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Transient species and its properties of melatonin

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Science china Chemistry 2006年第4期49卷 308-314页

作者： ZHU Hongping1,2. ZHANG Zhaoxia1,2. ZHAO Hongwei1, WANG Wenfeng1 & YAO Side1 1. Shanghai institute of Applied Physics, chinese academy of sciences, Shanghai 2.1800,{2. 2. Graduate University of the chinese academy of sciences, Beijing 100049,{2. 1. Shanghai institute of Applied Physics Chinese Academy of Sciences Shanghai 201800 China 2. Graduate University of the chinese academy of sciences Beijing 100049 China

The photo-physical and photo-chemical properties of melatonin (ML) werestudied by 2.6 nm laser flash photolysis (LFP). ML undergoes photo-ionization to produce radicalcation of ML (ML^(·+))and hydrated electrons (e_(aq)^-), while excited triplet state ~3ML~* is alsoformed during photolysis. The oxidation via one electron transfer from ML to SO_4^(·+) and thetriplet state of riboflavin (~3RF~*) has been also investigated and the rate constants for theprocess have been determined to be 8.0x10^9 and 1.4x10^9 L·mol^(-1)·s^(-1) respectively. Theradical cation of 2.2.'-azinobis(3-ethylbenzothiazoline-6-sulfonic acid)(ABTS^(·+)) scavengingcapacities of melatonin and other antioxidants are compared in this paper.

关键词： melatonin, laser flash photolysis, photoionization, triplet state.

Artificial coordinating field and its application to motion planning of robots in uncertain dynamic environments

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Science china(Technological sciences) 2004年第5期47卷 577-594页

作者： JING Xingjian1, 2. WANG Yuechao1 & TAN Dalong1 1. Robotics Laboratory, Shenyang institute of Automation, chinese academy of sciences, Shenyang 110016,{2. 2. Graduate School, chinese academy of sciences, Beijing 100039,{2. Correspondence should be addressed to Jing Xingjian 1. Robotics Laboratory Shenyang Institute of Automation Chinese Academy of Sciences 10016 Shenyang China 2. Graduate School Chinese Academy of Sciences 10039 Beijing China

Artificial coordinating fields (ACF) are proposed to deal with the motion planning problems of mobile robots in uncertain dynamic environments. An ACF around an obstacle can generate two orthogonal force vectors to a robot: one is called the coordinating force vector which is purposively designed in this paper, and the other is the repulsive force vector which is the same as that in a conventional artificial potential field. The ACF is designed according to the updated motion purpose and the relative states of the robot with respect to its local environment, and it also satisfies the robot’s dynamic constraints. The direction of the coordinating force can be determiend on line according to an optimal evaluation function. The ACF can effectively remove the local minima, and reduce the oscillation of the planned trajectory between multiple obstacles. Only local knowledge of the environments is needed in the ACF-based motion planning. The properties of the ACF such as controllability, adaptability, safety and reachability are studied and discussed in detail in this paper. Theoretical analysis and simulations are given to illustrate our main results.

关键词： artificial coordinating fields, artificial potential fields, mobile robots, motion planning, uncertain dynamic environments.

SHRIMP zircon U-Pb geochronology of early Mesozoic felsic igneous rocks from the southern Lancangjiang and its tectonic implications

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Science china Earth sciences 2006年第10期49卷 1032-1042页

作者： PENG Touping1,2. WANG Yuejun1, FAN Weiming1, LIU Dunyi3, SHI Yuruo3 & MIAO Laicheng4 1. Key Laboratory of Isotope Geochronology and Geochemistry, Guangzhou institute of Geochemistry, chinese academy of sciences, Guangzhou 510640,{2. 2. Graduate University of chinese academy of sciences, Beijing 100039,{2. 3. SHRIMP isotope Laboratory, chinese academy of Geological sciences, Beijing 100037,{2. 4. institute of Geology and Geophysics, chinese academy of sciences, Beijing 10002.,{2. Key Laboratory of Isotope Geochronology and Geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China Graduate University of chinese academy of sciences Beijing China SHRIMP isotope Laboratory Chinese Academy of Geological Sciences Beijing China institute of Geology and Geophysics Chinese Academy of Sciences Beijing China

The SHRIMP zircon U-Pb geochronology of three typical samples, including two monzo nitic granites from the Lincang batholith and a rhyolite from the Manghuai Formation are presented in the southern Lancangjiang, western Yunnan Province. The analyses of zircons for the biotite monzonitic granites from the northern (02.X-137) and southern (2.JH-10) Lincang batholith show the single and tight clusters on the concordia, and yield the weighted mean 2.6Pb/2.8U ages of 2.9.4 ± 3.0 Ma and 2.0.4 ± 3.6 Ma, respectively, representing the crystallized ages of these granites. The zircons for the rhyolitic sample (02.X-95) from the Manghuai Formation give a weighted mean 2.6Pb/2.8U age of 2.1.0 ± 5.0 Ma. These data suggest that the igneous rocks from the Lincang granitic batholith and Manghuai Formation have a similar crystallized age. In combination with other data, it is inferred that both were generated at a narrow age span (~2.0 Ma) and were originated from the postcollisional tectonic regime. An early Proterozoic 2.6Pb/2.8U apparent age of 1977±44 Ma is additionally obtained from one zircon from the biotite monzonitic granite (southern Lincang batholith), indicative of devel- opment of the early Proterozoic Yangtze basement in the region. These precisely geochronological data provide important constraints on better understanding the Paleozoic tectonic evolution of the Tethys, western Yunnan Province.

关键词： SHRIMP zircon U-Pb dating, Middle Triassic, Lincang granitic batholith, Manghuai Formation rhyolite, southern Lancangjiang.

Large-scale boron nanowire nanojunctions and their highly-oriented arrays

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Science china(Physics,Mechanics & Astronomy) 2004年第5期47卷 621-632页

作者： CAO Limin1,2. ZHANG Ze2.& WANG Wenkui1,2.1. Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, china 2. institute of Physics,{2., Beijing 100080, china 1. Key Laboratory of Metastable Materials Science and Technology Yanshan University 066004 Qinhuangdao China 2. institute of Physics Chinese Academy of Sciences 100080 Beijing China

Highly oriented multiple boron nanowire nanojunctions with unilateral feather- like morphology were first successfully prepared using a radio-frequency magnetron sputtering method. The branched boron nano-feathers always nucleate and grow on the same sidewall of the stems, and align in parallel to form multiple T- and/or Y-type nanojunctions. The diameters of the branches and the stems are in the range of 2.—40 and 60—80 nm, respectively. The thinner branches and thicker stems of the boron nanowires self-assembled into large-scale, highly ordered arrays on various substrates. During the formation and self-assembly of the arrays, no template or catalyst was needed. We believe that the approach presented here can be used to fabricate heterostructures with bottom-up assembly of a wide variety of one-dimensional nanostructures via the rational design of targets and the proper control of the experimental conditions.

关键词： boron nanowires, nanojunctions, self-assembly, magnetron sputtering.

Interfacial behaviors of PMMA-PEO block copolymers at the air/water interface

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Science china Chemistry 2005年第6期48卷 567-573页

作者： CHENG Caixia1, JIAO Tifeng2. TANG Rupei1, LIU Minghua2.& XI Fu1 1. State Key Laboratory of Polymer Physics and Chemistry, Joint Laboratory of Polymer Science and Materials, institute of Chemistry, chinese academy of sciences, Beijing 100080,{2. 2. CAS Key Laboratory of Colloid and Interface Science, institute of Chemistry, chinese academy of sciences, Beijing 100080,{2. 1. State Key Laboratory of Polymer Physics and Chemistry Joint Laboratory of Polymer Science and Materials Institute of Chemistry Chinese Academy of Sciences 100080 Beijing China 2. CAS Key Laboratory of Colloid and Interface Science Institute of Chemistry Chinese Academy of Sciences 100080 Beijing China

Diblock copolymer of PMMA2.1-b-PEO114 and triblock copolymer of PMMA12.-b- PEO2.7-b-PMMA12. were synthesized and their interfacial properties at the air-water interface were investigated, where both blocks of polyethylene oxide (PEO) and poly(methyl methacrylate) (PMMA) are surface active but the former is soluble in water while the latter is not. Both the block copolymers could form monolayers with two obvious transition regions. The first transition point is around 10 mN/m, which could be assigned to the pancake-brush change of the PEO chains. The other is around 18 mN/m, which could be ascribed to the condensed packing of PMMA. The surface morphological changes during the compression of the Langmuir monolayers are inves-tigated by using the AFM and SEM methods for the films deposited at different surface pressure or molecular areas. At a lower surface pressure, a typical morphology of PEO-con- taining lipopolymers is observed. Upon compression, sphere-dominant morphologies were observed. While the diblock copolymer is easy to folding, the triblock copolymer is in favor of formation of circular domains through vesiculation.

关键词： PMMA-PEO, block copolymers, monolayer, Langmuir-Blodgett films, AFM.

Plus cupping degrees do not form an ideal

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Science in china(Series F) 2004年第5期47卷 635-654页

作者： LI Angsheng1,2.& ZHAO Yicheng1 1. institute of Software,chinese {2. of sciences,Beijing 100080,china 2. School of Information sciences,Beijing Normal University,Beijing 100871,china 1. institute of Software Chinese Academy of Sciences 100080 Beijing China 2. School of Information sciences Beijing Normal University 100871 Beijing China

A computably enumerable (c.e.,for short)degree a is called plus cupping,if every c.e. degree x with 0 详细信息

A computably enumerable (c.e.,for short)degree a is called plus cupping,if every c.e. degree x with 0

关键词： computably enumerable set Turing degree definability.

Estimation of annual actual evapotranspiration from nonsaturated land surfaces with conventional meteorological data

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Science china Earth sciences 2004年第3期47卷 239-246页

作者： QIU Xinfa1, ZENG Yan2. MIAO Qilong1 & YU Qiang2.1. Department of Geography, Nanjing institute of Meteorology, Nanjing 2.0044, china 2. institute of Geographic sciences and Natural Resources Research, chinese academy of sciences, Beijing 100101, china Nanjing Inst Meteorol Dept Geog Nanjing 210044 Peoples R China chinese Acad Sci Inst Geog Sci Beijing 100101 Peoples R China chinese Acad Sci Nat Resources Res Beijing 100101 Peoples R China

Views diverge greatly on the relationship between actual evapotranspiration (AE) and potential evapotranspiration (PE). Penman showed that AE is determined in intensity by PE and changes proportionally as a function of PE. In contrast, Bouchet indicated that AE deter-mines PE and varies inversely with PE. Based on nearly 30 years data from 432.weather stations and 512.hydrological stations in china, the two different theories, Penman抯 assumption and Bouchet抯 complementary relationship between AE and PE, were tested on nine river basins. With data integration technique, the complementary relationship between AE and PE was dis-played entirely. A general model to estimate the actual evapotranspiration from nonsaturated surfaces by routine meteorological observations has been established on the basis of thorough analysis of the concept of PE. The results show that the calculations are all in error control of <10%, except for a few years over the Yellow River Basin.

关键词： complementary relationship of evapotranspiration, potential evapotranspiration, actual evapotranspiration.

THINNING OF THE THICKENED LITHOSPHERE AND ITS GEODYNAMIC CONSEQUENCE: APPLICATION FOR TIBETAN PLATEAU

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地学前缘 2000年第S1期7卷 368-369页

作者： Xiong Xiong,Houtse Hsu (institute of geodesy and Geophysics,{2., wuhan 430077, china)

As one of the most distinct tectonic blocks on the Earth’s surface, Tibetan Plateau draw great attention of the geoscientists from the world. Many authors have proposed various kinds of the mechanism to try to clarify the evolution of the plateau. While many studies are often restricted to crustal units, the important role of the mantle part of the lithosphere (mantle lithosphere) during and after the collision process has not been appreciated widely. The purpose of the paper is to investigate the dynamic process of the thinning (delamination and convective removal) of the thickened lithosphere and its influence upon the uplift of the plateau.1\ Thickened lithosphere root\;Parsons and McKenzie (1978) proposed that the continental lithosphere could be thought of as consisting of two distinct parts: the mechanical and thermal boundary layers. The lower, and hotter, part is the thermal boundary layer. Its viscosity is sufficiently low that the force of gravity acting on density contrasts between the thermal boundary layer and the underlying mantle lead to the episodic sinking of the thermal boundary layer and its replacement by hot asthenosphere. When continental crust shortens and thickens, the mantle directly beneath it must also be displaced downward. In other words, mountain building process shortens horizontally and thickens vertically the mechanical boundary layer, and presumably the thermal boundary layer. And the process stretches the isotherms vertically, thus reducing the geothermal gradient. Houseman’s numerical experiments (1981) show that thickening of the thermal boundary layer enhances the density contrasts between it and the underlying asthenosphere, and so leads to its removal and replacement with hot asthenosphere. This phenomenon is called the instability of the thickened lithosphere.

关键词： thinning thickened lithosphere Tibetan Plateau uplift

Slope safety control during mining below a landslide

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Science china(Technological sciences) 2005年第z1期48卷 47-52页

作者： MIN Hong1, DENG Jianhui1, WEI Jinbing1, ZHANG Qizhong2. ZOU Jiangang2.& ZHOU Zhibin2.1. institute of Rock and Soil Mechanics, chinese academy of sciences, {2. 430071, china 2. Daye Iron Mine of WISCO, Tieshan, Daye 435006, china chinese Acad Sci Inst Rock & Soil Mech Wuhan 430071 Peoples R China WISCO DAye Iron Mine Daye 425006 Peoples R China

The East Open Pits of Daye Iron Mine were closed in year 2.00 and the ore beyond the pit limit was planned to be mined by underground ways. In order to facilitate the smooth transition to underground mining, hanging-wall ores in the old pits were scheduled to be mined. Xiangbishan pit is one of the four mining spots selected. In 1979 when the pit was mined to around 36 m a.s.l., a landside of around 70000 m3 occurred in its North Slope, leading to the closure of the pit. The pit was then backfilled to 60 m a.s.l. to maintain the slope stability. The hanging-wall ore to be mined is just located below the old slide, so whether the slide will be reactivated and how to control its deformation and stability are the key issues concerned. Based on geological investigation and numerical analysis, it was predicted that the slide would be reactivated and a control measure using the intact ore body as a retaining wall was thus suggested. During mining, displacements were monitored to assure safety. By July, 2.03, 383000 tons of ore were successfully mined. Though the observed displacement reached 8795 mm, no major failure happened. The final slope is 110 m high with an angle of 70°.

关键词： open pit mine, hanging-wall ore mining, landslide, control measure, retaining wall.