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The study of two-color excitation upconversion of Pr(0.5)Yb(3):ZBLAN

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Science china(Physics,Mechanics & Astronomy) 2006年第2期49卷 169-177页

作者： CHEN Xiaobo1 & SONG Zengfu2.1. Applied Optics beijing Area Major Laboratory, Analysis and testing center, beijing Normal University, beijing 100875, china 2. Peking University, Physics school, beijing 100871, china Applied Optics beijing Area Major Laboratory Analysis testing center Beijing Normal University Beijing 100875 China Physics school Peking University Beijing 100871 China

The excited state absorption upconversion of Pr(0.5)Yb(3):ZBLAN glass material, under two-color excitation of the 960 nm semiconductor laser and the Xe lamp light simultaneously, is reported in this article. It was found that the upconversion emission spectra of 480.1, 519.0, 601.9 and 631.8 nm coincide with the common emission spectra. Meanwhile, the upconversion-excitation spectrum has three obvious peaks under two-color excitation, and they respectively correspond to the 856.0 nm upconversion ex-citation transition [1G4(Pr3+)→1I6(Pr3+) and 1G4(Pr3+)→3P1(Pr3+)], the 789.0 nm upconver-sion excitation transition 1G4(Pr3+)→3P2.Pr3+), and the 803.7 nm upconversion excitation transition 3H6(Pr3+)→1D2.Pr3+). The upconversion excitation transition 1G4(Pr3+)→1I6(Pr3+) is strong because its oscillator strength f = 2..040×10?6 is large, which results in a large peak appearing in the upconversion excitation spectrum. That is just the new interesting two-color excitation upconversion luminescence phenomenon of Pr(0.5)Yb(3):ZBLAN induced by one laser and one continuous normal light simultaneously.

关键词： upconversion volumetric three-dimensional display two-color excitation.

Geographical Agglomeration of chinese Manufacturing Industries

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中国人口·资源与环境：英文版 2007年第2期5卷 3-11页

作者： Zhang Hua 1, 2. Zheng Wei3 1. Institute of Geographical Sciences and Natural Resources Research, chinese Academy of Sciences, beijing 100101,{2. 2. graduate school of the chinese Academy of Sciences, beijing 100039,{2. 3. school of Geography, beijing Normal University, beijing 100875,{2. Institute of Geographical Sciences and Natural Resources Research Chinese Academy of Sciences Beijing 100101 China graduate school of the {2. Academy of Sciences Beijing 100039 China school of Geography Beijing Normal University Beijing 100875 China

Based on the plant level data from the First National Census of Basic Units, the Second National Census of Basic Units, and the First National Economic Census of china, this paper ex- amines the geographical agglomeration of chinese manufacturing industries at a more disaggregated level both by industrial classi-fication and spatial unit analysis. Applying the agglomeration index proposed by Maurel and Sedillot, studies show that the most agglomerated industries are resource-intensive, and capital and technology intensive while industries demanding localized inputs or serving localized markets or favored by local governments are fairly dispersed. The more disaggregated industries are more spa- tially agglomerated. At the finer spatial scale, industries are more dispersed. Results indicate that within-county spillovers are stronger than nearby-county spillovers, and within-prefecture spillovers are stronger than nearby prefecture spillovers. Local- ized spillovers are still quite substantial at a range beyond that of counties. Comparing the agglomeration index of chinese manu- facturing industries in 1996, 2.01 and 2.04, agglomeration seems to be a general tendency. Results also indicate that some industries have experienced remarkable changes in their levels of agglom- eration in the period 1996–2.04.

关键词： industrial agglomeration manufacturing industries the MS index

A new DNA algorithm to solve graph coloring problem

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Progress in Natural Science:Materials International 2007年第6期17卷 733-738页

作者： Jiang Xingpeng1, Li Yin2. Meng Ya3 and Meng Dazhi2.1. National Laboratory of Pattern Recognition,Institute of Automation, chinese Academy of Sciences, beijing 100080,{2. 2. College of Applied Sciences, beijing University of Technology, beijing 10002.,{2. 3. school of Science, beijing Institute of Technology, beijing 100081,{2.) National Laboratory of Pattern Recognition Institute of Automation Chinese Academy of Sciences Beijing 100080 China College of Applied Sciences Beijing University of Technology Beijing 100022 China school of Science Beijing Institute of Technology Beijing 100081 China

Using a small quantity of DNA molecules and little experimental time to solve complex problems successfully is a goal of DNA computing. Some NP-hard problems have been solved by DNA computing with lower time complexity than conventional computing. However, this advantage often brings higher space complexity and needs a large number of DNA encoding molecules. One example is graph coloring problem. Current DNA algorithms need exponentially increasing DNA encoding strands with the growing of problem size. Here we propose a new DNA algorithm of graph coloring problem based on the proof of four-color theorem. This algorithm has good properties of needing a relatively small number of operations in polynomial time and needing a small number of DNA encoding molecules (we need only 6R DNA encoding molecules if the number of regions in a graph is R).

关键词： DNA computing NP-hard problem graph coloring problem.

Kinetics and reaction mechanism of phenol hydroxylation catalyzed by La-Cu_4FeAlCO_3

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Science china Chemistry 2005年第6期48卷 530-537页

作者： CHEN Chunxia1,2. XU Chenghua1, FENG Liangrong1, SUO Jishuan1 & QIU Fali1 1. Chengdu Institute of Organic Chemistry, chinese Academy of Sciences, Chengdu 610041, china 2. {2. school of the chinese Academy of Sciences, beijing 100039, china 1. Chengdu Institute of Organic Chemistry Chinese Academy of Sciences 610041 Chengdu China 2. graduate school of the {2. Academy of Sciences 100039 Beijing China

The present work synthesizes La-Cu4FeAlCO3 catalyst under microwave irradiation and characterizes its structure using XRD and IR techniques. The results show that the obtained La-Cu4FeAlCO3 has a hydrotalcite structure. In the phenol hydroxylation with H2.2.catalyzed by La-Cu4FeAlCO3, the effects of reaction time and phenol/H2.2.molar ratio on the phenol hy-droxylation, and relationships between the initial hydroxylation rate with concentration of the catalyst, phenol, H2.2.and reaction temperature are also investigated in details. It is shown the phenol conversion can reach 50.09% (mol percent) in the phenol hydroxylation catalyzed by La-Cu4FeAlCO3, under the reaction conditions of the molar ratio of phenol/H2.2.1/2. the amount ratio of phenol/catalyst 2., reaction temperature 343 K, reaction time 12. min, 10 mL distilled water as solvent. Moreover, a kinetic equation of v = k[La ? Cu 4 FeAlCO 3 ][C 6 H 5 OH][H 2.O 2.. and the activation energy of Ea=58.37 kJ/mol are obtained according to the kinetic studies. Due to the fact that the HO-Cu+-OH species are detected in La-Cu4FeAlCO3/H2.2.system by XPS, the new mechanism about the generation of hydroxyl free radicals in the phenol hydroxylation is pro-posed, which is supposed that HO-Cu+-OH species are transition state in this reaction.

关键词： rare earth, hydrotalcite, microwave irradiation, phenol hydroxylation, kinetics, reaction mechanism.

Transient species and its properties of melatonin

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Science china Chemistry 2006年第4期49卷 308-314页

作者： ZHU Hongping1,2. ZHANG Zhaoxia1,2. ZHAO Hongwei1, WANG Wenfeng1 & YAO Side1 1. Shanghai Institute of Applied Physics, chinese Academy of Sciences, Shanghai 2.1800, china 2. {2. University of the chinese Academy of Sciences, beijing 10004., china 1. Shanghai Institute of Applied Physics Chinese Academy of Sciences Shanghai 201800 China 2. graduate University of the chinese Academy of Sciences Beijing 100049 China

The photo-physical and photo-chemical properties of melatonin (ML) werestudied by 2.6 nm laser flash photolysis (LFP). ML undergoes photo-ionization to produce radicalcation of ML (ML^(·+))and hydrated electrons (e_(aq)^-), while excited triplet state ~3ML~* is alsoformed during photolysis. The oxidation via one electron transfer from ML to SO_4^(·+) and thetriplet state of riboflavin (~3RF~*) has been also investigated and the rate constants for theprocess have been determined to be 8.0x10^9 and 1.4x10^9 L·mol^(-1)·s^(-1) respectively. Theradical cation of 2.2.'-azinobis(3-ethylbenzothiazoline-6-sulfonic acid)(ABTS^(·+)) scavengingcapacities of melatonin and other antioxidants are compared in this paper.

关键词： melatonin, laser flash photolysis, photoionization, triplet state.

Debris Flow Hazard Assessment Based on Support Vector Machine

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Wuhan University Journal of Natural Sciences 2006年第4期11卷 897-900页

作者： YUAN Lifeng 1, 2., ZHANG Youshui 3 1. Institute of Mountain Hazards and Environment, chinese Academy of Sciences, Chengdu 610041, Sichuan, china 2. {2. University of chinese Academy of Sciences, beijing 10004., china 3. Institute of Geographical Sciences and Natural Resources Research, chinese Academy of Sciences, beijing 100101, china Institute of Mountain Hazards Environment Chinese Academy of Sciences 610041 Chengdu Sichuan China graduate University of chinese Academy of Sciences 100049 Beijing China Institute of Geographical Sciences Natural Resources Research Chinese Academy of Sciences 100101 Beijing China

Seven factors, including the maximum volume of once flow , occurrence frequency of debris flow , watershed area , main channel length , watershed relative height difference , valley incision density and the length ratio of sediment supplement are chosen as evaluation factors of debris flow hazard degree. Using support vector machine （SVM） theory, we selected 2.9 basic data of 37 debris flow channels in Yunnan Province as learning samples in this study. We create a debris flow hazard assessment model based on SVM. The model was validated though instance applications and showed encouraging results.

关键词： debris flow hazard assessment support vector machine (SVM)

Temporal-spatial variations of euphotic depth of typical lake regions in Lake Taihu and its ecological environmental significance

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Science china Earth Sciences 2006年第4期49卷 431-442页

作者： ZHANG Yunlin1, 2. QIN Boqiang1, HU Weiping1, WANG Sumin1, CHEN Yuwei1 & CHEN Weimin1 1. Nanjing Institute of Geography & Limnology, chinese Academy of Sciences, Nanjing 2.0008, china 2. {2. school of the chinese Academy of Sciences, beijing 100039, china 1. Nanjing Institute of Geography & Limnology Chinese Academy of Sciences Nanjing 210008 China 2. graduate school of the {2. Academy of Sciences Beijing 100039 China

By using the data of underwater irradiance measured in the different lakeregions of Lake Taihu during 1998—2.04 and total suspended solids (TSS), wind speeds of the total13 stations in typical lake regions during 1993—2.03, this paper analyzes the factors ofinfluencing on PAR (pho-tosynthetically available radiation) attenuation, euphotic depth, andpresents the temporal and spatial variations of euphotic depth of typical lake regions in LakeTaihu, and the spectral distributions of euphotic depth at station 2. The results show that theconcentration of TSS is the most important factor impacting PAR attenuation, followed by chlorophylla; chromophoric dissolved organic matter (CDOM) has little impact on the PAR euphotic depth. During1993—2.03, the mean yearly PAR euphotic depths of the typical lake regions ranged from 1.04 to1.95 m with a mean value of 1.35±0.2. m. The PAR euphotic depth fell into 3 spatial zone types:Type Ⅰ, the lowest, including the lake center and the inflows of rivers; Type Ⅱ, intermediate,including Meiliang Bay, Wulihu Lake and Gonghu Bay; Type Ⅲ, the greatest, including the East LakeTaihu; corresponding mean depths were approximately 1.1, 1.4, 2.0 m, respectively. The seasonalvariations of euphotic depths were not quite the same in different lake regions. In the lake center,the mean values of PAR euphotic depth in summer and autumn were significantly greater than those inwinter and spring; in the Meiliang Bay, winter means were significantly greater than in the otherthree seasons; in the East Lake Taihu, winter means were significantly less than in the other threeseasons. However, no distinct seasonal change was recorded in the Wulihu Lake, Gonghu Bay and theinflows of rivers. The spectral distributions of euphotic depth present a minimal value at the bluelight wave band of 400 nm, and a peak at the green light wave band of around 580 nm. In 1998 and1999, based on the seasonal many-day continuous measurements, the PAR euphotic depths at station 2.

关键词： lake taihu euphotic depth diffuse attenuation coefficient total suspendedsolid ecological

Numerical simulations of the bi-level and branched structure of intracloud lightning flashes

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Science china Earth Sciences 2006年第6期49卷 661-672页

作者： TAN Yongbo1, TAO Shanchang1, ZHU Baoyou1, MA Ming2.& LU Weitao2.1. school of Earth and Space Sciences, University of Science and Technology of china, Hefei 2.002., china 2. chinese Academy of Meteorological Sciences, beijing 100081, china 1. school of Earth and Space Sciences University of Science and Technology of China Hefei 230026 China 2. chinese Academy of Meteorological Sciences Beijing 100081 China

Intracloud (IC) lightning flashes have been simulated in fine resolution (12.5 m) by using a bidirectional stochastic lightning parameterization scheme within 2.dimensional domain. The simu-lated results show that the IC flashes have a bilevel channel structure and the altitudes of the hori-zontal channels are at the same heights of potential wells, which are supported by the previous VHF source observations and balloon soundings of electric field profile in the thundercloud. Further con-clusions are: (1) After an IC flash is initiated near the boundary between positve and nagetive charge zone, the negative (or positive) leader tends to propagate into the positive (or negative) charge zone. Both types of positive and negative IC flashes have been reproduced and their polarity depends on the up and down disposition of the positive and negative charge regions. (2. The extension range of leaders is correlative with the cloud charge distribution. The leader is possible to extend through the inverted charge region all over where it is extending, but keeps away from the isolated charge area of the same polarity. (3) The channel structures also depend on the electric potential distributions in the thundercloud. Before propagating into the central area of potential wells, the leader tends to extend along the direction with the maximum of potential gradient. Once extending away from the center of potential wells, the leader tends to extend along the direction with the slowest potential change. (4) The IC flash channels have the fractal feature with fractal dimension 1.45 before leaders pass through the central area of charge regions. The exponent decreases rapidly once leaders extend into the low-density charge regions. (5) The induced charges of opposite polarity are deposited in the leader channels within preexisting positive and negative charge regions during IC flash discharges. This causes a new and complicated charge distribution in the thundercloud, and the potential

关键词： IC, lightning parameterization, branched bilevel structure, fractal feature, propagation tendency.

Characteristics and origins of primary fluids and noble gases in mantle-derived minerals from the Yishu area,Shandong Province,china

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Science china Earth Sciences 2006年第1期49卷 77-87页

作者： MA Jinlong1,2. TAO Mingxin2.3 & YE Xianren2.1. Resources and Environmental school, Lanzhou University, Lanzhou 730000, china 2. Key Laboratory of Gas Geochemistry, Institute of Geology and Geophysics, {2. Academy of Sciences, Lanzhou 730000, china 3. College of Resources Science & Technology, beijing Normal University, beijing 100875, china 1. Resources and Environmental school Lanzhou University Lanzhou 730000 China 2. Key Laboratory of Gas Geochemistry Institute of Geology and Geophysics Chinese Academy of Sciences Lanzhou 730000 China 3. College of Resources Science & Technology Beijing Normal University Beijing 100875 China

Fluids and noble gases of mantle-derived materials are important tracers forthe mantle information. Compositions of primary fluids and noble gases in mantle-derived mineralsfrom the Yishu area, Shandong Province, china, were tested by the methods of heat-bursting andheat-melting respectively. The fluids are mainly composed of CO_2. CO and H_2. which account forabout 90% of the total, and are similar to the mantle-derived rocks from other areas of easternchina; ratios of ~3He/~4He in almost all samples range from 0.82.Ra to 2.74 Ra, whereas^(40)Ar/^(36)Ar from 2.9.5 to 758.8. Both ranges are much lower than those of the typical oceanmantle-derived samples (such as MORB) and primarily reflect the influences of the atmosphericcomponents and the radiogenic isotopes. Ratios of C/~3He range from 2..6 x 10~9 to 1050 x 10~9,N_2.Ar from 92. to 56612. and N_2.~3He from 2.5 x 10~9 to 2. x 10~9, similar to those in westernUnited States and New Zealand which belong to the tectonic plate collision regions. The ratios fallin the intersect of mantle-crust-atmosphere in the comprehensive tracer-charts, reflecting theinfluences of the atmosphere and the crusts with organic components. Our results suggest that thecomposition of the primary fluids and the isotopic ratios of the noble gases may either reflect theevolution process of mantle-derived rocks connected with the rise and eruption of magma, or theinfluence of the ancient subduction-plate on the continental mantle of this region.

关键词： noble gases, primary fluids, mantle-derived minerals, Yishu area.