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Magma underplating and Hannuoba present crust-mantle transitional zone composition: Xenolith petrological and geochemical evidence

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Science china Earth Sciences 2005年第8期48卷 1089-1105页

作者： FAN Qicheng1,2. ZHANG Hongfu1, SUI Jianli1, ZHAI Mingguo1, SUN Qian2.& LI Ni2.1. institute of Geology and Geophysics, Chinese Academy of Sciences, beijing 100029,{2. 2. institute of Geology, china seismological bureau, beijing 100029,{2. 1. institute of Geology and Geophysics Chinese Academy of Sciences 100029 Beijing China 2. institute of Geology China Seismological Bureau 100029 Beijing China

On the basis of mineral assemblage, mineralogy, petrology, and major, trace ele-mental and isotopic geochemistry of the underplated granulite- and eclogite-facies accumulate, peridotite and pyroxenite xenoliths entrained in Hannuoba Cenozoic basalts, this work con-strained the petrological constituents for the crust-mantle transitional zone, which is supported by the results of high-temperature and pressure velocity experiments on rocks and geophysics deep survey. Present lower part of lower crust is mainly composed of granulite-facies mafic accumu-lates (dominantly plagioclase websterite) and crust-mantle transitional zone dominantly com-posed of eclogite-facies pyroxenites with or without garnet and spinel lherzolites; Archaean ter-rain granulite is only nominally early lower crust. Magma underplating in the crust-mantle boundary led to the crustal vertical accretion and the formation of the crust-mantle transitional zone, which is a significant mechanism for the chemical adjustment of the crust-mantle boundary since the Phanerozoic.

关键词： magma underplating, xenolith petrology, geochemistry, cust-mantle boundary constituent, Hannuoba.

The history of crustal uplift and metamorphic evolution of Panzhihua-Xichang micro-palaeoland, SW china:Constraints on Sm-Nd, ^(40)Ar/^(39)Ar and FT ages of granulites

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Science china Earth Sciences 2004年第8期47卷 689-703页

作者： XU Shijin1, LIU Wenzhong1, WANG Rucheng1, YU Hangbo1, LI Daming2. WAN Jinglin2.& FANG Zhong1 1. Department of Earth Sciences and State Key Laboratory for Mineral Deposits Research, Nanjing University, Nanjing 2.0093, china 2. institute of Geology,{2., beijing 100029, china 1. Department of Earth Sciences and State Key Laboratory for Mineral Deposits Research Nanjing University 210093 Nanjing China 2. institute of Geology China Seismological Bureau 100029 Beijing China

Panzhihua-Xichang (Panxi) micro-palaeoland is the oldest terrane on the western margin of the Yangtze Block. Some intermediate-basic granulites are considered to be the crys-talline basement of lower crust in the terrane. Granulite-facies metamorphism of the granulites was developed in the period from 1186 Ma to 112. Ma. The origin of granulites was related to the collision orogenic process occurring when the micro-palaeolands merged to form the Rodinia Supercontinent. Amphibolite-facies retrogressive metamorphism of granulites took place in the period from 877 Ma to 82. Ma. This period was consistent with the breakup time of the Rodinia Supercontinent. 40Ar/39Ar ages and fission track (FT) ages of granulites in the Panxi mi-cro-palaeoland show that the vertical movement history of crustal rocks was a slow uplift process of the rigid terrane in the time from Neoproterozoic to Mesozoic. The subduction of India Plate towards Euroasia Plate resulted in the rapid uplift of the Qinghai-Tibetan Block in Cenozoic. Meanwhile, the Qinghai-Tibetan Block moved towards east. Consequently the Panxi terrane was uplifted rapidly. As a result of the collision orogeny between the Qinghai-Tibetan Block and the Panxi terrane, the granulite-facies crystalline basement in this region was exhumed and exposed to the surface.

关键词： granulite,isotope geochronology,crustal uplift movement,Panzhihua-Xichang region,western margin of Yangtze Block.

Si-and alkali-rich melt inclusions in minerals of mantle peridotites from eastern china:Implication for lithospheric evolution

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Science china Earth Sciences 2006年第1期49卷 43-49页

作者： FAN Qicheng1, SUI Jianli2. XU Ping2. LI Ni1, SUN Qian1 & WANG Tuanhua1 1. institute of Geology, china seismological bureau,{2., china 2. institute of Geology and Geophysics, Chinese Academy of Sciences,{2., china 1. institute of Geology China Seismological Bureau Beijing 100029 China 2. institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China

Minerals of spinel- and garnet-facies mantle xenoliths entrained in Cenozoicbasalts from eastern china (North china, Northeastern china and Southeastern china coastal area)contains lots of melt inclusions. Studies on these melt inclusions show that the glass inclusionsare rich in SiO_2.(60%—68%) and alkalis (K_2.+Na_2. = 5%—11%, especially for K_2.) as well asvolatiles such as H_2. and CO_2.(2.—7%), which belong to dacites and andesites of the high-K calcicalkali series rocks with few shoshonites. High Al and Ca diopside in melt inclusion is the productof melt crystallization at high temperature and pressure, rather than the product ofdevitrification. Results show that these K-rich (in general K_2. > 3%) intermediate-acidic silicatemelt inclusions have characteristics of continent without a genetical link to host basalts and theirphenocrystic minerals. Thus, these trapped melt inclusions represent melts of Mesozoic lithosphericmantle-crust interaction and imply that the continental lithospheric mantle beneath eastern chinahad undergone fragmentation and recreation processes during the Mesozoic and Cenozoic periods. Thisresult undoubtly provides important implication for the evolution of sub-continental lithospherebeneath eastern china. We propose that these Si- and alkalis-rich melts should be responsible forthe mantle chemical heterogeneity underneath eastern china.

关键词： Si- and alkali-rich melt inclusion, mantle peridotite, lithospheric evolution, eastern china.

Research progress in synthesis and catalysis of polyoxometalates

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Progress in Natural Science:Materials International 2005年第5期15卷 385-394页

作者： GONG Yun1, HU Changwen1* and LIANG Hong2.1. Department of Chemistry, School of Science, the institute for Chemical Physics, beijing institute of Technology, beijing 100081, china 2. Chemical Industry Press, beijing 100029, china) Department of Chemistry School of Science the Institute for Chemical Physics Beijing Institute of Technology Beijing 100081 China Chemical Industry Press Beijing 100029 China

Recent progress in the synthetic chemistry and catalysis of polyoxometalates (POMs) is reviewed. The novel POMs and their derivatives emerging in nearly three years (2.02.2.04) are introduced, including POMs with novel structure, POMs-organic hybrid compounds and host-guest complexes. Our review is focused on the elaboration of POMs' supramolecular chemistry.

关键词： polyoxometalates hybrid host-guest structure supramolecule catalysis.

Mineralogy and crystal structure determination of Mg-fillowite

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Science china Earth Sciences 2005年第5期48卷 635-646页

作者： MA Zhesheng 1 , SHI Nicheng 1 & YE Danian 2.1. china University of Geosciences, beijing 100083, china 2. institute of Geology, Chinese Academy of Sciences, beijing 100029, china 1. china University of Geosciences 100083 Beijing China 2. institute of Geology Chinese Academy of Sciences 100029 Beijing China

Accurate crystal structure determination of complex phosphate Mg-fillowite ? Na2.a(Mn4Mg2.e)7[PO4]6 has been finished. Mg-fillowite occurs in muscovite-pegmatite in the Altay area, Xinjiang, china. It is of the trigonal lattice, with space group R-3, unit cell a=1.5143(3) nm, c=4.3191(2. nm, V=8.5736 nm3, Z = 18. The R-factor of the determination accuracy is R (I > 2. ( I )) = 0.0776. The cationic polyhedra consist of two kinds of structural units: compound col- umn and screw column. In three-dimensional space, they are linked with each other through corner sharing or edge sharing to build the entire structure. There are 45 atoms in an asymmetric unit and 72. atoms in a unit cell. In terms of types and connection manners of the coordination polyhedra, the degree of complicity is rarely seen in all mineral crystal structures. Study of such a structure is significant for the classification of phosphate and the building rule of coordination polyhedra in a complex crystal structure.

关键词： Mg-fillowite, complex phosphate, crystal structure, coordination polyhedron.

Comparison of eastern paleo-Tethyan ophiolites and its geodynamic significance--Evidence from Dur'ngoi ophiolite

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Science china Earth Sciences 2004年第4期47卷 378-384页

作者： CHEN Liang1,2. SUN Yong1,2. PEI Xianzhi2. Feng Tao2.& Zhang Guowei2.1. Open Laboratory of Continental Dynamics, Ministry of Education, Northwest University, Xi抋n 710069, china 2. institute of Geology and Geophysics, Chinese Academy of Sciences,{2., china Open Laboratory of Continental Dynamics Ministry of Education Northwest University Xi’an 710069 China institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China

Nd-Pb isotopic geochemistry of metabasalt from Dur抧goi ophiolite, Qinghai Prov-ince, NW china reveals the presence of DMM mixing with EMII components in its upper mantle source, which is comparable with present Indian MORB. Comparisons indicate that the geo-chemistry, chronology and source characteristics of Dur抧goi ophiolite coincide with Pa-leo-tethyan ophiolites from 揝anjiang?area. Together with evidences from regional geology in adjacent areas, this study proves that independent paleo-tethyan basins evolved contemporarily, the dynamics of which is attributed to the interaction of mantle plume with over-riding lithosphere.

关键词： ophiolite, Paleo-Tethys, DUPAL anomaly, Indosinian movement.

A circum-earth shear zone at low-latitudes and episodic large earthquakes in it and the circum-Pacific seismic zone

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Science china Earth Sciences 2006年第9期49卷 897-903页

作者： MA Zongjin1, DU Pinren1, REN Jinwei2.& GAO Xianglin1 1. institute of Geology, china Earthquake Administration,{2., china 2. institute of Earthquake Science, china Earthquake Administration, beijing 100036, china 1. institute of Geology China Earthquake Administration Beijing 100029 China 2. institute of Earthquake Science China Earthquake Administration Beijing 100036 China

Because of the differential motions between the Northern and Southern Hemispheres of the Earth, there exists a motion discordant zone between them. On the surface this zone consists of 13 large faults dominant with strike-slip. We call it a global shear zone at low-latitudes (E system). By statistical analysis of temporal distribution of earthquakes Mw≥7.5 in the E system and the circum-Pacific (P system) during 1900―2.03, we find that there exist quasi-episodic and alternative activities in and between these two systems. This phenomenon is likely associated with the half-sphere oscillation in dilation and contraction and the change of the Earth’s rotation rate.

关键词： shear zone, circum-Pacific zone, great earthquake, quasi-episode.

Adjoint method for the optimum planning of industrial pollutant sources

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Science china Earth Sciences 2005年第8期48卷 1270-1279页

作者： LIU Feng1,2. HU Fei2.& ZHU Jiang2.1. College of Environmental Sciences, Peking University, beijing 100871, china 2. LAPC, {2. of Atmospheric Physics, Chinese Academy of Sciences, beijing 100029, china 1. College of Environmental Sciences Peking University 100871 Beijing China 2. LAPC Institute of Atmospheric Physics Chinese Academy of Sciences 100029 Beijing China

The optimum planning of industrial pollutant sources, which optimizes the economic object without violating environmental constraints, is an important and hard task to be conquered. In this paper, an adjoint method is developed to solve the problem. The penalty function is in-troduced to deal with the environmental inequality constraints, and Lagrange function is con-structed to derive the adjoint equation and the gradient of the object function. In this means, the gradient of the object function can be calculated by solving the adjoint equation, and the infor-mation from the gradient is used to make the object function descend and approach to an optimal solution after some iterations. A two-dimensional, simplified model is used for numerical experi-ments. The theoretical derivations are verified by the results of the experiments. Furthermore, the adjoint method is shown to be of excellent convergence and efficiency, which is adaptive to the fast development of air quality numerical models and super computers.

关键词： optimum planning, industrial pollutant sources, adjoint equation, penalty function, gradient.

Crustal structure of Gondwana-and Yangtze-typed blocks:An example by wide-angle seismic profile from Menglian to Malong in western Yunnan

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Science china Earth Sciences 2005年第11期48卷 1828-1836页

作者： ZHANG Zhongjie1, BAI Zhiming1, WANG Chunyong2. TENG Jiwen1, Lü Qingtian3, LI Jiliang1, SUN Shanxue1 & WANG Xinzheng1 1. institute of Geology and Geophysics, Chinese Academy of Sciences, beijing 100029,{2. 2. institute of Geophysics, Chinese seismological bureau, beijing 100081,{2. 3. institute of Deposition Resource, Chinese Academy of Geological Sciences, beijing 100037,{2. 1. institute of Geology and Geophysics Chinese Academy of Sciences 100029 Beijing China 2. institute of Geophysics Chinese Seismological Bureau 100081 Beijing China 3. institute of Deposition Resource Chinese Academy of Geological Sciences 100037 Beijing China

The wide-angle seismic profile between Menglian and Malong crosses the Baoshan block (Gondwana-typed), and Simao and southwestern Yangtze blocks (Yangtze-typed). By in-terpreting the wide-angle seismic data, we obtained the seismic crust/upper mantle structure of P-wave velocities together with the seismic reflections of these three blocks, Changning- Menglian and Mojiang suture zones among the mentioned three blocks. Our interpreting results demonstrate that the P-wave crustal velocity of Simao block is slower than that of Baoshan and southwestern Yangtze block and the crustal thickness gradually thickens from the Baoshan block, Simao to southwestern Yangtze block. Crustal reflection patterns of these three blocks have dis-tinct differences too. For the Gondwana-typed blocks, seismic reflections in the upper crust are well developed while in middle-lower crust they are very weak. The crustal reflections in the Yangtze block are very well developed. The crustal reflection patterns in Simao and southwest-ern Yangtze blocks are distinguishable. The average thickness of the crust in the studied area is about 40 km. And we make some discussions on the crustal thickening model of the three blocks in western Yunnan and tectonic setting of seismic developing and interaction of Gondwana and Yangtze blocks.

关键词： Gondwana blocks,Yangtze blocks,wide-angle profile,crustal structure,tectonic setting