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The source of CO_2.in lamprophyres from Laowangzhai gold orefield, Yunnan Province, china

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Chinese Science Bulletin 1999年第S2期44卷 201-203页

作者： HUANG Zhilong, LIU Congqiang and XIAO Huayun Open Laboratory of Ore Deposit geochemistry, institute of geochemistry, chinses academy of sciences, guiyang 550002. china Open Laboratory of Ore Deposit geochemistry Institute of Geochemistry Chinses Academy of Sciences Guiyang 550002 China

CARBONATES in lamprophyres have various occurrences. The source of CO2.in lamprophyres provides animportant clue for us to understand the relationship between lamprophyres and gold *** et *** the C and O isotopic comp... 详细信息

CARBONATES in lamprophyres have various occurrences. The source of CO2./sub> in lamprophyres provides animportant clue for us to understand the relationship between lamprophyres and gold *** et *** the C and O isotopic composition of various carbonates from Mesozoic lamprophyres in Transdanubian Range of Hungary, and suggested that the carbonates with different occurrences were different in origin. That is to say, the CO2./sub> in lamprophyres has various sources. TheLaowangzhai gold deposits, Yunnan Province, china, is a typical orefield where lamprophyres are temporally and spatially related to gold mineralization. The CO2./sub> contents of relatively fresh lampropyres from theorefield （the range of content is 5.10%-9.56%, averaging 7.45% ） are obviously higher than that ofprimary lamprophyres （about 0.5%）. Huang et *** that the CO2./sub> in relatively fresh lam-

关键词： source of CO2 lamprophyres gold field Yunnan Province.

Mantle-derived sulfur and its time constraints on gold mineralization of Ailaoshan gold belt, china

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Chinese Science Bulletin 1999年第S2期44卷 242-244页

作者： BI Xianwu institute of geochemistry, Chinese {2. of sciences, guiyang 550002. china institute of geochemistry Chinese Academy of Sciences Guiyang 550002 China

IN the previous studies of hydrothermal deposits much attention was paid to their material sources ratherthan the mechanisms of dynamic association of ore-forming fluids. In recent years many studies haveshown that ore-forming elements were transferred into ore-forming solutions after some suitable mineralizerwas incorporated into hydrothermal solutions. Therefore, the time at which the mineralizer is incorporated into hydrothermal solutions could, to a great extent, reflect the time of ore deposition. In the dynamic study of the origin of ore deposits on a trial basis the author took the Ailaoshan gold belt in YunnanProvince as an example and carried out investigations into the sources of mineralizers (the anion coordinates of stable complexes of gold in hydrothermal solutions) in ore-forming hydrothermal solutions and theconstraints of relevant geological events on gold mineralization.

关键词： sulfur isotope mantle-derived sulfur dating gold mineralization Ailaoshan gold belt.

Evidence of acid nature of ore-forming solutions

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Chinese Science Bulletin 1999年第S2期44卷 199-201页

作者： CHEN Fu institute of geochemistry, Chinese {2. of sciences, guiyang 550002. china institute of geochemistry Chinese Academy of Sciences Guiyang 550002 China

THE author thinks that the ore-forming solution is formed not by the near-neutral brine but by the strongacid solutions. Some evidence are the following: （i） The simulating experiments showed that, all near-neutral supergenic water as volcanic hotspring water of Tengchong, K-brine of Mengyejing, seawater of Qingdao, oil-gasses-bearing water of Chitianhua, rain water of guiyang and CO2./sub>-bearing rain cannot form metal-bearing solutions by heating mixedabove-mentioned supergenic water with ore-source rocks as basalt, ore-bearing carbonate, sandstone andshale. The most content of Cu, Pb, Zn, Hg, Sb, As, Ag in solutions is only （0.3-0.5）×10-6.They cannot form any ore deposit. Oppositely, the acid solution of pH=1.0 is easy to form metal-bearingsolutions with every ore-source rocks. The most content of metal in solution is n×10-n×1000 × 10-6i.e. rose in 3-5 grades. The content of metals in humic acid-bearing solutions is variable, perhaps dueto the changes of humic components and content and due to easy-decomposition by oxidation or *** the best one in solutions to form ore-forming solution is only the acidic water.

关键词： ore-forming solution acid solution in nature genesis of brine.

Epithermal gold deposits in china and potential assessment

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Chinese Science Bulletin 1999年第S2期44卷 164-166页

作者： QIU Yuzhuo institute of geochemistry, Chinese {2. of sciences, guiyang 550002. china institute of geochemistry Chinese Academy of Sciences Guiyang 550002 China

THE epithermal gold deposit (epi-gold) is one of the most important types in various gold deposits all overthe world. The discovery of several superlarge deposits of this type around the circum-Pacific Rim duringthe 1980s, greatly stimulated the interest in searching for epi-golds in the world as well as in china. Theepi-gold has become a major target in gold exploration in china during last two-decade "Golden *** discovery of the Zijinshan Cu (Au) deposit in SE china and the Axi and other Au deposits in NWchina is the significant success in gold prospecting in this field. The author suggested that it is the timeto do an overview and the potential assessment of epi-golds in china Some people are holding an optimistic idea on this topic mainly based on the following considerations: (i) as a host rock, the subaerial volcanic rocks of Mesozoic are widespread in East china; (ii)

关键词： epithermal gold deposit china potential assessment.

Experimental measurement of the electrical conductivity of single crystal olivine at high temperature and high pressure under different oxygen fugacities

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Progress in Natural Science:Materials International 2006年第4期16卷 387-393页

作者： DAI Lidong, LI Heping, LIU Congqiang, CUI Tongdi, SHAN Shuangming, YANG Changjun, LIU Qingyou and DENG Heming Laboratory of the Earth’s Interior Materials and Fluid geochemistry, institute of geochemistry, Chinese academy of sciences, guiyang 550002. china Graduate School of the Chinese academy of sciences, Beijing 100039, china institute of geochemistry, Chinese academy of sciences, guiyang 550002. china Guizhou University, guiyang 550004, china Laboratory of the Earth's Interior Materials and Fluid geochemistry Institute of Geochemistry Chinese Academy of Sciences Guiyang 550002 China Graduate School of the Chinese academy of sciences Beijing 100039 China institute of geochemistry Chinese {2. of sciences Guiyang 550002 China Guizhou University Guiyang 550004 China

At 1.0-4.0 GPa and 112.-1473 K and under oxygen fugacity-controlled conditions (Ni + NiO, Fe + Fe3O4, Fe + FeO and Mo+ M0O2.buffers), a YJ-3000t Model six-anvil solid high-pressure apparatus and a Sarltron-12.0 Impedance/Gain-Phase analyzer were employed to conduct an in situ measurement of the electrical conductivity of single crystal olivine. Experimental results showed that: (1) within the range of experimentally selected frequencies (103-106 Hz), the electrical conductivity of the sample is of great dependence on the frequency; (2. with the rise of temperature ( T), the electrical conductivity (σ) will increase, and the Arrenhius linear relationship is established between lgσ and 1/T; (3) under the control of oxygen buffer Fe+ Fe3O4, with the rise of pressure, the electrical conductivity tends to decrease whereas the activation enthalpy and independent-of-temperature preexponential factor tend to increase, with the activation energy and activation volume of the sample estimated at (1. 2. ± 0.08) eV and (0.105 ±0.02.) cm3/mol, respectively; (4) under given pressure and temperature conditions, the electrical conductivity tends to increase whereas the activation energy tends to decrease with increasing oxygen fugacity; and ( 5) the mechanism of electrical conduction of small polarons can provide insight into the behavior of electrical conduction of olivine under high pressure and high temperature.

关键词： olivine high temperature and high pressure electrical conductivity oxygen fugacity small polaron.

Physical mechanisms of plant roots affecting weathering and leaching of loess soil

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Science china Earth sciences 2006年第9期49卷 1002-1008页

作者： LI Yong1,2. ZHANG Qingwen1,2. WAN Guojiang3, HUANG Ronggui3, PIAO Hechun3, BAI Lingyu2.& LI Lu2.1. State Key Laboratory of Soil Erosion and Dryland Farming on the Loess Plateau, institute of Soil and Water Conservation, Chinese academy of {2., Yangling 712.00, china 2. institute of Agro-Environment and Sustainable Development, Chinese academy of Agricultural {2., Beijing 100081, china 3. institute of geochemistry, Chinese academy of {2.,{12. State Key Laboratory of Soil Erosion and Dryland Farming on the Loess Plateau Institute of Soil and Water Conservation Chinese Academy of Sciences Yangling China institute of Agro-Environment and Sustainable Development Chinese Academy of Agricultural Sciences Beijing China institute of geochemistry Chinese Academy of Sciences Guiyang China

Plant roots have potential impacts on soil mineral weathering and *** objective is to understand the physical mechanisms of plant roots affecting weathering andleaching of loess soil. Root densities were measured through the method of a large-size dug profile,and transport fluxes of soil elements were determined using an undisturbed monolith soilinfiltration device on the hilly and gully regions of the Chinese Loess Plateau. The results showthat the improvement effects of soil environment by plant roots are mainly controlled by the densityand weight of the fibrous roots with the diameters less than 1 mm. Plant roots have the strongereffects on soil physical properties than chemical properties. The principal components analysis(PCA) indicates that soil physical properties by plant roots account for 56.7% of variations in soilenvironment whereas soil chemical properties and pH contribute about 2..2. of the soil *** roles of plant roots in controlling soil weathering and leaching increased in the followingorder: infiltration enhancement > increase of bio-active substance > stabilization of soilstructure. The effects of plant roots on soil mineral weathering and leaching can be quantifiedusing the multiple regression models with the high prediction accuracies developed in this study.

关键词： plant roots, soil weathering and leaching rates, soil environment field, principal components analysis (PCA), Chinese Loess Plateau.

Geological setting of some classical selenium-bearing formations in china

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Chinese Science Bulletin 1999年第S2期44卷 185-186页

作者： WEN Hanjie and QIU Yuzhuo institute of geochemistry, Chinese {2. of sciences, guiyang 550002. china institute of geochemistry Chinese Academy of Sciences Guiyang 550002 China

SELENIUM is a highly dispersed element with a lower Clarke of 0.05×10-6 and rarely forms its own independent deposits in the crust. In recent years by the discovery of a series of selenium-bearing deposits（such as Laerma selenium-gold deposit and Yutangba selenium deposit） and selenium-rich strata （westHubei, Laerma, Ziyang, Langao, northwest Hunan, etc.）, the character and genesis of the seleniumbearing formation （SBF） have been noted by many researchers. 1 Some classical SBF in china In china the classical SBFs include: （i） The Lower Cambrian SBF in Laerma, west Qinling: Thebackground value of selenium is 5.47×10-6, and the selenium content of the sillcalite and slate （mainrock type） averages 8.70×10-6 and 3.05×10-6 respectively. （ii） The Lower Cambrian SBF inZiyang and Langao, east Qinling: Selenium is present in relatively high abundance in the SBF, averaging3.89×10-6 in the slate, 2.86×10-6 in the sillcalite. （iii） The Lower Cambrian SBF in northwest Hu-

关键词： selenium selenium-bearing formation geological setting.

Hydrothermal sedimentation and lead-zinc deposit in Dengying formation of the Sinian system in Panxi region

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Chinese Science Bulletin 1999年第S2期44卷 67-68页

作者： ZHU Laiming and RONG Tianjun institute of geochemistry, Chinese {2. of sciences, guiyang 550002. china institute of geochemistry Chinese Academy of Sciences Guiyang 550002 China

IN addition to vanadium titano-magnetite, lead-zinc ore is also one of the mineral resources with great exploring potentiality in the Panxi region of Sichuan Province, china. In the carbonate rock strata of theSinian Dengying Formation which account for about 3.5%-11.4% of the total thickness of the strataexposed in the Panxi region there are quite a number of the Pb-Zn deposits that account for 53.4% of thetotal Pb-Zn ore reserve in the whole region. Furthermore, some large Pb-Zn deposits such as the Tianbaoshan Pb-Zn deposit in Huili, the Daliangzi Pb-Zn deposit in Huidong and the Yinchanggou Pb-Zn deposit in Ningnan are also hosted in the Sinian Dengying Formation. Why? Previous studies indicated that the high background values of Pb and Zn, favorable lithofacies andpaleogeographic conditions and good ore-hosting structures made the Sinian Dengying Formation a pre-

关键词： hydrothermal sedimentation lead-zinc deposit Dengying formation Panxi region.

Dynamic processes of ore-forming fluid and the localization of orebody: case study on the sediment-hosted gold deposits of southwestern Guizhou, china

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Chinese Science Bulletin 1999年第S2期44卷 263-265页

作者： ZHANG Chengbo and ZHANG Zheru institute of geochemistry, Chinese {2. of sciences, guiyang 550002. china institute of geochemistry Chinese Academy of Sciences Guiyang 550002 China

1 Geological setting and occurrence features of the sediment-hosted gold deposits OVER 100 sediment-hosted gold deposits and occurrences of southwestern Guizhou lie near the sonthemedge of the Yangtze craton, which is composed of crystalline rocks of Proterozoic age, overlain mainly byPaleozoic and Lower to Middle Triassic shallow-marine platform and reef facies carbonates that gradesouthward and eastward into a thick section of interbedded siltstones and turbidite sandstones. Clasticdeposits were from the Yunkai Old Land and the Jiangnan Old Land respectively. The rocks were foldedand faulted during the Yanshanian orogeny, 190-65 Ma ago. Mineral deposits were mainly located inthe breccia horizon at the base of the Longtan Formation of Upper Permian, underlain by the massive graylimestone of Lower Permian with a karst unconformity, and the high-angle fault zones in the Triassicargillaceous limestone interlayered with shale, arkose, and fine-grained turbidite sandstone. No

关键词： sediment-hosted gold deposits fossil hydrothermal system mathematical model.