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PREPARATION AND PROPERTIES OF ETHYL-CYANOETHYL CELLULOSE/POLYACRYLIC ACID COMPOSITE FILMS WITH REFLECTION COLORS

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chinese Journal of Polymer Science 2001年第3期19卷 277-282页

作者： Yong Huang institute of chemistry,{2., beijing 1.0080 china Laboratory of Cellulose and Lignocellulosics chemistry Guangzhou institute of chemistry{2., Guangzhou 510650, china 中科院化学所北京

Ethyl-cyanoethyl cellulose [(E-CE)C]/acrylic acid (AA) becomes a cholesteric liquid crystalline solution withvivid colors when the (E-CE)C concentration is 42.wt%～52.wt%. (E-CE)C/polyacrylic acid (PAA) composites withcholesteric structure were prepared by polymerzing AA in (E-CE)C/AA liquid crystalline solutions. The layers of orderedpolymer chains in the cholesteric phase were inclined during polymerization and the degree of the inclination depended onthe polymerization temperature and the concentration of the solution before polymerization. The cholesteric structure in thecomposites could not be changed when temperature was lower than 100℃. Cross-linking of the PAA in compositesimproved their water-resistance. The cholesteric order of the composites without cross-linking was destroyed when theywhere immersed in water. The color derived from the selective reflection of the cholesteric phase of the cross-linkedcomposites turned from blue to red after the composites absorbed water. The color of the composites could be returned to theoriginal one when the absorbed water was removed from the swollen composites.

关键词： Cholesteric structure Composites Selective reflection Liquid crystalline solutions

^(40)Ar/^(39)Ar dating of shear deformation of the Xianshuihe fault zone in west Sichuan and its tectonic significance

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Science china Earth sciences 2004年第9期47卷 794-803页

作者： ZHANG Yueqiao1, CHEN Wen2. 3 & YANG Nong1 1. institute of Geomechanics, chinese {2. of Geological sciences, beijing 100081, china 2. institute of Geology, chinese {2. of Geological sciences, beijing 100037, china 3. institute of Geology and Geophysics, chinese academy of sciences, beijing 10002., china institute of Geomechanics Chinese Academy of Geological Sciences Beijing China institute of Geology Chinese Academy of Geological Sciences Beijing China institute of Geology and Geophysics Chinese Academy of Sciences Beijing China

Based on field geological survey, structural measurements and classical Ar/Ar dating of mica, biotite and K-feldspar, we obtain cooling ages for Miocene left-lateral shear along the Xianshuihe fault zone. The results document two thermal events during the sinistral shear. The early event (12.10 Ma) corresponds to rapid cooling of the Zheduoshan granitic massif from above 700℃ to below 350℃. The late event (5-3.5 Ma) corresponds to cooling of granites intruded along the eastern side of the fault zone. These dating results provide important thermochronological constraint on the timing of late Cenozoic eastward extrusion of the Chuan-Dian Block in the SE Tibetan margin.

关键词： Xianshuihe fault zone, Zheduoshan granitic massif, sinistral shear deformation, 40Ar/39Ar dating, late Cenozoic.

Principles and methods of quantitative analysis on b-axis disorder in 2.: 1 dioctahedral phyllosilicate

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chinese Science Bulletin 1997年第22期42卷 1908-1912页

作者： WANG Ling and ZHANG Zhenyu1. Changsha institute of Geotectonics, chinese academy of sciences, Changsha 410013,{2. 2. institute of Geology, chinese academy of sciences, beijing 10002.,{2. Changsha institute of Geotectonics Chinese Academy of Sciences Changsha China institute of Geology Chinese Academy of Sciences Beijing China

IN XRD patterns of clay minerals, a phenomenon that strong peaks often have (00l) and(hkl) (k=3n) indices and show symmetric figures can be seen commonly, while a minorityof reflection peaks (hkl) (k≠3n) are comparat... 详细信息

关键词： b-axis disorder pyrophvllile 2 phyllosilicate clay minerals dioctahedral minerals orientating structure of hy-droxyls crystal structure analysis DTA-TG.

STUDY ON THE SYNTHESIS AND PROPERTIES OF POLY(ESTER-IMIDEETHER)MULTIBLOCK COPOLYMERS

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chinese Journal of Polymer Science 2000年第1期18卷 9-13页

作者： Zu-yao Shan Zhen-yi Li institute of chemistry,{2., beijing 1.0080, china 中科院化学所北京

A new class of poly(ester-imide-ether) multiblock copolymers was synthesized by transes-terification and melt copolymerization of dimethyl terephthalate (DMT) and N-(4-carbomethoxyphenyl)-4-(carbomethoxy)-phthalimide with ethylene glycol (EG) and polytetramethylene glycol (PTMG). The structure of the above copolymers was characterized by H-1-NMR and IR spectroscopy. Some properties of the coplymers were also examined. It was found that their mechanical properties and heat stability, compared with poly(ether-ester) copolymers, were obviously improved.

关键词： N-(4-carbomethoxyphenyl)-4-(carbomethoxy)-phthalimide polyester-polyether copolymer poly-(ester-imidether) multiblock copolymer imide modification

Discovery of immune related factors in Fenneropenaeus chinensis by annotation of ESTs

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Progress in Natural Science:Materials International 2004年第1期14卷 48-55页

作者： SHEN Yaoqing 1,2. , XIANG Jianhai 1*, WANG Bing 1,2. , LI Fuhua 1 and TONG Wei 3(1. Experimental Marine Biology Laboratory, institute of Oceanology, chinese academy of sciences, Qingdao 2.6071,{2. 2. Graduate School of the chinese academy of sciences, beijing 100039, china 3. Genomics & Bioinformatics institute, chinese academy of sciences, beijing 101300, china) chinese Acad Sci Inst Oceanol Expt Marine Biol Lab Qingdao 266071 Peoples R China chinese Acad Sci Grad Sch Beijing 100039 Peoples R China chinese Acad Sci Geonom & Bioinformat Inst Beijing 101300 Peoples R China

A total of 10446 expressed sequence tags (ESTs) are obtained by a large scale sequencing of a cDNA library from cephalothorax of adult Fenneropenaeus chinensis . An EST analysis platform was built up based on local computers and bioinformatic techniques were used to annotate these ESTs in order to promptly find possible functional genes, especially for immune related factors. About 4% of the ESTs show similarity to the coding sequences of such factors, including lectin, serine protease, serpin, lysozyme, etc. These ESTs provide a partial profile of the immune system in F. chinensis and useful information for further study on these genes.

关键词： Fenneropenaeus chinensis bioinformatics ESTs immune factors

High Throughput SNP Genotyping with Two Mini-sequencing Assays

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Acta Biochimica et Biophysica Sinica 2004年第6期36卷 379-384页

作者： Chunqing LUO1,2., Libin DENG1#, and Changqing ZENG1,2. The institute of Genetic and Developmental Biology, the chinese academy of sciences, {2. 100101, china 2.2. Genomics institute, the chinese academy of sciences, {2. 101300, china The institute of Genetic and Developmental Biology the Chinese Academy of SciencesBeijing 100101 China beijing Genomics institute the Chinese Academy of SciencesBeijing 101300 China

Two mini-sequencing methods, FP-TDI (template-directed dye-terminator incorporation with fluorescence-polarization) and MassArray (matrix assisted laser desorption ionization time of flight detection mass spectrometry), were optimized. A numeric standard was introduced to evaluate the SNP scoring quality of FP-TDI assay, thus made the optimization work easier. At the same time, using multi-PCR technology, 8-plex genotyping of MassArray assay was successfully carried out, some softwares were developed and the data process of MassArray was highly automated. Then these two methods were applied to high throughput SNP genotyping, the accuracy, efficiency and robustness were compared. The result shows FP-TDI is more sensitive to the concentration of SNPprimer and PCR product, as well as extension cycles, the SNPprimer length of FP-TDI should be 2.–30 bp long, whereas MassArray assay prefers to be as short as only 16 *** 6440 SNP sites of human chromosome 3 were genotyped in a sample of 90 individuals, 4792.sites by FP-TDI assay and 1648 sites by MassArray assay, the success rates of FP-TDI and MassArray were 67.7% and 93.6% respectively. The throughput of MassArray was higher than FP-TDI, and the cost of MassArray was lower, MassArray was more suitable for high throughput SNP genotyping.

关键词： SNP genotyping FP-TDI MassArray high throughput

Spectrophotometric determination of cationic surfactants by formation of ternary complexes with Fe(Ⅲ) and chrome azurol S

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chinese Journal of chemistry 1996年第3期14卷 228-234页

作者： SONG, Ming LIANG, Shu-Quan institute of chemistry,{2., beijing 1.0080, china institute of chemistry Chinese Academy of Sciences Beijing 100080 China

An extraction-free spectrophotometric method for the determination of cationic surfactants, such as cetylpyridinium chloride, cetyltrimethylammonium bromide and zephiramine is proposed, which is based on the formation of ternary complexes with Fe(Ⅲ) and chrome azurol S. The molar ratio of the complex is 2.1:1 (Fe(Ⅲ):chrome azurol S:cationic surfactant). The method is simple, rapid and sensitive, giving an apparent molar absorptivity of 4.5×104 ***-1 and a linear range of 0.1-6.0 umol/L cationic surfactants. The total cationic surfactant content can be determined directly in aqueous solutions by measuring the absorbance at 680 nm (pH 5.8). The method has been successfully applied to water samples.

关键词： Cationic surfactant determination spectrophotometry ternary complex Fe(Ⅲ) chrome azurol S

MODELLING AND NUMERICAL SOLUTIONS OF A GAUGE PERIODIC TIME DEPENDENT GINZBURG-LANDAU MODEL FOR TYPE-Ⅱ SUPERCONDUCTORS

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Journal of Computational Mathematics 1997年第4期15卷 365-384页

作者： Zhi-ming Chen (institute of Mathematics, chinese academy of sciences, {2., china) 中科院数学所北京

In this paper we seek the solutions of the time dependent Ginzburg-Landau model for type-Ⅱ superconductors such that the associated physical observables are spatially periodic with respect to some lattice whose basic lattice cell is not necessarily rectangular. After appropriately foring the gange, the model can be formulated as a system of nonlinear parabolic partial differential equations with quasi-periodic boundary conditions. We first give some results concerning the existence, uniqueness and regularity of solutions and then we propose a semiimplicit finite element scheme solving the system of nonlinear partial dmerential equations and show the optimal error estimates both in the L2.and energy *** also report on some numerical results at the end of the paper.

关键词： Math QT MODELLING AND NUMERICAL SOLUTIONS OF A GAUGE PERIODIC TIME DEPENDENT GINZBURG-LANDAU MODEL FOR TYPE SUPERCONDUCTORS

Interfacial behaviors of PMMA-PEO block copolymers at the air/water interface

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Science china chemistry 2005年第6期48卷 567-573页

作者： CHENG Caixia1, JIAO Tifeng2. TANG Rupei1, LIU Minghua2.& XI Fu1 1. State Key Laboratory of Polymer Physics and chemistry, Joint Laboratory of Polymer Science and Materials, institute of chemistry, chinese academy of sciences, beijing 1.0080, china 2. CAS Key Laboratory of Colloid and Interface Science, institute of chemistry, chinese academy of sciences, beijing 1.0080, china State Key Laboratory of Polymer Physics and chemistry Joint Laboratory of Polymer Science and Materials Institute of Chemistry Chinese Academy of Sciences Beijing China CAS Key Laboratory of Colloid and Interface Science Institute of Chemistry Chinese Academy of Sciences Beijing China

Diblock copolymer of PMMA2.1-b-PEO114 and triblock copolymer of PMMA12.-b- PEO2.7-b-PMMA12. were synthesized and their interfacial properties at the air-water interface were investigated, where both blocks of polyethylene oxide (PEO) and poly(methyl methacrylate) (PMMA) are surface active but the former is soluble in water while the latter is not. Both the block copolymers could form monolayers with two obvious transition regions. The first transition point is around 10 mN/m, which could be assigned to the pancake-brush change of the PEO chains. The other is around 18 mN/m, which could be ascribed to the condensed packing of PMMA. The surface morphological changes during the compression of the Langmuir monolayers are inves-tigated by using the AFM and SEM methods for the films deposited at different surface pressure or molecular areas. At a lower surface pressure, a typical morphology of PEO-con- taining lipopolymers is observed. Upon compression, sphere-dominant morphologies were observed. While the diblock copolymer is easy to folding, the triblock copolymer is in favor of formation of circular domains through vesiculation.

关键词： PMMA-PEO, block copolymers, monolayer, Langmuir-Blodgett films, AFM.