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Hydrogen isotopic compositions, distributions and source signals of individual n-alkanes for some typical crude oils in Lunnan Oilfield, Tarim Basin, NW china

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Science china Earth sciences 2005年第8期48卷 1220-1226页

作者： LU Hong1, LI Chao1, SUN Yongge1, PENG Ping’an1 & XIAO Zhongyao2.1. State Key Laboratory of Organic geochemistry, guangzhou {2. of geochemistry, chinese academy of sciences, guangzhou510640, china 2. Tarim Research {2. of Exploration and Development of Petroleum, china Petroleum, Korla 841000, china 1. State Key Laboratory of Organic geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences 510640 Guangzhou China 2. Tarim Research institute of Exploration and Development of Petroleum China Petroleum 841000 Korla China

Isotopic compositions of carbon-bound hydrogen in individual n-alkanes from sev-eral typical crude oil samples from Lunnan Oilfield, Tarim Basin, NW china, were firstly measured using newly developed gas chromatography-thermal conversion-isotope ratio mass spectrometry. The similar range of δ D of individual n-alkanes of crude oils among reservoirs of different geo-logical times reflects that hydrocarbons are all derived from the same marine depositional envi-ronment. Compared to the theoretic value (?150‰) and the reported δ D values (nC13―nC2., ?160‰―?90‰) of individual n-alkanes for Ordovician-sourced crude oils in the Canadian Wil-liston Basin, the hydrogen isotopic composition of individual n-alkanes in crude oils from Lunnan Oilfield is characterized by heavy hydrogen isotopic values (nC12.nC2., ?12.‰―?60‰). In terms of the factors that control the fractionation of hydrogen isotopes, relatively saline deposi-tional environment and higher thermal maturation were attributed to the heavy δ D values of in-dividual n-alkanes in crude oils from Lunnan Oilfield.

关键词： hydrogen isotopes, individual n-alkanes, distribution, hydrocarbon source, Lunnan Oilfield.

Arrangement models of alkylammonium cations in the interlayer of HDTMA^+pillared montmorillonites

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chinese Science Bulletin 2003年第4期48卷 368-372页

作者： ZHU Jianxi, HE Hongping, GUO Jiugao, YANG Dan & XIE Xiande guangzhou institute of {2., chinese academy of sciences, guangzhou 510640, china Correspondence should be addressed to He Hongping guangzhou institute of {2. Chinese Academy of Sciences Guangzhou 510640 China

The orientation of HDTMA+ in the interlayer of organic pillared montmorillonites prepared at different concentrations of HDTMA+ have been studied using X-ray powder diffraction (XRD) and theoretical calculation. A series of arrangement models of HDTMA+ in the interlayer of montmorillonite have been proposed as lateral-monolayer (LM), lateral-bilayer (LB), pseudotrilayer (PT), paraf-fin-type-monolayer (PM), paraffin-type-bilayer (PB). With the increase of the concentration of HDTMA+, the arrange-ment model of HDTMA+ in the interlayer of montmorillo-nites changes as lateral-monolayer→lateral-bilayer→para- ffin-type monolayer→pseudotrilayer→paraffin-type-bilayer and the packing density of HDTMA+ in the interlayer in-creases gradually. In the intermediate stages, different mod-els may coexist.

关键词：有机柱形蒙脱土粘土夹层 HDTMA^+ 烷基铵离子排列模式

ABUNDANCE AND DISTRIBUTION OF PLATINUM-GROUP ELEMENTS (PGE) IN PERIDOTITE FROM THE DAGZHUKA OPHIOLITE IN TIBET:IMPLICATIONS FOR MANTLE METASOMATISM

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地学前缘 2000年第S1期7卷 99-100页

作者： Xia Bing 1,2.,Yu Hengxiang 1,Mei Houjun 1,Qi Lang 2.(1 guangzhou institute of {2., chinese academy of sciences, guangzhou 510640, china 2.institute of {2., chinese academy of sciences, Guiyang 550002. china)

Information on abundance and distribution of platinum\|group elements (PGE) in peridotite from ophiolite is relevant to understand the nature and evolution of the upper mantle. The ophiolite suite outcropping along the famous suture zone of Yarlung Zangbo River, Tibet, has attracted wide attention of geologists both in china and abroad. The Dagzhuka ophiolite of in the suture zone is thought to display a complete ophiolitic sequence. The peridotite from the Dazhuka ophiolite is composed of fairly fresh or unaltered lherzolite, harzburgite and minor dunite which are the upper mantle residuum formed by 15%～35% partial melting. In this paper we have mainly studied the abundance and distribution of PGE in the harzburgites and lherzolites. The harzburgites and lherzolites preserve total PGE contents of 2. 37×10 -9 ～50 67×10 -9 respectively higher than Primitive mantle or the peridotite from some typical ophiolites and Alpine. They all have fractionated chondrite\|normalized PGE patterns with positive slopes from Ir to Pd (Fig.1), and Pd/Ir=1 13～2.40>1, Pd/Rh=2.2.～7 49>1, and Pd/Pt=0 2.～1 16 (average 0 67) higher than Primitive mantle (1 11, 2.35, 0 57) or CI\|chondrite (1 01, 2.73, 0 53). Consequently, the Dagzhuka peridotite are PGE\|enriched, but otherwise possess residual characteristics arising from a minimum of 15% partial melting. It is suggested that mantle residuum by partial melting have low total PGE contents, fractionated chondrite\|normalized PGE patterns with negative or slightly flat slopes from Ir to Pd, and Pd/Ir<1. But, the total PGE contents, chondrite\|normalized PGE patterns and Pt/Ir, Pd/Rh and Pd/Pt values of the Dagzhuka peridotite are completely inconsistent with a residual origin. Partial melting would have partitioned all sulfide in the source into the melt. In fact, no sulfide or silicate melt remained in the Dagzhuka peridotite. Therefore, PGE in Dagzhuka peridotite are not present in sulfides. The PGE\|enrichment and fractionation of the Dagz

关键词： platinum\|group elements(PGE) peridotites Dazhuka ophioli te Tibet

Experimental study of ore gabbro liquid immiscibility

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Science china Earth sciences 2005年第4期48卷 496-505页

作者： SANG Zunan1,2. XIA Bin1, ZHOU Yongsheng3 & JIN Zhenmin4 1. guangzhou institute of {2., chinese academy of sciences, guangzhou 510640, china 2. Wuhan University, Wuhan 430072. china 3. institute of Geology, china Seismological Bureau, Beijing 10002., china 4. Faculty of Earth sciences, china University of Geosciences, Wuhan 430074, china 1. guangzhou institute of {2. Chinese Academy of Sciences 510640 Guangzhou China 2. Wuhan University 430072 Wuhan China 3. institute of Geology China Seismological Bureau 100029 Beijing China 4. Faculty of Earth sciences China University of Geosciences 430074 Wuhan China

In this paper, the authors present the results of a preliminary experimental study on partial melting of fine-grained gabbro, Panzhihua, Sichuan Province, china. Experiments were conducted under (confining) pressure ranging from 450 to 500 MPa and temperature of 900— 12.0℃. The results show that the initial melt is distributed along grain boundaries and triple junctions. Liquid immiscibility phenomena are noted in the melt with two compositional different melt phases, i.e. matrix and sphere phases. The matrix phase is relatively rich in Si, Al and K, and is depleted in Mg, Fe, Ca, Na and Ti, whereas the sphere phase shows opposite trends. The calculation of the melt free energy indicates that the liquid immiscibility is governed by the rule of thermodynamics, as the liquid immiscibility would result in the decrease in free energy of the melt system. The field relationships suggest that the liquid immiscibility may have played an important role in the generation of ore magma of Panzhihua V-Ti magnetite ore deposit. This study thus provides experimental constraints on the mechanism of the formation of V-Ti magnetite deposite.

关键词： partial melting, experimental study, gabbro, liquid immiscibility, ore formation mechanism.

Ecology of the rehabilitation of vegetation on tropical coastal eroded land in Guangdong， china

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Journal of Environmental sciences 1995年第1期7卷 74-84页

作者： Yu Zuoyue Wang Zhuhao South china institute of Botany,{2.,guangzhou 510650,china South china Inst of Botany Chinese Academy of Science Guangzhou China

ＥｃｏｌｏｇｙｏｆｔｈｅｒｅｈａｂｉｌｉｔａｔｉｏｎｏｆｖｅｇｅｔａｔｉｏｎｏｎｔｒｏｐｉｃａｌｃｏａｓｔａｌｅｒｏｄｅｄｌａｎｄｉｎＧｕａｎｇｄｏｎｇ，ＣｈｉｎａＹｕＺｕｏｙｕｅ；ＷａｎｇＺｈｕｈａｏＳｏｕｔｈＣｈ... 详细信息

ＥｃｏｌｏｇｙｏｆｔｈｅｒｅｈａｂｉｌｉｔａｔｉｏｎｏｆｖｅｇｅｔａｔｉｏｎｏｎｔｒｏｐｉｃａｌｃｏａｓｔａｌｅｒｏｄｅｄｌａｎｄｉｎＧｕａｎｇｄｏｎｇ，ＣｈｉｎａＹｕＺｕｏｙｕｅ；ＷａｎｇＺｈｕｈａｏＳｏｕｔｈＣｈｉｎａＩｎｓｔｉｔｕｔｅｏｆＢｏｔ...

关键词： tropics ereded land ecology of vegetation recovery.

Subsolidus phase relations in the system MgO-ZnO-SiO_2.at high pressure

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chinese Science Bulletin 1999年第12期44卷 1146-1149页

作者： LI Jianping, Jacques Kornprobst Didier Laporte guangzhou institute of {2. , chinese academy of sciences , guangzhou 510640, china Departement des sciences de la Terre, University Blasie Pascal, 630038 Clermont-Ferrand, France guangzhou institute of {2. Chinese Academy of Sciences Guangzhou China Département des sciences de la Terre Université Blasie Pascal Clermont-Ferrand France

The subsolidus phase relations were determined experimentally in the system MgO-ZnO-SiO2.at 1.0 GPa and 1 2.0℃, by use of the high-pressure apparatus "piston-cylinder". The results showed characteristics of the phases assemblage different from that in similar ternary systems. It is impossible to form complete Mg2.iO4-Zn2.iO4 olivine and Mg2.i2.6-Zn2.i2.6 pyroxene solid solution. This is controlled by the properties of Zn2. with an outer layer of electron (Ar)3d10, different from others transition metal ions, like Fe2. , Ni2. , Co2. .

关键词： high pressure MgO-ZnO-SiO2 system subsolidus phase relation.

Summary of the 11th Conference on Magnetic Confined Fusion Theory and Simulation

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Plasma Science and Technology 2024年第10期26卷 1-7页

作者： guangzhou HAO Jianqiang XU Youwen SUN Zhibin GUO Organizing Committee of the 11th Conference on Magnetic Confined Fusion Theory and Simulation Southwestern institute of Physics Chengdu 610041People’s Republic of China institute of Plasma Physics Hefei Institutes of Physical ScienceChinese Academy of SciencesHefei 230031People’s Republic of China State Key Laboratory of Nuclear Physics and Technology Fusion Simulation CenterSchool of PhysicsPeking UniversityBeijing 100871People’s Republic of China 不详

This conference report summarizes recent progress in plasma theory and simulation that was presented in contributed papers and discussions at the 11th Conference on Magnetic Confined Fusion Theory and Simulation(CMCFTS)held in Chengdu,china,2.–30 October,*** in various fields has been *** example,results on zonal flow generation by mode coupling,simulations of the key physics of divertor detachment,energetic particle effects on magnetohydrodynamic(MHD)modes in addition to ion-and electron-scale turbulence,physics of edge coherent modes and edge-localized modes,and the optimization of ion heating schemes as well as confinement scenarios using advanced integrated modeling are presented at the *** this conference,the scientific research groups were organized into six categories:(a)edge and divertor physics;(b)impurity,heating,and current drive;(c)energetic particle physics;(d)turbulent transport;(e)MHD instability;and(f)integrated modeling and code development.A summary of the highlighted progress in these working groups is presented.

关键词： magnetic confined fusion(MCF) theory and simulation modeling tokamak

TWO TYPES OF CENOZOIC HIGH-K MAGMATINSM IN EASTERN TIBET:IMPLICATIONS FOR THE NATURE OF MANTLE SOURCES

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地学前缘 2000年第S1期7卷 295-296页

作者： Wang Jianghai, Xie Guanghong[WT5,5”BX](guangzhou institute of {2., chinese academy of sciences, Wushan, guangzhou 510640, china)

Cenozoic high\|K igneous rocks are widely distributed in eastern Tibet. These rocks are exposed as flows, dykes and small intrusions along a narrow north\|south trending zone, which follows Tertiary fold belts and the Batang—Lijiang and Ailao Shan—Red River strike\|slip systems. Although several models were proposed to interpret their petrogenesis (Deng, 1989; Arnaud et al., 1991; Turner et al., 1996; Yin et al., 1995; Miller et al., 1999), their origin still remains hotly debated. Moreover, the published results were only focused on the high\|K igneous rocks resulted from partial melting of an enriched lithospheric mantle. Here, we present the detailed documents to testify the existence of a new kind of high\|K igneous rocks in eastern *** new 39 Ar/ 40 Ar age data (Wang et al., 1999) and published age data for high\|K rocks in eastern Tibet show two distinctive magmatic episodes: one between 42.a and 2.Ma, and the other since ca.16Ma. They correspond to two types of high\|K magmatism in eastern Tibet. We name the older and younger groups as types Ⅰ and Ⅱ, respectively.

关键词： Cenozoic high\|K magmatism enriched and depleted mantle sour ce Pb\|Sr\|Nd isotopes transpressional and transtensional tectonics Eastern T ibet

Discovery of seep carbonate nodules as new evidence for gas venting on the northern continental slope of South china Sea

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chinese Science Bulletin 2006年第10期51卷 1228-1237页

作者： CHEN Zhong1,2.3, YAN Wen1,2.3, CHEN Muhong1,3, WANG Shuhong1,2.3, LU Jun1,3, ZHANG Fan1,3, XIANG Rong1,3, XIAO Shangbin1,3, YAN Pin1,2.3 & GU Senchang1,2.3 1. South china Sea institute of Oceanology, {2. academy of Sci-ences, guangzhou 510301, china 2. guangzhou Center for Gas Hydrate Research, chinese academy of sciences, guangzhou 510301, china 3. Key Laboratory of Marginal Sea Geology, South china Sea institute of Oceanology and guangzhou institute of geochemistry, chinese academy of sciences, guangzhou 510301, china South china Sea institute of Oceanology Chinese Academy of Science Guangzhou China guangzhou Center for Gas Hydrate Research Chinese Academy of Sciences Guanzhou China Key Laboratory of Marginal Sea Geology South China Sea Institute of Oceanology and Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China

Seep carbonate nodules were firstlycollected from the southwestern Dongsha area onnorthern continental slope of South china Sea formineralogical and geochemical studies. The resultsof X-ray diffraction show that carbonate nodules arecomposed of Fe-rich domolite,siderite and a few cal-cite and aragonite, as well as a small quantity ofnon-carbonate minerals such as goethite, quartz andclay minerals. Fe-rich dolomite and siderite charac-terized by euhedral microcrystalline structure weredirectly precipitated at cold seeps. The δ 13C valuesfor Fe-rich dolomite and siderite in the bulk nodulesvary from ?18.2.‰ to ?36.07‰, and the δ 18O valuesrange from 0.42.to 2.76‰. Their moderate depleted13C reflects that carbon origin is possibly thermoge- netic gas or mixed gas, which is evidence of gasventings in the seafloor. Moreover, massive wormtube fossils related to cold seeps were found on thesurfaces of carbonate nodules, and the conduitsand/or channels in semi-solidified nodules whichwere not filled by carbonate or sediment were alsoobserved. A preliminary conclusion is that activemicro gas venting with a conduit/channel diameterrange from 2.0 μm to 600 μm possibly exists inmodern seafloor of the carbonate nodule area.

关键词：渗出碳酸盐节碳氧同位素甲烷渗漏天然气水化物