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Preparation and characterization of a novel adsorbent for removing lipophilic organic from water

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Science china Chemistry 2005年第6期48卷 600-604页

作者： LIU Huijuan1, DAI Ruihua1, QU Jiuhui1 & RU Jia1,2.1. State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental sciences, chinese Academy of sciences, beijing 100085, china 2. graduate school of the chinese Academy of sciences, beijing 10003.. china 1. State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental Sciences Chinese Academy of Sciences 100085 Beijing China 2. graduate school of the {2. Academy of sciences 100039 Beijing China

A novel composite adsorbent containing a kind of lipid-triolein is studied. The ad-sorbent is prepared by embedding triolein into cellulose acetate (CA) sphere. The preparation method, the physical-chemical properties of the adsorbent and the removal efficiency of two or-ganochlorinated pesticides are studied. The adsorbent is stable in water and no triolein leaks into water for 465 h soaking. The adsorbent has high adsorption capacity for organochlorinated pes-ticides such as dieldrin and aldrin. The results suggest that triolein-containing adsorbent could serve as a good adsorbent for lipophilic organic pollutants. The adsorption rate for lipophilic pol-lutants is very fast and has relation with the logKow of the compounds.

关键词： triolein, cellulose acetate, adsorbent, lipophilic organic, drinking water.

Experimental investigation and numerical simulation on the effect of fissure water pressure in vertical sliding surface

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Science china(Technological sciences) 2005年第z1期48卷 53-64页

作者： ZHANG Lei1,2. LI Shihai1, LIAN Zhenzhong1,2.& WANG Yuannian1 1. Institute of Mechanics, chinese Academy of sciences, {2. 100080, china 2. graduate school, chinese Academy of sciences, {2. 100060, china 1. Institute of Mechanics Chinese Academy of Sciences 100080 Beijing China 2. graduate school Chinese Academy of Sciences 100060 Beijing China

This paper studies the effect of fissure water pressure in different fractures on the critical angle of landslide by laboratory investigation and numerical simulation in order to understand the mechanisms of fissure water pressure on landslide stability. Laboratory observations show that the effect of fissure water pressure on the critical angle of landslide is little when the distance between water-holding fracture and slope toe is three times greater than the depth of fissure water. These experimental results are also simulated by a three-dimensional face-to-face contact discrete element method. This method has included the fissure water pressure and can accurately calculate the critical angle of jointed slope when fissure water pressure in vertical sliding surface exists. Numerical results are in good agreement with experimental observations. It is revealed that the location of water-holding structural surface is important to landslide stability. The ratio of the distance between water-holding fissure and slope toe to the depth of fissure water is a key parameter to justify the effect of fissure water pressure on the critical angle of landslide.

关键词： jointed rock slope, discrete element method, fracture in vertical sliding surface, model experiment,fissure water pressure.

Effect of concentration on surfactant micelle shapes——A molecular dynamics study

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Science china Chemistry 2005年第5期48卷 470-475页

作者： GAO Jian1,2. GE Wei1 & LI Jinghai1 1. Multiphase Reaction Laboratory, Institute of Process Engineering, chinese Academy of sciences, {2. 100080, china 2. graduate school of The chinese Academy of sciences, {2. 100085, china 1. Multiphase Reaction Laboratory Institute of Process Engineering Chinese Academy of Sciences 100080 Beijing China 2. graduate school of The {2. Academy of sciences 100085 Beijing China

Many aspects of the behavior of surfactants have not been well understood due to the coupling of many different mechanisms. Computer simulation is, therefore, attractive in the sense that it can explore the effect of different mechanisms separately. In this paper, the shapes, structures and sizes of sodium dodecylbenzenesulfonate (SDBS) micelles under different con-centrations in an oil/water mixture were studied via molecular dynamics (MD) simulations using a simplified atomistic model which basically maintains the hydrophile and lipophile properties of the surfactant molecules. Above the critical micellar concentration (cmc), surfactant molecules ag-gregate spontaneously to form a wide variety of assemblies, from spherical to rodlike, wormlike and bilayer micelles. Changes in their ratios of the principle moments of inertia (g1/g3, g2.g3) in-dicated the transition of micelle shapes at different concentrations. The aggregation number of micelle is found to have a power-law dependence on surfactant concentration.

关键词： surfactant, MD simulation, sodium dodecylbenzenesulfonate, micelle shape.

A new principle of synthetic cascade utilization of chemical energy and physical energy

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Science china(Technological sciences) 2005年第2期48卷 163-179页

作者： JIN Hongguang1, HONG Hui1,2. WANG Baoqun1,2. HAN Wei1,2.& LIN Rumou1,2.1. Institute of Engineering Thermophysics, chinese Academy of sciences, {2. 100080, china 2. graduate school of the chinese Academy of sciences, beijing 10003.. china 1. Institute of Engineering Thermophysics Chinese Academy of Sciences 100080 Beijing China 2. graduate school of the {2. Academy of sciences 100039 Beijing China

We propose a new principle of the cascade utilization of both chemical energy and physical energy in energy systems with the integration of chemical processes and thermal cycles. Particularly, a general equation of energy levels of substance, Gibbs free energy of chemical reaction and physical energy is explicitly founded. On the basis of this equation, a chemical-looping combustion and an indirect combustion are investigated. Furthermore, a mechanism of energy release, with the combination of decreasing the energy level of Gibbs free energy and upgrading the energy level of low or middle- temperature thermal energy, is clarified. The promising results obtained here establish a theoretical basis for the further investigation of multi-function systems in which energy and the environment are compatible, and create a new approach to improve the performance of traditional thermal cycles.

关键词： chemical energy, cascade utilization, exergy, energy conversion.

Estimation on dynamic release of phosphorus from wind-induced suspended particulate matter in Lake Taihu

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Science china Earth sciences 2004年第8期47卷 710-719页

作者： FAN Chengxin1, ZHANG Lu1,2. QIN Boqiang1, WANG Sumin1, HU Weiping1 & ZHANG Chen1 1. Taihu Lake Laboratory for Ecosystem Research, Nanjing Institute of Geography & Limnology, chinese Academy of sciences, Nanjing 2.0008, {2. 2. graduate school of chinese Academy of sciences, beijing 10003.. china 1. Taihu Lake Laboratory for Ecosystem Research Nanjing Institute of Geography & Limnology Chinese Academy of Sciences 210008 Nanjing China 2. graduate school of {2. Academy of sciences 100039 Beijing China

Through man-made disturbance experiments, the corresponding relationships be-tween suspended particulate matter (SPM) and wind speed in different lake areas were simu-lated, the physicochemical formal transformation and biological mineralizing and decaying processes of phosphorus in SPM were studied, the contribution of phosphorus transformation to phosphorus loading of the water of Lake Taihu was quantitatively estimated. The results show that about 0.44 t·a-1 loading in Lake Taihu mainly comes from phosphorus-releasing action of SPM in physicochemical transformed to soluble reactive phosphorus (SRP), and the contribution mainly from biological mineralizing and decaying was about 42..8 t·a-1, which is equal to 15.0% of the total external loading of Lake Taihu, namely 4.7—7.5 times as much as SRP loading en-tering the lake by the rivers; thus it is the important source in dynamical internal loading of the lake. The determining factors for dynamical internal loading in lakes are organic phosphorus content in suspended solid and its biological transition availability.

关键词： phosphorus release,wind wave disturbance,particulate decaying,dynamical loading,Lake Taihu.

A subsurface runoff parameterization with water storage and recharge based on the Boussinesq-Storage Equation for a Land Surface Model

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Science china Earth sciences 2006年第6期49卷 622-631页

作者： TIAN Xiangjun1,2. XIE Zhenghui1, ZHANG Shenglei1 & LIANG Miaoling1 1. LASG, Institute of Atmospheric Physics, chinese Academy of sciences, {2. 10002., china 2. graduate school of the chinese Academy of sciences, beijing 10003.. china 1. LASG Institute of Atmospheric Physics Chinese Academy of Sciences Beijing 100029 China 2. graduate school of the {2. Academy of sciences Beijing 100039 China

Subsurface runoff in a land surface model is usually parameterized as a single-valued function of total storage in a basin aquifer reservoir. This kind of parameterization is often sin-gle-valued function of storage-discharge under a steady or “quasi-steady” state, which cannot rep-resent the influence of aquifer recharge on subsurface runoff generation. In this paper, a new sub-surface runoff parameterization with water storage and recharge based on the Boussinesq-storage equation is developed. This model is validated by a subsurface flow separation algorithm for an ex-ample river basin, which shows that the new model can simulate the subsurface flow reasonably.

关键词： Zsubsurface runoff parameterization Boussinesq-storage equation waterstorage and recharge

Infrared Galaxies in the Nearby Universe

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chinese Journal of Astronomy and Astrophysics 2008年第6期8卷 643-652页

作者： Jian-Ling Wang 1 National Astronomical Observatories,chinese Academy of sciences,{2. 100012.china 2.graduate school of chinese Academy of sciences,{2. 100049,china National Astronomical Observatories Chinese Academy of Sciences Beijing 100012 China graduate school of {2. Academy of sciences Beijing 100049 China

We used the Sloan Digital Sky Survey （SDSS） Data Release 5 （DR5） to study the morphological properties of 1137 nearby infrared （IR） galaxies, most of which are brighter than 15.9 mag in r-band. This sample was drawn from a cross-correlation of the Infra-Red Astronomical Satellite （IRAS） point source catalog redshift survey with DR5 at z ≤ 0.08. Based on this IR galaxy sample, we constructed five volume-limited sub-samples with IR luminosity ranging from 10^9.5 L⊙ to 10^12.⊙. By deriving the IR luminosity functions （LF） for different morphological types, we found that normal spiral galaxies are the dominant population below LIR ~ 8 ~ 10^10 L⊙; while the fraction of barred spiral galaxies increases with increasing IR luminosity and becomes dominant in spiral galaxies beyond LIR ≈ 5 × 10^10L⊙. As the IR luminosity decreases, the IR galaxies become more compact and have lower stellar masses. The analysis also shows that normal spiral galaxies give the dominant contribution to the total comoving IR energy density in the nearby universe, while, in contrast, the contribution from peculiar galaxies is only 39%.

关键词： galaxies evolution galaxies interactions galaxies starburst infrared galaxies galaxies luminosity function

Research on the method for retrieving soil moisture using thermal inertia model

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Science china Earth sciences 2006年第5期49卷 539-545页

作者： LIU Zhenhua1 & ZHAO Yingshi2.1. Information College, South china Agricultural University, Guangzhou 510642. china 2. {2. University of chinese Academy of sciences, beijing 100049, china 1. Information College South China Agricultural University Guangzhou 510642 China 2. graduate University of chinese Academy of {2. Beijing 100049 China

In order to improve accuracy of soil moisture inversion using remote sensing, a new thermal inertia model is proposed in this paper. The improved model needs only surface maximum temperature as the temperature parameter input instead of input of the surface temperature difference, as well as the surface sensible and latent fluxes are introduced into boundary conditions of thermal conductivity equation. Furthermore, surface soil conductive heat transfer equation of two-layer model is used to solve the soil thermal inertia so that the remote sensing thermal inertia method can be ap- plied to regions with better-covered vegetation, but usually only for the bare areas or worse vegetation covered areas. The model has been tested at several locations in the area of west Inner Mongolia. Comparing the simulation of the new model with the measurements obtained by apparent thermal inertia and by field test, the result shows that the inertia thermal model can be used to estimate soil moisture in more reasonable accuracy.

关键词： thermal model, thermal conductivity equation, soil initial, sensible flux, latent flux, two-layer model.

Evaluation of the Interfacial Adhesion between Brittle Coating and Ductile Substrate by Cross-Sectional Indention

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材料热处理学报 2004年第5B期25卷 1187-1190页

作者： SUJian-yu ZHANGKun CHENGuang-nan InstituteofMechanics ChineseAcademyofSciencesBeijingChina／／GraduateSchooloftheChineseAcademyofSciencesBeijingChina InstituteofMechanics ChineseAcademyofSciencesBeijingChina

The cross-sectional indentation method is extended to evaluate the interfacial adhesion between brittle coating and ductile substrate. The experimental results on electroplated chromium coating/steel substrate show that the interfacial separation occurs due to the edge chipping of brittle coating. The corresponding models are established to elucidate interfacial separation processes. This work further highlights the advantages and potential of this novel indentation method.

关键词：分界面附着刻痕可锻衬底应力涂层铬钢