource and Prospecting,{3. University of Petroleum,beijing 102249,{3. 4 Research Center of CNOOC,beijing 100027,{3. key lab of Geophysical Exploration of cnpc China Petroleum University Beijing China State key laboratory of Petroleum Resource and Prospecting China University of Petroleum Beijing China Basin & Reservoir Research Center China Petroleum University Beijing China Research Center of CNOOC Beijing China

Study on characterizing reservoir parameters dynamic variations by time-lapse seismic attributes is the theoretical basis for effectively distinguishing reservoir parameters variations and conducting time-lapse seismic interpretation,and it is also a key step for time-lapse seismic application in real oil fields. Based on the rock physical model of unconsolidated sandstone,the different effects of oil saturation and effective pressure variations on seismic P-wave and S-wave velocities are calculated and analyzed. Using numerical simulation on decoupled wave equations,the responses of seismic amplitude with different offsets to reservoir oil saturation variations are analyzed,pre-stack time-lapse seismic attributes differences for oil saturation and effective pressure variations of P-P wave and P-S converted wave are calculated,and time-lapse seismic AVO (Amplitude Versus Offset) response rules of P-P wave and P-S converted wave to effective pressure and oil saturation variations are compared. The theoretical modeling study shows that it is feasible to distinguish different reservoir parameters dynamic variations by pre-stack time-lapse seismic information,including pre-stack time-lapse seismic attributes and AVO information,which has great potential in improving time-lapse seismic interpreta-tion precision. It also shows that the time-lapse seismic response mechanism study on objective oil fields is especially important in establishing effective time-lapse seismic data process and interpreta-tion scheme.

关键词： time-lapse seismic dynamic monitoring rock physical model pre-stack attribute Amplitude Versus Offset (AVO)

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Indian Ocean-MORB-type isotopic signature of Yushigou ophiolite in North Qilian Mountains and its implications

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Science china Earth Sciences 2006年第6期49卷 561-572页

作者： HOU Qingye1,2, ZHAO Zhidan1,2, ZHANG Hongfei3. ZHANG Benren3.& CHEN Yuelong2 1. State key laboratory of Geological Processes and Mineral Resources, china University of Geosciences, {3. 100083, china 2. School of Earth Science and Mineral Resources, china University of Geosciences, {3. 100083, china 3. Faculty of Earth Sciences, china University of Geosciences, Wuhan 43.074, china State key laboratory of Geological Processes and Mineral Resources China University of Geosciences Beijing China School of Earth Science and Mineral Resources China University of Geosciences Beijing China Faculty of Earth Sciences China University of Geosciences Wuhan China

In order to explore the disputed issue concerning the tectonic affinity ofthe ancient ocean mantle of North Qilian Mountains (NQM), geochemical and Sr, Nd, Pb isotopiccompositions of pillow basalts of the Yushigou Ophiolite (YSGO) suite from NQM have been analyzedsystematically. The pillow basalts exhibit tholeiitic characteristics, with flatchondrite-normalized REE patterns ((La/Yb)_N = 0.98—1.27). They display no Nb, Ta, Zr, Hf negativeanomalies, and show MORB features in 2Nb-Zr/4-Y and Ti/100-Zr-YX3.tectonic discrimination *** results indicate that the Yushigou ophiolite is most likely to be formed in a mid-ocean ridgeor mature back-arc basin. Their isotopic data show a relatively broad and enriched ^(87)Sr/^(86)Sr(0.70509 — 0.70700), restricted ^(143.Nd/^(144)Nd (0.512955-0.512978). Pb isotopes are in the rangeof ^(206)Pb/^(204)Pb (18.054-20.562), ^(207)Pb/^(204)Pb (15.53.-15.743. and ^(208)Pb/^(204)Pb(3..068-3..53.). These isotopic data imply that the basalts originated from the depleted mantle(DMM), with the involvement of enriched mantle components (mainly EMII). Geochemical comparisonsbetween the basalts in YSGO and the MORB-type basalts of ophiolite suites occurring in the knownancient Tethyan tectonic domain indicate that the ancient oceanic mantle represented by YSGO suiteforming in early Paleozoic in the North Qilian Moutains is very similar to the Tethyan mantle inboth trace elements and isotopic compositions. The North Qilian Mountains should be a part of theTethyan tectonic domain in early Paleozoic. This further implies that the Tethyan tectonic domaincan be deduced to early Paleozoic in the study area, which will be helpful to discussing thetectonic affinity and evolution of the North Qilian Mountains.

关键词： geochemistry, Indian Ocean-MORB-type isotopic signatures, Tethyan tectonic domain, Yushigou ophiolite, North Qilian Mountains.

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The equilibrium between diagenetic calcites and dolomites and its impact on reservoir quality in the sandstone reservoir of Kela 2 gas field

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Progress in Natural Science:Materials International 2007年第9期17卷 1051-1058页

作者： Gao Zhiqian1,Yu Bingsong2,3.and Lai Xingyun2,3.1.School of Energy Resources,china University of Geosciences,beijing 100083.china 2.State key {3.oratory of Geological Processes and Mineral Resources,china University of Geosciences,beijing 100083.china 3.Ministry of Education key {3.oratory of Lithosphere Structure,Deep Processes and Exploration Technique,china University of Geosciences,beijing 100083.china) School of Energy Resources China University of Geosciences Beijing 100083 China State key laboratory of Geological Processes and Mineral Resources China University of Geosciences Beijing 100083 China Ministry of Education key laboratory of Lithosphere Structure Deep Processes and Exploration Technique China University of Geosciences Beijing 100083 China

Based on the equilibrium theory of chemical reactions between water and rocks,this paper establishes a thermodynamic phase relationship diagram among calcites,dolomites and water solution under the condition of diagenesis based on the thermodynamic database of related minerals and fluids and dolomite's degree of order *** has been discovered that the equilibrium between calcites and dolomites in the diagenetic environment is strongly impacted by temperature and the Ca/Mg ratios in groundwater,and that the dolomite's degree of order in the diagenetic environment is a function of crystallization temperature and time,not controlled by water ***,the authors make a further analysis of the close relationship of chemical reaction between carbonate cements and pore water in the sandstone reservoirs of Kala 2 gas field in Kuche *** can be seen that there are different impacts on sandstone reservoir quality among the equilibrium system of calcites,dolomites and pore water at different depths of reservoirs.

关键词： diagenesis equilibrium between calcites and dolomites secondary pores Kela 2 gas field

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Application of backflush and micro-flow techniques to the analysis of C5—C13.hydrocarbons in crude oils and its geochemical significance

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Progress in Natural Science:Materials International 2007年第11期17卷 1382-1387页

作者： Wang Peirong1,2, Zhao Hong2,3. Xu Guanjun1,4, Zhu Cuishan2,3. Xiao Tingrong4, Zhang Min2,3.and Zhang Bin1,4(1. key laboratory of Petroleum geochemistry, {3. National Petroleum Corporation, beijing 100083, {3. 2. geochemistry Department of Yangtze University, Jingzhou 43.023. {3. 3. key laboratory of Exploration Technologies for Oil and Gas Resources, Ministry of Education, Yangtze University, Jingzhou 43.023. {3. 4. Petroleum Geology Central laboratory, Research Institute of Petroleum Exploration and Development, Petro{3., beijing 100083, {3.) key laboratory of Petroleum geochemistry China National Petroleum Corporation Beijing 100083 China geochemistry Department Yangtze University Jingzhou 434023 China key laboratory of Exploration Technologies for Oil and Gas Resources Yangtze University Jingzhou 434023 China Petroleum Geology Central laboratory Research Institute of Petroleum Exploration and Development PetroChina Beijing 100083 China

An Agilent 6890N GC equipped with both FID and Agilent 5975 MSD analyzer has been employed to analyze C5—C13.hydrocarbon fractions of crude oils. A technical combination of program temperature volatilizer injection, backflush and micro-flow controller afforded a fine separation of C5—C13.compounds on a PONA column with the heavy part of crude oils being cut off before entering the analytical column. Both GC-FID chromatogram and GC-MS mass chromatograms (MID and full scan) could be obtained at the same time. The retension time differences of nC6—nC13.alkanes between GC and TIC were in the range of 0.02—0.58 minutes. Totally 286 peaks have been assigned group compositions. Results on 8 typical oil samples from cnpc key laboratory Crude Oil Library showed that the characteristics of C6—C13.hydrocarbon group composition could be used in oil-oil correlation studies.

关键词： GC analysis GC/MS analysis backflush micro-flow controller light fraction in crude oil

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Study on NDVI-T_s space by combining LAI and evapotranspiration

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Science china Earth Sciences 2006年第7期49卷 747-754页

作者： HAN Lijuan1,2,3. WANG Pengxin4, YANG Hua1,2,3. LIU Shaomin1,2,3.& WANG Jindi1,2,3.1. Research Center for Remote Sensing and GIS, School of Geography, beijing Normal University, beijing 100875, china 2. State {3. laboratory of Remote Sensing Science, beijing 100875, china 3. beijing {3. laboratory for Remote Sensing of Environment and Digital Cities, beijing 100875, china 4. Department of Information Management, College of Information and Electronic Engineering, china Agricultural University, beijing 100083, china Research Center for Remote Sensing and GIS School of Geography Beijing Normal University Beijing China State key laboratory of Remote Sensing Science Beijing China beijing key laboratory for Remote Sensing of Environment and Digital Cities Beijing China Department of Information Management College of Information and Electronic Engineering China Agricultural University Beijing China

This paper focuses on interpreting the different spatial relationships between NDVI and Ts, a triangular or a trapezoid, and on analyzing transformation conditions, the physical and ecological meanings of the vegetation index-surface temperature space as well. Further, we use the Tempera-ture-Vegetation Dryness Index (TVDI) to explain the existent meaning of a triangular space after NDVI reaches its saturated state by employing the relationships between NDVI, LAI and evapotranspiration. The specific relations between NDVI and Ts are useful for describing, validating and updating land surface models.

关键词： NDVI, land surface temperature, evapotranspiration, leave area index.

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Characteristics and origins of primary fluids and noble gases in mantle-derived minerals from the Yishu area,Shandong Province,china

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Science china Earth Sciences 2006年第1期49卷 77-87页

作者： MA Jinlong1,2, TAO Mingxin2,3.& YE Xianren2 1. Resources and Environmental School, Lanzhou University, Lanzhou 73.000, china 2. key laboratory of Gas {3., Institute of Geology and Geophysics, Chinese Academy of Sciences, Lanzhou 73.000, china 3. College of Resources Science & Technology, beijing Normal University, beijing 100875, china Resources and Environmental School Lanzhou University Lanzhou China key laboratory of Gas geochemistry Institute of Geology and Geophysics Chinese Academy of Sciences Lanzhou China College of Resources Science & Technology Beijing Normal University Beijing China

Fluids and noble gases of mantle-derived materials are important tracers forthe mantle information. Compositions of primary fluids and noble gases in mantle-derived mineralsfrom the Yishu area, Shandong Province, china, were tested by the methods of heat-bursting andheat-melting respectively. The fluids are mainly composed of CO_2, CO and H_2, which account forabout 90% of the total, and are similar to the mantle-derived rocks from other areas of easternchina; ratios of ~3.e/~4He in almost all samples range from 0.82 Ra to 2.74 Ra, whereas^(40)Ar/^(3.)Ar from 299.5 to 758.8. Both ranges are much lower than those of the typical oceanmantle-derived samples (such as MORB) and primarily reflect the influences of the atmosphericcomponents and the radiogenic isotopes. Ratios of C/~3.e range from 27.6 x 10~9 to 1050 x 10~9,N_2/Ar from 927 to 56612, and N_2/~3.e from 2.5 x 10~9 to 27 x 10~9, similar to those in westernUnited States and New Zealand which belong to the tectonic plate collision regions. The ratios fallin the intersect of mantle-crust-atmosphere in the comprehensive tracer-charts, reflecting theinfluences of the atmosphere and the crusts with organic components. Our results suggest that thecomposition of the primary fluids and the isotopic ratios of the noble gases may either reflect theevolution process of mantle-derived rocks connected with the rise and eruption of magma, or theinfluence of the ancient subduction-plate on the continental mantle of this region.

关键词： noble gases, primary fluids, mantle-derived minerals, Yishu area.

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