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Role of gallium wetting layer in high-quality ZnO growth on sapphire (0001) substrates

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Science china(Physics,Mechanics & Astronomy) 2004年第5期47卷 612-620页

作者： ZENG Zhaoquan1,3, WANG Yong2. DU Xiaolong1, MEI Zengxia1, KONG Xianghe3, JIA Jinfeng1, XUE Qikun1 & ZHANG Ze2. 4 1. State Key laboratory for Surface Physics, Institute of Physics, chinese academy of sciences,{2., china 2. laboratory of electron microscopy, Institute of Physics, chinese academy of sciences,{2., china 3. College of Physics and Engineering, Qufu Normal University, Qufu 2.3165, china 4. beijing University of Technology, beijing 10002., china 1. State Key laboratory for Surface Physics Institute of Physics Chinese Academy of Sciences 100080 Beijing China 2. College of Physics and Engineering Qufu Normal University 273165 Qufu China 3. laboratory of electron {2. Institute of Physics Chinese Academy of Sciences 100080 Beijing China 4. beijing University of Technology 100022 Beijing China

A Ga wetting layer was used to modify the surface structure of sapphire (0001) substrate to prepare high-quality ZnO film by radio frequency plasma-assisted molecule beam epitaxy. We found that this Ga layer plays a crucial role in eliminating 30 rotation domains, controlling polarity and decreasing defect density in ZnO epilayers, as demonstrated by in situ reflection high energy electron diffraction, ex situ high resolution X-ray diffraction and high resolution cross-sectional transmission electron {2.. Zn-polar film of ZnO was determined by convergent beam electron diffraction. A Ga bilayer model is proposed to understand the effects of the Ga wetting layer on high-quality ZnO growth.

关键词： Ga wetting layer, sapphire, polarity, defect density, zinc oxide, rf-MBE, RHEED, HRXRD, TEM, CBED.

Investigation of a New Exsolved Cu-Fe-S Phase in“Abnormal Sphalerite”

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Acta Geologica Sinica(English Edition) 1991年第1期65卷 27-36,110-111页

作者： Li Jiuling Wang Su Institute of Mineral Deposits, chinese academy of Geolgical {2.,beijing beijing laboratory of electron microscopy, chinese academy of sciences, beijing Institute of Mineral Deposits Chinese Academy of Geolgical Sciences Beijing China

A new exsolved copper-iron-sulfur phase in sphalerite has been found in the Dajing cassiterite- sulfidecopper-silver-tin deposit, Inner Mongolia, china. After investigating the optical properties, chemical composi-tion, crystal structure and exsolved Characters of the exsolved phase, the authors present important evidencefor its being a new exsolved copper-iron-sulfur phase mineral. Its formation mechenism is discussed in consider-ing heating experiments, phase equilibrium data and the geology of the deposit.

关键词： Ph Fe Abnormal Sphalerite Cu

Study on the atmospheric photochemical reaction of CF_3 radicals using ultraviolet photoelectron and photoionization mass spectrometer

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Science china Chemistry 2008年第4期51卷 316-321页

作者： YAO Li1,2. DU Lin1,2. YIN Shi1,2.& GE MaoFa1 1 beijing National laboratory for Molecular {2. (BNLMS), State Key laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, chinese academy of sciences, beijing 100080, china 2.Graduate University of chinese academy of sciences, beijing 100080, china 1. beijing National laboratory for Molecular {2. (BNLMS) State Key Laboratory for Structural Chemistry of Unstable and Stable Species Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China 2. Graduate University of chinese academy of sciences Beijing 100080 China

A study of the atmospheric photochemical reaction of CF3 radical with CO and O2.was performed by using a homemade ultraviolet photoelectron spectrometer-photoionization mass spectrometer (PES- PIMS). The electronic structures and mechanism of ionization and dissociation of CF3OC(O)OOC(O)- OCF3 were investigated. It was indicated that the two bands on the photoelectron spectrum of CF3OC(O)OOC(O)OCF3 are the result of ionization of an electron from a lone pair of oxygen and a fluo- rine lone pair of CF3 group. The outermost electrons reside in the oxygen lone pair. The experimental and theoretical first vertical ionization energy is 13.2. and 13.178 eV, respectively, with the PES and OVGF method. They are in good agreement. The photo ionization and dissociation processes were discussed with the help of theoretical calculations and PES-PIMS experiment. After ionization, the parent ions prefer the dissociation of the C-O bond and giving the fragments CF3OCO+ and CF3+. It demonstrated that the ultraviolet photoelectron and photoionization mass spectrometer could be ap- plied widely in the study of atmospheric photochemical reaction.

关键词： photochemical reaction CF3 radical ultraviolet photoelectron and photoionization mass spectroscopy transient species

Wet-chemical synthesis and characteristics of Au nanoshell

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Science china Chemistry 2005年第5期48卷 431-435页

作者： LIU Zhongxin1,2. SONG Hongwei1, YU Lixin1,2. YANG Linmei1,2.& PAN Guohui1,2.1. Key laboratory of Excited State Physics, Changchun Institute of Optics, Fine Mechanics and Physics, chinese academy of sciences, Changchun 130033,{2. 2. Graduate School of the chinese academy of sciences, beijing 100039,{2. 1. Key laboratory of Excited State Physics Changchun Institute of Optics Fine Mechanics and Physics Chinese Academy of Sciences 130033 Changchun China 2. Graduate School of the chinese academy of sciences 100039 Beijing China

Gold nanoshells were prepared by an easy wet-chemical method, with Ag nanoparticles used as the templates. Transmission electron microscopy (TEM) indicated that the shells were sphere in shape, the size was homogenous, being about 2. nm, and no hard ag-glomerates were observed. The plasma resonance absorption of gold was tuned from visible to near-infrared (NIR) with the increased volume of HAuCl4. The temperature grads (?T) of the gold nanoshell hydrosol under the exposure of an 808-nm optical fiber laser with different power den-sities were measured. The highest ?T was 30℃ (5 W/cm2. irradiation area was 2.cm2.. This kind of gold nanoshell hydrosol is a promising material to be used in biomedicine such as photo-thermal cancer therapy, and its special photothermal convert property will photothermally trigger drug release.

关键词： wet-chemical synthesis, Au, nanoshell, NIR absorption, photothermal conversion.

Photogeneration of the free radicals and singlet oxygen by chrysophanol from rheum

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Science china Chemistry 2004年第5期47卷 381-387页

作者： RAO Jing1,2. XIE Jie1, ZHAO Jingquan1 & ZHU Teng2.1. Key laboratory of Photochemistry, Center for Molecular Science, Institute of Chemistry, The chinese academy of sciences,{2., china 2. University of Science and Technology beijing, beijing 10083, china 1. Key laboratory of Photochemistry Center for Molecular Science Institute of Chemistry The Chinese Academy of Sciences 100080 Beijing China 2. University of Science and Technology beijing 10083 Beijing China

In the current work, chryosphanol (MHAQ) was isolated and purified from rheum, and the photosensitization activities were studied. In nitrogen-saturated DMSO solution, irradia- tion of chryosphanol (MHAQ) with visible light (>430 nm) produced the semiquinone radical anions (MHAQ??), which was intensified significantly by an electron donor NADH, suggesting electron transfer between the excited and ground state photosensitizer molecules. In an air-saturated DMSO solution, superoxide radical anions (O2.), trapped by DMPO, were detected. ?? It was proved that O2.was not originated from the singlet oxygen (1O2. but dependent on DMPO, ?? chrysophanol, oxygen and the irradiation time. The singlet oxygen and OH could also be pro- ? duced by the photosensitization of the photosensitizer. These suggest that chrysophanol pos- sesses the photosensitization activity via Type I mechanism and Type II mechanism. To evaluate the photosensitization activities of MHAQ, emodin and mixed anthraquinone derivatives ex- tracted from rheum, the relative productivities of O2.were estimated to be 1.8, 1.1 and 1.0 re- ?? spectively and the quantum yields for singlet oxygen to be 0.36, 0.53 and 0.14 respectively. Therefore, these low-cost pigments may be potentially used as phototherapeutic medicine for some kind of vascular diseases or photo-activated pesticides.

关键词： chrysophanol, ESR, semiquinone radical anions, superoxide radical anions, hydroxyl radical, singlet oxygen.

Experimental study of electron capture excitation in collisions between Li-like N^(4+) ions and Na atoms

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chinese Science Bulletin 1997年第5期42卷 368-371页

作者： LIU Zhanwen, ZHOU Sixin, ZHANG Wen, ZHANG Xuezhen GUOXiaohong, WANG Youde, MA Xinwen, YANGZhihu, LIU Huiping, ZHAO Mengchun, YANG Feng, PAN Guangyan and LI Dawan1. Institute of Modern Physics, chinese academy of sciences, Lanzhou 730000, china 2. Institute of Physics, chinese academy of sciences, beijing 100080, china Institute of Modern Physics Chinese Academy of Sciences Lamhou China Institute of Physia Chinese Academy of Sciences Beijing China

WITH the rapid development of the technique of ionized atoms, the charge states of atoms that can be obtained now are so high that the H-like U91+ ions and naked U92. ions

关键词： single electron capture double electron capture emission cross section excited states.

AFM study on the adsorption and aggregation behavior of dissolved humic substances on mica

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Science china Chemistry 2006年第3期49卷 256-266页

作者： GE Xiaopeng1, ZHOU Yanmei2. Lü Chunhua1 & TANG Hongxiao1 1. State Key laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental sciences,{2., beijing 100085, china 2. School of Civil Engineering & Architecture, beijing Jiaotong University, beijing 100044, china 1. State Key laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Beijing 100085 China 2. School of Civil Engineering & Architecture Beijing Jiaotong University Beijing 100044 China

Humic substances constitute the major organic fractions of soils, sediments and natural waters, and play a dominant role in the binding, mobilization, transport and ultimate fate of organic contaminants in subsurface systems. In this paper, two humic acid samples, Guanting and Tianjin, with different origin and chemical compositions have been investigated with AFM imaging for their adsorption and aggregation behaviors on mica. While the Tianjin humic sample is found to form small spheres with 2.0 to 330 nm in diameter at lower concentrations, irregular loop-chain assemblies of hundreds of nanometer in diameter with the chain width of about 40 nm are dominant for the Guanting humic sample, which may attribute to the more polar aliphatic fractions in the chemical composition in the latter. The heterogeneous and polydisperse nature of humic substances with multiple structural features, such as sponge-like structures, perforated sheets, aggregate of spheres, branches and chain-like assemblies etc., is apparent at higher concentrations for both humic samples, showing morphologically new evidence for the dominant view of the humic dual-mode sorption model. With naphthalene introduced, the assemblies of Guanting humic substances clearly become more compact with significantly narrowed branches and less porous the perforated sheet-like structures. It is indica- tive of that smaller nanometer scale rings present along the perforated assemblies could potentially represent hydrophobic domains, which may facilitate the adsorption and aggregation of naphthalene onto the natural particle surfaces and therefore lead to an important role of dissolved humic sub- stances in the sorption of environmental pollutants.

关键词： atomic force microscopy (AFM) dissolved humic substances morphology aggregation adsorption

Grain evolution of nano-crystals ZnO under HP and HT

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Science china(Physics,Mechanics & Astronomy) 2006年第3期49卷 281-290页

作者： SHAO Guangjie1, QIN Xiujuan1, LIU Riping1, WANG Wenkui1,2.& YAO Yushu2.1. Key laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, china 2. Institute of Physics,{2., beijing 100080, china 1. Key laboratory of Metastable Materials Science and Technology Yanshan University Qinhuangdao 066004 China 2. Institute of Physics Chinese Academy of Sciences Beijing 100080 China

Grain evolution of nano-crystals ZnO under high temperature and pressure is studied using a cubic high pressure apparatus. The structure, grain sizes and morphology of the samples are characterized by X-ray diffraction and field emission scanning electron microscopy. The results show that the grain sizes of ZnO grow rapidly at temperature 2.0℃ under pressure. At temperature lower than 300 ℃ (including 300 ℃), the grain sizes of the samples first increase with the pressure increasing from 1 to 3 GPa and later de- crease from 4 to 6 GPa. The activation volume from 1 to 3 GPa and from 4 to 6 GPa is calculated respectively using the phenomenological kinetic grain growth equation at temperature 300 ℃. At temperature higher than 400℃ (including 400 ℃), the grain sizes of the samples increase with the pressure increasing from 1 to 6 GPa. ZnO nano-bulks with good quality can be obtained under the specific conditions.

关键词： nano-crystals ZnO,high temperature and pressure,grain evolution

Observation results of relativistic electrons detected by Fengyun-1 satellite and analysis of relativistic electron enhancement (REE) events

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Science china(Physics,Mechanics & Astronomy) 2008年第12期51卷 1947-1956页

作者： YANG XiaoChao1,2. & WANG ShiJin1 1 Center for Space Science and Applied Research, chinese academy of sciences, beijing 100190,{2. 2.Graduate University of chinese academy of sciences, beijing 100049,{2. 1. Center for Space Science and Applied Research Chinese Academy of Sciences Beijing 100190 China 2. Graduate University of chinese academy of sciences Beijing 100049 China

The space particle component detector on Fengyun-1 satellite which works at the sun-synchronous orbit of about 870 km altitude has detected relativistic electrons for a long time. In comparison with the SAMPEX satellite observations during 1999–2.04, the relativistic electron data from Fengyun-1 satellite from June 1999 to 2.05 are used to analyze the relativistic electron enhancement (REE) events at the low earth orbit, and the possible correlation among REE events at the low earth orbit, high-speed solar wind and geomagnetic storms is discussed. The statistical result presents that 45 REE events are found in total during this time period, and the strong REE events with the maximum daily average flux > 400 cm?2.srt-1·s?1 occur mostly during the transition period from solar maximum to solar minimum. Among these 45 REE events, four strong REE events last a longer time period from 2.-to 51-day and correlate closely with high speed solar wind and strong geomagnetic storms. Meanwhile, several strong geomagnetic storms occur continuously before these REE events, and these continuous geomagnetic storms would be an important factor causing these long-lasting strong REE events. The correlation analysis for overall 45 events indicates that the strength of the REE events correlates with the solar wind speed and the strength of the geomagnetic storm, and the correlation for strong REE events is much stronger than that for weak REE events.

关键词： relativistic electron enhancement low earth orbit high-speed solar wind geomagnetic storm