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Description of Mechanism Function about Dehydration of Cobalt Oxalate Dihydrate by Multiple Rates Isotemperature Method

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wuhan university Journal of Natural {2. 2004年第2期9卷 239-246页

作者： LiLi-qing ChenDong-hua collegeofchemistryand{2.sciences SouthCentralUniversityforNationalitiesWuhan430074HubeiChina

A new method of the multiple rates isotemperature is proposed to define the most probable mechanismg(α) of thermal anlaysis; the iterative isoconversional procedure has been employed to estimate apparent activation energyE; the pre-exponential factorA is obtained on the basis ofE andg(α). By this new method, the thermal analysis kinetics triplet of dehydration of cobalt oxalate dihydrate is determined, apparent activation energyE is 99.84 kJ·mol?1; pre-exponential factorA is 3.42.×109–3.872.109 s?1 and the most probable mechanism belongs to nucleation and growth,A m model, the range ofm is from 1.50 to 1.70. Key words multiple rates isotemperature method - isoconversional method - cobalt oxalate dihydrate - accomodation function - differential scanning calorimetry (DSC) CLC number O 636.1 Foundation item: Supported by the Key Foundation of the Science and Technology Committee of Hubei Province (2.01ABA009)Biography: Li Li-qing (1977-), female, Master candidate, research direction: material synthesize and thermal analysis kinetics.

关键词： multiple rates isotemperature method isoconversional method cobalt oxalate dihydrate accomodation function differential scanning calorimetry (DSC)

MCM-41 Prepared with Ionic Liquid and Cethytrimethylammonium Bromide as Co-templates

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Journal of wuhan university of Technology(Materials Science) 2009年第1期24卷 25-29页

作者：张光旭 School of Chemical Engineering Wuhan University of Technology college of chemistry and Molecular {2. Wuhan University

The mesoporous molecular sieves MCM-41 were prepared using room tempera-ture ionic liquid （RTIL） synthesized in laboratory and cethytrimethylammonium bromide （CTAB） as compound templates for the first time. They were prepared under low aging temperature and short aging time. Via characterizing by XRD and nitrogen adsorption instrument, MCM-41 synthesized by this new method exhibited good crystal structure and narrow pore distribution. The following pre-paratory conditions was optimal： the molar ratio of RTIL to CTAB was 1.0∶1.0, aging at 80 ℃, for 40 h and calcined at 540 ℃. It is found that the acidified MCM-41 improves its activity as catalyst over the unmodified ones.

关键词： mesoporous molecular sieve hydrothermal crystallization co-templates ionicliquid MCM-41

Approach to the Relation of Mutual-Feed Joint-Variation in Groundwater Management Model

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Journal of Earth Science 2012年第3期23卷 349-358页

作者：李平卢文喜靳孟贵杨青春 college of chemistry and Materials South-Central University for Nationalities School of Environmental Studies China University of Geosciences college of Environment and Resources Jilin University

In groundwater management,the exchanges between groundwater and other water such as surface water and spring water need to be *** exchange is dependent on the ground-water level,which is called *** pumping rate,groundwater level,and covariate interact and the relation of mutual-feed joint-variation is used to describe their *** article presents a new approach of dealing with the relation in groundwater management *** mathematical for-mulation of the relation,as an additional equality constraint in the optimization model,is developed using response matrix *** the groundwater management model with covariate is set *** code for the simulation and management of groundwater system with covariate is programmed with Fortran 90,and the optimal pumping rate,groundwater level,and covariate are *** approach is verified with a hypothetical ***,the approach is applied to the groundwater management of Qianguo（前郭） area in western Jilin（吉林） *** results indicate that the ap-proach is *** provides a universal solution for various covariates and reduces the computational complexity compared to iteration *** approach is proven to be very efficient to solve ground-water management problem with covariate.

关键词： covariate relation of mutual-feed joint-variation groundwater management response matrix

Preparation and Characterization of Chitosan/Carboxymethylated Konjac Glucomannan Blend Films

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wuhan university Journal of Natural {2. 2002年第1期7卷 107-112页

作者： Zheng Hua 1 , Du Yu-min 2.1. Department of Chemical Engineering, wuhan university of Technology, wuhan 430070, Hubei, china 2. college of chemistry and Molecular sciences, wuhan university, wuhan 430072. Hubei, china Department of Chemical Engineering Wuhan University of Technology Wuhan Hubei China college of chemistry and Molecular {2. Wuhan University Wuhan Hubei China

In order to improve the mechanical and water swelling properties of the chitosan (CS) film, a series of transparent films were prepared by blending 2.(weight) chitosan acetic acid solution with 1.5%(weight) carboxymethylated konjac glucomannan (CMKGM) aqueous solution according to predetermined ratio and drying at 30°C. The morphological structure, miscibility, thermal stability, mechanical properies, and swelling capacity of the blend films were studied by infrared (IR), X-ray diffraction (XRD), differential thermal analysis (DTA), scanning electron micrograph (SEM), and measurements of the mechanical properties and swelling properties. The results demonstrated that there was strong interaction and good miscibility between CS and CMKGM resulted from intermolecular hydrogen bonding and electrostatic force. The mechanical properties in dry state and wet state, thermostability, and water swelling properties of the blend films were obviously improved. The best values of the tensile strength in the dry and wet state achieved 89 MPa and 49 MPa, respectively, when the CMKGM content was 30%(weight). The CS/ CMKGM blend films provided promising biomedical applications.

关键词： Key words chitosan carboxymethylated konjac glucomannan blend films structure characterization

Synthesis and purification of trialkyl compounds of gallium and indium

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Rare Metals 2002年第1期21卷 1-6页

作者： SHU Wangen, ZHOU Zhongcheng and LI Xiong chemistry and Chemical Engineering college, {2. south university, Changsha 410083, china chemistry and chemistry Engineering {2. Central South University Changsha 410083 chemistry and Chemical Engineering college Central South University Changsha 410083

The The research progress in trialkyl compounds of gallium andindium was discussed from two aspect, one was the chemical synthesisof the compounds and the other was the purification of them. Thereare three synthesis routes be- ing reported in the first aspect, *** route staring form pure metal, the route starting from the puremetal trihalides, and the electrochemical route. In the secondaspect, the purifying methods of decomposition-distillation and zonerefining were reviewed.

关键词： trialkyl compounds gallium nd indium synthesis purification

Silylated and acetylated β-cyclodextrins for gas chromatographic stationary phases

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Journal of central south {2. of Technology 2001年第4期8卷 239-243页

作者： TANG Ke wen 1,2.,YI Jian ming 2.ZHOU Chun shan 1,ZHONG Shi an 1 (1. college of chemistry and Chemical Engineering, {2. south university, Changsha 410083, china 2. college of chemistry and Chemical Engineering, Yueyang Normal university college of chemistry and Chemical Engineering Central South University Changsha China college of chemistry and Chemical Engineering Yueyang Normal University Yueyang China

Two new chiral stationary phases, 2.3 di O acetyl 6 O trimethylsilyl β cyclodextrin (DATBCD) and 2.6 di O trimethylsilyl 3 O acetyl β cyclodextrin(DTABCD), were synthesized, their structures were identified by means of infrared and NMR spectra. Capillary columns were coated with the two stationary phases by dynamic method. The chromatographic properties, and enantiomers separation, such as ketone, esters, alcohols and olefines, were investigated on the silylated and acetylated β cyclodextrin stationary phases. The experimental results show that the silylated and acetylated β cyclodextrins are suitable to be used as capillary gas chromatographic stationary phases, the relative polarity of DATBCD and DTABCD stationary phases is respectively 4143 and 392., the column efficiencies are respectively 3084 and 4198, and DATBCD is of stronger enantioselectivity than DTABCD, capacity factor of the first eluted enantiomer ( k 1) and separation factor(α)of α phenylethanol on DATBCD stationary phase are respectively 8.2. and 1.019.

关键词： capillary gas chromatography silylated and acetylated β-cyclodextrins enantiomeric separation

PEGylated PLGA Nanoparticles as Tumor Ecrosis Factor-α Receptor Blocking Peptide Carriers:Preparation,Characterization and Release in vitro

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Journal of wuhan university of Technology(Materials Science) 2007年第1期22卷 112-116页

作者：刘卫杨祥良 college of life Science and Technology Huazhong University of Science and Technology

To assess the merits of PEGylated poly （lactic-co-glycolic acid）（PEG-PLGA） nanoparticles as drug carriers for tumor necrosis factor-α receptor blocking peptide （TNFR-BP）, PEG-PLGA copolymer, which could be used to prepare the stealth nanoparticles, was synthesized with methoxypolyethyleneglycol, DL-lactide and glycolide. The structure of PEG-PLGA was confirmed with ^1H-NMR and FT-IR spectroscopy, and the molecular weight （MW） was determined by gel permeation chromatography. Fluorescent FITC-TNFR- BP was chosen as model protein and encapsulated within PEG-PLGA nanoparticles using the double emulsion method. Atomic force microscopy and photon correlation spectroscopy were employed to characterize the stealth nanoparticles fabricated for morphology, size with polydispersity index and zeta potential. Encapsulation efficiency （EE） and the release of FITC-TNFR-BP in nanopartieles in vitro were measured by the fluorescence measurement. The stealth nanoparticles were found to have the mean diameter less than 2.0 nm and zeta potential less than -2. mV. In all nanoparticle formulations, more than 45% of EE were obtained. FITC-TNFR-BP release from the PEG-PLGA nanoparticles exhibited a biphasic pattern, initial burst release and consequently sustained release. The experimental results show that PEG-PLGA nanoparticles possess the potential to develop as drug carriers for controlled release applications of TNFR-BP.

关键词： tumor necrosis factor-α receptor blocking peptide PEG-PLGA stealth nanoparticles ring-opening polymerization controlled and sustained drug release

Electrochemical characteristics of amorphous MgTi_xNi(x = 0,0.1,and 0.2. hydrogen storage alloys

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Rare Metals 2010年第5期29卷 486-490页

作者： LIU Suqin,ZHAO Wenjuan,HUANG Kelong,and HUANG Hongxia college of chemistry and Chemical Engineering,{2. south university,Changsha 410083,china college of chemistry and Chemical Engineering Central South University Changsha China

MgTixNi （x = 0, 0.1, and 0.2. alloys were successfully prepared by mechanical alloying （MA）, and the influence of milling time on the electrochemical characteristics of the electrodes was discussed. MgTixNi alloys after 90 h milling displayed the best electrochemical performance The X-ray diffraction patterns showed that the alloy ball-milled for 90 h was amorphous with a widened diffraction peak. The charge-discharge tests indicated that these alloys had good electrochemical activation properties, and the MgTi0.2.i alloy electrode exhibited the best cycle performance. The initial discharge capacity of the MgTi0.2.i alloy reached up to 401.1 mAh·g^-1, and the retention rate of capacity was 31.0% after 30 cycles, much higher than that of MgNi （17.3%）. The Tafel polarization curves revealed that Ti addition could enhance the anticorrosion performance of these alloys in alkali solution, which was responsible for the ameliorated cyclic stability of these alloy electrodes.

关键词： hydrogen storage alloys titanium electrochemical properties mechanical alloying

Electrophoretic Coating of Hydroxyapatite on Pyrolytic Carbon Using Glycol as Dispersion Medium

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Journal of wuhan university of Technology(Materials Science) 2008年第3期23卷 293-297页

作者：高林 college of life Science and Technology Huazhong University of Science and Technology college of chemistry and Environmental Engineering Yangtze UniversityJingzhou 434023China

Hydroxyapatite （HA） coatings on pyrolytic carbon were produced via electrophoretic deposition （EPD） using glycol and ethanol as dispersion medium respectively. The effect of the solubility of HA in the dispersion medium on crack occurrence and adherence of the coating was investigated by means of scanning electronic microscope （SEM） and atomic absorption spectrometer （AAS）. The results show that the solubility of HA in glycol is higher than that in ethanol. The usage of glycol as a dispersion medium can reduce the possibility of crack formation and enhance the adhesive strength between the coating and the carbon substrate. The green coatings can be sintered under vacuum at 1 000 ℃ whether the coatings are obtained using ethanol or glycol as dispersion medium. No HA decomposition was observed up to 1 000 ℃ by vacuum sintering by X-ray diffraction （XRD） analysis.

关键词： hydroxyapatite electrophoretic deposition coatings dispersion medium glycol