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High-temperature phases of pyrophyllite and their evolutionary characteristics

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chinese Science Bulletin 1997年第2期42卷 140-144页

作者： WANG Ling and ZHANG Zhenyu1. Changsha institute of Geotectonics, chinese {2. of Sciences, Changsha 410013, china 2. institute of geology, chinese {2. of Sciences, beijing 10002., china Changsha institute of Ceotectonics Chinese Academy of Sciences Changsha China institute of geology Chinese Academy of Sciences Beijing China

WITH the increase of heating temperature, phase of pyrophyllite will undergo a series of transformations. Former scholars have done some work in this respect; the temperature spans,however, were normally not more than 1150℃ and no relatively comprehensive results have been reported. Thus, the features of the phases from indoor temperature to melting point (1710℃±) for pyrophyllite and the entire evolutionary process of the phases are uncertain.

关键词： pyrophyllite high-temperature phase phase tranformation pyrophyllite anhydrite mullite cristobalite.

The crystal structure of (Fe_(4)Cr_(4)Ni)_(9)C_(4)

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Science china Earth Sciences 2005年第3期48卷 338-345页

作者： SHI Nicheng1, MA Zhesheng1, XIONG Ming1, DAI Mingquan1, BAI Wenji2. FANG Qingsong2. YAN Binggang2.& YANG Jingsui2.1. X-ray Diffraction Laboratory, china University of Geosciences, beijing 100083, china 2. institute of geology, chinese academy of geological Sciences, beijing 100037, china 1. X-ray Diffraction Laboratory China University of Geosciences 100083 Beijing China 2. institute of geology Chinese Academy of Geological Sciences 100037 Beijing China

(Fe4Cr4Ni)9C4 is a metal carbide mineral formed by combination of Fe, Cr and Ni with C. It occurs in a chromite deposit in the Luobusha ophiolite, Tibet. Based on the determina- tion of its crystal structure, the empirical formula is (Fe4.12.r3.84Ni0.96)8.92.3.70 and the simplified formula is (Fe4Cr4Ni)4C9. The mineral is hexagonal with a = 1.38392.2. nm, c = 0.44690(9) nm, space group P63 m c, Z=6 and the calculated specific gravity Dx = 7.089 g/cm3. Fe, Cr and Ni occupy different crystallographic sites and their coordination numbers are approximately 12. forming an alternate stacking sequence of flat and puckered layers along the c axis. Some me- tallic atoms have a defect structure. The interatomic distances of Fe, Cr and Ni are 0.2.2.— 0.2.66 nm, and the distances between Fe, Cr, Ni and C are 0.1893—0.2.69 nm. The coordina- tion number of carbon is 6. It occurs in interstices of the metallic atoms Fe, Cr and Ni to form trigonal-prismatically coordinated polyhedra. These coordination polyhedra are linked with each other via shared corners or shared edges into a new type of metal carbide structure.

关键词： Luobusha of Tibet, metal carbide, crystal structure.

Genetic Mechanism of Mineral Inclusions in Zircons from the Khondalite Series, Southeastern Inner Mongolia

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Acta Geologica Sinica(English Edition) 2003年第1期77卷 28-35页

作者： LIU Fulai and SHEN Qihan institute of geology, {2. academy of geological Sciences, beijing 100037 chinese Acad Geol Sci Inst Geol Beijing 100037 Peoples R China

The early Precambrian khondalite series is widely distributed in theJining-Zhuozi-Fengzhen-Liangcheng area, southeastern Inner Mongolia. The khondalite series mainlyconsists of sillimanite garnet potash feldspar (or two-feldspar) gneiss and garnet biotiteplagioclase gneiss. These gneissic rocks have commonly experienced granulite-facies metamorphism. Inzircons separated from sillimanite garnet potash feldspar gneisses, many mineral inclusions,including Sil, Grt, Ky, Kfs, Qtz and Ap, have been identified by the Laser Raman ***, prograde metamorphic mineral inclusion assemblages such as Ky + Kfs + Qtz + Ap and Ky +Grt + Kfs + Qtz are preserved in the core of zircon, while peak granulite-facies metamorphicminerals including Sil + Grt + Kfs + Qtz and Sil + Gif + Kfs + Qtz + Ap are identified in the mantleand rim of the same zircon. However, in some zircons are only preserved the peak metamorphicminerals such as Sil + Grt + Kfs + Qtz and Sil + Grt + Kfs + Qtz + Ap from core to rim, and inothers are inherited the primary cores with minor mineral inclusions of Kfs + Qtz, with peakmetamorphic mineral inclusions around the inherited cores. These data indicate that the mineralassemblage evolution of sillimanite garnet potash feldspar gneisses in the study are did experiencea polymorphic transformation of kyanite to sillimanite. In garnet biotite plagioclase gneisses,secondary electron microscopic images reveal that most zircons display distinct zoning textures,which comprise cores and rims, each with distinctive inclusion assemblages. The inherited mineralinclusions, mainly consisting of Kfs + Pl + Qtz, Kfs + Qtz and Kfs + Qtz + Ap, are preserved in theprimary cores, while peak granulite-facies mineral asemblages, including Grt + Bt + Pl + Qtz + Ap,Grt + Bt + Pl + Qtz and Grt + Bt + Pl + Qtz + Rt, are identified on the rims. The occurrence of peakmetamorphic mineral inclusions in zircons indicates that these gneissic rocks, includingsillimanite garnet potas

关键词： mineral inclusion zircon Laser Raman secondary electron microscopy genetic mechanism khondalite series Inner Mongolia

Megaclasts from the Carboniferous-Permian Rocks in the Langkawi Islands, Malaysia, and Their Implications

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Acta Geologica Sinica(English Edition) 1999年第1期73卷 120-122页

作者： Chen Tingyu institute of geology 2. Baiwanzhuang Road,{2. academy of geological Sciences, beijing 100037,china institute of geology 26 Baiwanzhuang Road Chinese Academy of Geological Sciences Beijing 100037 China

The Ninth Regional Congress on geology, Mineral andEnergy Resources of Southeast Asia was held in KualaLumpur of Malaysia in August of 1998. After the Con-gress, the author participated in the geological fieldexcursion and investigation in the Langkawi Islands,and noted that the Carboniferous-Permian rocks con-tain megaclasts of metamorphic and pegmatitic rocks,which indicate the existence of pre-Carboniferousmetamorphism and magmatism. The observation resultsare as follows:

关键词： Malaysia and Their Implications Megaclasts from the Carboniferous-Permian Rocks in the Langkawi Islands

Discovery of low grade metamorphic volcanic rock sheets within UHP in Dabie Mts. and its implications

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chinese Science Bulletin 1997年第14期42卷 1199-1203页

作者： DONG Shuwen, WANG Xiaofeng and HUANG Dezhi1. chinese academy of {2. Sciences (CAGS), beijing 100037, china 2. institute of Geomechanics of CAGS, beijing 100081 china 3. Anhui institute of {2. Sciences, Hefei 2.0001 chinese academy of {2. Sciences (CAGS) Beijing 100037 China

THE ultrahigh-pressure metamorphic zone (UHP), outcropping in the central and southernDabie Mts. with an area of about 1000 km^2. may be the largest one in the world. The forma-tion and exhumation mechanism of the UHP rocks become a hot point in the study of continen-tal orogen. The first finding of the Shiqiao structural window, which is composed of low

关键词： ultrahigh-pressure metamorphic zone (UHP) low grade metamorphic rock sheets Dabie Mts.

Re-Os age for molybdenite from the Gangdese porphyry copper belt on Tibetan plateau: Implication for geody- namic setting and duration of the Cu mineralization

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Science china Earth Sciences 2004年第3期47卷 221-231页

作者： HOU Zengqian1, QU Xiaoming1, WANG Shuxian2. DU Andao2. GAO Yongfeng3 & HUANG Wei4 1. institute of Mineral Resources, chinese {2. of geological Sciences, beijing 100037, china 2. National Center of Geoanalysis, chinese {2. of geological Sciences, beijing 100037, china 3. Shijiazhuang College of Economy, Shijiazhuang 056000, china 4. Xizang Bureau of {12. and Mineral Resources, Lhasa 850000, china chinese Acad Geol Sci Inst Mineral Resources Beijing 100037 Peoples R China chinese Acad Geol Sci Natl Ctr Geoanal Beijing 100037 Peoples R China Shijiazhuang Coll Econ Shijiazhuang 056000 Peoples R China Xizang Bur Geol & Mineral Resources Lhasa 850000 Peoples R China

The Gangdese porphyry copper belt consists of one large and five middle-small deposits in addition to dozens of ore-bearing porphyry bodies. The belt trends 350 km long along the EW-striking Gangdese batholith, and locally occurs as a string of beads extending about 50 km within the SN-trending rifting zones (grabens) on the Tibetan plateau. Monzonitic granite- porphyry and quartz monzonitic porphyry, as dominant host rocks, are shoshonitic and potassic calc-alkaline. Available dating data indicate that the ages of the shallow-level emplacement for these porphyries vary from 10 Ma to 18 Ma, which are identical to that of associated potassic calc-alkaline volcanic rocks (10—15 Ma) and mafic dykes (13—18 Ma). The timing and duration of Cu mineralization events are constrained by Re-Os ages for molybdenites from three porphyry copper deposits in the Gangdese porphyry copper belt. Five molybdenite samples from the Nanmu deposit yielded an 187Re-187Os isochron with a highly pre-cise age of (14.76?.2.) Ma; six molybdenites from the Chongjiang deposit gave an isochron age of (14.04?.16) Ma. Re-Os model ages for two molybdenite samples from Lakang抏 deposit vary from 13.5 Ma to 13.6 Ma, which are basically identical to isochron ages mentioned above. All the thirteen samples from these three deposits yielded a linear array in the isochron diagram with a higher correlation coefficient of 0.99719 and an isochron age of (14.39?.2.) Ma (1s error), suggesting an coeval event of the Cu mineralization and a shared source of ore materials for the Gangdese porphyry copper belt. Compared with the longer-lived felsic magmatic-hydrothermal system, the Cu mineralization is a relatively short event with duration of about 0.5 Ma, and usu-ally occurs in the later-stage of the complicate magmatic system. The emplacement age of the Gangdese porphyries indicates that they intruded after the rapid rising of the Gangdese Mountains at 2.—2. Ma, and formed in a post-collision crustal ex-tension env

关键词： porphyry copper deposit, Re-Os age, Gangdese, Tibetan plateau.

Mineralization episode of porphyry copper deposits in the Jinshajiang-Red River mineralization belt: Re-Os dating

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Science china Earth Sciences 2005年第2期48卷 192-198页

作者： WANG Denghong, QU Wenjun, LI Zhiwei, YIN Hanlong4 & CHEN Yuchuan institute of Mineral Resources, chinese {2. of geological Sciences, beijing 100037, china National Center of Rock and Mineral Analysis, chinese {2. of geological Sciences, beijing 100037, china Resource Assessment Center of Yunnan, Kunming 650011, china institute of geology and Geophysics, chinese {2. of Sciences, beijing 100101, china chinese {2. of geological Sciences, beijing 100037, china 1. institute of Mineral Resources Chinese Academy of Geological Sciences 100037 Beijing China 2. National Center of Rock and Mineral Analysis Chinese Academy of Geological Sciences 100037 Beijing China 3. Resource Assessment Center of Yunnan 650011 Kunming China 4. institute of geology and Geophysics Chinese Academy of Sciences 100101 Beijing China 5. chinese academy of {2. Sciences 100037 Beijing China

Re-Os isotopic dating for the molybdenites from the porphyry copper deposits of the Jinshajiang-Red River mineralization belt in Yunnan Province yields isochron ages of 33.9±1.1 Ma for the Machangqing deposit and 34.4±0.5 Ma for the Tongchang deposit. This result shows that both the Machangqing and the Tongchang porphyry Cu-Mo deposits from two different ore-fields formed simultaneously. This new data and the published Re-Os model ages of molybdenite (35.4 Ma, 35.9 Ma, 36.2.Ma) of the Yulong porphyry copper deposit in Tibet, which is located in the same Jinshajiang-Red River mineralization belt as the Machangqing deposit and the Tongchang deposit, suggest that these three Cenozoic porphyry copper deposits in the Jinshajiang-Red River mineralization belt were contemporary for their mineralization episode. That is to say, even their present locality is far away and nearly iso-distantly distributed, these three porphyry Cu(Mo) deposits belong to the same mineralization episode at the end of Eocene.

关键词： Re-Os isotopic dating, porphyry Cu deposits, Cenozoic, mineralization episode.

Magma underplating and Hannuoba present crust-mantle transitional zone composition: Xenolith petrological and geochemical evidence

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Science china Earth Sciences 2005年第8期48卷 1089-1105页

作者： FAN Qicheng1,2. ZHANG Hongfu1, SUI Jianli1, ZHAI Mingguo1, SUN Qian2.& LI Ni2.1. institute of geology and Geophysics, {2. academy of Sciences, beijing 10002., china 2. institute of geology, china Seismological Bureau, beijing 10002., china 1. institute of geology and Geophysics Chinese Academy of Sciences 100029 Beijing China 2. institute of geology China Seismological Bureau 100029 Beijing China

On the basis of mineral assemblage, mineralogy, petrology, and major, trace ele-mental and isotopic geochemistry of the underplated granulite- and eclogite-facies accumulate, peridotite and pyroxenite xenoliths entrained in Hannuoba Cenozoic basalts, this work con-strained the petrological constituents for the crust-mantle transitional zone, which is supported by the results of high-temperature and pressure velocity experiments on rocks and geophysics deep survey. Present lower part of lower crust is mainly composed of granulite-facies mafic accumu-lates (dominantly plagioclase websterite) and crust-mantle transitional zone dominantly com-posed of eclogite-facies pyroxenites with or without garnet and spinel lherzolites; Archaean ter-rain granulite is only nominally early lower crust. Magma underplating in the crust-mantle boundary led to the crustal vertical accretion and the formation of the crust-mantle transitional zone, which is a significant mechanism for the chemical adjustment of the crust-mantle boundary since the Phanerozoic.

关键词： magma underplating, xenolith petrology, geochemistry, cust-mantle boundary constituent, Hannuoba.

Carbon and Oxygen Stable Isotope Values and Microfossils at 41.4-4.5ka BP in Tai Co,Tibet,china,and Their Paleoclimatic Significance

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Acta Geologica Sinica(English Edition) 2011年第5期85卷 1036-1050+1052-1056+1051页

作者： ZHENG Mianping~(1,2,*),LIU Junying~(1,3),MA Zhibang~(1,4),WANG Hailei~(1,2) and MA Nina~(1,2) 1 MLR Key Laboratory of Saline Lake Resources and Environment,institute of Mineral Resources,CAGS, beijing 100037,china 2 Research and Development Center for Saline Lakes and Epithermal Deposits,chinese academy of geological Sciences,beijing 100037,china 3 institute of geology,chinese academy of geological Sciences,beijing 100037,china 4 Key Laboratory of Cenozoic geology and Environment,chinese academy of Sciences,beijing 100029, china MLR Key Laboratory of Saline Lake Resources and Environment Institute of Mineral Resources CAGS Beijing 100037 China Research and Development Center for Saline Lakes and Epithermal Deposits Chinese Academy of Geological Sciences Beijing 100037 China institute of geology Chinese Academy of Geological Sciences Beijing 100037 China Key Laboratory of Cenozoic geology and Environment Chinese Academy of Sciences Beijing 100029 China *Correspondence: Mianping ZHENG *Correspondence: Corresponding author. E-mail: zhengmp2010@***

Two sedimentary sections were measured at Tai Co(Co means lake in Tibetan) in western Tibet,*** two sections are almost all composed of clay carbonate beds except in their lower parts where there are carbonized plants at>10 cm depths and dark-colored carbonate clay and clay at 50-70 cm depths,yielding abundant gastropods,ostracods,and *** carbon and oxygen stable isotope values of carbonate,ostracods,and charophytes and ecological features of microfossil communities indicate the following climatic change in the area from 41.4 to 4.5 ka BP:at 41.4-2..2.ka BP,the climate was relatively wet;at 2..2.2..5 ka BP,it was slightly warm-dry;at 2..5-2..5 ka BP,it was warm-wet;at 2..5-2..0 ka BP,it was slightly cold-wet;at 2..5-17.5 ka BP,it became cold abruptly and slightly wet,implying the climate of the last glacial maximum;at 17.5-16.0 ka BP,it was slightly cold-dry;at 16.0-11.8 ka BP,it was slightly warm-wet;at 11.8-10.4 ka BP,it was relatively cold-dry, roughly equivalent to the climate of the Younger Dryas,and at 10.4 ka BP,the temperatures began to rise again;at 10.4-9.4 ka BP,it was slightly warm-wet;at 9.4-8.5 ka BP,there occurred short warm-wet oscillations;at 8.5-7.9 ka BP,it was slightly dry-cold,representing a strong temperature-lowering and drying event in the postglacial stage;at 7.8-6.3 ka BP,it was slightly warm-wet;at 6.3-4.5 ka BP,the climate tended to be cold-dry.4.5 ka BP recorded the maximum aridity since the late part of the late Pleistocene.

关键词： sedimentary environment index paleoclimatic changes late Pleistocene-Holocene(41.4-4.5 ka BP) Tai Co Tibet