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Paleomagnetic dating of the Cenjiawan Paleolithic site in the Nihewan Basin, northern china

Science china earth {2. 2006年第3期49卷 295-303页

作者： WANG Hongqiang1,2. DENG Chenglong1, ZHU Rixiang1 & XIE Fei3 1. Paleomagnetism and Geochronology Laboratory (SKL-LE), Institute of Geology and Geophysics, Chinese Academy of Sci- ences, Beijing 10002., china 2. school of the {2. sciences and resources, china university of geosciences, Beijing 100083, china 3. Hebei Province Institute of Cultural Relics, Shijiazhuang 050000, china 1. Paleomagnetism and Geochronology Laboratory (SKL-LE) Institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China 2. school of the earth {2. and resources China University of Geosciences Beijing 100083 China 3. Hebei Province Institute of Cultural Relics Shijiazhuang 050000 China

Rock magnetic and magnetostratigraphic investigations on a lacustrine sequence in the Nihewan Basin, northern china, which bears the Cenjiawan Paleolithic site, indicate that the dominant magnetic mineral and remanence carrier contained in the sediments is magnetite. While hematite co-exists with magnetite in some portions of the Cenjiawan sequence, where characteristic remanent magnetizations are carried by both magnetite and hematite. Measurements of anisotropy of magnetic susceptibility confirm that the Cenjiawan sequence has preserved the original sedimentary features and is suitable for magnetostratigraphic study. Paleomagnetic results indicate that the Cenjiawan Paleolithic site is formed just posterior to the Punaruu normal event, which is dated at about 1.1 Ma. Combined with the paleomagnetic results of the Donggutuo, Xiaochangliang and Majuangou sections, it is concluded that early humans were occupying the Nihewan Basin around 1.6, 1.3 and 1.1 Ma. This integrated result is significant to understanding the ability of migration and adaptation to the envi- ronment of early humans.

关键词： Nihewan Basin, Early Pleistocene, Cenjiawan, Paleolithic site, paleomagnetism.

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Chronological record of the Early Mesozoic underplating in the northern margin of North china—U-Pb chronometry of zircons in the Late Mesozoic andesite from Western Liaoning

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Progress in Natural Science:Materials International 2007年第8期17卷 943-947页

作者： Shao ji'an~(1,2.*) Zhang Hongfu~2.Liu Xiaoming~3 Li Zhitong~4 (1.school of earth and Space {2.,Peking university,Beijing 100871,china 2.Institute of Geology and Geophysics and Key Laboratory of mineral resources,Chinese Academy of {2.,Beijing 10002.,china 3.Key Laboratory of Continental Dynamics,Northwestern university,Xi'an 710069,china 4.Institute of Geology and mineral resources of Shenyang,Shenyang 110032.china) [a]school of earth and Space {2. Peking University Beijing China [b]Laboratory of mineral resources Chinese Academy of Sciences Institute of Geology and Continental Dynamics Beijing China [c]Key Laboratory of Continental Dynamics Northwestern university Xi'an China [d]Institute of Geology and mineral resources of Shenyang Shenyang China

Cathodoluminescence spectroscopic analysis of zircons in the uppermost sanukites of the early Cretaceous Yixian Forma- tion in Western Liaoning reveals zoning structures of the zircons in the volcanic rocks. LA-ICP-MS chronometry shows that the central part of the zircons is remnant zircon with a U-Pb dating of 2.4 Ma,which is consistent with the age of the Early Mesozoic underplating granulites,and that the periphery is zircon crystallizing out of the host magma with a U-Pb dating of 116 Ma,which is highly consistent with the Ar-Ar dating of the host volcanic *** of the clinopyroxenes xenocrystals in the sanukites are similar to those of the clinopyroxenes in the underplating granulites,indicating that the granulites accreted to the lower crust in the Early Mesozoic have been reformed and disrupted by the upwelling diapers of the asthenosphere and taken part in formation of the sanukites in the Late Mesozoic.

关键词： northern margin of North china Mesozoic volcanic rock U-Pb chronometry of zircon underplating granulite

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Analytical method of Cr stable isotope and its application to water pollution survey

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Chinese Science Bulletin 2010年第7期55卷 664-669页

作者： GAO YongJuan 1,2,3,MA Teng 4,5,LING WenLi 1,2,LIU CunFu 4,5 & LI Li 4,5 1Faculty of earth Science,china {2. of geosciences,Wuhan 430074,china 2State Key Laboratory of Geological Processes and mineral resources,china {2. of geosciences,Wuhan 430074,china 3 Graduate school,china {2. of geosciences,Wuhan 430074,china 4 Biogeological and Environmental Geology Laboratory of Ministry of Education(china {2. of geosciences) ,Wuhan 430074,china 5 Sino-Hungary Joint Laboratory of Environmental {2.} and Health,china {2. of geosciences,Wuhan 430074,china Faculty of earth Science China University of Geosciences Wuhan 430074 China State Key Laboratory of Geological Processes and mineral resources China University of Geosciences Wuhan 430074 China Graduate school China University of Geosciences Wuhan 430074 China Biogeological and Environmental Geology Laboratory of Ministry of Education (china university of {2.) Wuhan 430074 China Sino-Hungary Joint Laboratory of Environmental sciences and Health China University of Geosciences Wuhan 430074 China

High Cr(VI) concentration is a potential serious risk to environment and ecologic ***,it is essential to effectively monitor Cr contamination in water systems and scientifically evaluate its evolution trend.A new method of in-situ tracer technique by Cr isotopic analysis for quantitatively estimating Cr-contamination and its regional evolution in natural waters as well as a case application are reported in this *** on documented literatures,an experimental procedure for chemical separation and purification of Cr in water samples and its analytical method for Cr isotopic measurement by thermal ionization mass spectrometry(TIMS) are *** samples collected around a chemical factory in Hubei Province were analyzed by this *** samples showδ53Cr values ranging from-1.7‰to 7.3‰and an elevating trend with an increasing in distance from the sampling site to pollution source.A functional correlation following Rayleigh fractionation law was established between sample'sδ53Cr value and its extent of Cr *** study suggests that Cr isotopic analysis is an effective method to reveal the spatial distribution and its evolution trend of Cr contamination in the regional water *** is thus helpful to assessing the self-purifying ability of local water system according to Cr isotopic fractionation.

关键词：铬(VI) 水污染调查稳定同位素应用同位素分析供水系统演变趋势示踪技术

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Isotopic compositions of small shelly fossil Anabarites from Lower Cambrian in Yangtze Platform of South china: Implications for palaeocean temperature

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Progress in Natural Science:Materials International 2007年第10期17卷 1185-1191页

作者： Chen Yongquan1,2. Jiang Shaoyong1, Ling Hongfei1, Yang Jinghong1 and Wan Defan3(1. State Key Laboatory for mineral Deposits Research and Center for Marine Geochemistry Research, Department of earth {2., Nanjing university, Nanjing 2.0093, china 2. Tarim Oilfield Company Exploration & Development Research Institute, Ku’erle 841000, china 3. Institute of mineral resources, Chinese Academy of Geological {2., Beijing 100037, china) State Key Laboatory for mineral Deposits Research and Center for Marine Geochemistry Research Department of Earth Sciences Nanjing University Nanjing 210093 China arim Oilfield Company Exploration & Development Research Institute Ku’erle 841000 China Institute of mineral resources Chinese Academy of Geological Sciences Beijing 100037 China

Anabarites belong to small shelly fossils (SSF), which occur widely in the Lower Cambrian strata of Yangtze Platform in South china. They are phosphate shell in composition and represent the earliest stage of the Cambrian bioradiation of Bilateria, the so-called "Cambrian Explosion". In this study, we attempted to separate Anabarites fossils from Lower Cambrian dolostones, and we obtained samples of both the fossils (SSF) and the granular phosphates (GP). Isotopic analyses were performed on samples of SSF, GP, and matrix dolostone (DH-2.). The results showed that the δ30Si values of the quartz filling in fossils celoms, and the siliceous materials in granular phosphates are -0.6‰ and -0.7‰, which is different from normal sedimentary siliceous rocks from the Lower Cambrian strata (0—0.7‰) as reported by Li et al., but is consistent with the data for siliceous rocks and cherts of submarine hydrothermal origin. It is likely that a later hydrothermal replacement could have taken place in the SSF-bearing sedimentary rocks. The oxygen isotope values of the phosphate of SSF and GP are 16.8‰ and 17.0‰, respectively. These are significantly higher than the Neoproterozoic phosphate ores (10.9‰—13.9‰) as reported by Ling et al., hence, late diagenesis and hydrothermal replacement may not have caused a significant change in the oxygen isotope compositions of the small shelly fossils, and the calculated temperatures (2..4—2..3℃) for palaeo-seawater using a SSF phosphate oxygen isotope thermometer are therefore considered here as the upper limit of seawater temperature in the Early Cambrian ocean of the Yangtze Platform.

关键词： Anabarites oxygen isotope silicon isotope paleo-temperature.

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Low temperature albitization in Caino-Mesozoic reservoir sandstones from North Tarim, and a discussion on the fluid origin

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Chinese Science Bulletin 1999年第S2期44卷 35-37页

作者： YE Ying~1, HU Shouxi~2.and SUN Jinggui~2.1. Department of earth sciences, Zhejiang {2., Hangzhou 31002., china 2. Department of earth sciences, Nanjing {2., Nanjing 2.0008, china Department of earth sciences Zhejiang University Hangzhou 310027 China Department of earth sciences Nanjing University Nanjing 210008 China

CAJNOZOIC and Mesozoic in North Tarim are predominantly a set of terrestrial detrital formations. In thereservoir sandstones in the area, albite is one of the widely developed authigenic mineral. Micro-structural evidence shows that diagenetic albite occurs as euhedral crystals in the pore, and replaces feldsparand other detritus along cleavage and micro-crack. EPMA analyzing found that some of the alteration product has a chemical composition between purealbite and the replaced detrital feldspar. For example, composition of replaced alkali feldspar is betweenmicrocline and albite, and content of altered plagioclase decreases continuously. This has been regardedas direct evidence for fluid replacement, for feldspar crystallized from solution or magma is usually withfixed chemical composition. Taking alkali feldspar as an example, although Kf and Ab forming completeisomorphous admixture in high temperature, they exsolved out as two relative pure phases while temperature decreases.

关键词： low temperature albitization sandstones fluid origin North Tarim.

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Laser Ablation ICP-MS Titanite U-Th-Pb Dating of the Tonglushan Cu-Fe-Au Skarn Deposit,Southeastern Hubei Province

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矿物学报 2009年第S1期29卷 314-316页

作者： LI Jian-wei 1,2.DENG Xiao-dong1,2.ZHOU Mei-fu3,LIU Yong-sheng1(1. State Key Laboratory of Geological Processes and mineral resources,{2. university of geosciences,Wuhan 430074,{2. 2. Faculty of earth resources,{2. university of geosciences,Wuhan 430074,{2. 3. Department of earth sciences,the university of Hong Kong,Hong Kong)

Titanite(CaTi2.iO5) is an important accessory mineral not only in magmatic and metamorphic rocks,but also commonly in hydrothermal mineral deposits. It incorporates appreciable amounts(usually 10×10-6 s to 100×10-6 s) of U and Th into its structure and has a closure temperature of Pb diffusion higher than 660～700 ℃(Scott and St-Onge,1995) ,making it an ideal U-Th-Pb geochronometer. The Daye metallogenic district is located in the west of the giant Middle-Lower Yangtze River(MLYR) Cu-Fe-Au province,eastern{2. and is well endowed with Fe,Cu,and polymetallic skarn deposits.

关键词： Pb Laser Ablation ICP-MS Titanite U-Th-Pb Dating of the Tonglushan Cu-Fe-Au Skarn Deposit,Southeastern Hubei Province Th Fe ICP Cu MS

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The history of crustal uplift and metamorphic evolution of Panzhihua-Xichang micro-palaeoland, SW china:Constraints on Sm-Nd, ^(40)Ar/^(39)Ar and FT ages of granulites

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Science china earth {2. 2004年第8期47卷 689-703页

作者： XU Shijin1, LIU Wenzhong1, WANG Rucheng1, YU Hangbo1, LI Daming2. WAN Jinglin2.& FANG Zhong1 1. Department of earth sciences and State Key Laboratory for {2. Deposits Research, Nanjing university, Nanjing 2.0093, china 2. Institute of Geology, china Seismological Bureau, Beijing 10002., china 1. Department of earth sciences and State Key Laboratory for {2. Deposits Research Nanjing University 210093 Nanjing China 2. Institute of Geology China Seismological Bureau 100029 Beijing China

Panzhihua-Xichang (Panxi) micro-palaeoland is the oldest terrane on the western margin of the Yangtze Block. Some intermediate-basic granulites are considered to be the crys-talline basement of lower crust in the terrane. Granulite-facies metamorphism of the granulites was developed in the period from 1186 Ma to 112. Ma. The origin of granulites was related to the collision orogenic process occurring when the micro-palaeolands merged to form the Rodinia Supercontinent. Amphibolite-facies retrogressive metamorphism of granulites took place in the period from 877 Ma to 82. Ma. This period was consistent with the breakup time of the Rodinia Supercontinent. 40Ar/39Ar ages and fission track (FT) ages of granulites in the Panxi mi-cro-palaeoland show that the vertical movement history of crustal rocks was a slow uplift process of the rigid terrane in the time from Neoproterozoic to Mesozoic. The subduction of India Plate towards Euroasia Plate resulted in the rapid uplift of the Qinghai-Tibetan Block in Cenozoic. Meanwhile, the Qinghai-Tibetan Block moved towards east. Consequently the Panxi terrane was uplifted rapidly. As a result of the collision orogeny between the Qinghai-Tibetan Block and the Panxi terrane, the granulite-facies crystalline basement in this region was exhumed and exposed to the surface.

关键词： granulite,isotope geochronology,crustal uplift movement,Panzhihua-Xichang region,western margin of Yangtze Block.

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Geochemical simulation of the formation of brine and salt minerals based on Pitzer model in Caka Salt Lake

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Science china earth {2. 2004年第8期47卷 720-726页

作者： LIU Xingqi1, CAI Keqin2.& YU Shengsong3 1. Nanjing Institute of Geography and Limnology, Chinese Academy of sciences, Nanjing 2.0008, china 2.{2., Beijing 100083, china 3. Institute of Salt Lakes, Chinese Academy of sciences, Xining 810008, china 1. Nanjing Institute of Geography and Limnology Chinese Academy of Sciences 210008 Nanjing China 2. china university of geosciences 100083 Beijing China 3. Institute of Salt Lakes Chinese Academy of Sciences 810008 Xining China

The geochemical simulation of the formation of brine and salt minerals based on Pitzer model was made in Caka Salt Lake. The evolution of the mixed surface-water and the mineral sequences were calculated and compared with the hydrochemical compositions of the brine and the salt minerals of the deposit in Caka Salt Lake. The results show that the formation temperature of the lake is between 0°C and 5°C, which is well identical with other studies. The mixing of salt-karst water with the surface waters, neglected by the former researchers, is very important to the formation of the lake, indicating that the initial waters resulting in the formation of the lake are multi-source. It is the first time to use Pitzer model in china for making geochemical simulation of the formation and evolution of inland salt lake and satisfactory results have been achieved.

关键词： Pitzer model,Caka Salt Lake,geochemical simulation,salt-karst water.

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Electron microscopy study of the sakhaite from endogenous borate deposit in Hunan, china

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Science china earth {2. 2004年第3期47卷 232-238页

作者： LIU Xiangwen1,2. YANG Guangming2. ZOU Huamin3, QU Jing1 & ZHAO Wenxia4 1. Graduate school, china university of geosciences, Wuhan 430074,{2. 2. Test Center, china university of geosciences, Wuhan 430074,{2. 3. Physics and Technology College, Wuhan university, Wuhan 430072.{2. 4. Test Center, Zhongshan university, Guangzhou 5102.5,{2. china Univ Geosci Grad Sch Wuhan 430074 Peoples R China china Univ Geosci Test Ctr Wuhan 430074 Peoples R China Wuhan Univ Phys & Technol Coll Wuhan 430072 Peoples R China Zhongshan Univ Test Ctr Guangzhou 510275 Peoples R China

Sakhaite specimens from an endogenous borate deposit in Hunan Province, china have been studied in detail by means of transmission electron microscopy (TEM). The selected area electron diffraction (SAED) patterns obtained with different crystal zone axes show that the crystal system is cubic, with a = 1.463 nm. The convergent beam electron diffraction (CBED) patterns indicate that the point group and space group of sakhaite is m3m and Fd3m, respec-tively. The space group of synthetic sakhaite determined by Chichagov (1974) is F4132. The possible reasons why the space groups of the natural and the synthetic sakhaites are different are discussed.

关键词： sakhaite, space group, convergent beam electron diffraction (CBED).

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Application of rock creep experiment in calculating the viscoelastic parameters of earth medium

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Science china earth {2. 2006年第5期49卷 492-498页

作者： SHI Xingjue1, WEN Dan1, BAO Xueyang1, LI Chengbo1 & HUANG Yun2.1. school of earth and Space {2., university of Science and Technology of china, Hefei 2.002., china 2. Seismological Bureau of Jiangsu Province, Nanjing 2.0014, china 1. school of earth and Space {2. University of Science and Technology of China Hefei 230026 China 2. Seismological Bureau of Jiangsu Province Nanjing 210014 China

Based on the rock creep experiment, the data of aftershock sequence and post-earth- quake deformation are used to estimate the viscosity of crust medium near earthquake focus. Firstly 9 samples that belong to 3 kinds of rock are conducted in creep experiment under constant pressure to obtain the creep curves directly. Inversion results show that the standard linear model is the best one to present the earth medium. It exhibits obvious elasticity within a short time, while it exhibits obvious rheology within a long time. The relationship between element module μ 2.and the whole module μ of standard linear model or the module of real earth medium is calculated and analyzed. On the basis of μ 2.= 2. μ, the sequence of aftershock of Gonghe earthquake in Qinghai Province is analyzed and the relationship between accumulated released strain and the time is obtained, which, combined with the creep experiment results, is used to estimate the viscosity of crustal medium in this area. The measured vertical deformation after the same earthquake also is combined with the creep experiment results, then it is used to calculate the relaxation time and viscosity through three different methods respectively, i.e. inversion of Kelvin model, difference method of deformation and viscoelastic dislo- cation theory. The viscosity of crustal medium in 32.km depth of earthquake focus of Gonghe area deduced from the different data and methods is about 1019 Pa·s, which is the same as the research results by other authors at home and abroad.

关键词： creep experiment, aftershock sequence, post-earthquake deformation, crustal viscosity.

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