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Science china chemistry 2004年第6期47卷 507-511页

作者： LI Li1, WU Qingsheng1 DING Yaping2.& LI Ping3 1. department of chemistry, Tongji {2., Shanghai 2.0092. china 2. department of chemistry, Shanghai {2., Shanghai 2.0436, china 3. department of Food, Anhui Agricultural {2., Hefei 2.0036, china 1. department of chemistry Tongji University 200092 Shanghai China 2. department of chemistry Shanghai University 200436 Shanghai China 3. department of Food Anhui Agricultural University 230036 Hefei China

Multi-armed nanorods and nanobars of semiconductor selenium were simultane- ously synthesized in the light of biomineralization process through bio-membrane bi-templates of rush at room temperature. The multi-armed nanorods are 60 nm in diameter and 1.5 μm in length; the nanobars are 150 nm in diameter and 1000—1100 nm in length. The XRD pattern indicates that these nanocrystals were crystallized in the hexagonal structure with lattice constants a = 0.437 nm, c = 0.495 nm. The possible formation mechanism was investigated.

关键词： selenium, multi-armed nanorods, nanobars, bio-membrane, bi-templates.

Adsorption and corrosion inhibition behavior of imidazole on cobalt electrodes studied by SERS and electrochemical methods

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Science china chemistry 2005年第6期48卷 497-503页

作者： GU Wei1, LIU Guokun2. REN Bin2. WU Deyin2. GU Renao1 & TIAN Zhongqun2.1. department of chemistry, College of chemistry and Chemical Engineering, Suzhou university, Suzhou 2.5006, china 2. State Key Laboratory for Physical chemistry of Solid Surfaces and department of chemistry, College of chemistry and Chemical Engineering, Xiamen university, Xiamen 361005, china 1. department of chemistry College of Chemistry and Chemical Engineering Suzhou University 215006 Suzhou China 2. State Key Laboratory for Physical chemistry of Solid Surfaces and department of chemistry College of Chemistry and Chemical Engineering Xiamen University 361005 Xiamen China

The interaction of imidazole with Co electrodes in an electrochemical system was studied by surface-enhanced Raman scattering (SERS) and electrochemical methods. The SER spectra of Co in an imidazole solution as a function of the applied potential were analyzed and the assignment of the Raman bands was made. It was found that there were three kinds of sur-face species on the Co surface in different potential regions and they were interchangeable de-pending on the potential. In a relatively negative potential region (?1.2.to ?0.9 V), imidazole was adsorbed on the surface and its orientation might change from a vertical configuration via the N-end of the pyridine ring to a tilted configuration via the C2.N3 double bond. In a more positive potential region (?0.8 to ?0.7 V), the SERS signal from the adsorbed imidazole weakened and finally disappeared, meanwhile the signal from the Co and imidazole complex strengthened gradually. At the open circuit potential (?0.6 V), we detected very strong bands from the Co ox-ides. By comparing the Tafel curves of the Co electrode in the solution without and with imidazole, we found that imidazole has a marked effect on the corrosion inhibition of the Co electrode. This result demonstrates that we may be able to reveal the complicated interaction of surface species with metal surface at the molecular level by combining the SERS and electrochemical methods.

关键词： cobalt, imidazole, inhibition, surface-enhanced Raman spectroscopy, Tafel plot.

A new definition of restricted Lie superalgebras

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Chinese Science Bulletin 2000年第4期45卷 316-321页

作者： WANG Ying & ZHANG Yongzheng1. department of Mathematics, Harbin Institute Technology, Harbin 150001, china 2. department of Mathematics, Northeast normal university, Changchun 13002., china department of Mathematics Harbin Institute Technology Harbin China department of Mathematics Northeast Normal University Changchun China

A new definition of restricted Lie superalgebras has been given; some important results on the representation theory of restricted Lie superalgebra have been obtained.

关键词： restricted Lie superalgebra p-mapping p-semilinear mapping α-representation.

Utilization of a spiropyran derivative in a polymeric film optode for selective fluorescent sensing of zinc ion

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Science china chemistry 2006年第3期49卷 246-255页

作者： ZHANG Ying1, SHAO Na1, YANG Ronghua1, LI Ke’an1, LIU Feng1, CHAN Winghong2.& MO Tian2.1. College of chemistry and Molecular Engineering, Peking university, Beijing 100871,{2. 2. department of chemistry, Hong Kong Baptist university, Hong Kong,{2. 1. College of chemistry and Molecular Engineering Peking University Beijing 100871 China 2. department of chemistry Hong Kong Baptist University Hong Kong China

A new spiropyran derivative was synthesized and first utilized in a polymericfilm-based optical sensor for zinc ion. Spiropyrans, combining the characteristics of metal bindingand signal transduction, show potential function in the design of optical chemical sensors(optodes) toward metal ions. When embedded in a plasticized poly (vinyl chloride) (PVC) membrane,the newly synthesized spiropyran derivative 1 exhibits obvious fluorescence enhancement at 630 nm inthe presence of zinc ion in aqueous solution. With the optimum condition described, the optodemembrane responds to zinc ion over a dynamic range of 4.94x10^(-7) to 4.15x10^(-4)mol·L^(-1), witha detection limit of 1.51x10^(-7) mol·L^(-1). The membrane not only displays excellentphotostability, reproducibility and reversibility, but also exhibits high selectivity toward zincion over transition metal ions including Hg^(2.), Cd^(2.), Pb^(2.), Cu^(2.), Fe^(3+) and commoncationic ions presented in the physiological fluids.

关键词： spiropyran, sensor, PVC membrane, zinc ion, fluorescent spectroscopy.

Particle tunnels across the horizon of Garfinkle-Horowitz-Strominger dilaton black hole

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Science china(Physics,Mechanics & Astronomy) 2007年第5期50卷 601-610页

作者： FANG HengZhong1 & ZHAO Zheng2.1 department of Physics, china {2. of Petroleum, Dongying 2.7061, china 2.department of Physics, Beijing normal {2., Beijing 100875, china department of Physics China University of Petroleum Dongying 257061 China department of Physics Beijing Normal University Beijing 100875 China

We promote the work of Parikh and Wilczek on the black hole radiation to the emission of massive and charged particles from Garfinkle-Horowitz-Strominger black hole. The energy and charge of the space-time are conservational during the course of the evaporation. The calculation shows that the emission spectrum is not precisely thermal, while has a correction, and the conclusion supports the view- point of information conservation.

关键词： Hawking radiation, black body spectrum, barrier, information loss, entropy of black hole, Komar energy

Theoretical study of the potential energy surface and the highly excited rovibra-tional spectroscopy of H_2. molecule

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Chinese Science Bulletin 2001年第8期46卷 650-652页

作者： XIE Junkai & YAN Guosendepartment of chemistry, Sichuan {2. university, Chengdu 610066, china department of chemistry, Sichuan university, Chengdu 610064, china department of chemistry Sichuan Normal University Chengdu China department of chemistry Sichuan University Chengdu China

This note reports the potential energy surface of H2. that has been refined by using SCF-CI approach and the high-resolution experimental data. The calculated splitting values of the local mode vibration states pair close to observed values. This vibration state calculation has shown that there are no obvious non-Born Oppenheimer effects occurring in the lower vibration states of the system.

关键词： potential energy surface local mode vibration state non- Born Oppenheimer effect.

Determination of Trace Amount of Yttrium with Bromopyrogallol Red by solid-phase Spectrophotometry

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Rare Metals 2001年第3期20卷 202-204页

作者： Jinzhang Gao,Gang Ni, Li Yuan, Jingwan Kang department of chemistry, Northwest {2. university, Lanzhou 730070, china NW normal Univ Dept Chem Lanzhou 730070 Peoples R China

A simple and sensitive method for the determination of trace amount of yttrium by solid-phase spectrophotometry has been studied. Yttrium can form a 1 : 1 complex with bromopyrogallol red (BPR) on resin, which was determined directly at 605 nm, pH=6.5. It has a highly sensitivity (epsilon = 6.3 x 10(6)) which is 300-fold higher than the corresponding spectrophotometry in solution. The method was applied to the determination of yttrium in churchite.

关键词： solid-phase spectrophotometry bromopyrogallol red (BPR) yttrium

The kink-soliton and antikink-soliton in quasi-one-dimensional nonlinear monoatomic lattice

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Science china(Physics,Mechanics & Astronomy) 2005年第2期48卷 150-157页

作者： XU Quan1 & TIAN Qiang2.1. Scientific and Technological Office, Daqing Teacher College, Daqing 163712. china 2. department of Physics , Beijing {2. university, Beijing 100875, china Scientific and Technological Office Daqing Teacher College Daqing 163712 China department of Physics Beijing Normal University Beijing 100875 China

The quasi-one-dimensional nonlinear monoatomic lattice is analyzed. The kink-soliton and antikink-soliton are presented. When the interaction of the lattice is strong in the x-direction and weak in the y-direction, the two-dimensional (2.) lattice changes to a quasi-one-dimensional lattice. Taking nearest-neighbor interaction into account, the vibration equation can be transformed into the KPI, KPII and MKP equation. Considering the cubic nonlinear potential of the vibration in the lattice, the kink-soliton solution is presented. Considering the quartic nonlinear potential and the cubic interaction potential, the kink-soliton and antikink-soliton solutions are presented.

关键词： two-dimensional nonlinear lattice, quasi-one-dimensional nonlinear lattice, kink-soliton, antikink-soliton.

Synthesis of Nanocrystalline α-Mo_2. from Peroxomolybdenum Compounds

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复旦学报（自然科学版） 2007年第5期46卷 859-860页

作者： Beibei Zhang1, Huaming Li1, Huoming Shu2. Wenshuai Zhu1, Jiexiang Xia1(1.College of chemistry and Chemical Engineering, Jiangsu university, Zhenjiang 2.2.13,{2. 2.department of chemistry, hainan normal university, Haikou 5702.8,{2.) College of chemistry and Chemical Engineering Jiangsu university Zhenjiang 212013 department of chemistry{2. Haikou 570228

1 Introduction Considerable attentions have been focused on transition metal carbide because of their numerous valuable properties, particularly of excellent catalysis similar to noble metal[1]. There are many routes[2.to synthesize molybdenum carbide. Among them, the temperature programmed reduction of MoO3 using the mixture of hydrocarbon and hydrogen is the most promising procedure to prepare carbide catalyst. Traditionally, CH4/H2.and C2.6/H2.are the most widely used to be the carburizing resource. ...

关键词： α-Mo2. synthesis nanocrystalline peroxopolymolybdic compounds

Existence of the solutions and the attractors for the large-scale atmospheric equations

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Science china Earth Sciences 2006年第6期49卷 650-660页

作者： HUANG Haiyang1 & GUO Boling2.1. department of Mathematics, Beijing normal {2., Beijing 100875, china 2. Institute of Applied Physics and Computational Mathematics, Beijing 100080, china 1. department of Mathematics Beijing Normal University Beijing 100875 China 2. Institute of Applied Physics and Computational Mathematics Beijing 100080 China

In this paper, firstly, the proper function space is chosen, and the proper expression of the operators is introduced such that the complex large-scale atmospheric motion equations can be described by a simple and abstract equation, by which the definition of the weak solution of the atmospheric equations is made. Secondly, the existence of the weak solution for the atmospheric equations and the steady state equations is proved by using the Galerkin method. The existence of the non-empty global attractors for the atmospheric equations in the sense of the Chepyzhov-Vishik’s definition is obtained by constructing a trajectory attractor set of the atmospheric motion equations. The result obtained here is the foundation for studying the topological structure and the dynamical behavior of the atmosphere attractors. Moreover, the methods used here are also valid for studying the other atmospheric motion models.

关键词： atmosphere equations, weak solution, trajectory attractor, global attractor, equilibrium.