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Some key technics of drop tower experiment device of National Microgravity Laboratory (China) (NMLC)

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Science China(Technological sciences) 2005年第3期48卷 305-316页

作者： ZHANG Xiaoqian 1 , YUAN Longgen 1 , WU Wendong 1 , TIAN Lanqiao 2.& YAO Kangzhuang 2.1. institute of Engineering Thermophysics, chinese academy of sciences,{2., China 2. institute of Mechanics, chinese academy of sciences,{2., China 1. institute of Engineering Thermophysics Chinese Academy of Sciences 100080 Beijing China 2. institute of Mechanics Chinese Academy of Sciences 100080 Beijing China

Drop tower is an important ground based facility for microgravity science experiment. The technical performances of the drop tower NMLC are advanced compared with similar facilities in the US, Germany and Japan. The main components such as drop capsule, deceleration devices, release mechanism present its advantages and creativities.

关键词： drop tower facility,drop capsule,deceleration devices,release mechanism.

Algebraically explicit analytical solu-tions for the unsteady non-Newtonian swirling flow in an annular pipe

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Science China(Physics,Mechanics & Astronomy) 2006年第4期49卷 396-400页

作者： CAI Ruixian1 & GOU Chenhua1,2.1. institute of Engineering Thermophysics, chinese academy of sciences,{2., China 2. Graduate School, chinese academy of sciences,{2., China 1. institute of Engineering Thermophysics Chinese Academy of Sciences Beijing 100080 China 2. Graduate School Chinese Academy of Sciences Beijing 100080 China

This paper presents two algebraically explicit analytical solutions for the incompressible unsteady rotational flow of Oldroyd-B type in an annular pipe. The first solution is derived with the common method of separation of variables. The second one is deduced with the method of separation of variables with addition developed in recent years. The first analytical solution is of clear physical meaning and both of them are fairly simple and valuable for the newly developing computational fluid dynamics. They can be used as the benchmark solutions to verify the applicability of the existing numerical computational methods and to inspire new differencing schemes, grid generation ways, etc. Moreover, a steady solution for the generalized second grade rheologic fluid flow is also presented. The correctness of these solutions can be easily proven by substituting them into the original governing equation.

关键词： analytical solution, Oldroyd-B type fluid, swirling flow, non-Newtonian.

Interfacial behaviors of PMMA-PEO block copolymers at the air/water interface

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Science China chemistry 2005年第6期48卷 567-573页

作者： CHENG Caixia1, JIAO Tifeng2. TANG Rupei1, LIU Minghua2.& XI Fu1 1. State Key Laboratory of Polymer Physics and chemistry, Joint Laboratory of Polymer Science and Materials, institute of chemistry, chinese academy of sciences, beijing 100080, China 2. CAS Key Laboratory of Colloid and Interface Science, institute of chemistry, chinese academy of sciences, beijing 100080, China 1. State Key Laboratory of Polymer Physics and chemistry Joint Laboratory of Polymer Science and Materials Institute of Chemistry Chinese Academy of Sciences 100080 Beijing China 2. CAS Key Laboratory of Colloid and Interface Science Institute of Chemistry Chinese Academy of Sciences 100080 Beijing China

Diblock copolymer of PMMA2.1-b-PEO114 and triblock copolymer of PMMA12.-b- PEO2.7-b-PMMA12. were synthesized and their interfacial properties at the air-water interface were investigated, where both blocks of polyethylene oxide (PEO) and poly(methyl methacrylate) (PMMA) are surface active but the former is soluble in water while the latter is not. Both the block copolymers could form monolayers with two obvious transition regions. The first transition point is around 10 mN/m, which could be assigned to the pancake-brush change of the PEO chains. The other is around 18 mN/m, which could be ascribed to the condensed packing of PMMA. The surface morphological changes during the compression of the Langmuir monolayers are inves-tigated by using the AFM and SEM methods for the films deposited at different surface pressure or molecular areas. At a lower surface pressure, a typical morphology of PEO-con- taining lipopolymers is observed. Upon compression, sphere-dominant morphologies were observed. While the diblock copolymer is easy to folding, the triblock copolymer is in favor of formation of circular domains through vesiculation.

关键词： PMMA-PEO, block copolymers, monolayer, Langmuir-Blodgett films, AFM.

Explicit analytical solutions of the anisotropic Brinkman model for the natural convection in porous media(Ⅱ)

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Science China(Physics,Mechanics & Astronomy) 2005年第4期48卷 422-430页

作者： CAI Ruixian1, GOU Chenhua1, 2.& ZHANG Na1 1. institute of Engineering Thermophysics, chinese academy of sciences,{2., China 2. Graduate School, chinese academy of sciences,{2., China 1. institute of Engineering Thermophysics Chinese Academy of Sciences 100080 Beijing China 2. Graduate School Chinese Academy of Sciences 10080 Beijing China

Some algebraically explicit analytical solutions are derived for the anisotropic Brinkman model―an improved Darcy model―describing the natural convection in porous media. Besides their important theoretical meaning (for example, in analyzing the non-Darcy and anisotropic effects on the convection), such analytical solutions can be the benchmark solutions that can promote the development of computational heat and mass transfer. Some solutions considering the anisotropic effect of permeability have been given previously by the authors, and this paper gives solutions including the anisotropic effect of thermal conductivity and the effect of heat sources.

关键词： explicit analytical solution, porous medium, natural convection, Brinkman model, anisotropic.

Study on the atmospheric photochemical reaction of CF_3 radicals using ultraviolet photoelectron and photoionization mass spectrometer

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Science China chemistry 2008年第4期51卷 316-321页

作者： YAO Li1,2. DU Lin1,2. YIN Shi1,2.& GE MaoFa1 1 beijing National Laboratory for Molecular sciences (BNLMS), State Key Laboratory for Structural {2. of Unstable and Stable Species, institute of {2., chinese academy of sciences, beijing 100080, China 2.Graduate University of chinese academy of sciences, beijing 100080, China 1. beijing National Laboratory for Molecular sciences (BNLMS) State Key Laboratory for Structural Chemistry of Unstable and Stable Species Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China 2. Graduate University of chinese academy of sciences Beijing 100080 China

A study of the atmospheric photochemical reaction of CF3 radical with CO and O2.was performed by using a homemade ultraviolet photoelectron spectrometer-photoionization mass spectrometer (PES- PIMS). The electronic structures and mechanism of ionization and dissociation of CF3OC(O)OOC(O)- OCF3 were investigated. It was indicated that the two bands on the photoelectron spectrum of CF3OC(O)OOC(O)OCF3 are the result of ionization of an electron from a lone pair of oxygen and a fluo- rine lone pair of CF3 group. The outermost electrons reside in the oxygen lone pair. The experimental and theoretical first vertical ionization energy is 13.2. and 13.178 eV, respectively, with the PES and OVGF method. They are in good agreement. The photo ionization and dissociation processes were discussed with the help of theoretical calculations and PES-PIMS experiment. After ionization, the parent ions prefer the dissociation of the C-O bond and giving the fragments CF3OCO+ and CF3+. It demonstrated that the ultraviolet photoelectron and photoionization mass spectrometer could be ap- plied widely in the study of atmospheric photochemical reaction.

关键词： photochemical reaction CF3 radical ultraviolet photoelectron and photoionization mass spectroscopy transient species

PREPARATION AND PROPERTIES OF ETHYL-CYANOETHYL CELLULOSE/POLYACRYLIC ACID COMPOSITE FILMS WITH REFLECTION COLORS

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chinese Journal of Polymer Science 2001年第3期19卷 277-282页

作者： Yong Huang institute of chemistry,{2., beijing 100080 China Laboratory of Cellulose and Lignocellulosics chemistry Guangzhou institute of chemistry{2., Guangzhou 510650, China 中科院化学所北京

Ethyl-cyanoethyl cellulose [(E-CE)C]/acrylic acid (AA) becomes a cholesteric liquid crystalline solution withvivid colors when the (E-CE)C concentration is 42.wt%～52.wt%. (E-CE)C/polyacrylic acid (PAA) composites withcholesteric structure were prepared by polymerzing AA in (E-CE)C/AA liquid crystalline solutions. The layers of orderedpolymer chains in the cholesteric phase were inclined during polymerization and the degree of the inclination depended onthe polymerization temperature and the concentration of the solution before polymerization. The cholesteric structure in thecomposites could not be changed when temperature was lower than 100℃. Cross-linking of the PAA in compositesimproved their water-resistance. The cholesteric order of the composites without cross-linking was destroyed when theywhere immersed in water. The color derived from the selective reflection of the cholesteric phase of the cross-linkedcomposites turned from blue to red after the composites absorbed water. The color of the composites could be returned to theoriginal one when the absorbed water was removed from the swollen composites.

关键词： Cholesteric structure Composites Selective reflection Liquid crystalline solutions

Mass Spectrometric Evidence of Heparin Disaccharides for the Catalytic Characterization of A Novel Endolytic Heparinase

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Acta Biochimica et Biophysica Sinica 2004年第12期36卷 840-844页

作者： Yapeng CHAO1,3, Shaoxiang XIONG2. Xiulan CHENG1, and Shijun QIAN1* 1institute of Microbiology, chinese academy of sciences,{2., China 2.enter of Mass Spectrometry, institute of chemistry, chinese academy of sciences,{2., China 3Graduate School of the chinese academy of sciences, beijing 100039, China institute of Microbiology Chinese Academy of SciencesBeijing 100080 China Graduate School of the chinese academy of sciencesbeijing 100039 China Center of Mass Spectrometry Institute of Chemistry Chinese Academy of SciencesBeijing 100080 China

Heparinase from different sources can eliminate heparin or/and heparan sulfate into various low-molecular weight heparins with different characteristics. Porcine intestinal mucosa heparin was de- graded into a series of oligosaccharides by a novel heparinase from the species Sphingobacterium. Disaccha- ride components from the digests were separated and purified by ultrafiltration and HPLC. Five major peaks appeared as three types according to their retention time. The mass spectrometry of peak I mainly gave the non-sulfated disaccharide with the mass of 379 Da. Peak II and III were indicated as two major monosulfated disaccharides with molecular mass of 417 and 459 Da respectively. Moreover, the peak III represented an N- acetyl disaccharide. Both peak IV and V showed the same mass of 496 Da, hinting that they were disulfate- substituted disaccharides. No trisulfate-substituted disaccharides were detected in the mixture of the heparin digest though they were abundant in the heparin structure. The results revealed that the heparinase might specifically cut the sites with low sulfated domain in heparin.

关键词： electrospray ionization-mass spectrometry heparin disaccharides heparinase high perfor- mance liquid chromatography Sphingobacterium sp.

STUDY ON THE SYNTHESIS AND PROPERTIES OF POLY(ESTER-IMIDEETHER)MULTIBLOCK COPOLYMERS

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chinese Journal of Polymer Science 2000年第1期18卷 9-13页

作者： Zu-yao Shan Zhen-yi Li institute of chemistry,{2., beijing 100080, China chinese Acad Sci Inst Chem Beijing 100080 Peoples R China

A new class of poly(ester-imide-ether) multiblock copolymers was synthesized by transes-terification and melt copolymerization of dimethyl terephthalate (DMT) and N-(4-carbomethoxyphenyl)-4-(carbomethoxy)-phthalimide with ethylene glycol (EG) and polytetramethylene glycol (PTMG). The structure of the above copolymers was characterized by H-1-NMR and IR spectroscopy. Some properties of the coplymers were also examined. It was found that their mechanical properties and heat stability, compared with poly(ether-ester) copolymers, were obviously improved.

关键词： N-(4-carbomethoxyphenyl)-4-(carbomethoxy)-phthalimide polyester-polyether copolymer poly-(ester-imidether) multiblock copolymer imide modification

A mixed method for measuring low-frequency acoustic properties of macromolecular materials

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Science China(Physics,Mechanics & Astronomy) 2006年第6期49卷 729-739页

作者： LIU Hongwei1,YAO Lei1,3,ZHAO Hong1,3,ZHANG Jichuan2.3 & XUE Zhaohong2.1. National Key Laboratory of Acoustics,institute of Acoustics,chinese {2. of sciences,beijing 100080,China 2. institute of chemistry,chinese {2. of sciences,beijing 100080,China 3. Graduate University of chinese academy of sciences,beijing 100049,China National Key Laboratory of Acoustics Institute of Acoustics Chinese Academy of Sciences Beijing 100080 China institute of chemistry Chinese Academy of Sciences Beijing 100080 China Graduate University of chinese academy of sciences Beijing 100049 China

A mixed method for measuring low-frequency acoustic properties of macro-molecular materials is presented. The dynamic mechanical parameters of materials are first measured by using Dynamic Mechanical Thermal Apparatus(DMTA) at low frequen-cies,usually less than 100 Hz; then based on the Principles of Time-Temperature Super-position (TTS),these parameters are extended to the frequency range that acousticians are concerned about,usually from hundreds to thousands of hertz; finally the extended dynamic mechanical parameters are transformed into acoustic parameters with the help of acoustic measurement and inverse analysis. To test the feasibility and accuracy,we measure a kind of rubber sample in DMTA and acquire the basic acoustic parameters of the sample by using this method. While applying the basic parameters to calculating characteristics of the sample in acoustic pipe,a reasonable agreement of sound absorp-tion coefficients is obtained between the calculations and measurements in the acoustic pipe.

关键词： low-frequency acoustic properties,dynamic mechanical properties,Principles of Time-Temperature Superposition,acoustic pipe,sound absorption coefficient.