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Dehydration melting of solid amphibolite at 2.0 GPa: Effects of time and temperature

Science china Earth Sciences 2005年第8期48卷 1120-1133页

作者： ZHOU Wenge1, XIE Hongsen1, LIU Yonggang1, ZHENG Xiaogang1, ZHAO Zhidan2.& ZHOU Hui3 1. Laboratory of Material in the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002. china 2. department of geology,{2., beijing 100083, china 3. department of geology, Peking university, beijing 100871, china Laboratory of Material in the Earth’s Interior Institute of Geochemistry Chinese Academy of Sciences Guiyang China department of geology China University of Geosciences Beijing China department of geology Peking University Beijing China

Two sets of dehydration-melting with a natural solid amphibolite, collected from North Himalayan structure zone, Tibet, have been carried out in multi-anvil apparatus at 2.0 GPa and 800―1000℃, for 12.2.0 h. One is keeping the pressure at 2.0 GPa and the annealing time of 12.h, changing the temperature (800―1000℃). The other is keeping the pressure at 2.0 GPa and temperature at 850℃, varying the annealing time (12.2.0 h). The products are inspected with microscope and electron probe. The results indicate that at 2.0 GPa, annealing time of 12.h, garnets, melts and clinopyroxenes occur in amphibolite gradually with increasing temperature and the chemical compositions of melt vary from tonalite to granodiorite, and then to tonalite. However, at 2.0 GPa and 850℃, with the annealing time increasing, the garnets, melts and cli-nopyroxenes also occur in amphibolite gradually and the chemical compositions of melt vary from tonalite to granodiorite. In both cases, melts interconnect with each other when the contents of melt are over the 5 vol.%. the viscosities of the melt produced in amphibolite at temperature higher than 850℃ are on a level with 104 Pa·s. The interconnected melt with such a viscosity may segregate from the source rock and form the magma over reasonable geological time. Therefore, it is believed that at the lower part of the overthickened crust, the tonlitic and grano-dioritic magma may be generated through the dehydration melting of amphibolite.

关键词： solid amphibolite, high pressure, high temperature, time, partial melting.

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Mineralogy and crystal structure determination of Mg-fillowite

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Science china Earth Sciences 2005年第5期48卷 635-646页

作者： MA Zhesheng 1 , SHI Nicheng 1 & YE Danian 2.1. china university of geosciences, beijing 100083,{2. 2. Institute of geology, Chinese Academy of Sciences, beijing 10002.,{2. china university of {2. Beijing China Institute of geology Chinese Academy of Sciences Beijing China

Accurate crystal structure determination of complex phosphate Mg-fillowite ? Na2.a(Mn4Mg2.e)7[PO4]6 has been finished. Mg-fillowite occurs in muscovite-pegmatite in the Altay area, Xinjiang, china. It is of the trigonal lattice, with space group R-3, unit cell a=1.5143(3) nm, c=4.3191(2. nm, V=8.5736 nm3, Z = 18. The R-factor of the determination accuracy is R (I > 2. ( I )) = 0.0776. The cationic polyhedra consist of two kinds of structural units: compound col- umn and screw column. In three-dimensional space, they are linked with each other through corner sharing or edge sharing to build the entire structure. There are 45 atoms in an asymmetric unit and 72. atoms in a unit cell. In terms of types and connection manners of the coordination polyhedra, the degree of complicity is rarely seen in all mineral crystal structures. Study of such a structure is significant for the classification of phosphate and the building rule of coordination polyhedra in a complex crystal structure.

关键词： Mg-fillowite, complex phosphate, crystal structure, coordination polyhedron.

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Petrogenesis of Songshugou dunite body in the Qinling orogenic belt, Central china: Constraints from geochemistry and melt inclusions

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Science china Earth Sciences 2005年第8期48卷 1146-1157页

作者： SU Li1,2. SONG Shuguang3 & ZHOU Dingwu1 1. Key Laboratory of Continental Dynamics of the Ministry of Education, department of geology, Northwestern {2., Xi’an 710069, china 2. The Geological Lab Center, china university of geosciences (beijing), beijing 100083, china 3. Key Laboratory of Orogenic Belts of the Ministry of Education, department of geology, Peking {2., beijing 100871, china Key Laboratory of Continental Dynamics of the Ministry of Education Department of Geology Northwestern University Xi’an China The Geological Lab Center China University of Geosciences (Beijing)Beijing China Key Laboratory of Orogenic Belts of the Ministry of Education Department of Geology Peking University Beijing China

The Songshugou dunite body, which occupies an area of about 2. km2. is the largest ultramafic massif in the eastern Qinling orogenic belt, Central china. The major compo-nent of this body is dunitic rocks including mylonitic dunite and coarse-grained dunite; they oc-cupy about 95 vol% of the total body. Petrography, mineral composition, major and trace ele-ments and primitive melt inclusions have been investigated in this paper; all revealed that this dunite body is the product of melt-rock interaction by porous percolation flow. In comparison with dunite sills or veins in harzburgite from the basal part of Oman ophiolite, this dunite body is characterized by lower contents of Al2.3, CaO and HREE but higher content of highly incom-patible elements and Zr and Hf. The LREE enriched patterns and primitive mantle normalized spidergrams of trace elements are also different from the Oman dunite. Combining with melt in-clusions observed in olivines, we conclude that this dunite body is the product of large- scale porous percolation flow of high-MgO melts within depleted mantle peridotites. The high-MgO magma, in essence, was most probably produced at the hot head of an upwelling mantle plume. The occurrence of the Songshugou dunite body is closely associated with the activity of mantle super-plume in Neo-Proterozoic era in the Yangtze Craton.

关键词： Songshugou dunite body, geochemistry, melt inclusion, mantle plume, Qinling orogenic belt.

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In situ reproductive organs of Early Cretaceous ferns from Northeast china

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Chinese Science Bulletin 1997年第23期42卷 1977-1980,2026页

作者： DENG Shenghui and CHEN Fen1. Research Institute of Petroleum and Development, beijing 100083 2. china university of geosciences, beijing 100083, china Research Institute of Petroleum and Development Beijing china university of {2. Beijing China

FILICOPSIDA is a predominant group of the Early Cretaceous floras of Northeast china, whichapproximates 100 species and accounts for more than one third of the floras. The majority ofthis group are of great importance and significance in stratigraphy. The previous studies ofthese ferns are mainly morphological, with only a few concerning the in situ spores andsporangia. In recent years. the authors have carried out a research project on the in situreproductive organs of the Early Cretaceous ferns from/ basins of Inner Mongolia, Liaoning,Jilin and Heilongjiang of Northeast china. The study focuses on 35 species of 17 genera be-longing to 10 families. The present note briefly introduces the results of this study by listingsome representative species.

关键词： Northeast china Early Cretaceous Filicopsida in situ reproductive organs.

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Electrical Properties of Expanded Graphite Intercalation Compounds

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Journal of Materials Science & Technology 2001年第3期17卷 371-374页

作者： Xiuyun CHUAN department of geology, Peking {2., beijing 100871, china Daizhang CHEN and Xunruo ZHOU department of Materials Science, china university of geosciences, beijing 100083, china E-mail: cxyljhcj@*** Dept. of Geol. Beijing Univ. Beijing 100871 China

The intercalation compounds of CuCl2.were synthesized with expanded graphite, whose magnitude of the electrical conductivity is about 10(3)S(.)cm(-1). Their electrical conductivity is 3 similar to6 times as high as that of the expanded graphite, and about 10 times as high as that of GIC made of the non-expanded graphite. The microanalysis results of chemical compounds by X-ray energy spectrum scanning of TEM testified that the atomic ratio of chloride and cupric is nonstoichoimetric. The multivalence and exchange of electrovalence of the cupric ion was confirmed by the XPS-ESCA. Vacancy of chlorine anion increases the concentration of charge carrier. The special stage structure, made of graphite and chloride, produces a weak chemical bond belt and provides a carrier space in the direction of GIC layer. These factors develop the electrical properties.

关键词： In Ph Electrical Properties of Expanded Graphite Intercalation Compounds Graphite ESCA

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Discovery of potassic spilite (or poenite) in Langshan Group of Tanyaokou District,Inner Mongolia,china

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Chinese Science Bulletin 1999年第6期44卷 563-567页

作者： PENG Runmindepartment of geology and Mineral Resources ,{2., beijing 100083, china department of geology and Mineral Resources China University of Geosciences Beijing China

It is believed that the albite-potash-feldspar-greenschists in the middle Proterozoic Langshan Group in Tanyaokou District are synsedimentary potassic spilite （or poenite） based on the following facts and features: （ ⅰ ） they occur in beds and look blackish （or apple） green and compact; （ ⅱ ） they bear blasto-glomeroporphyritic and blastocrystalloclastic crystals which consist of （altered） albite laths with hollow skeleton crystal texture in which there are slender dark strips and minor pyroxene, and blasto-amygdaloid filled with pyrite, chlorite, magnetite, etc.; （ ⅲ ） the results of the petrochemical diagrams show that they are orthometamorphites; （ Ⅳ ） Sm-Nd isotopic age of them is 1 82. Ma (model age (tDM) is 2.006—2.132.Ma).

关键词： potassic spilite (or poenite) middle Proterozoic Tanyaokou Deposit Inner Mongolia.

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引用

Science china Earth Sciences 2004年第10期47卷 896-911页

作者： ZHANG Changhou1,2. WU Ganguo1,2. WANG Genhou2. ZHANG Weijie2.& SONG Honglin2.1. Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology, china university of geosciences, Ministry of Education of china,{2., china 2. School of Earth Sciences and Mineral Resources, china university of geosciences,{2., china Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology China University of Geosciences Ministry of Education of China Beijing China School of Earth Sciences and Mineral Resources China University of Geosciences Beijing China

The northwest trending tectonic belt in the middle part of the Mesozoic intraplate Yanshan Orogenic Belt, northeast Hebei Province, is composed of thrusts, extensional faults, strike-slip faults and syntectonic sedimentations as well. The northeastward basement-involved major thrusting deformation occurred between 174Ma and 168MaBP and was followed by an intrusion of the granitic plutonic rocks. As a part of the post-thrusting extensional deformations a northwest extending volcano-sedimentation system of Late Jurassic and Early Cretaceous formed in the southwest side of the belt. These volcano-sedimentary sequences are divided into Tuchengzi Formation, Zhangjiakou Formation, Yixian Formation and Jiufotang Formation re- spectively. They are characterized by southeastward migration as a result of the increasing down-dip slip displacement along the major extensional fault toward the southeast of the belt. The provenance area of the Jiufotang Formation north to it experienced southwestward thrusting during and after its later sedimentation. The thrusting in this stage resulted in the formation of an asymmetric footwall syncline with vergence to SW in the Jiufotang Formation in the NE side of the basin. Finally a dextral strike-slip deformation occurred along the NW tectonic belt. The striking tectono-geomorphological features and present seismic activities along this belt indicate that it has been being active since Cenozoic era and is still in the active state at present. This northwest extending tectonic belt was following the same direction and location as the existing fault systems within the basement as revealed by former geological and geophysical studies. So it is reasonable to infer the Mesozoic deformation along this belt to be a result of reactivation of the basement structures in a favorable tectonic stress field. The reactivation of basement struc- tures might be taken as one of the mechanisms of intraplate deformation and orogeny.

关键词： Yanshan Orogenic Belt, northwest extending tectonic complex, thrust system, geochronology.

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The Thermal Structure of the Upper Mantle in Eastern china——Inferred from the Petrological Model

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Acta Geologica Sinica(English Edition) 1991年第2期65卷 195-201页

作者： Deng Jinfu and Zhao Hailing china university of geosciences, beijing 100083,{2. china university of {2. Beijing 100083 China

Cenozoic basalt in eastern china contains abundant ultramafic xenoliths which are specimens of pyrolitesreleased during basaltic magma eruption. A total of 405 P-T data of pyroxene in the ultramafic rocks have beencollected, which present a more precise pyroxene geotherm. The average geothermal gradient in the upper man-tle represented by the pyroxene geotherm is about 3.3℃ / km, which is much less than that derived from theconductive thermal model (≈14℃ / km), implying the great significance of convective heat transfer. The calcu-lation shows that the contributions of convective and conductive heat transfers are 79% and 2.%, *** perturbation in the thermal structure of the upper mantle is an important manifestation of thetectonothermal event of Cenozoic continental rifting and intense basaltic volcanism in eastern china. Based onthe pyroxene geotherm and its comparison with the current geothermal field derived from the measurements ofthe surface heat flows, it is suggested that the Moho may be a secondary thermal boundary. The currentgeothermal field and the thermal structure of the lithosphere in eastern china may mainly reflect the result ofthe tectonothermal disturbance in the Neogene-Quaternary, in other words, the lithosphere has just begun toCool.

关键词： The Thermal Structure of the Upper Mantle in Eastern china

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Modeling of 3-D terrain effect on MT field using BEM

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Chinese Science Bulletin 1997年第9期42卷 764-767页

作者： XU Shizhe, RUAN Baiyao, ZHOU Hui and CHEN Leshou1.Institute of geology and Geophysics, Ocean university of Qingdao, Qingdao 2.6003,{2. 2. china university of geosciences, beijing 100083,{2. Institute of geology and Geophysics Ocean University of Qingdao Qingdao 266003 China|

THE modeling of 2.D terrain effect on magnetotelluric(MT)has been solved using finite ele-ment method(FEM)and boundary element method(BEM).This note uses BEM tosolve the *** solution of H_x- and E_x-polarization wave ... 详细信息

关键词： MT 3-D terrain boundary element method.

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Changes of infrared absorption wave number of aromatic-ring C=C bond of vitrinite and their significance

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Chinese Science Bulletin 1998年第12期43卷 1048-1050页

作者： XIAO Jianxin 1 and CHEN Shanqing 2.1. china university of geosciences, beijing 100083,{2. 2. Yichang Institute of geology and Mineral Resources, Yichang 443003,{2. china university of {2. Beijing China Yichang Institute of geology and Mineral Resources Yichang China

The humilith series of lignite, longflame coal, gas coal, fat coal, coking coal, lean coal, meagre coal and anthracite are measured by FIR1600 infrared spectrophotometer. The variation curve between the infrared absorption wave number of aromaticring C--C bond of vitrinite and its reflectance values are gained, which shows the shift of infrared absorption wave number of aromaticring C--C bond of humic coals towards lower wave number with the increase of coalification. It is believed that the coal rank of humilith series can be determined and more evolutional information about coal composition and structure can be obtained by the infrared spectroscopic method.

关键词： aromatic_nucleus C--C bond infrared absorption wave number vitrinite humic coal.

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