检索结果-南通市图书馆

Study on the coating of nano-scale SiO_2.film on the surface of nanocrystalline Mg-Al layered double hydroxides

Science China chemistry 2005年第2期48卷 107-114页

作者： ZHANG Zejiang1,2.3. MEI Xiujuan2. XU Chenghua1 & QIU Fali1 1. Chengdu institute of Organic {3., {2., Chengdu 610041, China 2. Sichuan Fire Research institute of Public Security Ministry, Chengdu 61183., China 3. Graduate School of the {2., Beijing 10003., China Correspondence should be addressed to Zhang Zejiang (email: zzjzzjzz@***) Chengdu institute of Organic chemistry Chinese Academy of Sciences Chengdu China Sichuan Fire Research institute of Public Security Ministry Chengdu China Graduate School of the chinese academy of sciences Beijing China

The coating process of a nano-scale SiO2.film on the nanocrystalline Mg-Al layered double hydroxides via a sol-gel process was investigated. The uniform and dense SiO2.ilm with a thickness of about 5 nm on the nano-LDHs particles was characterized by the solubility test in the dilute HNO3.or HCl acid, TEM and FT-IR, XRD, TG and DSC. The chemical shifts of binding en- ergies of Al 2., Mg 2., Si 2. and O 1s on the coated particles indicate that the coating of the SiO2.nano-film on the surface of the nano-LDHs proceeds through the formation of Mg-O-Si and Al-O-Si bonds. The thermal analysis shows that both the SiO2.coated nano-LDHs and the nano-LDHs have a similar mass loss process, in which there are three obvious stages of mass loss in the temperature range of 40—700℃. Furthermore, the more the coatedamount of SiO2.n the surface of the nano-LDHs is, the less the mass loss of the samples is at 700℃.The nano- LDHs have two obvious endothermic peaks at 2.4.67℃ and 43..13., whose corresponding heat absorption capacities are 412.2. J/g and 3.6.3. J/g, respectively. In contrast, the coated nano-LDHs have only one endothermic peak at 2.3.60℃ with a heat absorption capacity of 2.1.2. J/g.

关键词： layered double hydroxides, nanocrystalline, silica, coating.

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Sequence analysis of mRNA polyadenylation signals of rice genes

引用

chinese Science Bulletin 2006年第9期51卷 1069-1077页

作者： LU Ying1, 2. GAO Chenxi1,2.3.& HAN Bin1,3.41. National Center for Gene Research, Shanghai institutes for Biological {3., {2., Shanghai 2.02.3. China 2. Graduate School of the {2., Beijing 10003., China 3. institute of Plant Physiology and Ecology, Shanghai institutes for Biological {3., {2., Shanghai 2.003.0} China National Center for Gene Research Shanghai Institutes for Biological Sciences Chinese Academy of Sciences Shanghai China Graduate School of the chinese academy of sciences Beijing China institute of Plant Physiology and Ecology Shanghai Institutes for Biological Sciences Chinese Academy of Sciences Shanghai China

The formation of eukaryotic mRNAs involves the cleavage and polyadenylation of pre- mRNAs. To investigate the sequence requirement of putative polyadenylation signals (PASs), poly(A) sites and downstream elements (DUEs) in 3.-end-pro- cessing in rice, we compared expressed sequences tags (ESTs) with poly(A) extremity to full-length cDNA sequences and constructed a database of 12.69 pre- mRNA sequences in ?40―+40 nt surrounding the poly(A) sites, which were from 9953.genes. The al- ternative poly(A) sites were revealed in approxi- mately 2.% of mRNAs. Nearly 80% of pre-mRNAs showed stringent requirement of the YA (CA or UA) at poly (A) sites for polyadenylation. About 7.9% had the AAUAAA signals on ?40―?1 nt upstream of the poly(A) sites. Over 60% of mRNAs probably used the one- or two-base variants of AAUAAA hexamers as their PASs in 3. fragments. The single-base variants of AAUGAA revealed the high frequency in 11.5% of 3. fragments. The DUEs were detected in 90% of pre- mRNAs, especially more than half of the pre-mRNAs with multi-base variants of AAUAAA had the DUEs surrounding the poly(A) site. The location of DUE is also important for defining the cleavage site. Al- though most of the rice pre-mRNAs did not contain AAUAAA signal, the existence of downstream ele- ments ensured the efficiency of cleavage-polyade-

关键词：多聚腺苷酸序列分析 mRNA 水稻基因工程

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Holocene grassland vegetation, climate and human impact in central eastern Inner Mongolia

引用

Science China Earth sciences 2005年第7期48卷 1025-1039页

作者： HUANG Fei1, Kealhofer Lisa2. XIONG Shangfa3.& HUANG Fengbao1 1. Nanjing institute of Geology and Paleontology,chinese academy of sciences,Nanjing 2.0008,China 2. Anthropology and Sociology Department,Santa Clara University,CA 95053.USA 3. institute of Geology and Geophysics,chinese academy of sciences,Beijing 10002.,China Nanjing institute of Geology and Paleontology Chinese Academy of Sciences Nanjing 210008 China Anthropology and Sociology Department Santa Clara University CA 95053 United States institute of Geology and Geoohysics Chinese Academy of Sciences Beijina 100029 China

Phytolith and pollen preserved in the Taipusi Banner paleosol profile, central eastern Inner Mongolia, provide evidence of Holocene grassland vegetation, climate and human impact. The combined phytolith and pollen records reveal a major change in vegetation composition about 5000 a BP. Before 5000 a BP, the vegetation was dominated by Aneurolepidium chinese-Stipa grandis grassland of C4 grasses. After 5000 a BP, C4 grasses rapidly retreated, indicating a shift to colder and more arid conditions. The gradual invasion of Stipa krylovii, Ag-ropyron desertorum, Ephedra, Chenopodiaceae and Caragana reveal the onset of grassland degeneration. Between 10000 and 872. a BP, the Aneurolepidium chinese-Stipa grandis grassland included a small proportion of Artemisia shrub and Echionopos type plants, implying a strong winter monsoon and very weak summer monsoon. From 872. to 7000 a BP, C4 grasses were common, indicating a strengthening of the summer monsoon. Between 7000 and 5000 a BP, the Holocene thermal maximum was evident, with a significant expansion of C4 grasses and the presence of some trees (such as Pinus and Betula, and so on) in or near the study site. From 42.0?000 a BP, a sandy grassland of Artemisia and Agropyron desertorum together with Aster-type taxa occurred. Precipitation amelioration took place between 3.00 and 2.70 a BP, with a rapid development of Echinops type plants and a small expansion of C4 grasses. From 2.70 a BP to present, human activities accelerated the process of grassland degeneration.

关键词： phytolith and pollen records grassland environment change human impact Holocene central eastern Inner Mongolia.

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

The Juancheng chondrite──A new meteorite falling recently in China

引用

chinese Science Bulletin 1998年第21期43卷 1834-1837页

作者： CHEN Yongheng 1,2. WANG Daode+2.and WANG Ruitian+3.. Department of chemistry, Guangzhou Normal University, Guangzhou 510400, China 2. Guangzhou institute of Geochemistry, chinese academy of sciences, Guangzhou 510640, China 3. Heze Bureau of Seismolo Department of chemistry Guangzhou Normal University Guangzhou China Guangzhou institute of Geochemistry Chinese Academy of Sciences Guangzhou China Heze Bureau of Seismology Shandong Province Heze China

The Juancheng chondrite, a new meteorite falling recently in Juancheng County, Shandong Province, China, is classified as an H5 (S2. chondrite based on the compositions of olivine (Fa= 19.2. σ Fa=0.46) and low-Ca pyroxene (Fs=16.9, σ Fa=0.4). The plagioclase in the Juancheng chondrite is rich in CaO, indicating a relatively high metamorphic temperature the parent body underwent.

关键词： Juancheng ordinary chondrite new meteorite.

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Characteristics and geological significance of olivine xenocrysts in Cenozoic volcanic rocks from western Qinling

引用

Progress in Natural Science:Materials International 2006年第12期16卷 1300-1306页

作者： SU Benxun~ 1,2.**, ZHANG Hongfu~1, XIAO Yan~ 1,2.and ZHAO Xinmiao~ 1,2.(1. State Key Laboratory of Lithospheric Evolution, {3. of Geology and Geophysics, chinese academy of sciences, Beijing 10002., China 2. Graduate School of chinese academy of sciences, Beijing 10003., China) State Key Laboratory of Lithospheric Evolution Institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China Graduate School of chinese academy of sciences Beijing 100039 China

Cenozoic volcanic rocks from the Haoti, Dangchang County of the western Qinling Mountains, contain a few clearly-zoned olivines. These olivines are relatively big in grain sizes and usually have cracks or broken features. Their cores have similar compositions （Mg#=90.4-91.0） to those for the peridotitic xenoliths entrained in host volcanic rocks and their rims are close to the compositions of olivine phenocrysts （Mg#=85.5-81.9）. The CaO contents in these zoned olivines are lower than 0.1%. These features demonstrate that the clearly-zoned olivines are xenocrysts and disaggregated from mantle peridotites. The zoned texture was the result of the interaction between the olivine and host magma. Available data show that the volcanic rocks would have been derived from the mantle source metasomatized by subducted hydrathermally-altered oceanic crust. The formation of these Cenozoic volcanic rocks was perhaps related to the rapid uplift of the Tibetan Plateau.

关键词： Western Qinling Dangchang Haoti Cenozoic volcanic rocks olivine xenocrysts zoned texture.

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Fluorescence dynamics of interactions between polyamide PyPyPyβDp and DNA

引用

Science China chemistry 2006年第1期49卷 75-80页

作者： ZHANG Huijuan1,2. WANG Jin3. WU Yishi1, YUAN Gu3. AI Xicheng1, WANG Li4 & ZHANG Jianping1 1. State Key Laboratory for Structural chemistry of Unstable and Stable Species, institute of chemistry, chinese academy of sciences, Beijing 100080, China 2. School of Life Science and Technology, Beijing institute of Technology, Beijing 100081, China 3. College of chemistry and Molecular Engineering, Peking University, Beijing 100080, China 4. Center for Condensed Matter Physics, institute of Physics, chinese academy of sciences, Beijing 100080, China Correspondence should be addressed to Ai Xicheng and Zhang Jianping State Key Laboratory for Structural chemistry of Unstable and Stable Species Institute of Chemistry Chinese Academy of Sciences Beijing China School of Life Science and Technology Beijing Institute of Technology Beijing China College of chemistry and Molecular Engineering Peking University Beijing China Center for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences Beijing China

The photophysical properties of the polyamide PyPyPyβDp (PPP) were investigated by means of steady-state absorption and fluorescence spectroscopies, as well as time-resolved fluo-rescence spectroscopy. It was found that the excited-state properties of PPP are very sensitive to solvents. In TKMC buffer PPP exhibited weak fluorescence with a decay time constant of 16 ps, while with the decrease of the solvent polarity PPP showed the blue-shifted peak position, increased inten-sity and lengthened life-time for its fluorescence behavior. In the presence of calf thymus DNA, it was observed that the fluorescence intensity was enhanced and the fluorescence lifetime increased from 16 to 3.0}ps for PPP, which verified that PPP bound into the minor groove of DNA duplex.

关键词： polyamide (PPP), calf thymus DNA (ctDNA), time-resolved fluorescence spectroscopy, recognition dynamics.

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Study on the atmospheric photochemical reaction of CF_3.radicals using ultraviolet photoelectron and photoionization mass spectrometer

引用

Science China chemistry 2008年第4期51卷 316-321页

作者： YAO Li1,2. DU Lin1,2. YIN Shi1,2.& GE MaoFa1 1 Beijing National Laboratory for Molecular {3. (BNLMS), State Key Laboratory for Structural chemistry of Unstable and Stable Species, {2. of chemistry, chinese academy of sciences, Beijing 100080, China 2.Graduate University of chinese academy of sciences, Beijing 100080, China Beijing National Laboratory for Molecular sciences (BNLMS) State Key Laboratory for Structural Chemistry of Unstable and Stable Species Institute of Chemistry Chinese Academy of Sciences Beijing China Graduate University of chinese academy of sciences Beijing China

A study of the atmospheric photochemical reaction of CF3.radical with CO and O2.was performed by using a homemade ultraviolet photoelectron spectrometer-photoionization mass spectrometer (PES- PIMS). The electronic structures and mechanism of ionization and dissociation of CF3.C(O)OOC(O)- OCF3.were investigated. It was indicated that the two bands on the photoelectron spectrum of CF3.C(O)OOC(O)OCF3.are the result of ionization of an electron from a lone pair of oxygen and a fluo- rine lone pair of CF3.group. The outermost electrons reside in the oxygen lone pair. The experimental and theoretical first vertical ionization energy is 13.2. and 13.178 eV, respectively, with the PES and OVGF method. They are in good agreement. The photo ionization and dissociation processes were discussed with the help of theoretical calculations and PES-PIMS experiment. After ionization, the parent ions prefer the dissociation of the C-O bond and giving the fragments CF3.CO+ and CF3.. It demonstrated that the ultraviolet photoelectron and photoionization mass spectrometer could be ap- plied widely in the study of atmospheric photochemical reaction.

关键词： photochemical reaction CF3 radical ultraviolet photoelectron and photoionization mass spectroscopy transient species

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Preparation of Pt/K_2.a_2.i_3._(10) and its photo-catalytic activity for hydrogen evolution from methanol water solution

引用

Science China chemistry 2006年第2期49卷 162-168页

作者： CUI Wenquan1,3. LIU Li2. FENG Liangrong1, XU Chenghua1, LI Zijian1, Lü Shaojie1 & QIU Fali1 1. Chengdu institute of Organic chemistry, {2., Chengdu 610041, China 2. chemistry Department, Sichuan University of Science & Engineering, Zigong 643.3., China 3. Graduate School of the {2., Beijing 10003., China Correspondence should be addressed to Qiu Fali Chengdu institute of Organic chemistry Chinese Academy of Sciences Chengdu China Graduate School of the chinese academy of sciences Beijing China chemistry Department Sichuan University of Science & Engineering Zigong China

A layered perovskite-type oxide K2.a2.i3.10 was prepared with high-temperature solid-state reaction, and characterized with X-ray diffraction (XRD) and ultraviolet-visible diffuse re-flectance spectroscopy (UV-Vis DRS). Platinum was loaded onto K2.a2.i3.10 as a co-catalyst with different methods. The dispersion of platinum on K2.a2.i3.10 was determined with HOT method. The photocatalytic activity of Pt/K2.a2.i3.10 was studied. This catalyst showed much higher activity in hydrogen evolution reaction than Ni/K2.a2.i3.10. The effects of different amounts of loaded platinum and several preparation methods were evaluated. The best achieved hydrogen evolution rate was 2.3.88 μmol·h?1 by Pt(2.)/K2.a2.i3.10. A possible band structure and mechanism were discussed based on the results.

关键词： photocatalysis hydrogen platinum K_2.a_2.i_3._(10) support

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Global convergence property of s-dependent GFR conjugate gradient method

引用

chinese Science Bulletin 1998年第23期43卷 1959-1965页

作者： WANG Changyu 1,2.and ZHANG Yuzhong\+1 1. institute of Operations Research in Qufu Normal University, Qufu 2.3.65, China 2. institute of Applied Mathematics, {2., Beijing 100080, China institute of Operations Research Qufu Normal University Qufu China institute of Applied Mathematics Chinese Academy of Sciences Beijing China

An \%S\%_dependent GFR method and a generalized conjugate gradient method are designed. Two estimated values of upper bounds for the ratio of β k to β FR k are given. The two convergence theorems are proved. The global convergent properties of \%s\%_dependent GFR method are obtained adopting several choice strategies of steplength and some results in recent literature are extended.

关键词： steplength linear search global convergence conjugate gradient.

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Grain-size features of a Miocene loess-soil sequence at Qinan: Implications on its origin

引用

Science China Earth sciences 2006年第7期49卷 731-738页

作者： QIAO Yansong1,3. GUO Zhengtang2.1, HAO Qingzhen1, YIN Qiuzhen1, YUAN Baoyin1 & LIU Tungsheng1 1. institute of Geology and Geophysics, chinese academy of sciences, Beijing 10002., China 2. institute of Earth Environment, chinese academy of sciences, Xi’an 710075, China 3. institute of Geomechanics, chinese academy of Geological sciences, Beijing 100081, China institute of Geology and Geophysics Chinese Academy of Sciences Beijing China institute of Geomechanics Chinese Academy of Geological Sciences Beijing China institute of Earth Environment Chinese Academy of Sciences Xi’an China

In this study, grain-size of 507 bulk samples from the QA-I Mioceneloess-soil sequence at Qinan were analyzed, and the grain-size features are compared with those oftypical Quaternary loess and soil samples, representative lacustrine and fluvial samples. Theresults indicate that the grain-size distribution pattern of the Miocene loess is essentiallysimilar to that of Quaternary loess, but greatly differs from the lacustrine and fluvial *** layers are regularly coarser than soil layers, indicating cyclical climate changes. Mediangrain-size along the 2.3.1 m sequence varies from 6 to 13.μm and the > 63.μm fraction representsonly 5.3. in maximum, 0.9% in average. Long-term grain-size variations are consistent with the loessaccumulation rate at Qinan and with the eolian mass accumulation rate in the North Pacific. Thesefeatures firmly indicate an eolian origin of the studied sequence, and also reveal a coeval changesbetween the long-term changes of eolian grain-size and continental aridity in the dust sourceregions.

关键词： Qinan, Miocene loess-soil sequence, grain-size, eolian origin.

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：