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Controlled synthesis and magnetic properties of Fe_3O_4 walnut spherical particles and octahedral microcrystals

Science China(Technological Sciences) 2008年第11期51卷 1911-1920页

作者： JIAO Hua1,2.& YANG HeQing1 1 Key Laboratory of Macromolecular Science of Shaanxi Province, School of Chemistry and Materials Science, Shaanxi normal university, Xi’an 710062. China 2.Department of Chemistry and {2. engineering, Weinan Teachers university, Wei nan 714000, China Key Laboratory of Macromolecular Science of Shaanxi Province School of Chemistry and Materials Department of Chemistry and chemical engineering Weinan Teachers University

Magnetite Fe3O4 walnut spherical particles and octahedral microcrystals were suc- cessfully synthesized from K4 [Fe (CN) 6], K3 [Fe (CN) 6] and NaOH reagents via a simple hydrothermal process. And the uniform morphology of octahedral micro- crystals was obtained in the presence of ethylene glycol. The morphology and structure of products were characterized by powder X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The results showed that the Fe3O4 walnut spherical particles and octahedral microcrystals were single crystals with the face-center cubic structure and with size distributions from 2.2.to 8.6 μm and 1.6 to 12.5 μm, respectively. Their magnetic properties were detected by a vibrating sample magnetometer at room temperature. The walnut spherical parti- cles exhibited a ferromagnetic behavior with the coercive force (Hc), saturation magnetization (Ms) and remanent magnetization (Mr) being 150.57 Oe, 97.634 and 12.05 emu/g, respectively. For the octahedral microcrystals they were 75.2. Oe, 101.90 and 6.69 emu/g, respectively. Different sizes of walnut spherical particles were controlled synthesized through adjusting the NaOH concentration. It was found that ethylene glycol molecules have a significant effect on the formation of Fe3O4 octahedra. A possible mechanism was also proposed to account for the growth of these Fe3O4 products

关键词： a hydrothermal route Fe3O4 walnut spherical particles octahedral microcrystals magnetic property

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Non-invasive scanning ion-selective electrode technique and its applications to the research of higher plants

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Progress in Natural Science:Materials International 2007年第6期17卷 625-629页

作者： Sun Tong1, Xu Yue2. Li Peng1, Yu Shangguan2.and Yin Liping1(1. college of Life Science, Capital normal {2., Beijing 100037, China 2. Younger USA Science & Technology Corporation, 7 Dayton Lane, Amherst MA 01002. USA) college of Life Science Capital Normal University Beijing 100037 China Younger USA Science & Technology Corporation 7 Dayton Lane Amherst MA 01002 USA

The process of various ions and molecules getting into and out of cells is critical for plant survival. The non-invasive scanning ion-selective electrode technique (SIET) is a non-invasive method to obtain the information of ions/molecules across membranes in plant. This technique can measure the absolute concentration of ions and molecules, and also their fluxes and directions of movement. The samples to be analyzed can be a single cell, a piece of tissue, a whole organ and even an intact seedling. This article reviews the recent progress made in plant physiology by using this technique and discusses its potentials in future studies on plant physiology.

关键词： non-invasive electrophysiology technique ion-selective electrode ion transport across membrane SIET.

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Fluorescence Enhancing Effect of OP on Ga(Ⅲ)-ECBBR system and its Analytical Application

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Rare Metals 2001年第2期20卷 130-132页

作者： Jinzhang Gao, Jianniao Tian, Yanchun Zhao, the Yang, Jingguo Hou, Jingwan Kang (Chemistry and chemical engineering {2., Northwest normal university, Lanzhou 730070, China) 西北师范大学甘肃兰州 730070

The fluorophotometric determination of gallium(Ⅲ) With eriochrome blue black R (ECBBR) was investigated in the presence of OP at pH 2.0n.5. The calibration graph has a good linear relationship in the rabid of 1.6×10-7-1.2. 10-5 mol/L Ga(Ⅲ). The effect of foreign ions was studied and the proposed method was applied to the determination of gallium in aluminum alloy.

关键词： gallium, eriochrome blue black R OP aluminum alloy

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Development of simple sequence repeats (SSR) markers of ramie and comparison of SSR and inter-SSR marker systems

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Progress in Natural Science:Materials International 2005年第02期15卷 42-47页

作者： ZHOU Jianlin1*, JIE Yucheng2., JIANG Yanbo2. ZHONG Yingli1, LIU Yunhai1 and ZHANG Jian1**(1. Department of Biochemistry and Molecular Biology, college of Life Science, Hunan normal {2., Changsha 410081, China 2. Institute of Bast Fiber Crops, Chinese Academy of Agricultural Science, Changsha 410006, China) Department of Biochemistry and Molecular Biology College of Life Science Hunan Normal University Changsha 410081 China. Institute of Bast Fiber Crops Chinese Academy of Agricultural Science Changsha 410006 China

Ramie (Boehmeria nivea L.) is an important bast fiber crop. To study genetic background of this species, we isolated and characterized microsatellite markers of ramie. A genomic library containing inserts of rapid amplification of polymorphic DNA (RAPD) fragments was constructed, and screened by PCR amplification using anchored simple sequence repeats as primers. A total of 2. clones were identified as positives, and 13 microsatellite loci were found after sequencing. The polymorphism of these 13 microsatellite loci was examined and the utility of simple sequence repeats (SSR) and inter-SSR (ISSR) marker systems for genetic characterization compared using 19 selected ramie cultivars. Both approaches successfully discriminated the 19 cultivars which differed in the amount of polymorphism detected. The level of polymorphism detected by SSR was 95.0%, higher than that by ISSR (72.3%), but the average polymorphism information content (PIC) of ISSR (0.651) was higher than that of SSR (0.441). The higher PIC value of ISSR suggests that ISSR is more efficient for fingerprinting ramie cultivars than SSR markers. However, because the SSR loci are codominant, they are more suitable for determining the homozygosity levels of ramie, constructing linkage map, quantitative trait loci study of complex traits and marker-assisted selection.

关键词： ramie (Boehmeria nivea L.Gaud) simple sequence repeats inter-simple sequence repeats

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3D-QSAR studies on glycogen phosphorylase inhibitors by flexible comparative molecular field analysis

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Science China Chemistry 2007年第4期50卷 568-573页

作者： ZHOU Peng1 & LI ZhiLiang1,2.1 college of Chemistry and chemical {2., Chongqing university, Chongqing 400044, China 2.State Key Laboratory of Chemo/Biosensing and Chemometrics, Changsha 410082. China college of Chemistry and chemical {2. Chongqing UniversityChongqing 400044China State Key Laboratory of Chemo/Biosensing and Chemometrics Changsha 410082China

Canceling grids accommodating probes in comparative molecular field analysis (CoMFA), the idea of flexibleness is introduced into the CoMFA, and in combination with swarm intelligent algorithm which attempts to optimize distributions of diverse probes around drug molecules, a new 3D-QSAR method is proposed in this context as flexible comparative molecular field analysis (FCoMFA). In preliminary at-tempts to performing QSAR studies on 47 glycogen phosphorylase inhibitors, FCoMFA is employed and confirmed to be potent to exploring ligand-receptor interaction manners at active positions and thus to generating stable and predictable models. Simultaneously by an intuitive graphics regarding probe distribution patterns, impacts of different substituted groups on activities is also given an insight into.

关键词： flexible comparative molecular field analysis (FCoMFA) three-dimensional quantitative structure-activity relationship (3D-QSAR) particle swarm optimization algorithm (PSO) glycogen phosphorylase inhibitor probe distribution pattern

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Thermal oxide synthesis and characterization of Fe_3O_4 nanorods and Fe_2._3 nanowires

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Science China Chemistry 2009年第5期52卷 599-604页

作者： JIAO Hua1,2.& YANG HeQing1 1 Key Laboratory of Macromolecular Science of Shaanxi Province, School of Chemistry and Materials Science, Shaanxi normal university, Xi’an 710062. China 2.Department of Chemistry and {2. engineering, Weinan Teacher’s university, Weinan 714000, China Key Laboratory of Macromolecular Science of Shaanxi Province School of Chemistry and Materials Science Shaanxi Normal University Xi’an China Department of Chemistry and chemical engineering Weinan Teacher’s University Weinan China

Fe3O4 nanorods and Fe2.3 nanowires have been synthesized through a simple thermal oxide reaction of Fe with C2.2.4 solution at 2.0-600℃ for 1 h in the air. The morphology and structure of Fe3O4 nanorods and Fe2.3 nanowires were detected with powder X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The influence of temperature on the morphology development was experimentally investigated. The results show that the polycrystals Fe3O4 nanorods with cubic structure and the average diameter of 0.5-0.8 μm grow after reaction at 2.0-500℃ for 1 h in the air. When the temperature was 600℃, the samples completely became Fe2.3 nanowires with hexagonal structure. It was found that C2.2.4 molecules had a significant effect on the formation of Fe3O4 nanorods. A possible mechanism was also proposed to account for the growth of these Fe3O4 nanorods.

关键词： thermal oxide process nanorods nanowires C2.2.4 iron sheet

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Applications of functionalized ionic liquids

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Science China Chemistry 2006年第5期49卷 385-401页

作者： LI Xuehui1, ZHAO Dongbin2.3, FEI Zhaofu2.& WANG Lefu1 1. Department of chemical engineering, Guangdong Provincial Laboratory of Green chemical Technology, South China Uni-versity of Technology, Guangzhou 510641, China 2. Swiss Federal Institute of Technology, Lausanne, EPFL, CH-1015 Lausanne, Switzerland 3. PKU Green Chemistry Center, Beijing National Laboratory for Molecular Sciences, college of Chemistry and Molecular engineering, Peking university, Beijing 100871, China Department of chemical engineering Guangdong Provincial Laboratory of Green Chemical Technology South China University of Technology Guangzhou China Lausanne EPFL Swiss Federal Institute of Technology Lausanne Switzerland PKU Green Chemistry Center Beijing National Laboratory for Molecular Sciences College of Chemistry and Molecular Engineering Peking University Beijing China

Recent developments of the synthesis and applications of functionalized ionic liquids (including dual-functionalized ionic liquids) have been highlighted in this review. Ionic liquids are at-tracting attention as alternative solvents in green chemistry, but as more functionalized ILs are pre-pared, a greater number of applications in increasingly diverse fields are found.

关键词： ionic liquids functionalized ionic liquids dual-functionallzed ionicliquids reaction media asymmetric synthesis nano-materials porous materials lubricants flue-gas desulfurization oil desul-furization

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Resonance scattering spectral detection of ultratrace IgG using immunonanogold-HAuCl_4-NH_2.H catalytic reaction

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Science China Chemistry 2008年第5期51卷 440-446页

作者： JIANG ZhiLiang1,2.ZHANG ShengSen1,LIANG AiHui2.& HUANG SiYu1 1 School of Environment and Resource,Guangxi normal university,Guilin 541001,China 2.Department of Material and {2. engineering,Guilin university of Technology,Guilin 541001,China School of Environment and Resource Guangxi Normal University Guilin China Department of Material and chemical engineering Guilin University of Technology Guilin China

Nanogold particles of 10 nm were used to label goat anti-human IgG (GIgG) to obtain nanogold-labeled GIgG (AuGIgG). In a citrate-HCl buffer solution of pH 2.2.,AuGIgG showed a strong catalytic effect on the reaction between HAuCl4 and NH2.H to form big gold particles that exhibited a resonance scatter-ing (RS) peak at 796 nm. Under the chosen conditions,AuGIgG combined with IgG to form immuno-complex AuGIgG-IgG that can be removed by centrifuging at 16000 r/min. AuGIgG in the centrifuging solution also showed catalytic effect on the reaction. On those grounds,an immunonanogold catalytic RS assay for IgG was designed. With addition of IgG,the amount of AuGIgG in the centrifuging solution decreased; the RS intensity at 796 nm (I796 nm) decreased linearly. The decreased intensity ΔI796 nm was linear with respect to the IgG concentration in the range of 0.08-16.0 ng·mL-1 with a detection limit of 0.02.ng·mL-1. This assay was applied to analysis of IgG in sera with satisfactory sensitivity,selectivity and rapidity.

关键词： immunonanogold nanocatalysis gold-enhancement resonance scattering assay IgG

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Microwave-assisted reaction of peptide formation by amino acid with phosphate:Exploration of the most possible channels for the origin of life

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Science China Chemistry 2006年第4期49卷 351-356页

作者： HU Rong1, TIAN Jinping2.& YIN Yingwu2.3 1. college of Chemistry & Environment Protection engineering, Southwest {2. for Nationalities, Chengdu 610041, China 2. TH-UNIS Insight Co., Ltd., Beijing 100085, China 3. Key Laboratory of Bioorganic Phosphorus Chemistry & chemical Biology, Ministry of Education, Department of Chemistry, Tsinghua {2., Beijing 100084, China college of Chemistry & Environment Protection engineering Southwest University for Nationalities Chengdu China TH-UNIS Insight Co. Ltd. Beijing China Key Laboratory of Bioorganic Phosphorus Chemistry & chemical Biology Ministry of Education Department of Chemistry Tsinghua University Beijing China

Microwave-assisted reaction of peptide formation by amino acids with phosphate was studied. The results showed that the products were a mixture of peptides containing dipeptide, oc- tapeptides and cyclic peptides, which could be obtained in a short time. Polyphosphate was also produced synchronously by the intermolecular condensation of phosphate. The polymerization de- gree reached 99% (pyrophosphate 64%, trimetaphosphate 35%) after 2.h at 2.0℃ under microwave irradiation. The intermediates of the mixed anhydrides formed by the intermolecular condensation of phosphates and glycin were determined by ESI-MS. Peptides were also produced by the reaction of amino acids with trimetaphosphate in aqueous solution. The conversion degree of valine reached 46.5% even at room temperature. The cyclic process of peptide formation and phosphate polymeri- zation, regeneration and utilization in amino acids-phosphate system under microwave irradiation was detected and proved. Peptides could be continually formed only by inputting energy into this system. The above recycle may be the most possible process for primitive peptide formation in the origin of life.

关键词： microwave, phosphate, amino acid, peptide, origin of life.

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Investigation on Vibrational Spectra and Structures of 4-Mercaptopyridine Monomer and Its Dihydrate

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chemical Research in Chinese Universities 2006年第1期22卷 90-93页

作者： CHENG Jian-bo 1,2., XUE Wei-qing 1 , ZHAO Bing 1** , ZHANG Gang 3 and GONG Bao-an 2.1. Key Laboratory for Supramolecular Structure and Material of Ministry of Education, Jilin university, Changchun 130012. P. R. China 2. Science and engineering {2. of Chemistry and Biology, Yantai university, Yantai 2.4005, P. R. China 3. State Key Laboratory of Theoretical and Computational Chemistry, Jilin university, Changchun 13002., P. R. China Key Laboratory for Supramolecular Structure and Material of Ministry of Education Jiln University Changchun 130012 P. R. China Science and engineering college of Chemistry and Biology Yantai University Yantai 264005 P. R. China State Key Laboratory of Theoretical and Computational Chemistry Jiln University Changchun 130023 P. R. China

The optimized molecular structures and vibrational frequencies of 4-mercaptopyridine(4MPY) monomer and its dihydrate were studied by means of the density functional theory(DFT), viz. B3LYP method with the 6-311++G(d,p) basis set. On the basis of the calculations, the assignments of the vibrational spectra of the monomer and the dihydrate were performed, and so were investigated the changes in the structure and the vibrational spectrum of the dihydrate as well as the intermolecular force resulting in the formation of the dihydrate. The calculated results show that each of the water molecule planes is vertical to the pyridine ring plane in the dihydrate that is formed via the H-bonds between 4MPY and water molecules. Furthermore, the structure and the vibrational spectrum of 4MPY can be consi- derably affected by the water molecules.

关键词： 4MPY Dihydrate Vibrational spectra DFT Molecular structure

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