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Mass Spectrometric Evidence of Heparin Disaccharides for the Catalytic Characterization of A Novel Endolytic Heparinase

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Acta Biochimica et Biophysica Sinica 2004年第12期36卷 840-844页

作者： Yapeng CHAO1,3, Shaoxiang XIONG2, Xiulan CHENG1, and Shijun QIAN1* 1institute of Microbiology, chinese academy of sciences, beijing 100080, china 2center of Mass Spectrometry, institute of Chemistry, chinese academy of sciences, beijing 100080, china 3Graduate School of the chinese academy of sciences, beijing 100039, china institute of Microbiology Chinese Academy of SciencesBeijing 100080 China Graduate School of the chinese academy of sciencesbeijing 100039 China center of Mass Spectrometry Institute of Chemistry Chinese Academy of SciencesBeijing 100080 China

Heparinase from different sources can eliminate heparin or/and heparan sulfate into various low-molecular weight heparins with different characteristics. Porcine intestinal mucosa heparin was de- graded into a series of oligosaccharides by a novel heparinase from the species Sphingobacterium. Disaccha- ride components from the digests were separated and purified by ultrafiltration and HPLC. Five major peaks appeared as three types according to their retention time. The mass spectrometry of peak I mainly gave the non-sulfated disaccharide with the mass of 379 Da. Peak II and III were indicated as two major monosulfated disaccharides with molecular mass of 417 and 459 Da respectively. Moreover, the peak III represented an N- acetyl disaccharide. Both peak IV and V showed the same mass of 496 Da, hinting that they were disulfate- substituted disaccharides. No trisulfate-substituted disaccharides were detected in the mixture of the heparin digest though they were abundant in the heparin structure. The results revealed that the heparinase might specifically cut the sites with low sulfated domain in heparin.

关键词： electrospray ionization-mass spectrometry heparin disaccharides heparinase high perfor- mance liquid chromatography Sphingobacterium sp.

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PHASE STRUCTURE AND PROPERTIES OF EPOXY RESIN MODIFIED BY POLYSILOXANE BEARING PENDANT AMINO GROUPS

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chinese Journal of Polymer Science 2000年第2期18卷 133-138页

作者： Bing Zhang Xiang-luan Liu Ying Huang center of Molecular sciences, institute of Chemistry, chinese academy of sciences, beijing 100080, china chinese Acad Sci Inst Chem Ctr Mol Sci Beijing 100080 Peoples R China

Polysiloxane-modified epoxy resins were prepared through the reaction of epoxy resin with polydimethylsiloxanes bearing pendant N-(beta-aminoethyl)-gamma-aminopropyl groups. The morphology and properties of the cured epoxy resins modified by the polysiloxanes were investigated. It was found that the phase structure and properties of the cured epoxy resins depend mainly on the amino group content in the polydimethylsiloxane and the level of the modifier. The change of phase structure in the cured epoxy resin systems was responsible for the dramatic change in their mechanical and surface properties.

关键词： phase structure polysiloxane epoxy resin mechanical property

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Low Spring Constant Regulates P-selectin-PSGL-1 Bond Rupture

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生物物理学报 2009年第S1期25卷 91-92页

作者： Yan Zhang, Ganyun Sun, Shouqin Lü, Ning Li, and Mian Long Key Laboratory of Microgravity(National Microgravity Laboratory) and center for biomechanics and bioengineering, institute of mechanics, chinese academy of sciences, beijing 100190, china

Forced dissociation of selectin-ligand bonds is crucial to such biological processes as leukocyte recruitment, thrombosis formation, as well as tumor metastasis. While

关键词： Selectin-ligand bonds Rupture Spring constant Optical trap

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Teleconnection between the Indian summer monsoon onset and the Meiyu over the Yangtze River Valley

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Science china Earth sciences 2008年第7期51卷 1021-1035页

作者： LIU YunYun1,2,3 & DING YiHui2 1 chinese academy of Meteorological sciences, beijing 100081, china 2 National Climate center, beijing 100081, china 3 Graduate University of chinese academy of sciences, beijing 100049, china 1. chinese academy of Meteorological sciences Beijing 100081 China 2. National Climate center Beijing 100081 China 3. Graduate University of chinese academy of sciences Beijing 100049 China

Based on the Indian and chinese precipitation data and the NCEP-NCAR reanalysis circulation data, the relationship between the Indian summer monsoon (ISM) onset and the Meiyu over the Yangtze River Valley has been discussed by the methods of correlation analysis and composite analysis. The results show that the date of ISM onset over Kerala in the southwestern coast of the Indian Peninsula is about two weeks earlier than the beginning of the Meiyu over the Yangtze River Valley. After the outbreak of ISM, the teleconnection mode sets up from the western coast of India via the Bay of Bengal (BOB) to the Yangtze River Valley and southern Japan. It is different both in time and space from the telecon- nection mode which is from the northwest of India via the Tibetan Plateau to northern china. The for- mer mode is defined as the "south" teleconnection of the Asian summer monsoon, forming in the pe- riod of ISM onset; while the latter mode is called the "north" teleconnection, mainly occurring in the Asian monsoon culminant period. During the process of the "south" teleconnection’s formation, the Asian monsoon circulation has experienced a series of important changes: ISM onset, the northward movement of the south Asia high (SAH), the onset vortex occurrence, the eastward extension of the stronger tropical westerly belt, and the northeastward jump of the western Pacific subtropical high (WPSH), etc. Consequently, since ISM sets up over Kerala, the whole Asian continent is covered by the upper SAH after about two weeks, while in the mid- and lower troposphere, a strong wind belt forms from the Arabian Sea via the southern India, BOB and the South china Sea (SCS), then along the western flank of WPSH, to the Yangtze River Valley and southern Japan. With the northward moving of the subtropical jet streams, the upper westerly jet stream and the low level jet have been coupled ver- tically over east Asia, while the Yangtze River Valley happens to locate in the ascending motion

关键词： Indian summer monsoon (ISM) the Meiyu over the Yangtze River Valley teleconnection mode

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Mineralization episode of porphyry copper deposits in the Jinshajiang-Red River mineralization belt: Re-Os dating

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Science china Earth sciences 2005年第2期48卷 192-198页

作者： WANG Denghong, QU Wenjun, LI Zhiwei, YIN Hanlong4 & CHEN Yuchuan institute of Mineral Resources, chinese academy of Geological sciences, beijing 100037, china National center of Rock and Mineral Analysis, chinese academy of Geological sciences, beijing 100037, china Resource Assessment center of Yunnan, Kunming 650011, china institute of Geology and Geophysics, chinese academy of sciences, beijing 100101, china chinese academy of Geological sciences, beijing 100037, china 1. institute of Mineral Resources Chinese Academy of Geological Sciences 100037 Beijing China 2. National center of Rock and Mineral Analysis Chinese Academy of Geological Sciences 100037 Beijing China 3. Resource Assessment center of Yunnan 650011 Kunming China 4. institute of Geology and Geophysics Chinese Academy of Sciences 100101 Beijing China 5. chinese academy of Geological sciences 100037 Beijing China

Re-Os isotopic dating for the molybdenites from the porphyry copper deposits of the Jinshajiang-Red River mineralization belt in Yunnan Province yields isochron ages of 33.9±1.1 Ma for the Machangqing deposit and 34.4±0.5 Ma for the Tongchang deposit. This result shows that both the Machangqing and the Tongchang porphyry Cu-Mo deposits from two different ore-fields formed simultaneously. This new data and the published Re-Os model ages of molybdenite (35.4 Ma, 35.9 Ma, 36.2 Ma) of the Yulong porphyry copper deposit in Tibet, which is located in the same Jinshajiang-Red River mineralization belt as the Machangqing deposit and the Tongchang deposit, suggest that these three Cenozoic porphyry copper deposits in the Jinshajiang-Red River mineralization belt were contemporary for their mineralization episode. That is to say, even their present locality is far away and nearly iso-distantly distributed, these three porphyry Cu(Mo) deposits belong to the same mineralization episode at the end of Eocene.

关键词： Re-Os isotopic dating, porphyry Cu deposits, Cenozoic, mineralization episode.

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Effect of external and internal phosphate status on arsenic toxicity and accumulation in rice seedlings

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Journal of Environmental sciences 2009年第3期21卷 346-351页

作者： WANG Lihong,DUAN Guilan Research center for Eco-Environmental sciences,chinese academy of sciences,beijing 100085,china [a]Research center for Eco-Environmental sciences Chinese Academy of Sciences Beijing 100085 China

Phosphorus （P） deficiency is thought to exacerbate the arsenic （As） phytotoxicity in paddy rice. The experiments were conducted to investigate the effects of external phosphate supply on As accumulation in rice and its toxicity under phosphate deficiency conditions. Rice seedlings pretreated with a phosphorus deficient nutrient solution （-P） for 14 d accumulated more As than those pretreated with a normal phosphorus supply nutrient solution （＋P）. Rice protreated with -P showed As toxicity symptoms after being exposed to 50 μmol/L arsenate for 4 h, while ＋P rice did not show any toxicity symptoms. Arsenic toxicity symptoms can be alleviated by increasing external P concentrations. The arsenate uptake rate and accumulation corresponded with the As toxicity in rice plants. Arsenic concentrations in rice roots decreased with increasing external phosphate concentrations. The lowest As accumulation and the highest P accumulation were found when the external P concentration reached 100μmol/L. In short, P deficiency increased the sensitivity of rice to arsenate and increasing of external phosphate supply could alleviate As toxicity.

关键词： phosphorus arsenate arsenic toxicity arsenic accumulation rice seedlings

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SILICA-SUPPORTED NICKEL AND ZIRCONIUM CATALYSTS FOR BRANCHED POLYETHYLENE

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chinese Journal of Polymer Science 2003年第4期21卷 453-458页

作者：孙文华 State Key Laboratory of Engineering Plastics The center for Molecular sciences institute of Chemistry chinese academy of sciences beijing 100080 china chinese Acad Sci Inst Chem Ctr Mol Sci State Key Lab Engn Plast Beijing 100080 Peoples R China

8-Aminoquinoline nickel dichloride and bis(cyclopentadienyl)zirconium dichloride (Cp_2ZrCl_2) were supportedsimultaneously on silica to produce branched polyethylene successfully by combined polymerization. The supportedpolymerization results showed that the molecular weight of polyethylene increased while the molecular weight distributionbecame wider and the molecular chains of oligomers remaning in the final solution became shorter as compared to theoligomers obtained in polymerization processes with pure 8-aminoquinoline nickel dichloride catalysis, as well as theCp_2ZrCl_2 and nickel combination system. With decreasing amount of Ni catalyst in the supported catalyst, the molecular chains of oligomers in the resulting solution became shorter, while α-olefin selectivity increased.

关键词： 8-Aminoquinoline nickel dichloride, Cp_2ZrCl_2 Silica supported catalysts Branched polyethylene

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Influence of processing temperature on microstructure and microhardness of copper subjected to high-pressure torsion

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Science china(Technological sciences) 2010年第6期53卷 1534-1539页

作者： XIE ZiLing1,2,XIE JiJia2,HONG YouShi2 & WU XiaoLei2 1 College of Architecture and Civil Engineering,University of Wenzhou,Wenzhou 325035,china 2 State Key Laboratory of Nonlinear mechanics,institute of mechanics,chinese academy of sciences,beijing 100190,china 1. College of Architecture and Civil Engineering University of Wenzhou Wenzhou 325035 China2. State Key Laboratory of Nonlinear Mechanics Institute of Mechanics Chinese Academy of Sciences Beijing 100190 China

Cu samples were subjected to high-pressure torsion (HPT) with up to 6 turns at room temperature (RT) and liquid nitrogen temperature (LNT),*** effects of temperature on grain refinement and microhardness variation were *** the samples after HPT processing at RT,the grain size reduced from 43 μm to 265 nm,and the Vickers microhardness increased from HV52 to ***,for the samples after HPT processing at LNT,the value of microhardness reached its maximum of HV150 near the center of the sample and it decreased to HV80 at the periphery *** observations revealed that HPT straining at LNT induced lamellar structures with thickness less than 100 nm appearing near the central region of the sample,but further deformation induced an inhomogeneous distribution of grain sizes,with submicrometer-sized grains embedded inside micrometer-sized *** submicrometer-sized grains with high dislocation density indicated their nonequilibrium *** the contrary,the micrometer-sized grains were nearly free of dislocation,without obvious deformation trace remaining in *** images demonstrated that the appearance of micrometer-sized grains is the result of abnormal grain growth of the deformed fine grains.

关键词： copper high pressure torsion (HPT) microstructure grain size microhardness cryogenic temperature

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Astronomical function and date of the Taosi observatory

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Science china(Physics,mechanics & Astronomy) 2009年第1期52卷 151-158页

作者： WU JiaBi1, CHEN MeiDong2 & LIU CiYuan3 1 National Astronomical Observatories, chinese academy of sciences, beijing 100012, china 2 institute for the History of Natural Science, chinese academy of sciences, beijing 100010, china 3 National Time Service center, chinese academy of sciences, Xi’an 710600, china 1. National Astronomical Observatories Chinese Academy of Sciences Beijing 100012 China 2. institute for the History of Natural Science Chinese Academy of Sciences Beijing 100010 China 3. National Time Service center Chinese Academy of Sciences Xi’an 710600 China

The Taosi site in Xiangfen County,Shanxi Province,may be the capital of the King Yao. Archeologists recently discovered a large semi-circular stamped-earth platform, II FJT1,which has a clear and definite pounded-earth central core together with a curved wall perforated by twelve gaps. The platform is said to be an ancient observatory used to determine the seasons by watching the sunrise. Each feature of II FJT1 was precisely measured and the data are reproduced in this paper. An astronomical analysis of slots E2 and E12 was carried out using the azimuths of the slots' centerlines and the vertical angle of the mountain ridge opposite, above which the sun rises. The results show that at present the sun is close to the two slots but does not exactly enter them at summer and winter solstice sunrise. Using 14C analysis archeologists dated the site to about 2100 BC. Because of the secular change in the obliquity of the ecliptic,at that date on the summer solstice the half-risen sun would have appeared inside slot E12 just to the right of the centerline,and on the winter solstice the sun would have been exactly on the centerline of slot E2. This result provides compelling proof that II FJT1 is an ancient observatory.

关键词： astro-archeology astro-chronology Taosi culture ancient observatory time service

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Differentiation transforming system

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Progress in Natural Science:Materials International 2009年第3期19卷 397-406页

作者： Qiang Chenga,b,c,*, Haibin Zhang d, Bin Wanga, Yonghua Zhao c a LASG, institute of Atmospheric Physics, chinese academy of sciences, beijing 100029, PR china b LSEC, institute of Computing Mathematics, chinese academy of sciences, beijing 100080, PR china c SC, institute of Computer Network Information center, chinese academy of sciences, beijing 100190, PR china d College of Applied sciences, beijing University of Technology, beijing 100124, PR china [a]LASG Institute of Atmospheric Physics Chinese Academy of Sciences Beijing 100029 PR China [b]LSEC Institute of Computing Mathematics Chinese Academy of Sciences Beijing 100080 PR China [c]SC Institute of Computer Network Information Center Chinese Academy of Sciences Beijing 100190 PR China [d]College of Applied Sciences Beijing University of Technology Beijing 100124 PR China

The differentiation transforming (DFT) system is developed to produce the tangent linear codes, which is used to calculate the Jaco- bian- and the Hessian-vector products with no truncation errors. This paper first gives the introduction of the functionality and features of the DFT system, and then discusses several techniques for the implementation of automatic differentiation tools, including data depen- dence analysis, singular differentiation and code optimization. Finally, the codes generated with DFT used in several applications have been demonstrated.

关键词： Jacobian Hessian Tangent linear model Automatic differentiation

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